CN105454241A - Insecticidal composition - Google Patents
Insecticidal composition Download PDFInfo
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- CN105454241A CN105454241A CN201410433229.4A CN201410433229A CN105454241A CN 105454241 A CN105454241 A CN 105454241A CN 201410433229 A CN201410433229 A CN 201410433229A CN 105454241 A CN105454241 A CN 105454241A
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- cyclaniliprole
- composition
- nitenpyram
- pesticidal combination
- cycolxylidin
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Abstract
The invention discloses an insecticidal composition. The insecticidal composition comprises two active components, i.e., an active component A and an active component B, wherein the active component A is cyclaniliprole, the active component B is one selected from the group consisting of nitenpyram, IPP, cycloxaprid and cycolxylidin, and a mass ratio of the active component A and the active component B is 1: 80 to 80: 1. Through blending of the two active components, the insecticidal composition has substantial synergistic effect, has obviously improved insecticidal activity compared with individually used cyclaniliprole or nitenpyram, can reduce the usage amount of the active components, delays generation of resistance of insects and pest mites to the novel drug cyclaniliprole, and exerts good prevention and treatment effects on a plurality of insects like whiteflies, plant hoppers and thrips.
Description
Technical field
The invention belongs to agricultural insecticide field, relate to Pesticidal combination and application thereof that a class contains cyclaniliprole particularly.
Background technology
Cyclaniliprole (test code number IKI-3106) is the bisamide insecticides of Japanese Ishihara Sangyo Kaisha, Ltd. development.There is the insecticidal activity of wide spectrum, to diamond-back moth, prodenia litura, aleyrodid, aphid, thrips, housefly, liriomyza bryoniae, termite etc., there is good control efficiency, and there is good systemic activity, although structurally possess the biamide structure of ryanodine receptor inhibitor, there is different mechanism of action.
Nitenpyram, english common name is nitenpyram, is another novel product that Japan develops after Imidacloprid, Acetamiprid.Quick-acting is good, has that remarkable interior absorption, osmosis, insecticidal spectrum are wide, safety is without poisoning.Good effect is had to various pests such as sucking mouth partss, can be widely used in paddy rice, wheat, cotton, fruit tree prevent and treat various rice fulgorid, aphid, thrips, trialeurodes vaporariorum, Bemisia tabaci, leafhopper, thrips, stinkbug silk worms etc., insect conventional pesticides having been produced to resistance has good control efficiency.
The pyridine of piperazine worm, chemical formula is C
17h
23clN
4o
3, be new and effective, wide spectrum, the low toxicity nicotinic insecticide of the exploitation of Jiangsu Ke Sheng group, be mainly used in preventing and treating homoptera pest, have good control efficiency to insects such as rice fulgorid, leafhopper, aphids.
Cycloxaprid is a kind of high activity, the hypotoxic nicotinic insecticide of East China University of Science's research invention.Efficient to homoptera pest, to lepidoptera pest, also there is double anti-effect, have good control efficiency to Brown Planthopper and Bemisia tabaci, may be used for the control of the insects such as cabbage aphid, diamond-back moth, rice leaf roller in addition.
Cycolxylidin chemical molecular formula is C
6h
10n
4o
3, see Chinese patent CN101503406, have the insecticidal spectrum the same with Imidacloprid and insecticidal effect, its lasting effect is higher than Imidacloprid, and toxicity is lower, has interior suction, tags and stomach poison function.
Summary of the invention
The object of the present invention is to provide a kind of synergistic effect remarkable, the Pesticidal combination that control efficiency is good and application thereof.
For reaching goal of the invention, the technical solution used in the present invention is:
A kind of containing cyclaniliprole and B composition composition, the active ingredient of said composition is made up of cyclaniliprole and B composition, and described B composition is the one in Nitenpyram, the pyridine of piperazine worm, cycloxaprid, cycolxylidin; The mass ratio of cyclaniliprole and B composition is 80:1 ~ 1:80, and preferred mass is than being 20:1 ~ 1:40.
Pesticidal combination of the present invention also can have weeding with other, the compound of bactericidal property uses, also can be used in combination with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Pesticidal combination of the present invention compared with the existing technology, at least can produce following beneficial effect:
1. in composition, two kinds of active components are composite according to the above ratio has notable synergistic effect afterwards to insect, and the insecticidal effect of mixed composition comparatively its single dose is significantly improved, and plays good insect protected seedling protecting effect;
2. in this Pesticidal combination, the mechanism of action of two kinds of active components is different, and the application of composition can delay or overcome the pesticide resistance of insect;
3. there is the Pesticidal combination of synergistic effect, field dosage can be reduced, effectively reduce environmental pollution and residue of pesticide, reduce the harm to beneficial organism;
4. composition has the advantages that quick-acting is good and lasting effect is long.
