CN103814909A - Synergistic pesticidal composition - Google Patents
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- CN103814909A CN103814909A CN201410049027.XA CN201410049027A CN103814909A CN 103814909 A CN103814909 A CN 103814909A CN 201410049027 A CN201410049027 A CN 201410049027A CN 103814909 A CN103814909 A CN 103814909A
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- pymetrozine
- afidopyropen
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
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Abstract
The invention discloses a synergistic pesticidal composition. The synergistic pesticidal composition has the active components of afidopyropen and pymetrozine, wherein the mass ratio of the afidopyropen to the pymetrozine is 1:80 to 80:1. The synergistic pesticidal composition has a significant synergistic effect, has significantly-enhanced pesticidal activity compared with a single agent, and has a very good control effect on planthoppers, leafhoppers, whiteflies, thrips and other pests.
Description
Technical field
The present invention relates to a kind of Synergistic insecticidal compositions that contains two kinds of active components and application thereof.
Background technology
Afidopyropen (test code number ME5343) is a kind of novel pesticide of Japanese Meiji Pharmaceutial Ltd. and the joint research exploitation of Japanese Kitasato Kenkyusho (JP) 9-1, Shirokane 5-chome, Minato-ku, Tokyo 108, Japan.This product is a kind of brand-new structure and has brand-new mechanism of action, can be for vegetables, fruit tree, vine, intertillage crop and ornamental plants etc., and as effective in aphid, plant hopper, scale insect and leafhopper to suction type mouthpart insect.
Pymetrozine, English common name: Pymetrozine, is Triazinone insecticide, has good systemic activity, effective to the homoptera pest such as aphid, plant hopper.Pymetrozine shortcoming is that insect is not had to direct lethal effect, effective slow.
At present have no technology report about afidopyropen with the technical scheme that pymetrozine is used in combination.
Summary of the invention
The object of the present invention is to provide a kind of synergistic effect remarkable, the Pesticidal combination that control efficiency is good and application thereof.
Technical solution of the present invention is:
A kind of Synergistic insecticidal compositions, its active ingredient is afidopyropen and pymetrozine, and the mass ratio of afidopyropen and pymetrozine is 80:1～1:80, and preferred mass is than being 40:1～1:40.
Pesticidal combination of the present invention also can use with other compound with weeding, bactericidal property, or mixes use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Pesticidal combination of the present invention compared with the existing technology, at least can produce following beneficial effect:
1. in composition, two kinds of active components are composite according to the above ratio has notable synergistic effect afterwards to insect, and the insecticidal effect of mixed composition is significantly improved compared with its single dose, plays good insect protected seedling protecting effect;
2. the mechanism of action difference of two kinds of active ingredients in this Pesticidal combination, the application of composition can delay or overcome the pesticide resistance of insect;
3. there is the Pesticidal combination of synergistic effect, can reduce field dosage, effectively reduce environmental pollution and residue of pesticide, reduce the harm to beneficial organism;
4. composition has the advantages that quick-acting is good and lasting effect is long.
Embodiment
For making object of the present invention, technical scheme and technological merit clearer, below in conjunction with embodiment, content of the present invention is described further, but the present invention is limited to absolutely not these examples.Specific embodiment only, for explaining the present invention, is not intended to limit the present invention.All any modifications of making within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Inventor has significant synergies to plant hopper, aphid, aleyrodid, thrips etc. sucking pest after surprisingly finding that by a large amount of biologicall test tests afidopyropen and pymetrozine are composite with aforementioned proportion.On the basis of above-mentioned discovery, through composition is carried out to symphyogenetic quantitative analysis, form the present invention, take afidopyropen as a kind of effective ingredient, take pymetrozine as another active ingredient, two kinds of compositions complement each other, synergy, plays excellent synergistic effect.
The Pesticidal combination of the embodiment of the present invention can according to use crop, environmental condition of living in, prevent and treat the various factors such as method, cost accounting, effective ingredient is processed into together with carrier (filler) to acceptable any one formulation in pesticides application with auxiliary agent, preferred dosage form is granule, microcapsule suspending agent, microemulsion, suspending agent, aqueous emulsion, wetting powder, water dispersible granules or ultra low volume liquids.Adopt known auxiliary agent, carrier and process technology preparation.In formulation products, the gross mass percentage composition of active component afidopyropen and pymetrozine is 0.5%～85%, and for example, in the time that the quality percentage composition of afidopyropen and pymetrozine is respectively 10% and 5%, total content is 15%; In the time that the quality percentage composition of afidopyropen and pymetrozine is respectively 24% and 6%, total content is 30%, shown in the following example of value of concrete gross mass percentage composition.
