CN103814939A - Insecticidal composition - Google Patents
Insecticidal composition Download PDFInfo
- Publication number
- CN103814939A CN103814939A CN201410064054.4A CN201410064054A CN103814939A CN 103814939 A CN103814939 A CN 103814939A CN 201410064054 A CN201410064054 A CN 201410064054A CN 103814939 A CN103814939 A CN 103814939A
- Authority
- CN
- China
- Prior art keywords
- flometoquin
- pesticidal combination
- clothianidin
- diacloden
- nitenpyram
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
Abstract
The invention discloses an insecticidal composition, active components of which are composed of flometoquin and a neonicotinoid insecticide. The neonicotinoid insecticide is any one of imidacloprid, acetamiprid, thiamethoxam, thiacloprid, nitenpyram, clothianidin, dinotefuran, C17H23CIN4O3, cycloxaprid or cycolxylidin. The mass ratio of flometoquin to the neonicotinoid insecticide is 1:80-80:1. The insecticidal composition provided by the invention has remarkable synergism. Insecticidal activity of the insecticidal composition is obviously enhanced in comparison with that of a single dose. The insecticidal composition has good control efficiency for controlling various kinds of insects such as plant hopper, thrips and the like.
Description
Technical field
The invention belongs to agricultural insecticide field, relate to particularly Pesticidal combination and application thereof that a class contains flometoquin.
Background technology
Flometoquin (test code number ANM-138) is the novel quinoline insecticides of Japanese Meiji Seika Kaisha and Nippon Kayaku joint development.Very little, such as thrips etc. of unmanageable insect are had to significant preventive effect, diamond-back moth and other lepidoptera pest are had to certain preventive effect.
Anabasine insecticide is that control sucking pest is as one of the most effective insecticide such as aphid, plant hopper.Its mechanism of action is by controlling insect nerve system nicotinic acetylcholine esterase acceptor, the normal conduction of blocking-up insect central nervous system, thus cause insect to occur paralysis and then dead.Itself and common insecticides do not have cross resistance, can breathe out and impact the insect having developed immunity to drugs other kind for control.Anabasine insecticide not only has efficiently, absorption in wide spectrum and good root, tag and stomach poison function, and low to mammalian toxicity, environmentally safe.Both can be for cauline leaf processing, also can be used for soil, seed treatment, therefore caused people's extensive concern.Principal item has Imidacloprid, Acetamiprid, Nitenpyram, Diacloden, thiacloprid, clothianidin, MTI-446, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline etc. at present.
Summary of the invention
The object of the present invention is to provide a kind of synergistic effect remarkable, the Pesticidal combination that control efficiency is good and application thereof.
For reaching goal of the invention, the technical solution used in the present invention is:
One contains flometoquin and anabasine pesticide composition, the active ingredient of said composition is made up of flometoquin and anabasine insecticide, and described anabasine insecticide is Imidacloprid, Acetamiprid, Diacloden, thiacloprid, Nitenpyram, clothianidin, MTI-446, the pyridine of piperazine worm, cycloxaprid or epoxy insect quinoline; The mass ratio of flometoquin and anabasine insecticide is 80: 1～1: 80, and preferred mass ratio is 40: 1～1: 40.
Pesticidal combination of the present invention also can use with other compound with weeding, bactericidal property, also can mix use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Pesticidal combination of the present invention compared with the existing technology, at least can produce following beneficial effect:
1. in composition, two kinds of active components are composite according to the above ratio has notable synergistic effect afterwards to insect, and the insecticidal effect of mixed composition is significantly improved compared with its single dose, plays good insect protected seedling protecting effect;
2. the mechanism of action difference of two kinds of active ingredients in this Pesticidal combination, the application of composition can delay or overcome the pesticide resistance of insect;
3. there is the Pesticidal combination of synergistic effect, can reduce field dosage, effectively reduce environmental pollution and residue of pesticide, reduce the harm to beneficial organism;
4. composition has the advantages that quick-acting is good and lasting effect is long.
Embodiment
For making object of the present invention, technical scheme and technological merit clearer, below in conjunction with embodiment, content of the present invention is described further, but the present invention is limited to absolutely not these examples.Specific embodiment only, for explaining the present invention, is not intended to limit the present invention.All any modifications of making within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
The embodiment of the present invention provides one to contain flometoquin and anabasine pesticide composition, the active ingredient of said composition is made up of flometoquin and anabasine insecticide, and described anabasine insecticide is Imidacloprid, Acetamiprid, Diacloden, thiacloprid, Nitenpyram, clothianidin, MTI-446, the pyridine of piperazine worm, cycloxaprid or epoxy insect quinoline; The mass ratio of flometoquin and anabasine insecticide is 80: 1～1: 80, and preferred mass ratio is 40: 1～1: 40.