Embodiment
For making object of the present invention, technical scheme and technological merit clearly understand, below in conjunction with embodiment, content of the present invention is described further, but the present invention is limited to absolutely not these examples.Specific embodiment only for explaining the present invention, is not intended to limit the present invention.All any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
The embodiment of the present invention provides a kind of composition pesticide containing cyclaniliprole and B composition, the active ingredient of said composition is made up of cyclaniliprole and B composition insecticide, and described B composition insecticide is the one in Nitenpyram, the pyridine of piperazine worm, cycloxaprid, cycolxylidin; The mass ratio of cyclaniliprole and B composition insecticide is 80:1 ~ 1:80, and preferred mass is than being 20:1 ~ 1:40.
Inventor, by the screening of a large amount of bioassay test, after unexpected discovery cyclaniliprole and B composition insecticide is composite with aforementioned proportion, has significant synergies to various pests such as plant hopper, aleyrodid, thrips.On the basis of above-mentioned discovery, through carrying out symphyogenetic quantitative analysis to composition, define the present invention, namely with cyclaniliprole for a kind of active ingredient, be another active component with B composition insecticide, two kinds of compositions complement each other, synergy, plays excellent synergistic effect.
The Pesticidal combination of the embodiment of the present invention can according to various factorss such as the crop of required control, residing environmental condition, prevention and controls, cost accountings, active component is processed into any one formulation acceptable in pesticides application with auxiliary agent together with carrier (filler), and preferred dosage form is granule, microcapsule suspending agent, microemulsion, suspending agent, aqueous emulsion, wetting powder, water dispersible granules or ultra low volume liquids.Adjuvant used, carrier and process technology adopt known component.In above-mentioned various formulation, the gross mass percentage composition of cyclaniliprole and B composition insecticide is 0.5% ~ 85%, and such as, when the mass percentage of cyclaniliprole and Nitenpyram is respectively 20% and 3%, total content is 23%; When the mass percentage of cyclaniliprole and the pyridine of piperazine worm is respectively 15% and 5%, total content is 20%, shown in the following example of value of concrete gross mass percentage composition.
In order to make object of the present invention, technical scheme and advantage clearly understand, the present invention is described by following specific experiment example further.If no special instructions, the ratio (comprising percentage) below mentioned is all mass ratio.
One, preparation processing formulation Example
Embodiment 1:40%cyclaniliprole piperazine worm pyridine suspending agent (cyclaniliprole: piperazine worm pyridine=1:1)
Conveniently technique is made, wherein cyclaniliprole20g, piperazine worm pyridine 20g, sodium lignin sulfonate (dispersant) 4g, ethylene glycol (antifreeze) 4g, bentonite (thickener) 3g, organic silicone (defoamer) 3g, deionized water is mended to 100g.
In the present embodiment, the part by weight of cyclaniliprole and the pyridine of piperazine worm can change between 20:1 ~ 1:40, and both weight percentages can change between 5 ~ 60%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
The pyridine of piperazine worm can also be replaced to Nitenpyram, cycloxaprid, cycolxylidin form new embodiment.
Embodiment 2:60%cyclaniliprole Nitenpyram water dispersible granules (cyclaniliprole: Nitenpyram=1:5)
Conveniently technique is made, cyclaniliprole10g, Nitenpyram 50g, Negel (dispersant) 5g, sodium lignin sulfonate (dispersant) 7g, lauryl sodium sulfate (wetting agent) 2g, ammonium sulfate (disintegrant) 5g, precipitated calcium carbonate (filler) complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and Nitenpyram can change between 20:1 ~ 1:40, and both weight percentages can change between 5 ~ 80%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Nitenpyram can also be replaced to the pyridine of piperazine worm, cycloxaprid, cycolxylidin form new embodiment.