In order to make object of the present invention, technical scheme and advantage clearer, the present invention further describes by following specific experiment example.If no special instructions, the ratio (comprising percentage) of below mentioning is all mass ratio.
One, preparation processing formulation Example
Embodiment 1:41%afidopyropen pymetrozine suspension agent (afidopyropen: pymetrozine=40:1)
Make wherein afidopyropen40g, pymetrozine 1g according to common process, sodium lignin sulfonate (dispersant) 4g, ethylene glycol (antifreeze) 4g, bentonite (thickener) 3g, organic silicone (defoamer) 3g, deionized water is mended to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 2:60%afidopyropen pymetrozine water dispersing granule (afidopyropen: pymetrozine=1:5)
Make according to common process, afidopyropen10g, pymetrozine 50g, Negel (dispersant) 5g, sodium lignin sulfonate (dispersant) 7g, lauryl sodium sulfate (wetting agent) 2g, ammonium sulfate (disintegrant) 5g, precipitated calcium carbonate (filler) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 3:55%afidopyropen pymetrozine wetting powder (afidopyropen: pymetrozine=10:1)
Afidopyropen50g, pymetrozine 5g, lauryl sodium sulfate (wetting agent) 2g, sodium lignin sulfonate (dispersant) 3g, NNO (dispersant) 5g, kaolin complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 4:12%afidopyropen pymetrozine microemulsion (afidopyropen: pymetrozine=5:1)
Make according to common process, afidopyropen10g, pymetrozine 2g, 1-METHYLPYRROLIDONE (cosolvent) 10g, calcium dodecyl benzene sulfonate (emulsifier) 8g, phenethyl phenol polyethenoxy ether (emulsifier) 7g, triphen ethyl-phenol polyoxyethylene (emulsifier) 5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 5:10%afidopyropen pymetrozine micro-capsule suspension (afidopyropen: pymetrozine=1:1)
Afidopyropen5g, pymetrozine 5g, cyclohexanone (solvent) 1g, polyisocyanates (curing agent) 0.4g, ethylene glycol (solvent) 0.4g, gum Arabic (thickener) 1g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 6:15%afidopyropen pymetrozine aqueous emulsion (afidopyropen: pymetrozine=1:2)
Afidopyropen5g, pymetrozine 10g, calcium dodecyl benzene sulfonate (emulsifier) 2.1g, phenethyl phenol polyethenoxy ether (emulsifier) 1.5g, cyclohexanone (solvent) 10.1g, toluene (solvent) 10.2g, xanthans (thickener) 0.5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 7:8.2%afidopyropen pymetrozine granule (afidopyropen: pymetrozine=40:1)
Afidopyropen8g, pymetrozine 0.2g, dioctyl sodium sulphosuccinate 1g, wood is moulded sodium sulfonate 2g, vinyl alcohol-vinyl alkyl ethers copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 8:12%afidopyropen pymetrozine ultra low volume liquids (afidopyropen: pymetrozine=1:5)
Afidopyropen2g, pymetrozine 10g, 1-METHYLPYRROLIDONE 10g, DMF 15g, n-octyl alcohol 2g, dodecyl sodium sulfonate calcium 2g, OPEO 3g, C10 aromatic hydrocarbons complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Embodiment 9:4.1%afidopyropen pymetrozine granule (afidopyropen: pymetrozine=1:40)
Afidopyropen0.1g, pymetrozine 4g, dioctyl sodium sulphosuccinate 1g, wood is moulded sodium sulfonate 2g, vinyl alcohol-vinyl alkyl ethers copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of afidopyropen and pymetrozine can change between 40:1～1:40, forms new embodiment.