Inventor, by a large amount of biologicall test experiment sievings, after unexpected discovery flometoquin and anabasine insecticide are composite with aforementioned proportion, has significant synergies to the sucking pest such as plant hopper, thrips.On the basis of above-mentioned discovery, through composition is carried out to symphyogenetic quantitative analysis, form the present invention, take flometoquin as a kind of effective ingredient, take anabasine insecticide as another active ingredient, two kinds of compositions complement each other, synergy, plays excellent synergistic effect.
The Pesticidal combination of the embodiment of the present invention can be according to the crop of required control, environmental condition of living in, prevent and treat the various factors such as method, cost accounting, active ingredient is processed into together with carrier (filler) to acceptable any one formulation in pesticides application with auxiliary agent, preferred dosage form is granule, microcapsule suspending agent, microemulsion, suspending agent, aqueous emulsion, wetting powder, water dispersible granules or ultra low volume liquids.Adjuvant used, carrier and process technology adopt known component.In above-mentioned various each formulations, the gross mass percentage composition of flometoquin and anabasine insecticide is 0.5%～85%, and for example, in the time that the quality percentage composition of flometoquin and MTI-446 is respectively 20% and 3%, total content is 23%; In the time that the quality percentage composition of flometoquin and Diacloden is respectively 15% and 5%, total content is 20%, shown in the following example of value of concrete gross mass percentage composition.
In order to make object of the present invention, technical scheme and advantage clearer, the present invention further describes by following specific experiment example.If no special instructions, the ratio (comprising percentage) of below mentioning is all mass ratio.
One, preparation processing formulation Example
Embodiment 1:40%flometoquin imidacloprid suspending agent (flometoquin: Imidacloprid=1: 1)
Make wherein flometoquin20g, Imidacloprid 20g according to common process, sodium lignin sulfonate (dispersant) 4g, ethylene glycol (antifreeze) 4g, bentonite (thickener) 3g, organic silicone (defoamer) 3g, deionized water is mended to 100g.
In the present embodiment, the part by weight of flometoquin and Imidacloprid can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Imidacloprid can also be replaced to Diacloden, thiacloprid, Acetamiprid, Nitenpyram, clothianidin, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 2:60%flometoquin MTI-446 water dispersible granules (flometoquin: MTI-446=1: 5)
Make according to common process, flometoquin10g, MTI-446 50g, Negel (dispersant) 5g, sodium lignin sulfonate (dispersant) 7g, lauryl sodium sulfate (wetting agent) 2g, ammonium sulfate (disintegrant) 5g, precipitated calcium carbonate (filler) complements to 100g.
In the present embodiment, the part by weight of flometoquin and MTI-446 can change between 40: 1～1: 40, and both weight percentages can change between 5～80%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
MTI-446 can also be replaced to Diacloden, thiacloprid, Imidacloprid, Acetamiprid, Nitenpyram, clothianidin, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 3:55%flometoquin Diacloden wetting powder (flometoquin: Diacloden=10: 1)
Flometoquin50g, Diacloden 5g, lauryl sodium sulfate (wetting agent) 2g, sodium lignin sulfonate (dispersant) 3g, NNO (dispersant) 5g, kaolin complements to 100g.
In the present embodiment, the part by weight of flometoquin and Diacloden can change between 40: 1～1: 40, and both weight percentages can change between 5～85%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Diacloden can also be replaced to MTI-446, thiacloprid, Imidacloprid, Acetamiprid, Nitenpyram, clothianidin, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 4:12%flometoquin acetamiprid micro emulsion agent (flometoquin: Acetamiprid=1: 5)
Make according to common process, flometoquin2g, Acetamiprid 10g, 1-METHYLPYRROLIDONE (cosolvent) 10g, calcium dodecyl benzene sulfonate (emulsifier) 8g, phenethyl phenol polyethenoxy ether (emulsifier) 7g, triphen ethyl-phenol polyoxyethylene (emulsifier) 5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of flometoquin and Acetamiprid can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Acetamiprid can also be replaced to Imidacloprid, thiacloprid, Diacloden, Nitenpyram, clothianidin, MTI-446, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 5:10%flometoquin clothianidin micro-capsule suspension (flometoquin: clothianidin=1: 1)
Flometoquin5g, clothianidin 5g, cyclohexanone (solvent) 1g, polyisocyanates (curing agent) 0.4g, ethylene glycol (solvent) 0.4g, gum Arabic (thickener) 1g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of flometoquin and clothianidin can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Clothianidin can also be replaced to Imidacloprid, thiacloprid, Acetamiprid, Diacloden, Nitenpyram, MTI-446, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 6:15%flometoquin Nitenpyram aqueous emulsion (flometoquin: Nitenpyram=1: 2)
Flometoquin5g, Nitenpyram 10g, calcium dodecyl benzene sulfonate (emulsifier) 2.1g, phenethyl phenol polyethenoxy ether (emulsifier) 1.5g, cyclohexanone (solvent) 10.1g, toluene (solvent) 10.2g, xanthans (thickener) 0.5g, deionized water (carrier) complements to 100g.
