CN106135230A - A kind of nematicide disease-resistant composition and application thereof - Google Patents
A kind of nematicide disease-resistant composition and application thereof Download PDFInfo
- Publication number
- CN106135230A CN106135230A CN201510172220.7A CN201510172220A CN106135230A CN 106135230 A CN106135230 A CN 106135230A CN 201510172220 A CN201510172220 A CN 201510172220A CN 106135230 A CN106135230 A CN 106135230A
- Authority
- CN
- China
- Prior art keywords
- lentinan
- nematicide
- disease
- fluorine alkene
- alkene line
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a kind of nematicide disease-resistant composition and application thereof, the active ingredient of said composition is made up of fluorine alkene line sulfone and lentinan, and fluorine alkene line sulfone is 1:80～80:1 with the mass ratio of lentinan.The present composition has significant synergies, it is possible to prevents and treats the nematicide of whole crop growth period, and can improve crop autoimmunity, the soil-borne disease such as virosis and droop is had good prevention effect.
Description
Technical field
The present invention relates to a kind of composition pesticide, relate to a kind of nematicide disease-resistant composition containing fluorine alkene line sulfone
And the application of preventing and treating corps diseases, belong to technical field of pesticide.
Background technology
Plant nematode specifically includes that Meloidogyne, kidney shape Turbatrix, Heterodera, short body line
Eimeria, Aphelenchoides, minute hand Turbatrix, Xiphinema, burr Turbatrix, Bursaphelenchus.Line
Worm the most directly endangers host plant, moreover it is possible to spread germs and virus.Chemical prevention prevents and treats process nematicide
In occupy an important position, but currently used most of nematocides belong to high-toxic pesticide, there is toxicity
Greatly, environmental pollution is serious, preventive effect is not notable, nematicide is easily generated the problems such as Drug resistance.
Viroses of plant proportion in plant disease is only second to fungal disease, produces at present and prevents and treats virus
Sick pharmacy control efficacy is poor, it is difficult to effectively controls the harm of virosis, is badly in need of the new medicament preventing and treating virosis.
Fluorine alkene line sulfone, CAS accession number: 318290-98-1, English name: fluensulfone, trade name:
MCW-2, test code number: BYI1921, MAI-08015, MAI-08016, other titles: Nimitz,
Connection fluorine sulfone, fluorine thiophene worm sulfone, the spirit of fluorine sulfone, be by the fluoro of Makhteshim Chemical Works company exploitation
Olefines nematicide antiviral agents.But the production that fluorine alkene line sulfone is current and use cost are the highest, and for a long time
It is used alone and also has the biggest resistance risk.
Summary of the invention
It is an object of the invention to provide a kind of effect obvious, mixture reasonably prevent and treat Plant nematode, virosis,
The compositions of droop.
Another object of the present invention also resides in offer above-mentioned composition and is preventing and treating Plant nematode, virosis, withering
Application in disease.
Lentinan is the effective active composition extracted from quality xianggu sporophore, is that a kind of host immunity increases
Strong agent, has antiviral, regulation plant immunization function and stimulates the functions such as interferon formation.By passivation disease
Cytotoxic activity, effective break virus gene and virocyte, suppress virus replication.
For reaching goal of the invention, the technical solution used in the present invention is:
A kind of nematicide disease-resistant composition, containing effective ingredient fluorine alkene line sulfone and lentinan, fluorine in compositions
The mass ratio of alkene line sulfone and lentinan is 80:1～1:80, and preferred mass ratio is for 20:1～1:20.
The present composition is particularly suitable for preventing and treating plant nematode, such as Pratylenchidae, similar perforation line
Worm, fuller's teasel Ditylenchus dipsaci, Tylenchulus Semipenetrans, Heterodera kind, ball Heterodera kind, root-knot nematode
Belong to kind, kidney shape Turbatrix kind, Aphelenchoides kind, minute hand Turbatrix kind, sword shape Turbatrix kind, burr line
Eimeria kind, Bursaphelenchus kind.
