CN106140780A - One way of life refuse disposal system - Google Patents

One way of life refuse disposal system Download PDF

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Publication number
CN106140780A
CN106140780A CN201510170350.7A CN201510170350A CN106140780A CN 106140780 A CN106140780 A CN 106140780A CN 201510170350 A CN201510170350 A CN 201510170350A CN 106140780 A CN106140780 A CN 106140780A
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anaerobic fermentation
biogas
unit
way
remove impurity
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CN106140780B (en
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樊军
程利文
韩国忠
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Beijing Santai Environmental Technology Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/78Recycling of wood or furniture waste

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  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)

Abstract

One way of life refuse disposal system, by mechanical sorting unit, anaerobic fermentation unit and burning electricity generation unit composition, wherein mechanical sorting unit is by garbage feeding, broken bag, magnetic separation, cylinder sieves, selecting crude drugs with winnower, rotating disk sieves, eddy current separation, broken remove impurity, slurrying remove impurity operation forms, anaerobic fermentation unit is by hydrolysis acidification, anaerobic fermentation, marsh gas purifying, Methane decarbonization, biogas residue is dehydrated, composting, sewage disposal operation forms, the present invention is on the basis of original waste incineration and generating electricity system, use the hands section of mechanical sorting, by content in house refuse more than 50%, the burning electricity generation contribution biomass less than 10% are elected and carries out anaerobic fermentation, it is not only advantageous to burning electricity generation, also obtain extra natural gas energy resource and organic manure resource.