In the present embodiment, the part by weight of flometoquin and Nitenpyram can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Nitenpyram can also be replaced to Imidacloprid, thiacloprid, Acetamiprid, Diacloden, MTI-446, clothianidin, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 7:8.2%flometoquin clothianidin granule (flometoquin: clothianidin=40: 1)
Flometoquin8g, clothianidin 0.2g, dioctyl sodium sulphosuccinate 1g, wood is moulded sodium sulfonate 2g, vinyl alcohol-vinyl alkyl ethers copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of flometoquin and clothianidin can change between 40: 1～1: 40, and both weight percentages can change between 0.5～85%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Clothianidin can also be replaced to Imidacloprid, thiacloprid, Acetamiprid, Diacloden, MTI-446, Nitenpyram, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 8:12%flometoquin Diacloden ultra low volume liquids (flometoquin: Diacloden=1: 5)
Flometoquin2g, Diacloden 10g, 1-METHYLPYRROLIDONE 10g, DMF 15g, n-octyl alcohol 2g, dodecyl sodium sulfonate calcium 2g, OPEO 3g, C10 aromatic hydrocarbons complements to 100g.
In the present embodiment, the part by weight of flometoquin and Diacloden can change between 40: 1～1: 40, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
Diacloden can also be replaced to Imidacloprid, thiacloprid, Acetamiprid, clothianidin, MTI-446, Nitenpyram, the pyridine of piperazine worm, cycloxaprid, epoxy insect quinoline and form new embodiment.
Embodiment 9:4.1%flometoquin piperazine worm pyridine granule (flometoquin: piperazine worm pyridine=1: 40)
Flometoquin0.1g, piperazine worm pyridine 4g, dioctyl sodium sulphosuccinate 1g, wood is moulded sodium sulfonate 2g, vinyl alcohol-vinyl alkyl ethers copolymer 2.5g, clay complements to 100g.
In the present embodiment, the part by weight of flometoquin and the pyridine of piperazine worm can change between 40: 1～1: 40, and both weight percentages can change between 0.5～85%, and the proportioning of used additives is also adjusted accordingly thereupon, formed new embodiment.
The pyridine of piperazine worm can also be replaced to Imidacloprid, thiacloprid, Acetamiprid, clothianidin, MTI-446, Nitenpyram, Diacloden, cycloxaprid, epoxy insect quinoline and form new embodiment.
Two, biological activity determination and test of pesticide effectiveness example
The combination of active principles of different agricultural chemicals is made to agricultural chemicals, is effectively and the efficiently mode of one of the upper resistant insect of current development novel pesticide and control agricultural.The agricultural chemicals of different cultivars shows three kinds of type of action: summation action, synergistic effect and antagonism after mixing conventionally.But be specially which kind of effect, unpredictable, only have by lot of experiments and could determine.
Inventor is by a large amount of screening tests, find that flometoquin and anabasine insecticide combination have obvious synergistic function to the sucking pest such as plant hopper, thrips, thus, the embodiment of the present invention also provides the application of above-mentioned Pesticidal combination suckings pest such as control Brown Planthopper, Frankliniella occidentalis.Control efficiency is not only the simple addition of two kinds of medicaments, is specifically illustrated with following biologicall test example.
One) the composite joint toxicity measuring to Brown Planthopper of biologicall test example: flometoquin and anabasine insecticide
For examination object: Brown Planthopper (Nilaparvata lugens (Stdl)), resource environment institute of Agricultural University Of South China Pesticide Science be the sensitive population providing, and use pot rice indoor culture, picking consistent 3 age nymph be used for test.
Test method: with reference to farm-chemical indoor determination test rule insecticidal n Y/T1154.11-2008, adopt rice stem infusion process.
Mode of application is judged co-toxicity coefficient (CTC) method that adopts.The computing formula of co-toxicity coefficient is as follows:
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) × l00
The percentage composition of B in percentage composition+B medicament ATI × mixture of A in theoretical toxicity index (TTI)=A medicament ATI × mixture
Co-toxicity coefficient (CTC)=[the theoretical toxicity index of mixture actual measurement toxicity index (ATI)/mixture (TTI)] × 100
When CTC≤80, composition performance, for antagonism, is worked as 80<CTC<120, and composition performance is for summation action, and when CTC >=120, composition performance is synergistic effect.
Result of the test: flometoquin and Imidacloprid, flometoquin and Acetamiprid, flometoquin and Diacloden, flometoquin and thiacloprid, flometoquin and clothianidin, flometoquin and MTI-446, flometoquin and Nitenpyram, flometoquin and the pyridine of piperazine worm, flometoquin and cycloxaprid, flometoquin and epoxy insect quinoline, the composite rear joint toxicity measuring to Brown Planthopper the results are shown in Table 1-10 respectively.