The described viroses of plant be tobacco mosaic virus disease, Fructus Lycopersici esculenti mosaic virus, squash virus,
Cucurbita maxima mosaic virus, Fructus Piperis virosis, Herba Medicaginis virosis, lily viral diseases, downright bad pinta, cucumber
One or more in leaf disease viral disease, ring spot, rosette.
Preferably be used for the present composition preventing and treating Cereal, Oryza sativa L., Semen Tritici aestivi, fruit tree, Cotton Gossypii, vegetable,
The nematicide of the oil crop such as Semen sojae atricolor and Semen arachidis hypogaeae, flowers etc., such as Semen Tritici aestivi root-knot nematode and Cyst nematode, Citrus root
Tie lines worm, Fructus Cucumidis sativi root-knot nematode, tomato root-knot eelworm, Fructus Capsici root-knot nematode, soybean cyst nematode Heterodera glycines, Semen arachidis hypogaeae
Root-knot nematode etc., the most double viral disease of curing the disease, droop.
Insecticide-applying way can use spraying, pouring root, leaching root, soak seed, gets rid of and execute, spread fertilizer over the fields, ditch spread, spread manuer in holes,
Preventing and treating nematicide and preferred ditch spread during virosis, spread manuer in holes, soil treatment or the leaching root such as pouring root, soak seed, plant attached bag
Clothing processes.
The present composition can have weeding with other, the compound of bactericidal property is used in mixed way, it is also possible to
It is used in mixed way with nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner.
The present composition compared with the existing technology, at least can produce following beneficial effect:
1. in compositions, nematicide, virosis and droop are had substantially after compounding according to the above ratio by two kinds of active components
Potentiation, can respectively with prevent and treat Plant nematode, virosis, droop simultaneously；
2. field dosage can be greatly decreased, reduce and produce and use cost, effectively reduce environmental pollution and agriculture
Medicine remains, and reduces the harm to beneficial organism；
3. can the cover crop of long period from the harm of nematicide, the lasting period is long；
4. regulation plant inner metabolism balance, improves resistance and the yield of crop self.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with embodiment to this
Summary of the invention is described further, but the present invention is limited to absolutely not these examples.Specific embodiment is only used for explaining
The present invention, is not intended to limit the present invention.All made within the spirit and principles in the present invention any amendment,
Equivalent and improvement etc., should be included within the scope of the present invention.Therefore, patent of the present invention
Protection domain should be as the criterion with claims.
The present invention can be prepared as being suitable for the dosage form of agricultural use by known method, and compositions can be according to institute
The various factors such as the crop that need to prevent and treat, local environment condition, prevention and controls, cost accounting, by effective ingredient
Any one dosage form acceptable in pesticides application it is processed into, preferably together with auxiliary agent and carrier (filler)
Dosage form is granule, microcapsule suspending agent, water preparation, suspending agent, aqueous emulsion, wettable powder, water-dispersible grain
Agent, dry suspending agent.Adjuvant used, carrier and process technology use known component.In above-mentioned various dosage forms
In, the gross mass percentage composition of effective ingredient fluorine alkene line sulfone and lentinan is 0.5%～85%, such as, when
When the weight/mass percentage composition of fluorine alkene line sulfone and lentinan is respectively 20% and 3%, gross mass percentage composition is
23%.
One, preparation processing formulation Example
Embodiment 1:10% fluorine alkene line sulfone lentinan suspending agent (fluorine alkene line sulfone: lentinan=1:1)
Make according to common process, wherein fluorine alkene line sulfone 5g, lentinan 5g, sodium lignin sulfonate (dispersion
Agent) 4g, ethylene glycol (antifreeze) 4g, bentonite (thickening agent) 3g, organic silicone (defoamer) 3g,
Deionized water is mended to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 5%～60%, makes the proportioning of used additives make corresponding tune the most therewith
Whole, form new embodiment.
Embodiment 2:30% fluorine alkene line sulfone lentinan water dispersible granules (fluorine alkene line sulfone: lentinan=5:1)
Make according to common process, fluorine alkene line sulfone 25g, lentinan 5g, Negel (dispersant)
5g, sodium lignin sulfonate (dispersant) 7g, sodium lauryl sulphate (wetting agent) 2g, ammonium sulfate (collapses
Solve agent) 5g, precipitated calcium carbonate (filler) complements to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 5%～80%, makes the proportioning of used additives make corresponding tune the most therewith
Whole, form new embodiment.
