CN106386840A - Insecticidal composition containing cyclaniliprole - Google Patents
Insecticidal composition containing cyclaniliprole Download PDFInfo
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- CN106386840A CN106386840A CN201610818229.5A CN201610818229A CN106386840A CN 106386840 A CN106386840 A CN 106386840A CN 201610818229 A CN201610818229 A CN 201610818229A CN 106386840 A CN106386840 A CN 106386840A
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- grams
- ring bromine
- active component
- insect amide
- bromine insect
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
Abstract
The invention discloses an insecticidal composition containing cyclaniliprole. The effective active components comprise a first active component cyclaniliprole and a second active component chloronicotinyl insecticide from one of imidacloprid, acetamiprid, nitenpyram, thiamethoxam, thiacloprid, clothianidin and dinotefuran, wherein the weight ratio of the first active component to the second active component is 1:50 to 50:1; and the content sum is 1 to 80 percent of the total weight of the composition. The composition can be prepared into agriculturally acceptable missible oil, suspending agent, wettable powder, water dispersible granule, water emulsion, microemulsion, microcapsule, granule and water form. The composition has reasonable components and has good effects on homopteran, hemipteran and thysanopteran insects, such as aphids, plant hoppers, aleyrodid, thrips, tea lesser leafhopper and the like; the insecticidal effect is not simple superposition of each component activity; and compared with the existing single insecticide, the composition has significant insecticidal effect and significant synergistic effect, reduces the use amount and has high safety on crops.
Description
Technical field
The present invention relates to a kind of Pesticidal combination containing ring bromine insect amide and application thereof, compositionss are by the first active component
Ring bromine insect amide, the second active component nicotinic insecticide and auxiliary agent composition, belong to technical field of compounded pesticide.
Background technology
Ring bromine insect amide, English name is cyclaniliprole, and chemical name is：The bromo- N- of 3- [the chloro- 6- of the bromo- 4- of 2-
[[(1- cyclopropylethyl) amine] carbonyl] phenyl] -1- (3- Chloro-2-Pyridyle) -1H- pyrazoles -5- Methanamide, test code number is IKI-
3106, CAS：1031756-98-5.The bisamide insecticides that Japanese Ishihara Sangyo Kaisha, Ltd. develops.There is systemic activity,
Broad-spectrum insecticidal activity, has good prevention effect to insects such as diamondback moth, Prodenia litura, aleyrodid, aphid, thrips, liriomyza bryoniaes.
Nicotinic insecticide mechanism of action mainly controls insect nerve system nicotinic acetylcholine ester by selectivity
Enzyme acceptor, blocks the normal conduction of insect CNS, thus leading to insect paralysis and then death.The present invention is main
The nicotinic insecticide being related to mainly has：Imidacloprid, Acetamiprid, Nitenpyram, Diacloden, thiacloprid, clothianidin, MTI-446.
Applicant through test find, ring bromine insect amides different for the mechanism of action is compounded with nicotinic insecticide, have with
Lower advantage and beneficial effect：1st, use compound scheme, to the Homopteras such as aphid, plant hopper, aleyrodid, thrips, tea lesser leafhopper, half wing
Mesh, Thysanoptera have notable synergistic effect, significantly improve prevention effect；2nd, reduce dosage and times for spraying, reduce
Cost accounting；3rd, overcome the single for a long time shortcoming using easy generation resistance, extend the service life of medicament.
Content of the invention
It is an object of the invention to provide a kind of component is reasonable, potentiation is notable, good disinsection effect, drug cost are low,
Agricultural insecticidal composite to crop safety.
Another object of the present invention is to providing the Pesticidal combination dosage form containing ring bromine insect amide and nicotinic insecticide.
It is still another object of the present invention to provide above-mentioned composition anti-eliminate aphis, plant hopper, aleyrodid, thrips, the little greenery of tea
Application on the Homopteras such as Cicadae, Semiptera, Thysanoptera.
For achieving the above object, the technical scheme is that such solution：
A kind of Pesticidal combination containing ring bromine insect amide and nicotinic insecticide and application thereof it is characterised in that
（1）First active component：Ring bromine insect amide；
（2）Second active component：Nicotinic insecticide imidacloprid, Acetamiprid, Nitenpyram, Diacloden, thiacloprid, clothianidin,
One of MTI-446；
The weight of the first active component and the second active component is than for 1:50～50:1, content sum is described composition total weight
1%～80%, preferably 5%～50%.