Embodiment 3:55%cyclaniliprole cycloxaprid wettable powder (cyclaniliprole: cycloxaprid=10:1)
Cyclaniliprole50g, cycloxaprid 5g, lauryl sodium sulfate (wetting agent) 2g, sodium lignin sulfonate (dispersant) 3g, NNO (dispersant) 5g, kaolin complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and cycloxaprid can change between 20:1 ~ 1:40, and both weight percentages can change between 5 ~ 85%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Cycloxaprid can also be replaced to Nitenpyram, the pyridine of piperazine worm, cycolxylidin form new embodiment.
Embodiment 4:12%cyclaniliprole cycolxylidin microemulsion (cyclaniliprole: cycolxylidin=1:5)
Conveniently technique is made, cyclaniliprole2g, cycolxylidin 10g, 1-METHYLPYRROLIDONE (cosolvent) 10g, calcium dodecyl benzene sulfonate (emulsifier) 8g, phenethyl phenol polyethenoxy ether (emulsifier) 7g, triphenoethyl benzene phenol polyethenoxy (emulsifier) 5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and cycolxylidin can change between 20:1 ~ 1:40, and both weight percentages can change between 5 ~ 60%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Cycolxylidin can also be replaced to Nitenpyram, the pyridine of piperazine worm, cycolxylidin form new embodiment.
Embodiment 5:10%cyclaniliprole piperazine worm pyridine micro-capsule suspension (cyclaniliprole: piperazine worm pyridine=1:1)
Cyclaniliprole5g, piperazine worm pyridine 5g, cyclohexanone (solvent) 1g, polyisocyanates (curing agent) 0.4g, ethylene glycol (solvent) 0.4g, gum Arabic (thickener) 1g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and the pyridine of piperazine worm can change between 20:1 ~ 1:40, and both weight percentages can change between 5 ~ 60%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
The pyridine of piperazine worm can also be replaced to Nitenpyram, cycloxaprid, cycolxylidin form new embodiment.
Embodiment 6:15%cyclaniliprole Nitenpyram aqueous emulsion (cyclaniliprole: Nitenpyram=1:2)
Cyclaniliprole5g, Nitenpyram 10g, calcium dodecyl benzene sulfonate (emulsifier) 2.1g, phenethyl phenol polyethenoxy ether (emulsifier) 1.5g, cyclohexanone (solvent) 10.1g, toluene (solvent) 10.2g, xanthans (thickener) 0.5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and Nitenpyram can change between 20:1 ~ 1:40, and both weight percentages can change between 5 ~ 60%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Nitenpyram can also be replaced to the pyridine of piperazine worm, cycloxaprid, cycolxylidin form new embodiment.
Embodiment 7:10.5%cyclaniliprole Nitenpyram granule (cyclaniliprole: Nitenpyram=20:1)
Cyclaniliprole10g, Nitenpyram 0.5g, dioctyl sodium sulphosuccinate 1g, sodium sulfonate 2g moulded by wood, and polyvinyl alcohol-co-vinyl base alkyl ether copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and Nitenpyram can change between 20:1 ~ 1:40, both weight percentages can change between 0.5 ~ 85%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Nitenpyram can also be replaced to the pyridine of piperazine worm, cycloxaprid, cycolxylidin form new embodiment.
Embodiment 8:12%cyclaniliprole cycolxylidin ultra low volume liquids (cyclaniliprole: cycolxylidin=1:5)
Cyclaniliprole2g, cycolxylidin 10g, 1-METHYLPYRROLIDONE 10g, DMF 15g, n-octyl alcohol 2g, dodecyl sodium sulfonate calcium 2g, OPEO 3g, C10 aromatic hydrocarbons complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and cycolxylidin can change between 20:1 ~ 1:40, and both weight percentages can change between 5 ~ 60%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Cycolxylidin can also be replaced to Nitenpyram, the pyridine of piperazine worm, cycloxaprid form new embodiment.
Embodiment 9:4.1%cyclaniliprole piperazine worm pyridine granule (cyclaniliprole: piperazine worm pyridine=1:40)
Cyclaniliprole0.1g, piperazine worm pyridine 4g, dioctyl sodium sulphosuccinate 1g, sodium sulfonate 2g moulded by wood, and polyvinyl alcohol-co-vinyl base alkyl ether copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of cyclaniliprole and the pyridine of piperazine worm can change between 20:1 ~ 1:40, and both weight percentages can change between 0.5 ~ 85%, the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
The pyridine of piperazine worm can also be replaced to Nitenpyram, cycloxaprid, cycolxylidin form new embodiment.