Description

One way of life refuse disposal system
One way of life refuse disposal system, particularly to the organic-biological matter processing system that a kind of and existing most of waste incineration and generating electricity is supporting.
Background technology:
Traditional trash processing way is broadly divided into landfill, burning, compost, anaerobism, a few class of pyrolysis.
The advantage of sanitary landfills processing method is that processing cost is low, and method is simple, but Anti-seeping technology is bad, easily causes the secondary pollution to groundwater resources, more importantly take a large amount of soil.
The advantage of burning disposal is reduced training good (after burning, volume reduces more than 90%, and weight reduces more than 80%).But the construction of incineration plant and operating cost are expensive, the calorific value of rubbish being required height, the dioxin of generation has toxicity, and the common people generally oppose.
Compost treatment is the outlet solving organic-biological matter rubbish, can reach the purpose of resource, but the effect of compost depends on garbage preliminary sorting technological level, and not so life-time service easily causes soil compaction and groundwater quality degenerates.
The advantage of anaerobic fermentation is to obtain the bio-natural gas energy and organic manure resource, technology maturation, is not likely to produce foul smell, environmental friendliness, but high to the pre-processing requirements of house refuse.
Pyrolysis is in an enclosed environment, under high temperature, anaerobic or anaerobic environment, refuse is completely converted into synthesis gas and callable solid residue.Fume emission is greatly decreased, resource efficiency high.But the technology maturity of which and economic benefit are the bottlenecks of its development of restriction.
From the point of view of the Engineering Projects of China's actual application now, the processing mode of overwhelming majority house refuse is based on landfill and burning.Wherein waste incineration and generating electricity development is relatively rapid, and the whole nation has been built up and built nearly 300 of waste incineration and generating electricity project.Garbage incinerating power plant widespread practice be mixed consumer waste is deposited in refuse-unloading hole in 3 to 5 days, make portion of water diafiltration from rubbish out, then house refuse be put into incinerator and burn.
China a distinguishing feature of domestic waste be high (50 ~ 60%) containing tax water rate, organic-biological matter content is high (45 ~ 65%).Although the overall status calorific value of domestic waste is improving constantly, incinerator has progressively been suitable for the characteristic of Municipal Solid Waste in China also by technological improvement, supplementary means.But the organic-biological confrontation consumer waste incineration system in house refuse remains a unfavorable factor.Through the domestic waste on the ground such as Beijing, Shenzhen and Guangzhou, Hangzhou, Xi'an, Chongqing is analyzed, it can be deduced that as drawn a conclusion:
1. in domestic waste, plastics are the main sources of rubbish heat, accounting about 50%;、
2. rubbish from cooking (i.e. organic-biological matter) average content about 54% in domestic waste, but heat contribution is less than 15%;
About above average Lower heat value 5600kJ/kg of Typical Urban rubbish, the generated energy of mixed consumer waste per ton about 310kwh(is in terms of generating efficiency 20%), if the organic-biological matter in 1 ton of mixed consumer waste is peeled off away, the quality of remaining component accounts for the half of the quality of original composting, but heat accounts for more than the 85% of composting heat), (about more than 10000kJ/kg) is increased again due to the calorific value of remaining component, generating efficiency increases, its generated energy is also about 310kwh (improving 3 percentage points with generating efficiency, 23% meter).Rubbish from cooking will sort away and have no effect on burning electricity generation amount.
4. if using mechanical sorting to process, classify at garbage transfer station, then the rubbish being directly entered landfill yard landfill is about about 12%.Need transporting compressed to burning electricity generation factory rubbish quality only have about 30% (this part combustiblerefuse compression precontract of the total volume more than 60%);If carrying out mechanical sorting at garbage incinerating power plant, then the rubbish quality entering incinerator only has about 50%.
5. the rubbish from cooking sorted out in 1 ton of mixed consumer waste can obtain 60m through anaerobic fermentation3Left and right biogas and the fertilizer of about 100kg.
The conventional garbage burning electricity generation factory overwhelming majority is all directly by consumer waste incineration;Minority garbage incinerating power plant carries out simple pretreatment to house refuse, also mainly selects the metal of the inside through magnetic separation, or crushes the requirement of rubbish size by house refuse to meet incinerator.
And existing domestic refuse anaerobic fermentation process mode, although emphasize house refuse through sorting, it is achieved the integrated treatment of house refuse and recycling, but technological process length, system complex, item success rate is low.
Summary of the invention