Two, biological activity determination and test of pesticide effectiveness example
The combination of active principles of different agricultural chemicals is made to agricultural chemicals, is effectively and the efficiently mode of one of the upper resistant insect of current development novel pesticide and control agricultural.The agricultural chemicals of different cultivars shows three kinds of type of action: summation action, synergistic effect and antagonism after mixing conventionally.But be specially which kind of effect, unpredictable, only have by lot of experiments and could determine.
Inventor is by a large amount of screening tests, find that afidopyropen and pymetrozine combination have obvious synergistic function to suckings pest such as plant hopper, aphid, thrips, aleyrodids, thus, the embodiment of the present invention also provides the application of above-mentioned Pesticidal combination suckings pest such as control Brown Planthopper, Frankliniella occidentalis, Bemisia tabaci, radish aphids.Control efficiency is not only the simple addition of two kinds of medicaments, is specifically illustrated with following biologicall test example.
One) biologicall test example: afidopyropen and the Pyraphione compound joint toxicity measuring to Brown Planthopper
For examination object: Brown Planthopper (Nilaparvata lugens (Stdl)), use pot rice indoor culture, picking consistent 3 age nymph for test; Bemisia tabaci (Bemisia tabaci Gennadius), uses cucumber seedling indoor culture, picking consistent 3 age nymph for test; Radish aphid (Lipaphis erysimi (Kaltenbach)), picks up from the Natural Population on Turnip Sprouts, selects the one-tenth aphid of uniformity and tests; Frankliniella occidentalis (Frankliniella occidentalis), picks up from capsicum and takes, and indoor snap bean is raised, select consistent 3 age nymph for test.
Test method: Brown Planthopper, with reference to farm-chemical indoor determination test rule insecticidal n Y/T1154.11-2008, adopts rice stem infusion process; Bemisia tabaci and radish aphid, with reference to farm-chemical indoor determination test rule insecticidal n Y/T1154.9-2008, adopt spray-on process; Frankliniella occidentalis, with reference to farm-chemical indoor determination test rule insecticidal n Y/T1154.8-2008, adopts medicine embrane method.
Mode of application is judged co-toxicity coefficient (CTC) method that adopts.The computing formula of co-toxicity coefficient is as follows:
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) × 100
The percentage composition of B in percentage composition+B medicament ATI × mixture of A in theoretical toxicity index (TTI)=A medicament ATI × mixture
Co-toxicity coefficient (CTC)=[the theoretical toxicity index of mixture actual measurement toxicity index (ATI)/mixture (TTI)] × 100
Work as CTC<80, composition performance, for antagonism, is worked as 80<CTC<120, and composition performance, for summation action, is worked as CTC>120, and composition performance is synergistic effect.
After result of the test: afidopyropen and Pyraphione compound, the joint toxicity measuring of Brown Planthopper, Bemisia tabaci, radish aphid, Frankliniella occidentalis be the results are shown in Table to 1-4.
Table 1afidopyropen and pymetrozine different proportion are composite to Brown Planthopper co-toxicity
The result of table 1 co-toxicity test shows, afidopyropen and the Pyraphione compound co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring in the ratio range of 80:1～1:80 is all greater than 120, has synergistic effect.Especially in the ratio range of 40:1～1:40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 2afidopyropen and the composite co-toxicity to Frankliniella occidentalis of pymetrozine different proportion
The result of table 2 co-toxicity test shows, afidopyropen and the Pyraphione compound co-toxicity coefficient CTC to Frankliniella occidentalis joint toxicity measuring in the ratio range of 80:1～1:80 is all greater than 120, has synergistic effect.Especially in the ratio range of 40:1～1:40, CTC is all greater than 180, and synergistic effect is remarkable.
The result of table 3 co-toxicity test shows, afidopyropen and the Pyraphione compound co-toxicity coefficient CTC of the joint toxicity measuring to Bemisia tabaci in the ratio range of 80:1～1:80 is all greater than 120, has synergistic effect.Especially in the ratio range of 40:1～1:40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 4afidopyropen and the composite joint toxicity measuring to radish aphid of pymetrozine different proportion
The result of table 4 co-toxicity test shows, afidopyropen and the Pyraphione compound co-toxicity coefficient CTC of the joint toxicity measuring to radish aphid in the ratio range of 80:1～1:80 is all greater than 120, has synergistic effect.Especially in the ratio range of 40:1～1:40, CTC is all greater than 180, and synergistic effect is remarkable.