Table 1flometoquin and Imidacloprid different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.25 | 100.00 | ? | ? |
| Imidacloprid | 18.63 | 1.34 | ? | ? |
| Flometoquin80: Imidacloprid 1 | 0.17 | 147.06 | 98.78 | 148.87 |
| Flometoquin40: Imidacloprid 1 | 0.13 | 192.31 | 97.59 | 197.05 |
| Flometoquin20: Imidacloprid 1 | 0.11 | 227.27 | 95.30 | 238.48 |
| Flometoquin10: Imidacloprid 1 | 0.15 | 166.67 | 91.03 | 183.09 |
| Flometoquin5: Imidacloprid 1 | 0.10 | 250.00 | 83.56 | 299.20 |
| Flometoquin1: Imidacloprid 1 | 0.16 | 156.25 | 50.67 | 308.36 |
| Flometoquin1: Imidacloprid 5 | 0.58 | 43.10 | 17.78 | 242.36 |
| Flometoquin1: Imidacloprid 10 | 1.30 | 19.23 | 10.31 | 186.51 |
| Flometoquin1: Imidacloprid 20 | 1.59 | 15.72 | 6.04 | 260.32 |
| Flometoquin1: Imidacloprid 40 | 3.51 | 7.12 | 3.75 | 190.02 |
| Flometoquin1: Imidacloprid 80 | 6.35 | 3.94 | 2.56 | 153.79 |
The result of table 1 co-toxicity test shows, flometoquin and Imidacloprid composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 2flometoquin and Acetamiprid different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.27 | 100.00 | ? | ? |
| Acetamiprid | 11.34 | 2.38 | ? | ? |
| Flometoquin80: Acetamiprid 1 | 0.21 | 128.57 | 98.79 | 130.14 |
| Flometoquin40: Acetamiprid 1 | 0.15 | 180.00 | 97.62 | 184.39 |
| Flometoquin20: Acetamiprid 1 | 0.12 | 225.00 | 95.35 | 235.97 |
| Flometoquin10: Acetamiprid 1 | 0.14 | 192.86 | 91.13 | 211.64 |
| Flometoquin5: Acetamiprid 1 | 0.16 | 168.75 | 83.73 | 201.54 |
| Flometoquin1: Acetamiprid 1 | 0.24 | 112.50 | 51.19 | 219.77 |
| Flometoquin1: Acetamiprid 5 | 0.71 | 38.03 | 18.65 | 203.90 |
| Flometoquin1: Acetamiprid 10 | 1.29 | 20.93 | 11.26 | 185.96 |
| Flometoquin1: Acetamiprid 20 | 1.65 | 16.36 | 7.03 | 232.79 |
| Flometoquin1: Acetamiprid 40 | 2.89 | 9.34 | 4.76 | 196.19 |
| Flometoquin1: Acetamiprid 80 | 5.97 | 4.52 | 3.59 | 126.11 |
The result of table 2 co-toxicity test shows, flometoquin and Acetamiprid composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 3flometoquin and Diacloden different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.21 | 100.00 | ? | ? |
| Diacloden | 4.55 | 4.62 | ? | ? |
| Flometoquin80: Diacloden 1 | 0.15 | 140.00 | 98.82 | 141.67 |
| Flometoquin40: Diacloden 1 | 0.10 | 210.00 | 97.67 | 215.00 |
| Flometoquin20: Diacloden 1 | 0.12 | 175.00 | 95.46 | 183.33 |
| Flometoquin10: Diacloden 1 | 0.08 | 262.50 | 91.33 | 287.42 |
| Flometoquin5: Diacloden 1 | 0.13 | 161.54 | 84.10 | 192.07 |
| Flometoquin1: Diacloden 1 | 0.21 | 100.00 | 52.31 | 191.18 |
| Flometoquin1: Diacloden 5 | 0.52 | 40.38 | 20.51 | 196.88 |
| Flometoquin1: Diacloden 10 | 0.78 | 26.92 | 13.29 | 202.63 |
| Flometoquin1: Diacloden 20 | 1.24 | 16.94 | 9.16 | 184.94 |
| Flometoquin1: Diacloden 40 | 1.51 | 13.91 | 6.94 | 200.34 |
| Flometoquin1: Diacloden 80 | 2.56 | 8.20 | 5.79 | 141.60 |
The result of table 3 co-toxicity test shows, flometoquin and the Thiamethoxam compound co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring in the ratio range of 80: 1～1: 80 is all greater than 120, has synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 4flometoquin and clothianidin different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.26 | 100.00 | ? | ? |
| Clothianidin | 4.84 | 5.37 | ? | ? |
| Flometoquin80: clothianidin 1 | 0.14 | 185.71 | 98.83 | 187.91 |
| Flometoqui n40: clothianidin 1 | 0.13 | 200.00 | 97.69 | 204.73 |
| Flometoquin20: clothianidin 1 | 0.15 | 173.33 | 95.49 | 181.51 |
| Flometoquin10. clothianidin 1 | 0.11 | 236.36 | 91.40 | 258.61 |
| Flometoquin5: clothianidin 1 | 0.17 | 152.94 | 84.23 | 181.58 |
| Flometoquin1: clothianidin 1 | 0.25 | 104.00 | 52.69 | 197.40 |