In order to optimize the deficiency of existing municipal solid wastes incineration power generation system, it is an object of the invention to rely on existing Msw Incineration Power-generating System, by anaerobic fermentation means, while not reducing conventional garbage burning electricity generation economic benefit, it is achieved the resource of the organic-biological matter in house refuse and energy.
The purpose of the present invention is achieved through the following technical solutions: one way of life refuse disposal system, and system includes rubbish machinery separation unit, burning electricity generation unit and anaerobic fermentation unit.House refuse, after mechanical sorting cell processing, is divided into three partial material, and Part I is two kinds of materials of plastics of recoverable material, mainly metal and high-quality;Part II is organic-biological matter, mainly the high-moisture such as melon and fruit, food biomass;Part III is other remaining ingredient, mainly paper, diaper, fabric, bamboo wood, dregs, sandstone and other material.Part I material accounts under 5% ~ 8%(wet basis state of house refuse total amount), directly recycle and reuse, Part II material accounts under 45% ~ 55%(wet basis state of house refuse total amount), pass through mechanical sorting, make abiotic matter component therein (using plastics and sandstone as measuring index) content less than under 5%(wet basis state), subsequently into anaerobic fermentation unit;Part III material accounts under 40% ~ 50%(wet basis state of house refuse total amount), it is sent directly into waste incineration and generating electricity unit.
Wherein said mechanical sorting unit is made up of garbage feeding, broken bag, magnetic separation, cylinder screening, selecting crude drugs with winnower, rotating disk screening, eddy current separation, broken remove impurity, slurrying remove impurity operation;
Wherein said anaerobic fermentation unit is by hydrolysis acidification, anaerobic fermentation, marsh gas purifying, compressed biogas, Methane decarbonization, compression CO2, biogas residue dehydration, composting, sewage disposal operation composition;
Wherein said burning electricity generation unit is existing recirculating fluidized bed or grate furnace burning electricity generation system;
Wherein said rotating disk screening, broken remove impurity, slurrying remove impurity operation are for being linked in sequence, the main plastic bag of bulk, diaper and the fragment of brick etc. removed in biomass of rotating disk screening, material is mainly crushed to below 10mm by broken remove impurity, simultaneously remove inside more than 90% plastics and fabric, slurrying remove impurity mainly by add water will broken after biomass make serosity, remove simultaneously inside more than 80% sandstone and remaining thin plastic sheet and other foreign material.
Wherein said hydrolysis acidification operation is passed through biogas slurry and the steam of burning electricity generation unit generation that a certain amount of anaerobic fermentation produces, the carbon dioxide that Methane decarbonization generates is passed through the bottom of hydrolization and acidification tank simultaneously, hydrolysis acidification serosity is stirred mass transfer, accelerate Hydrolysis Acidification, improve follow-up anaerobic fermentation methane production.Reaction condition is: 24 ~ 48 hours time of staying, reaction temperature 35 ± 1 DEG C, PH3.5 ~ 5, and every cube of serosity is passed through 0.1 ~ 0.2m3 carbon dioxide compression gas.
Wherein said anaerobic fermentation operation use compressed biogas the serosity in anaerobic fermentation tank is carried out pneumatic stirring, biogas pressure is 0.4 ~ 0.6MPa, compressed biogas is by being distributed on the nozzle of anaerobic fermentation pot bottom, it is interrupted injection according to the program set, serosity solid content 8% ~ 15% in anaerobic fermentation tank, 20 ~ 25 days time of staying, reaction temperature 35 ± 1 DEG C, PH6.5 ~ 7.2.
Wherein said marsh gas purifying operation mainly carries out dedusting, desulfurization and dehydration to biogas.
The beneficial effects of the present invention is: house refuse, according to the characteristic variations of China's house refuse, is divided into three class materials by (1) present invention, the maximum resource benefit that domestic rubbish disposal is disposed can be realized;(2) biomass of the high-moisture of the present invention nearly 50% sort out, and make the calorific value of the rubbish of entrance incinerator increase, although the rubbish total amount of burning reduces, but burning electricity generation total amount does not reduce;(3) biomass process bio-natural gas and the fertilizer obtaining cleaning through anaerobic fermentation, not only obtain extra new forms of energy, moreover it is possible to reduce greenhouse gas emission;(4) waste or used plastics of expendable-limited-recoverable metal and high-quality has obtained high-value-use rather than has obtained energy simply by burning;(5) carbon dioxide that Methane decarbonization produces is passed through hydrolysis acidification serosity by the present invention, not only plays stirring action, is also beneficial to shorten hydrolytic acidification time and improve follow-up anaerobic fermentation methane production.
Accompanying drawing explanation