Embodiment 3:84% fluorine alkene line sulfone lentinan wettable powder (fluorine alkene line sulfone: lentinan=20:1)
Fluorine alkene line sulfone 80g, lentinan 4g, sodium lauryl sulphate (wetting agent) 2g, lignin sulfonic acid
Sodium (dispersant) 3g, NNO (dispersant) 5g, Kaolin complements to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 5%～85%, makes the proportioning of used additives make corresponding tune the most therewith
Whole, form new embodiment.
Embodiment 4:3% fluorine alkene line sulfone lentinan water preparation (fluorine alkene line sulfone: lentinan=1:5)
Make according to common process, fluorine alkene line sulfone 0.5g, lentinan 2.5g, ethylene glycol (antifreezing agent) 5g,
Glycerol (antifreezing agent) 5g, carbamide (stabilizer) 5g, deionized water complements to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 0.5%～60%, makes the proportioning of used additives make the most therewith accordingly
Adjust, form new embodiment.
Embodiment 5:5% fluorine alkene line sulfone lentinan microcapsule suspending agent (fluorine alkene line sulfone: lentinan=1:1)
Fluorine alkene line sulfone 2.5g, lentinan 2.5g, Ketohexamethylene (solvent) 1g, polyisocyanates (firming agent)
0.4g, ethylene glycol (antifreezing agent) 0.4g, arabic gum (thickening agent) 1g, deionized water complements to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 5%～60%, makes the proportioning of used additives make corresponding tune the most therewith
Whole, form new embodiment.
Embodiment 6:10% fluorine alkene line sulfone lentinan aqueous emulsion (fluorine alkene line sulfone: lentinan=1:1)
Fluorine alkene line sulfone 5g, lentinan 5g, calcium dodecyl benzene sulfonate (emulsifying agent) 2.1g, phenethyl phenol
Polyoxyethylene ether (emulsifying agent) 1.5g, Ketohexamethylene (solvent) 10.1g, toluene (solvent) 10.2g, yellow
Virgin rubber (thickening agent) 0.5g, deionized water complements to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 1%～60%, makes the proportioning of used additives make corresponding tune the most therewith
Whole, form new embodiment.
Embodiment 7:10.5% fluorine alkene line sulfone lentinan granule (fluorine alkene line sulfone: lentinan=20:1)
Fluorine alkene line sulfone 10g, lentinan 0.5g, corn starch (dispersing aid) 0.5g, Polyethylene Glycol is (viscous
Knot agent) 0.1g, polyvinyl alcohol (slow releasing agent) 0.1g, Kaolin (filler) complements to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 0.5%～85%, makes the proportioning of used additives make the most therewith accordingly
Adjust, form new embodiment.
Embodiment 8:0.5% fluorine alkene line sulfone lentinan microcapsule suspending agent (fluorine alkene line sulfone: lentinan=1:1)
Fluorine alkene line sulfone 0.25g, lentinan 0.25g, Ketohexamethylene (solvent) 1g, polyisocyanates (solidification
Agent) 0.4g, ethylene glycol (antifreezing agent) 0.4g, arabic gum (thickening agent) 1g, deionized water complements to
100g。
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 0.5%～60%, makes the proportioning of used additives make the most therewith accordingly
Adjust, form new embodiment.
Embodiment 9:4.2% fluorine alkene line sulfone lentinan granule (fluorine alkene line sulfone: lentinan=1:20)
Fluorine alkene line sulfone 0.2g, lentinan 4g, corn starch (dispersing aid) 0.5g, Polyethylene Glycol is (viscous
Knot agent) 0.1g, polyvinyl alcohol (slow releasing agent) 0.1g, Kaolin (filler) complements to 100g.
In the present embodiment, the part by weight of fluorine alkene line sulfone and lentinan can change between 20:1～1:20,
Both weight/mass percentage composition can change between 0.5～85%, makes the proportioning of used additives make the most therewith accordingly
Adjust, form new embodiment.