| Flometoquin1: clothianidin 5 | 0.63 | 41.27 | 21.14 | 195.19 |
| Flometoquin1: clothianidin 10 | 0.92 | 28.26 | 13.97 | 202.23 |
| Flometoquin1: clothianidin 20 | 1.35 | 19.26 | 9.88 | 194.97 |
| Flometoquin1: clothianidin 40 | 1.78 | 14.61 | 7.68 | 190.19 |
| Flometoquin1: clothianidin 80 | 2.64 | 9.85 | 6.54 | 150.59 |
The result of table 4 co-toxicity test shows, flometoquin and clothianidin composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 5flometoquin and thiacloprid different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.27 | 100.00 | ? | ? |
| Thiacloprid | 15.39 | 1.75 | ? | ? |
| Flometoquin80: thiacloprid 1 | 0.18 | 150.00 | 98.79 | 151.84 |
| Flometoquin40: thiacloprid 1 | 0.13 | 207.69 | 97.60 | 212.79 |
| Flometoquin20: thiacloprid 1 | 0.15 | 180.00 | 95.32 | 188.83 |
| Flometoquin10: thiacloprid 1 | 0.16 | 168.75 | 91.07 | 185.30 |
| Fl ometoquin5: thiacloprid 1 | 0.14 | 192.86 | 83.63 | 230.62 |
| Flometoquin1: thiacloprid 1 | 0.29 | 93.10 | 50.88 | 183.00 |
| Flometoquin1: thiacloprid 5 | 0.68 | 39.71 | 18.13 | 219.02 |
| Flometoquin1: thiacloprid 10 | 1.32 | 20.45 | 10.69 | 191.42 |
| Flometoquin1: thiacloprid 20 | 1.87 | 14.44 | 6.43 | 224.45 |
| Flometoquin1: thiacloprid 40 | 3.12 | 8.65 | 4.15 | 208.50 |
| Flometoquin1: thiacloprid 80 | 6.51 | 4.15 | 2.97 | 139.77 |
The result of table 5 co-toxicity test shows, flometoquin and thiacloprid are composite is all greater than 120 to the equal co-toxicity coefficient CTC of Brown Planthopper joint toxicity measuring in the ratio range of 80: 1～1: 80, has synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 6flometoquin and Nitenpyram different proportion are composite to Brown Planthopper joint toxicity measuring
| Process LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.31 | 100.00 | ? | ? |
| Nitenpyram | 0.92 | 33.70 | ? | ? |
| Flometoquin80: Nitenpyram 1 | 0.23 | 134.78 | 99.18 | 135.90 |
| Flometoquin40: Nitenpyram 1 | 0.14 | 221.43 | 98.38 | 225.07 |
| Flometoquin20: Nitenpyram 1 | 0.16 | 193.75 | 96.84 | 200.07 |
| Flometoquin10: Nitenpyram 1 | 0.18 | 172.22 | 93.97 | 183.27 |
| Flometoquin5: Nitenpyram 1 | 0.10 | 310.00 | 88.95 | 348.51 |
| Flometoquin1: Nitenpyram 1 | 0.21 | 147.62 | 66.85 | 220.83 |
| Flometoquin1: Nitenpyram 5 | 0.32 | 96.88 | 44.75 | 216.50 |
| Flometoquin1: Nitenpyram 10 | 0.39 | 79.49 | 39.72 | 200.10 |
| Flometoquin1: Nitenpyram 20 | 0.35 | 88.57 | 36.85 | 240.34 |
| Flometoquin1: Nitenpyram 40 | 0.46 | 67.39 | 35.31 | 190.84 |
| Flometoquin1: Nitenpyram 80 | 0.72 | 43.06 | 34.51 | 124.75 |
The result of table 6 co-toxicity test shows, flometoquin and Nitenpyram composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 7flometoquin and MTI-446 different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.29 | 100.00 | ? | ? |
| MTI-446 | 1.54 | 18.83 | ? | ? |
| Flometoquin80: MTI-446 1 | 0.21 | 138.10 | 99.00 | 139.49 |
| Flometoquin40: MTI-446 1 | 0.16 | 181.25 | 98.02 | 184.91 |
| Flometoquin20: MTI-446 1 | 0.13 | 223.08 | 96.13 | 232.05 |
| Flometoquin10: MTI-446 1 | 0.15 | 193.33 | 92.62 | 208.74 |
| Flometoquin5: MTI-446 1 | 0.14 | 207.14 | 86.47 | 239.55 |
| Flometoquin1: MTI-446 1 | 0.26 | 111.54 | 59.42 | 187.73 |
| Flometoquin1: MTI-446 5 | 0.43 | 67.44 | 32.36 | 208.42 |
| Flometoquin1: MTI-446 10 | 0.52 | 55.77 | 26.21 | 212.78 |
| Flometoquin1: MTI-446 20 | 0.61 | 47.54 | 22.70 | 209.47 |
| Flometoquin1: MTI-446 40 | 0.58 | 50.00 | 20.81 | 240.26 |
| Flometoquin1: MTI-446 80 | 1.03 | 28.16 | 19.83 | 141.96 |
The result of table 7 co-toxicity test shows, flometoquin and MTI-446 composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 8flometoquin and piperazine worm pyridine different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.22 | 100.00 | ? | ? |