A kind of Pesticidal combination containing ring bromine insect amide of the present invention is according to the side well known to those skilled in the art of the present technique
The preparation formulation that method can be prepared is cream, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, microcapsule
Agent, granule, water preparation.
To cream, spendable auxiliary agent has：Emulsifying agent is selected from calcium dodecyl benzene sulfonate（Agriculture breast 500#）, Nongru-700 #,
Agriculture breast 2201, this disk -60#, emulsifying agent T-60（Common name：Anhydrous sorbitol single-hard ester acid ester polyoxyethylene ether）、TX-10（Logical
With name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601#, agriculture breast 600#, one or more of agriculture breast 400# etc.；Solvent selects
From dimethylbenzene, solvent naphtha（S-150、S-180、S-200）, toluene, biodiesel, one of methylated vegetable oil etc. or many
Kind；Cosolvent is selected from one or more of ethyl acetate, methanol, dimethylformamide, Ketohexamethylene, acetone, butanone etc.；Surely
Determine agent and be selected from one or more of triphenyl phosphite, epoxychloropropane, acetic anhydride etc..
To suspending agent, spendable auxiliary agent has：Dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate（Expand
Powder NNO）、TERSPERSE 2020（Huntsman Corporation of the U.S. produces, alkyl naphthalene sulfonic acid salt）In one or more；Emulsifying agent
As Nongru-700 #（Common name：Alkyl phenol formaldehyde resin polyoxyethylene ether）, agriculture breast 2201, this disk -60#（Common name：Sorbitan
Alcohol stearate）, Tween-60 #（Common name：Polyoxyethylene sorbitan stearate）, agriculture breast 1601#（Common name：Triphen
Ethyl -phenol polyoxyethylene polyoxypropylene block polymer）、TERSPERSE 4894（Huntsman Corporation of the U.S. produces）Deng in
One or more；Wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy base ether phosphoric acid
Ester, phenethyl phenol polyoxyethylene groups ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500
（Huntsman Corporation of the U.S. produces）One or more of Deng；Thickening agent such as xanthan gum, polyvinyl alcohol, bentonite, aluminium-magnesium silicate
One or more of Deng；Preservative such as one or more of formaldehyde, benzoic acid, sodium benzoate etc.；Stabilizer such as epoxy is big
One or more of Oleum Glycines, epoxychloropropane, triphenyl phosphate etc.；Defoamer such as silicone defoamer；Antifreezing agent such as second
One or more of glycol, propylene glycol, glycerol, carbamide, inorganic salts such as sodium chloride etc.；Water is deionized water.
To wettable powder, spendable auxiliary agent has：Dispersant such as polycarboxylate, lignosulfonates, polyoxyethylene gather
Oxypropylene group ether block copolymers, alkyl naphthalene formaldehyde condensate sulfonates, alkylphenol-polyethenoxy base ether phosphate, poly alkyl alcohol
One or more of oxygen ethylene ether phosphate, alkylphenol-polyethenoxy base ether sulfonate etc.；Wetting agent such as alkyl sulfate, alkane
One or more of base sulfonate, alkylnaphthalene sulfonate etc.；Filler such as ammonium sulfate, carbamide, sucrose, glucose, kieselguhr, height
One or more of ridge soil, white carbon, fine particle calcium carbonate, Pulvis Talci, attapulgite, potter's clay etc..
To water dispersible granules, spendable auxiliary agent has：Dispersant such as polycarboxylate（TERSPERSE 2700、T36、GY-
D06 etc.）, lignosulfonates, one or more of alkylnaphthalene sulfonate etc.；Wetting agent such as alkyl sulfate, alkyl sulfonic acid
One or more of salt, naphthalene sulfonate etc.；Disintegrating agent such as ammonium sulfate, sodium sulfate, Polyvinylpyrrolidone, starch and its derivative
One or more of thing, bentonite etc.；Binding agent such as starch, glucose, polyvinyl alcohol, Polyethylene Glycol, carboxymethyl cellulose
One or more of sodium, sucrose etc.；Filler such as kieselguhr, Kaolin, white carbon, fine particle calcium carbonate, Pulvis Talci, attapulgite, potter's clay
One or more of Deng.