Fig. 1 one way of life refuse disposal system figure, wherein three master units are mechanical sorting unit;Anaerobic fermentation unit;Burning electricity generation unit;Anaerobic fermentation unit is divided into again hydrolysis acidification, anaerobic fermentation, marsh gas purifying, compressed biogas, Methane decarbonization, compression CO2, biogas residue dehydration, composting, sewage disposal.
Fig. 2 house refuse mechanical sorting unit figure, including garbage feeding, broken bag, magnetic separation, cylinder screening, rotating disk screening, selecting crude drugs with winnower, eddy current separation, broken remove impurity, slurrying remove impurity.
Detailed description of the invention
With specific embodiment, the detailed description of the invention of the present invention is further described below in conjunction with the accompanying drawings:
Embodiment 1
The purpose of the present invention is achieved through the following technical solutions: one way of life refuse disposal system, and system includes rubbish machinery separation unit, burning electricity generation unit and anaerobic fermentation unit.
Mechanical sorting unit is made up of garbage feeding, broken bag, magnetic separation, cylinder screening, selecting crude drugs with winnower, rotating disk screening, eddy current separation, broken remove impurity, slurrying remove impurity operation;Anaerobic fermentation unit is made up of hydrolysis acidification, anaerobic fermentation, marsh gas purifying, Methane decarbonization, biogas residue dehydration, composting, sewage disposal operation.
House refuse is after garbage feeding and broken bag, and the house refuse in refuse bag is spread out.Then ferrous metal therein is selected by magnetic separation, after the screening (space of rotary screen is 60mm) of rotary screen, rubbish is sized the siftage of the oversize into more than 60mm and below 60mm, and oversize is divided into the plastics of high-quality, biomass and other material through sorting;Siftage enters other material of bulk inside rotating disk screening removal further, and the material under rotating disk sieve is based on biomass.The biomass that the lower biomass of sieve after rotating disk screening go out with selecting crude drugs with winnower enter eddy current separation after mixing, select copper and the aluminum metalloid of the inside, subsequently into broken remove impurity operation, biomass are fractured into the material of below 10mm, remove the most further inside more than 90% plastics and fabric;Biomass after Po Sui send into slurrying remove impurity operation via spiral, and biomass are made into the serosity that solid content is 10%, in serosity producing process, remove sandstone and the little plastic sheet of slurry surface suspension and the fiber etc. of bottom deposit.
After above-mentioned mechanical sorting cell processing, being divided into three partial material, Part I is two kinds of materials of plastics of recoverable material, mainly metal and high-quality;Part II is organic-biological matter, mainly the high-moisture such as melon and fruit, food biomass;Part III is other remaining ingredient, mainly paper, diaper, fabric, bamboo wood, dregs, sandstone and other material.Part I material accounts under 5% ~ 8%(wet basis state of house refuse total amount), directly recycle and reuse, Part II material accounts under 45% ~ 55%(wet basis state of house refuse total amount), pass through mechanical sorting, make abiotic matter component therein (using plastics and sandstone as measuring index) content less than under 5%(wet basis state), subsequently into anaerobic fermentation unit;Part III material accounts under 40% ~ 50%(wet basis state of house refuse total amount), it is sent directly into waste incineration and generating electricity unit.
Biomass slurry is by being pumped into hydrolysis acidification operation, biogas slurry and the steam of burning electricity generation unit generation that a certain amount of anaerobic fermentation produces it is passed through in Hydrolysis Acidification, the carbon dioxide that Methane decarbonization generates is passed through the bottom of hydrolization and acidification tank simultaneously, hydrolysis acidification serosity is stirred mass transfer, accelerate Hydrolysis Acidification, improve follow-up anaerobic fermentation methane production.Reaction condition is: 36 hours time of staying, reaction temperature 35 ± 1 DEG C, PH3.5 ~ 5, and every cube of serosity is passed through 0.1 ~ 0.2m3 carbon dioxide compression gas.
Serosity through hydrolysis acidification passes through and is pumped in anaerobic fermentation tank, the compressed biogas using pressure to be 0.4 ~ 0.6MPa carries out pneumatic stirring to the serosity in anaerobic fermentation tank, serosity solid content 10 % in anaerobic fermentation tank, 20 days time of staying, reaction temperature 35 ± 1 DEG C, PH6.5 ~ 7.2.
Within the anaerobic fermentation time of 20 days, fresh serosity constantly supplements, and the serosity simultaneously fermented the most constantly is discharged, and the serosity of discharge is after biogas residue is dehydrated, biogas slurry partial reflux to hydrolysis acidification pool, be partially into sewage disposal system, biogas residue then makes fertilizer.
The biogas that anaerobic fermentation produces is after purifying, and part biogas is after compression for the Gas Stirring of anaerobic fermentation.Being partially into Methane decarbonization operation, be purified to bio-natural gas, take off is then passed directly in hydrolysis acidification serosity with CO2 position main component part waste gas.