| The pyridine of piperazine worm | 0.94 | 23.40 | ? | ? |
| Flometoquin80: piperazine worm pyridine 1 | 0.16 | 137.50 | 99.05 | 138.81 |
| Flometoquin40: piperazine worm pyridine 1 | 0.11 | 200.00 | 98.13 | 203.81 |
| Flometoquin20: piperazine worm pyridine 1 | 0.10 | 220.00 | 96.35 | 228.33 |
| Flometoquin10: piperazine worm pyridine 1 | 0.13 | 169.23 | 93.04 | 181.90 |
| Flometoquin5: piperazine worm pyridine 1 | 0.09 | 244.44 | 87.23 | 280.22 |
| Flometoquin1: piperazine worm pyridine 1 | 0.18 | 122.22 | 61.70 | 198.08 |
| Fl ometoquin1: piperazine worm pyridine 5 | 0.24 | 91.67 | 36.17 | 253.43 |
| Flometoquin1: piperazine worm pyridine 10 | 0.34 | 64.71 | 30.37 | 213.08 |
| Flometoquin1: piperazine worm pyridine 20 | 0.41 | 53.66 | 27.05 | 198.36 |
| Flometoquin1: piperazine worm pyridine 40 | 0.46 | 47.83 | 25.27 | 189.24 |
| Flometoquin1: piperazine worm pyridine 80 | 0.70 | 31.43 | 24.35 | 129.07 |
The result of table 8 co-toxicity test shows, flometoquin and the pyridine of piperazine worm composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 9flometoquin and cycloxaprid different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.28 | 100.00 | ? | ? |
| Cycloxaprid | 1.42 | 19.72 | ? | ? |
| Flometoquin80: cycloxaprid 1 | 0.21 | 133.33 | 99.01 | 134.67 |
| Flometoquin40: cycloxaprid 1 | 0.13 | 215.38 | 98.04 | 219.69 |
| Flometoquin20: cycloxaprid 1 | 0.15 | 186.67 | 96.18 | 194.09 |
| Flometoquin10: cycloxaprid 1 | 0.16 | 175.00 | 92.70 | 188.78 |
| Flometoquin5: cycloxaprid 1 | 0.13 | 215.38 | 86.62 | 248.66 |
| Flometoquin1: cycloxaprid 1 | 0.23 | 121.74 | 59.86 | 203.38 |
| Flometoquin1: cycloxaprid 5 | 0.35 | 80.00 | 33.10 | 241.70 |
| Flometoquin1: cycloxaprid 10 | 0.42 | 66.67 | 27.02 | 246.76 |
| Flometoquin1: cycloxaprid 20 | 0.53 | 52.83 | 23.54 | 224.42 |
| Flometoquin1: cycloxaprid 40 | 0.67 | 41.79 | 21.68 | 192.80 |
| Flometoquin1: cycloxaprid 80 | 0.84 | 33.33 | 20.71 | 160.96 |
The result of table 9 co-toxicity test shows, flometoquin and cycloxaprid composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Table 10flometoquin and epoxy insect quinoline different proportion are composite to Brown Planthopper joint toxicity measuring
| Process | LC 50(μg／mL) | ATI | TTI | Co-toxicity coefficient CTC |
| flometoquin | 0.22 | 100.00 | ? | ? |
| Epoxy insect quinoline | 2.87 | 7.67 | ? | ? |
| Flometoquin80: epoxy insect quinoline 1 | 0.17 | 129.41 | 98.86 | 130.90 |
| Fometoquin40: epoxy insect quinoline 1 | 0.12 | 183.33 | 97.75 | 187.56 |
| Flometoquin20: epoxy insect quinoline 1 | 0.1 | 220.00 | 95.60 | 230.12 |
| Flometoquin10: epoxy insect quinoline 1 | 0.12 | 183.33 | 91.61 | 200.13 |
| Flometoquin5: epoxy insect quinoline 1 | 0.14 | 157.14 | 84.61 | 185.72 |
| Flometoquin1: epoxy insect quinoline 1 | 0.21 | 104.76 | 53.83 | 194.61 |
| Flometoquin1: epoxy insect quinoline 5 | 0.38 | 57.89 | 23.05 | 251.12 |
| Flometoquin1: epoxy insect quinoline 10 | 0.68 | 32.35 | 16.06 | 201.46 |
| Flometoquin1: epoxy insect quinoline 20 | 0.96 | 22.92 | 12.06 | 189.98 |
| Flometoquin1: epoxy insect quinoline 40 | 1.14 | 19.30 | 9.92 | 194.59 |
| Flometoquin1: epoxy insect quinoline 80 | 1.75 | 12.57 | 8.81 | 142.77 |
The result of table 10 co-toxicity test shows, flometoquin and epoxy insect quinoline composite in the ratio range of 80: 1～1: 80 the co-toxicity coefficient CTC to Brown Planthopper joint toxicity measuring be all greater than 120, there is synergistic effect.Especially in the ratio range of 40: 1～1: 40, CTC is all greater than 180, and synergistic effect is remarkable.