Two) field medicine effect test example
1, the control efficiency to Brown Planthopper
Tested in October, 2013 and carry out at Yunfu City one paddy field, test adopts knapsack sprayer (ultra low volume liquids ultra low volume sprayer) to carry out the method for full field even spraying, the paddy rice growth of choosing is basically identical, be in tillering stage, that a situation arises is basically identical for plant hopper, investigation insect population radix before medicine, and 1d, 7d, 15d check the borer population of living after medicine.From table 5, data can draw, after afidopyropen and Pyraphione compound, various formulation synergistic effects are obvious; 1d after dispenser, 7d and 15d, each compound drug to the control efficiency of brown planthopper also significantly better than single dose.
Table 5afidopyropen and the field control effect of Pyraphione compound to Brown Planthopper
2, the control efficiency to capsicum Frankliniella occidentalis
Tested in April, 2013 and carry out in Li Nong food market, Huidong County of Guangdong Province, test adopts knapsack sprayer (ultra low volume liquids ultra low volume sprayer) to carry out the method for even spraying, the experimental field capsicum of choosing is in the Sheng phase of yielding positive results, plant strain growth is basically identical, Frankliniella occidentalis occurs heavier, and it is basically identical to distribute, investigation insect population radix before medicine, and 1d, 3d, 7d check the borer population of living after medicine.From table 6, data can draw, after afidopyropen and Pyraphione compound, various formulation synergistic effects are obvious; 1d after dispenser, 3d and 7d, each compound drug to the control efficiency of Frankliniella occidentalis also significantly better than single dose.
Table 6afidopyropen and the field control effect of Pyraphione compound to capsicum Frankliniella occidentalis
3, the control efficiency to radish aphid
Tested in November, 2013 and carry out in Yu Lv food market, Baoan district of Shenzhen city, test adopts knapsack sprayer (ultra low volume liquids ultra low volume sprayer) to carry out the method for even spraying, the experimental field radish of choosing is in growing mid-term, grow basically identical, radish aphid occurs heavier, and it is basically identical to distribute, investigation insect population radix before medicine, and 1d, 3d, 7d and 15d check the borer population of living after medicine.From table 7, data can draw, after afidopyropen and Pyraphione compound, various formulation synergistic effects are obvious; 1d after dispenser, 3d, 7d and 15d, each compound drug to the control efficiency of radish aphid also significantly better than single dose.
Table 7afidopyropen and the field control effect of Pyraphione compound to radish aphid
4, the control efficiency to cucumber Bemisia tabaci
Tested in April, 2013 and carry out in Li Nong food market, Huidong County of Guangdong Province, test adopts knapsack sprayer (ultra low volume liquids ultra low volume sprayer) to carry out the method for even spraying, the experimental field cucumber of choosing is in the growth later stage, grow basically identical, Bemisia tabaci occurs heavier, and it is basically identical to distribute, investigation insect population radix before medicine, and 1d, 3d, 7d check the borer population of living after medicine.From table 8, data can draw, after afidopyropen and Pyraphione compound, various formulation synergistic effects are obvious; 1d after dispenser, 3d and 7d, each compound drug to the control efficiency of Bemisia tabaci also significantly better than single dose.
Table 8afidopyropen and the field control effect of Pyraphione compound to Bemisia tabaci
Field efficacy to Brown Planthopper, capsicum Frankliniella occidentalis, radish aphid and cucumber Bemisia tabaci from afidopyropen and Pyraphione compound, each compound drug control efficiency is significantly better than single dose, illustrates that this compositely has a synergistic effect; Lasting period extends, and can reduce dosage and spraying times, delays pest resistance to insecticide and produces, and can reduce cost accounting simultaneously.
These are only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (7)
1. a Synergistic insecticidal compositions, the active ingredient that it is characterized in that said composition is afidopyropen and pymetrozine, the mass ratio of afidopyropen and pymetrozine is 80:1～1:80.
2. Pesticidal combination according to claim 1, is characterized in that, described afidopyropen and pymetrozine mass ratio be 40:1～1:40.
3. Pesticidal combination according to claim 1 and 2, is characterized in that the active ingredient of said composition and auxiliary composition are mixed with the preparation that is applicable to agricultural use.