Two, biological activity determination and test of pesticide effectiveness example
The active ingredient combinations of different agricultural chemicals is made agricultural chemicals, is current development novel pesticide and the one of preventing and treating agriculturally resistant insect effectively and efficiently mode.After the pestsides synthesis of different cultivars, usually show three kinds of type of action: summation action, synergistic effect and antagonism.But be specially which kind of effect, unpredictable, only have and could be determined by lot of experiments.
Inventor is by a large amount of screening tests, find that cyclaniliprole and B composition insecticide composition has obvious synergistic function to various pests such as plant hopper, aleyrodid, thrips, thus, the embodiment of the present invention also provides above-mentioned Pesticidal combination in the application of water prevention brown plant-hopper, fresh kidney beans thrips.Control efficiency is not only the simple addition of two kinds of medicaments, is specifically illustrated with following biologicall test example.
One) biologicall test example: cyclaniliprole and B composition pesticide compositional is to the joint toxicity measuring of Brown Planthopper
For examination object: Brown Planthopper (Nilaparvatalugens (Stdl)), the sensitive population that Pesticide Science system of resource environment institute of Agricultural University Of South China provides, uses pot rice indoor culture, picking consistent 3 age nymph be used for test.
Test method: with reference to farm-chemical indoor determination test rule insecticidal n Y/T1154.11-2008, adopt rice-stem dipping method.
Mode of application judges to adopt co-toxicity coefficient (CTC) method.The computing formula of co-toxicity coefficient is as follows:
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100
In theoretical toxicity index (TTI)=A medicament ATI × mixture A percentage composition+B medicament ATI × mixture in the percentage composition of B
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100
When CTC≤80, then composition shows as antagonism, and as 80 < CTC < 120, then composition shows as summation action, and when CTC >=120, then composition shows as synergistic effect.
Result of the test: cyclaniliprole and Nitenpyram, cyclaniliprole and the pyridine of piperazine worm, cyclaniliprole and cycloxaprid, cyclaniliprole and cycolxylidin, the composite rear joint toxicity measuring to Brown Planthopper the results are shown in Table 1-4 respectively.
Table 1cyclaniliprole and Nitenpyram different proportion composite to Brown Planthopper joint toxicity measuring
The result of table 1 co-toxicity test shows, cyclaniliprole and Nitenpyram is composite is all greater than 120 to the co-toxicity coefficient CTC of Brown Planthopper joint toxicity measuring in the ratio range of 80:1 ~ 1:80, has synergistic effect.Especially in the ratio range of 20:1 ~ 1:40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 2cyclaniliprole and piperazine worm pyridine different proportion composite to Brown Planthopper joint toxicity measuring
The result of table 2 co-toxicity test shows, cyclaniliprole and the pyridine of piperazine worm is composite is all greater than 120 to the co-toxicity coefficient CTC of Brown Planthopper joint toxicity measuring in the ratio range of 80:1 ~ 1:80, has synergistic effect.Especially in the ratio range of 20:1 ~ 1:40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 3cyclaniliprole and cycloxaprid different proportion composite to Brown Planthopper joint toxicity measuring
The result of table 3 co-toxicity test shows, cyclaniliprole and cycloxaprid is composite is all greater than 120 to the co-toxicity coefficient CTC of Brown Planthopper joint toxicity measuring in the ratio range of 80:1 ~ 1:80, has synergistic effect.Especially in the ratio range of 20:1 ~ 1:40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 4cyclaniliprole and cycolxylidin different proportion composite to Brown Planthopper joint toxicity measuring
The result of table 4 co-toxicity test shows, cyclaniliprole and cycolxylidin is composite is all greater than 120 to the co-toxicity coefficient CTC of Brown Planthopper joint toxicity measuring in the ratio range of 80:1 ~ 1:80, has synergistic effect.Especially in the ratio range of 20:1 ~ 1:40, CTC is all greater than 180, and synergistic effect is remarkable.
Two) field medicine effect test example
1, to the control efficiency of Brown Planthopper
Test and carry out at Zhaoqing City of Guangdong Province one paddy field in June, 2014, test adopts knapsack sprayer to carry out the method for full field even spraying, the paddy rice growth chosen is basically identical, be in tillering stage, that a situation arises is basically identical for plant hopper, investigation insect population radix before medicine, and 1d, 7d, 15d check borer population of living after medicine.From table 5, data can draw, after cyclaniliprole and B composition agriculture chemical compounding, various formulation synergistic effect is obvious; 1d, 7d and 15d after dispenser, each compound drug to the control efficiency of brown planthopper also significantly better than single dose.