Two) field medicine effect test example
1, the control efficiency to Brown Planthopper
Tested in September, 2013 and carry out at Guangdong Province's Qingyuan City one paddy field, test adopts knapsack sprayer to carry out the method for full field even spraying, the paddy rice growth of choosing is basically identical, be in tillering stage, that a situation arises is basically identical for plant hopper, investigation insect population radix before medicine, and 1d, 7d, 15d check the borer population of living after medicine.From table 11, data can draw, the composite rear various formulation synergistic effects of flometoquin and anabasine pesticide are obvious; 1d after dispenser .7d and 15d, each compound drug to the control efficiency of brown planthopper also significantly better than single dose.
Table 11flometoquin and the composite field control effect to Brown Planthopper of anabasine pesticide
2, the control efficiency to capsicum Frankliniella occidentalis
Tested in May, 2013 and carry out in one food market, Longgang District of Shenzhen City, test adopts knapsack sprayer to carry out the method for full field even spraying, the experimental field capsicum of choosing is in the Sheng phase of yielding positive results, plant strain growth is basically identical, Frankliniella occidentalis occurs heavier, and it is basically identical to distribute, investigation insect population radix before medicine, and 1d, 3d, 7d check the borer population of living after medicine.From table 12, data can draw, the composite rear various formulation synergistic effects of flometoquin and anabasine pesticide are obvious; 1d after dispenser, 3d and 7d, each compound drug to the control efficiency of Frankliniella occidentalis also significantly better than single dose.
Table 12fometoquin and the composite field control effect to capsicum Frankliniella occidentalis of anabasine pesticide
From flometoquin and the composite field efficacy to Brown Planthopper, capsicum Frankliniella occidentalis of anabasine insecticide, each compound drug control efficiency, significantly better than single dose, illustrates the composite synergistic effect that has; Lasting period extends, and can reduce dosage and spraying times, delays pest resistance to insecticide and produces, and can reduce cost accounting simultaneously.
These are only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (7)
1. a Pesticidal combination, the active ingredient that it is characterized in that said composition is made up of flometoquin and anabasine insecticide, and described anabasine insecticide is one of in Imidacloprid, Acetamiprid, Diacloden, thiacloprid, Nitenpyram, clothianidin, MTI-446, the pyridine of piperazine worm, cycloxaprid or epoxy insect quinoline; The mass ratio of flometoquin and anabasine insecticide is 80: 1～1: 80.
2. Pesticidal combination according to claim 1, is characterized in that, described flometoquin and anabasine insecticide mass ratio be 40: 1～1: 40.
3. Pesticidal combination according to claim 1 and 2, is characterized in that the active ingredient of said composition and auxiliary composition are mixed with the preparation that is applicable to agricultural use.
4. Pesticidal combination according to claim 3, is characterized in that, the preparation of described applicable agricultural use is granule, microcapsule suspending agent, microemulsion, aqueous emulsion, suspending agent, wetting powder, water dispersible granules, ultra low volume liquids.
5. Pesticidal combination according to claim 4, is characterized in that, described flometoquin and the anabasine insecticide gross mass percentage composition in each preparation is 0.5%～85%.
6. described in claim 1 to 5, Pesticidal combination is used for preventing and treating the application of paddy rice, fruit tree, vegetable crop sucking pest aspect.