Two, biological activity determination and test of pesticide effectiveness example
The combination of active principles of different pesticide is made pesticide, is to develop at present and develop novel pesticide and preventing and treating
A kind of effective and quick way that agriculturally resistance evil nematicide is disease-resistant.After the pestsides synthesis of different cultivars, logical
Often show three kinds of type of action: summation action, potentiation and antagonism.But it is specially which kind of effect,
Unpredictable, only just be can determine that by lot of experiments.
Inventor, by substantial amounts of screening test, finds that multiple nematicide is had by fluorine alkene line sulfone with lentinan combination
There is obvious synergistic function.Thus, the embodiment of the present invention also provides for above-mentioned nematicide disease-resistant composition and exists
Preventing and treating Fructus Cucumidis sativi root-knot nematode, the application of tomato root-knot eelworm, and have been surprisingly found that compositions to virosis and is withered
Disease has well prevention and prevention effect, agricultural product quality and yield to be greatly improved.Effect is not only two kinds
The simple addition of medicament, is specifically illustrated with following bioassay example.
One) bioassay example
Fluorine alkene line sulfone joint toxicity measuring to Fructus Cucumidis sativi root-knot nematode compounding with lentinan is tested
For examination object: Fructus Cucumidis sativi root-knot nematode, it is quick that Pesticide Science system of resource environment institute of Agricultural University Of South China provides
Sense population, consistent 2 instar larvaes of picking are used for testing.
Test method: the second instar larvae suspension taking certain volume puts into (diameter 6cm) in culture dish, adds
Equal-volume series concentration reagent agent, makes medicament ultimate density set concentration for test, often processes 4 times and repeat,
With clear water as blank.Cultivate 36h for 25 DEG C, check the active situation of nematicide, calculate each chemicals treatment to line
The relative lethality of worm second instar larvae.
Dead nematicide polypide is the most stiff, bending in arciform or screw type, living nematode mostly bends or twists,
During if it is determined that stiff nematicide is had any problem anyway, nematicide to be identified can be placed in 2% sodium chloride solution,
Observe again after 2min, dead stiff, movable curling or twisting (Fang Zhongda, 1998).
Mode of application judges to use co-toxicity coefficient (CTC) method.The computing formula of co-toxicity coefficient is as follows:
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
Percentage composition+B medicament ATI × the mixture of A in theoretical toxicity index (TTI)=A medicament ATI × mixture
The percentage composition of middle B
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100
When CTC≤80, then compositions shows as antagonism, as 80 ＜ CTC ＜ 120, then and compositions performance
For summation action, when CTC >=120, then compositions shows as potentiation.
Result of the test: after fluorine alkene line sulfone and lentinan are compounding, the joint toxicity measuring to Fructus Cucumidis sativi root-knot nematode is tied
Fruit is shown in Table 1.
Table 1 fluorine alkene line sulfone and the compounding joint toxicity measuring result of the test to Fructus Cucumidis sativi root-knot nematode of lentinan
The result of table 1 co-toxicity test shows, fluorine alkene line sulfone and lentinan compound at 80:1～1:80
Ratio range in the co-toxicity coefficient CTC of Fructus Cucumidis sativi root-knot nematode joint toxicity measuring is all higher than 120, have
Potentiation.Especially in the ratio range of 20:1～1:20, CTC is all higher than 180, potentiation
Significantly.
Two) field medicine effect test example
1, the prevention effect to Fructus Cucumidis sativi root-knot nematode
Test and carry out at Shouguang City of Shandong Province one green house of vegetables in November, 2013, use pouring root (granule
Ditch spread) method, the cucumber growth chosen is basically identical, is in vegetative growth phase, and former years, nematicide occurred
Heavier, and 60d, 90d check that Radix Cucumidis sativi is compromised situation after medicine.From table 2, data can draw, fluorine
After alkene line sulfone is compounding with lentinan, various dosage form potentiations are obvious；60d and 90d after dispenser, each compound medicine
Agent is also significantly better than single dose to the prevention effect of nematicide.