Table 5cyclaniliprole and B composition agriculture chemical compounding is to the field control effect of Brown Planthopper
2, to the control efficiency of fresh kidney beans thrips
Test and carry out in food market, Sanya, Hainan Province one in March, 2014, test adopts knapsack sprayer to carry out the method for full field even spraying, the experimental field fresh kidney beans chosen are in the Sheng phase of yielding positive results, plant strain growth is basically identical, thrips occurs heavier, and it is basically identical to distribute, investigation insect population radix before medicine, and 1d, 3d, 7d check borer population of living after medicine.From table 12, data can draw, after cyclaniliprole and B composition agriculture chemical compounding, various formulation synergistic effect is obvious; 1d, 3d and 7d after dispenser, each compound drug to the control efficiency of fresh kidney beans thrips also significantly better than single dose.
Table 12cyclaniliprole and B composition agriculture chemical compounding is to the field control effect of fresh kidney beans thrips
| Medicament | Using dosage (g or | 1d preventive effect % | 3d preventive effect % | 7d preventive effect % |
| mL/667m 2) | ||||
| 20%cyclaniliprole suspending agent | 10mL | 64.35 | 73.68 | 70.25 |
| 10% Nitenpyram soluble concentrate | 30mL | 73.54 | 62.34 | 54.38 |
| 10% piperazine worm pyridine suspending agent | 40mL | 65.38 | 70.25 | 60.25 |
| 25% cycloxaprid wettable powder | 30g | 65.34 | 70.25 | 57.68 |
| 10% cycolxylidin wetting powder | 40g | 63.82 | 69.38 | 58.34 |
| Embodiment 1 | 15mL | 78.39 | 93.65 | 75.84 |
| Embodiment 2 | 10g | 80.62 | 98.36 | 82.84 |
| Embodiment 3 | 10g | 78.96 | 97.31 | 76.28 |
| Embodiment 4 | 15mL | 76.34 | 93.68 | 75.87 |
| Embodiment 5 | 15mL | 70.12 | 89.69 | 78.64 |
| Embodiment 6 | 15mL | 76.38 | 95.26 | 74.85 |
| Embodiment 7 | 15g | 72.35 | 93.62 | 79.84 |
| Embodiment 8 | 60mL | 82.14 | 99.35 | 82.68 |
| Embodiment 9 | 15g | 73.54 | 89.18 | 75.38 |
| CK | Clear water | / | / | / |
From the field efficacy of cyclaniliprole and B composition pesticide compositional to Brown Planthopper, fresh kidney beans thrips, each compound drug control efficiency, significantly better than single dose, illustrates compositely have synergistic effect; Lasting period extends, and can reduce dosage and spraying times, delays pest resistance to insecticide and produces, can reduce cost accounting simultaneously.
These are only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. a Pesticidal combination, it is characterized in that the active ingredient of said composition is made up of A and B, the A composition one that to be cyclaniliprole, B composition be in Nitenpyram, the pyridine of piperazine worm, cycloxaprid, cycolxylidin, it is 1:80 ~ 80:1 that described two kinds of active ingredient A and B form mass ratio.
2. Pesticidal combination according to claim 1, is characterized in that, the mass ratio of described cyclaniliprole and B composition is 20:1 ~ 1:40.
3. Pesticidal combination according to claim 1 and 2, is characterized in that, the formulation of described Pesticidal combination is granule, microcapsule suspending agent, microemulsion, aqueous emulsion, suspending agent, wetting powder, water dispersible granules, ultra low volume liquids.
4. Pesticidal combination according to claim 3, is characterized in that, the gross mass percentage composition of described cyclaniliprole and B composition in each preparation is 0.5% ~ 85%.
5. Pesticidal combination described in Claims 1-4 is for preventing and treating the various pests such as plant hopper, aleyrodid, thrips on the crops such as paddy rice, fruit tree, vegetables.
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|---|---|---|---|---|
| CN103518767A (en) * | 2006-12-14 | 2014-01-22 | 石原产业株式会社 | Pesticidal compositions |
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|---|---|---|---|---|
| CN103518767A (en) * | 2006-12-14 | 2014-01-22 | 石原产业株式会社 | Pesticidal compositions |
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| CN106386840A (en) * | 2016-09-13 | 2017-02-15 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing cyclaniliprole |
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