Claims (7)

1. one way of life refuse disposal system, system includes rubbish machinery separation unit, burning electricity generation unit and anaerobic fermentation unit, wherein said mechanical sorting unit is made up of garbage feeding, broken bag, magnetic separation, cylinder screening, selecting crude drugs with winnower, rotating disk screening, eddy current separation, broken remove impurity, slurrying remove impurity operation, and wherein said anaerobic fermentation unit is by hydrolysis acidification, anaerobic fermentation, marsh gas purifying, compressed biogas, Methane decarbonization, compression CO2, biogas residue dehydration, composting, sewage disposal operation composition, the CO that wherein said Methane decarbonization operation produces2Being passed through hydrolysis acidification operation after compression, the biogas after marsh gas purifying operation is passed through anaerobic fermentation operation after compression.
One way of life refuse disposal system the most according to claim 1, it is characterized in that house refuse is divided into three partial material by described mechanical sorting unit, Part I is recoverable material, mainly metal and two kinds of materials of plastics of high-quality, account under 5% ~ 8%(wet basis state of house refuse total amount);Part II is organic-biological matter, mainly the high-moisture such as melon and fruit, food biomass, accounts for the 45% ~ 55% of house refuse total amount, and abiotic matter component therein (using plastics and sandstone as measuring index) content is less than under 5%(wet basis state);Part III is other remaining ingredient, mainly paper, diaper, fabric, bamboo wood, dregs, sandstone and other material, accounts under 40% ~ 50%(wet basis state of house refuse total amount).
One way of life refuse disposal system the most according to claim 1, it is characterised in that described burning electricity generation unit is recirculating fluidized bed or grate furnace burning electricity generation system.
One way of life refuse disposal system the most according to claim 1, it is characterized in that described rotating disk screening, eddy current separation, broken remove impurity, slurrying remove impurity operation are for being linked in sequence, the main plastic bag of bulk, diaper and the fragment of brick etc. removed in biomass of rotating disk screening, material is mainly crushed to below 10mm by broken remove impurity, simultaneously remove inside more than 90% plastics and fabric, slurrying remove impurity mainly by add water will broken after biomass make serosity, remove simultaneously inside more than 80% sandstone and remaining thin plastic sheet and other foreign material.
One way of life refuse disposal system the most according to claim 1, it is characterized in that described hydrolysis acidification operation is passed through biogas slurry and the steam of burning electricity generation unit generation that a certain amount of anaerobic fermentation produces, the carbon dioxide that Methane decarbonization generates is passed through the bottom of hydrolization and acidification tank simultaneously, hydrolysis acidification serosity is stirred mass transfer, accelerate Hydrolysis Acidification, improve follow-up anaerobic fermentation methane production;Reaction condition is: 24 ~ 48 hours time of staying, reaction temperature 35 ± 1 DEG C, PH3.5 ~ 5, and every cube of serosity is passed through 0.1 ~ 0.2m3Carbon dioxide compression gas.
One way of life refuse disposal system the most according to claim 1, it is characterized in that described anaerobic fermentation operation using compressed biogas the serosity in anaerobic fermentation tank is carried out pneumatic stirring, biogas pressure is 0.4 ~ 0.6MPa, compressed biogas is by being distributed on the nozzle of anaerobic fermentation pot bottom, it is interrupted injection, serosity solid content 8% ~ 15% in anaerobic fermentation tank, 20 ~ 25 days time of staying according to the program set, reaction temperature 35 ± 1 DEG C, PH6.5 ~ 7.2.
One way of life refuse disposal system the most according to claim 1, it is characterised in that described marsh gas purifying operation mainly carries out dedusting, desulfurization and dehydration to biogas.
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Cited By (7)

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CN106906128A (en) * 2017-05-08 2017-06-30 西南交通大学 A kind of diphasic anaerobic fermentation system of application dynamic hydraulic combined stirring
CN107511389A (en) * 2017-07-24 2017-12-26 深圳市海吉星环保有限责任公司 A kind of household waste hydraulic sorting and pulping process and processing system
CN108723067A (en) * 2018-07-12 2018-11-02 武汉都市环保工程技术股份有限公司 A kind of integrated form domestic garbage resource processing system and its processing method
CN109433807A (en) * 2018-12-26 2019-03-08 宁波开诚生态技术有限公司 A kind of food waste processing method
CN110252763A (en) * 2019-05-13 2019-09-20 江苏天楹环保能源成套设备有限公司 A kind of rubbish from cooking dry type anaerobic fermentation system
CN110577418A (en) * 2019-10-14 2019-12-17 武汉农尚环境股份有限公司 in-situ ecological restoration device and method for refuse landfill
CN113134502A (en) * 2020-01-19 2021-07-20 西安佳世洁环保科技有限公司 Harmless treatment method for decomposed materials on removed clean surface

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106906128A (en) * 2017-05-08 2017-06-30 西南交通大学 A kind of diphasic anaerobic fermentation system of application dynamic hydraulic combined stirring
CN107511389A (en) * 2017-07-24 2017-12-26 深圳市海吉星环保有限责任公司 A kind of household waste hydraulic sorting and pulping process and processing system
CN108723067A (en) * 2018-07-12 2018-11-02 武汉都市环保工程技术股份有限公司 A kind of integrated form domestic garbage resource processing system and its processing method
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CN110577418A (en) * 2019-10-14 2019-12-17 武汉农尚环境股份有限公司 in-situ ecological restoration device and method for refuse landfill
CN113134502A (en) * 2020-01-19 2021-07-20 西安佳世洁环保科技有限公司 Harmless treatment method for decomposed materials on removed clean surface

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