This time test have been surprisingly found that fluorine alkene line sulfone and lentinan after compounding to Cucumber Mosaic Virus, droop
Having good prevention effect, and robust plant, yield and quality increases, and test data is shown in Table 3.
Table 2 fluorine alkene line sulfone field control effect to Fructus Cucumidis sativi root-knot nematode compounding with lentinan
Table 3 fluorine alkene line sulfone is compounding with lentinan to Fructus Cucumidis sativi virus, droop and the result of yield
2, the prevention effect to tomato root-knot eelworm
Test and carry out on farm, Huidong County of Guangdong Province one in April, 2014, by pouring root (granule ditch spread)
Method, the tomato growth chosen is basically identical, is in vegetative growth phase, and former years, nematicide occurred heavier, and
After medicine, 60d, 90d check that tomato root is compromised situation.From table 4, data can draw, fluorine alkene line sulfone with
After lentinan is compounding, various dosage form potentiations are obvious；60d and 90d after dispenser, each compound drug is to Fructus Lycopersici esculenti
The prevention effect of root-knot nematode is also significantly better than single dose.
Can be obtained by data in table 5, after fluorine alkene line sulfone is compounding with lentinan, tomato virus disease also be had well
Prevention and therapeutic effect, plant strain growth is healthy and strong, and yield increases.
Table 4 fluorine alkene line sulfone field control effect to tomato root-knot eelworm compounding with lentinan
Table 5 fluorine alkene line sulfone is compounding with lentinan to tomato virus disease and the result of yield
Compounding to Fructus Cucumidis sativi root-knot nematode from fluorine alkene line sulfone and lentinan, Fructus Cucumidis sativi virosis, droop and yield,
The field efficacy of tomato root-knot eelworm, tomato virus disease and yield is seen, nematicide is not only had very by each compound drug
Good prevention effect, also has a good prevention effect to virosis, droop, and can improve yield and
Tree vigo(u)r, effect be significantly better than single dose, illustrate compound there is potentiation；Lasting period extends, and can reduce use
Dose and spraying times, delay Drug resistance to produce, and can reduce cost accounting simultaneously.
These are only presently preferred embodiments of the present invention, not in order to limit the present invention, all the present invention's
Any amendment, equivalent and the improvement etc. made within spirit and principle, should be included in the guarantor of the present invention
Within the scope of protecting.
Claims (5)
1. a nematicide disease-resistant composition, it is characterised in that: containing effective ingredient fluorine alkene line sulfone in compositions
And lentinan, both mass ratioes are 80:1～1:80.
Nematicide disease-resistant composition the most according to claim 1, it is characterised in that: effective ingredient fluorine alkene
Line sulfone is 20:1～1:20 with the mass ratio of lentinan.
Nematicide disease-resistant composition the most according to claim 1 and 2, it is characterised in that: compositions can
With the dosage form made have granule, microcapsule suspending agent, water preparation, aqueous emulsion, suspending agent, wettable powder,
Water dispersible granules.
Nematicide disease-resistant composition the most according to claim 3, it is characterised in that: in compositions effectively
The gross mass percentage composition of composition is 0.5%～85%.