4. Pesticidal combination according to claim 3, is characterized in that, the preparation of described applicable agricultural use is granule, microcapsule suspending agent, microemulsion, aqueous emulsion, suspending agent, wetting powder, water dispersible granules, ultra low volume liquids.
5. Pesticidal combination according to claim 4, is characterized in that, described afidopyropen and the pymetrozine gross mass percentage composition in each formulation is 0.5%～85%.
Described in claim 1 to 5 Pesticidal combination for preventing and treating the application of paddy rice, fruit tree, vegetable crop sucking pest.
7. the application of Pesticidal combination according to claim 6, is characterized in that, described sucking pest is plant hopper, leafhopper, aphid, aleyrodid, thrips.
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| CN201410049027.XA CN103814909A (en) | 2014-02-11 | 2014-02-11 | Synergistic pesticidal composition |
| PCT/CN2014/080774 WO2015120684A1 (en) | 2014-02-11 | 2014-06-25 | Synergistic pesticidal composition and uses thereof |
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| CN201410049027.XA CN103814909A (en) | 2014-02-11 | 2014-02-11 | Synergistic pesticidal composition |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015120684A1 (en) * | 2014-02-11 | 2015-08-20 | 深圳诺普信农化股份有限公司 | Synergistic pesticidal composition and uses thereof |
| WO2016038067A1 (en) * | 2014-09-10 | 2016-03-17 | Basf Se | Use of afidopyropene in genetically modified plants |
| CN106106500A (en) * | 2016-06-24 | 2016-11-16 | 江苏省绿盾植保农药实验有限公司 | A kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application |
| WO2016181339A1 (en) * | 2015-05-13 | 2016-11-17 | Basf Se | Molluscicide and bait composition comprising a molluscicide |
| CN109221191A (en) * | 2018-10-11 | 2019-01-18 | 泰安市农业科学研究院 | Pesticidal combination and its application containing double third ring worm esters and pymetrozine |
| CN110214786A (en) * | 2019-06-28 | 2019-09-10 | 广西壮族自治区农业科学院 | A kind of ultra low volume liquids containing double third ring worm esters and rosin acid sodium |
| CN111357758A (en) * | 2018-12-26 | 2020-07-03 | 燕化永乐（乐亭）生物科技有限公司 | Compound insecticide |
| CN115281203A (en) * | 2022-07-15 | 2022-11-04 | 新疆天禾嘉信农业科技有限公司 | Quick-acting pesticide for preventing and controlling cotton aphids and application thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015120684A1 (en) * | 2014-02-11 | 2015-08-20 | 深圳诺普信农化股份有限公司 | Synergistic pesticidal composition and uses thereof |
| WO2016038067A1 (en) * | 2014-09-10 | 2016-03-17 | Basf Se | Use of afidopyropene in genetically modified plants |
| WO2016181339A1 (en) * | 2015-05-13 | 2016-11-17 | Basf Se | Molluscicide and bait composition comprising a molluscicide |
| CN106106500A (en) * | 2016-06-24 | 2016-11-16 | 江苏省绿盾植保农药实验有限公司 | A kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application |
| CN109221191A (en) * | 2018-10-11 | 2019-01-18 | 泰安市农业科学研究院 | Pesticidal combination and its application containing double third ring worm esters and pymetrozine |
| CN111357758A (en) * | 2018-12-26 | 2020-07-03 | 燕化永乐（乐亭）生物科技有限公司 | Compound insecticide |
| CN110214786A (en) * | 2019-06-28 | 2019-09-10 | 广西壮族自治区农业科学院 | A kind of ultra low volume liquids containing double third ring worm esters and rosin acid sodium |
| CN110214786B (en) * | 2019-06-28 | 2021-11-30 | 广西壮族自治区农业科学院 | Ultralow-volume liquid containing dicyclopropyl succinate and sodium rosinate |
| CN115281203A (en) * | 2022-07-15 | 2022-11-04 | 新疆天禾嘉信农业科技有限公司 | Quick-acting pesticide for preventing and controlling cotton aphids and application thereof |
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| Publication number | Publication date |
|---|---|
| WO2015120684A1 (en) | 2015-08-20 |
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Application publication date: 20140528 |