7. the application of Pesticidal combination according to claim 6, is characterized in that, described sucking pest is plant hopper, thrips.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410064054.4A CN103814939A (en) | 2014-02-21 | 2014-02-21 | Insecticidal composition |
| PCT/CN2014/080775 WO2015123949A1 (en) | 2014-02-21 | 2014-06-25 | Insecticidal composition and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410064054.4A CN103814939A (en) | 2014-02-21 | 2014-02-21 | Insecticidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103814939A true CN103814939A (en) | 2014-05-28 |
Family
ID=50750470
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410064054.4A Pending CN103814939A (en) | 2014-02-21 | 2014-02-21 | Insecticidal composition |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN103814939A (en) |
| WO (1) | WO2015123949A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015123949A1 (en) * | 2014-02-21 | 2015-08-27 | 深圳诺普信农化股份有限公司 | Insecticidal composition and use thereof |
| CN106852325A (en) * | 2015-12-09 | 2017-06-16 | 上海生农生化制品有限公司 | A kind of Pesticidal combination and its application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007088978A1 (en) * | 2006-02-03 | 2007-08-09 | Meiji Seika Kaisha, Ltd. | Novel quinoline derivative and pesticide for agricultural and horticultural applications comprising the derivative as active ingredient |
| JP2010053129A (en) * | 2008-07-31 | 2010-03-11 | Meiji Seika Kaisha Ltd | Pest control composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4319223B2 (en) * | 2004-08-04 | 2009-08-26 | 明治製菓株式会社 | Quinoline derivatives and insecticides comprising them as active ingredients |
| AU2011218939B2 (en) * | 2010-02-23 | 2015-08-13 | Meiji Seika Pharma Co., Ltd. | Stable crystal form of 2-ethyl-3,7-dimethyl- 6-(4-(trifluoromethoxy) phenoxy) quinoline -4-ylmethyl carbonate, method of manufacturing same and agricultural chemical composition containing crystals of same |
| CN103814939A (en) * | 2014-02-21 | 2014-05-28 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
-
2014
- 2014-02-21 CN CN201410064054.4A patent/CN103814939A/en active Pending
- 2014-06-25 WO PCT/CN2014/080775 patent/WO2015123949A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007088978A1 (en) * | 2006-02-03 | 2007-08-09 | Meiji Seika Kaisha, Ltd. | Novel quinoline derivative and pesticide for agricultural and horticultural applications comprising the derivative as active ingredient |
| JP2010053129A (en) * | 2008-07-31 | 2010-03-11 | Meiji Seika Kaisha Ltd | Pest control composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015123949A1 (en) * | 2014-02-21 | 2015-08-27 | 深圳诺普信农化股份有限公司 | Insecticidal composition and use thereof |
| CN106852325A (en) * | 2015-12-09 | 2017-06-16 | 上海生农生化制品有限公司 | A kind of Pesticidal combination and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015123949A1 (en) | 2015-08-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103814937B (en) | A kind of Pesticidal combination | |
| CN103814909A (en) | Synergistic pesticidal composition | |
| CN104488943B (en) | A kind of Pesticidal combination | |
| CN101647463A (en) | Insecticidal and acaricidal composition containing spirodiclofen | |
| CN102696601B (en) | Insecticidal composition containing flubendiamide | |
| CN101617688A (en) | Pesticide composition containing thiacloprid | |
| CN101669473B (en) | Synergic insecticide composition | |
| CN103004867A (en) | Insecticidal composition with synergism | |
| CN103814939A (en) | Insecticidal composition | |
| CN101444221B (en) | Composite containing oxadiazines and pyrromonazole pesticide | |
| CN104522000B (en) | A kind of miticide composition containing cyflumetofen and ivermectin | |
| CN101653145B (en) | Synergistic pesticide composition containing fenazaquin | |
| CN101473828B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN103109839B (en) | Insecticidal composition containing penta-imidacloprid guanidine and metaflumizone and preparation thereof | |
| CN105454241A (en) | Insecticidal composition | |
| CN105794859A (en) | Insecticidal compound containing conidioblous thromboides and biological sources | |
| CN103229776A (en) | Weeding composition for rice field and preparation thereof | |
| CN107114392A (en) | Bio-insecticidal composition comprising destruxins | |
| CN102204561A (en) | Agricultural pesticide composition | |
| CN107372522A (en) | A kind of composition pesticide containing fenazaquin | |
| CN101502268B (en) | Pesticide composition containing Thiamethoxam and Pyridaben and use thereof | |
| CN106165690A (en) | A kind of composition pesticide containing avilamycin | |
| CN107637602A (en) | A kind of composition pesticide containing emamectin-benzoate | |
| CN105994341B (en) | Anthranilamide compound and nicotine compound compounded pesticides | |
| CN104521999B (en) | A kind of Synergistic mite killing composition containing tebufenpyrad and Ivermectin HCL |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140528 |