5. nematicide disease-resistant composition described in claim 1 is used for preventing and treating Plant nematode, virosis, droop
Purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510172220.7A CN106135230B (en) | 2015-04-13 | 2015-04-13 | A kind of nematicidal disease-resistant composition and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510172220.7A CN106135230B (en) | 2015-04-13 | 2015-04-13 | A kind of nematicidal disease-resistant composition and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106135230A true CN106135230A (en) | 2016-11-23 |
| CN106135230B CN106135230B (en) | 2018-05-15 |
Family
ID=57336609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510172220.7A Active CN106135230B (en) | 2015-04-13 | 2015-04-13 | A kind of nematicidal disease-resistant composition and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106135230B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111011382A (en) * | 2020-02-17 | 2020-04-17 | 南京理工大学 | β application of glucan and succinoglycan in preventing and controlling soil-borne fungal diseases |
| CN114885948A (en) * | 2022-06-20 | 2022-08-12 | 广西壮族自治区农业科学院 | Nematicidal composition for preventing and treating taro root knot nematode disease |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1359379A (en) * | 1999-07-06 | 2002-07-17 | 日本拜耳农药株式会社 | Nematicidal trifluorobutenes |
| WO2012096115A1 (en) * | 2011-01-14 | 2012-07-19 | 株式会社エス・ディー・エス バイオテック | Fluorine-containing quinazoline-derived pest-control agent for use in agriculture and horticulture |
-
2015
- 2015-04-13 CN CN201510172220.7A patent/CN106135230B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1359379A (en) * | 1999-07-06 | 2002-07-17 | 日本拜耳农药株式会社 | Nematicidal trifluorobutenes |
| WO2012096115A1 (en) * | 2011-01-14 | 2012-07-19 | 株式会社エス・ディー・エス バイオテック | Fluorine-containing quinazoline-derived pest-control agent for use in agriculture and horticulture |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111011382A (en) * | 2020-02-17 | 2020-04-17 | 南京理工大学 | β application of glucan and succinoglycan in preventing and controlling soil-borne fungal diseases |
| CN111011382B (en) * | 2020-02-17 | 2021-09-03 | 南京理工大学 | Application of beta-glucan and succinoglycan in prevention and control of soil-borne fungal diseases |
| CN114885948A (en) * | 2022-06-20 | 2022-08-12 | 广西壮族自治区农业科学院 | Nematicidal composition for preventing and treating taro root knot nematode disease |
| CN116326585A (en) * | 2022-06-20 | 2023-06-27 | 广西壮族自治区农业科学院 | Nematicide composition for improving prevention and control effect of taro root knot nematode disease |
| CN116326585B (en) * | 2022-06-20 | 2024-05-07 | 广西壮族自治区农业科学院 | Nematicide composition for improving prevention and control effect of taro root knot nematode disease |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106135230B (en) | 2018-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104855392B (en) | A kind of nematicidal composition | |
| CN103814909A (en) | Synergistic pesticidal composition | |
| CN105532681A (en) | Ternary sterilizing and nematode killing composite with synergistic effect | |
| CN104488943A (en) | Insecticidal composition | |
| CN103404530B (en) | Insecticide compound and application and preparation thereof | |
| CN106489956A (en) | Composition pesticide and its application | |
| CN106135230B (en) | A kind of nematicidal disease-resistant composition and its application | |
| CN107494569A (en) | A kind of bactericidal composition is used for the purposes for preventing and treating dragon fruit canker | |
| CN106962353A (en) | A kind of combinations of herbicides containing trichlopyr and its application | |
| CN106135253A (en) | A kind of nematicidal composition | |
| CN108419804A (en) | A kind of bactericidal composition and its application | |
| CN103563910A (en) | Bactericidal composition containing prothioconazole and validamycin and application thereof | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN104542648B (en) | Bactericidal composition and application thereof | |
| CN105145642A (en) | Nematicidal granules containing fosthiazate | |
| CN106172484B (en) | It is a kind of for preventing and treating the granule of carrot root-knot nematode | |
| CN103704258B (en) | A kind of Fungicidal insecticidal composition containing abietic acid ketone | |
| CN108477199A (en) | A kind of bactericidal composition and application thereof | |
| CN103734181B (en) | A kind of Fungicidal insecticidal composition containing cyflufenamid | |
| CN107006489A (en) | A kind of nematicidal composition of fluorine-containing thiophene worm sulfone and recinine | |
| CN106508924A (en) | Nematicide composition containing fluazaindolizine and amino-oligosaccharin | |
| CN106889079A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and alkene oxime amine | |
| CN105941438A (en) | {0><}0{>Sterilization composition containing fluoride ether bacteria amide and thiophal and application of sterilization composition<0} | |
| CN105052959B (en) | The complex composition of osthole and thifluzamide and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190114 Address after: 523820 Daling Village, Dalingshan Town, Dongguan City, Guangdong Province Patentee after: Guangdong Haode Crop Technology Co., Ltd. Address before: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee before: Nuopuxin Agricultural Chemical Co., Ltd., Shenzhen |