To aqueous emulsion, spendable auxiliary agent has：Emulsifying agent such as Nonyl pheno（EO=10）Ether phosphate, triphen second
Base phenol polyoxyethylene phosphonate, Nongru-700 #（Common name：Alkyl phenol formaldehyde resin polyoxyethylene ether）, agriculture breast 2201#, this
Disk -60#（Common name：Span60）, Tween-60 #（Common name：Polyoxyethylene sorbitan stearic acid
Ester）、TX-10（Common name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601（Common name：Triphenoethyl benzene phenol polyoxypropylene gathers
Oxygen ethylene block polymer）, agriculture breast 600#, one or more of agriculture breast 400# etc.；Solvent for example dimethylbenzene, toluene, Ketohexamethylene,
Solvent naphtha（The trade mark：S-150、S-180、S-200）One or more of Deng；Stabilizer such as triphenyl phosphite, epoxy chloropropionate
One or more of alkane, epoxy soybean oil etc.；Antifreezing agent such as ethylene glycol, propylene glycol, glycerol, carbamide, inorganic salts such as chlorination
One or more of sodium etc.；Thickening agent such as one or more of xanthan gum, polyvinyl alcohol, bentonite, aluminium-magnesium silicate etc.；Anti-
Rotten agent such as one or more of formaldehyde, benzoic acid, sodium benzoate etc., water is deionized water.
To microemulsion, spendable auxiliary agent has：Emulsifying agent is selected from calcium dodecyl benzene sulfonate（Agriculture breast 500#）, agriculture breast
700#, agriculture breast 2201, this disk-60#, polysorbate60-#, TX-10, agriculture breast 1601（Common name：Phenethyl phenol polyoxyethylene polyoxy
Propylene ether）, agriculture breast 600#, one or more of agriculture breast 400# etc.；Co-emulsifier is selected from methanol, isopropanol, n-butyl alcohol, second
Alcohol；Solvent is selected from Ketohexamethylene, N-Methyl pyrrolidone, dimethylbenzene, toluene, solvent naphtha（The trade mark：S-150、S-180、S-200）Deng
One or more of；Stabilizer is selected from one or more of triphenyl phosphite, epoxychloropropane etc.；Water is deionization
Water.
To microcapsule, spendable auxiliary agent has：Emulsifying dispersant such as Nonyl pheno（EO=10）Ether phosphate,
Triphenoethyl benzene phenol polyethenoxy ether phosphate, Nongru-700 #（Common name：Alkyl phenol formaldehyde resin polyoxyethylene ether）, agriculture breast
2201#, this disk -60#（Common name：Span60）, Tween-60 #（Common name：Polyoxyethylene sorbitan
Stearate）、TX-10（Common name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601（Common name：Triphenoethyl benzene phenol polyoxy
Propylene polyoxyethylene block polymers）, agriculture breast 600#, one or more of agriculture breast 400# etc.；Antifreezing agent for example ethylene glycol, third
One or more of glycol, glycerol, carbamide, inorganic salts such as sodium chloride etc.；Thickening agent such as white carbon, polyvinyl alcohol, swelling
One or more of soil, aluminium-magnesium silicate etc.；Defoamer such as silicone oil, silicone compound, C10-20 saturated fat acids chemical combination
One or more of thing, C8-10 aliphatic alcohols, hexanol, butanol, capryl alcohol etc.；Water is deionized water.
To granule, spendable auxiliary agent has：Carrier such as clay, Kaolin, Talcum, Calcium Carbonate, corn starch, aluminium silicate
One or more of；Dispersant such as one or more of polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate；Moistening
Agent such as one or more of alkyl sulfate, alkylsulfonate, naphthalene sulfonate；Binding agent such as polyvinyl alcohol, dextrin, polyethylene
One or more of ketopyrrolidine etc..
To water preparation, spendable auxiliary agent has：Emulsifying agent such as calcium dodecyl benzene sulfonate, alkylphenol-formaldehyde resin polyoxyethylene
Ether, agriculture breast 2201#, sorbitan monostearate, sorbitan monostearate polyoxyethylene ether, octyl phenol polyoxyethylene
（10）Ether, fatty alcohol-polyoxyethylene ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, agriculture breast 600#, agriculture breast 400#, dodecane
One or more of base dimethyl benzyl ammonium chloride etc.；Water is deionized water.
Instant component is reasonable, good disinsection effect, and drug cost is low, and its activity and insecticidal effect are not each composition activities
Simple superposition, but have significant potentiation, good to crop safety, meet the security requirement of pesticidal preparations.This
Bright have significant preventing and treating effect to the Homopteras such as aphid, plant hopper, aleyrodid, thrips, tea lesser leafhopper, Semiptera, Thysanoptera
Really.
Specific embodiment
To illustrate ring bromine insect amide and nicotinic insecticide mixture to Homoptera, half wing below by Toxicity Determination
Whether mesh, Thysanoptera have potentiation.
1st, ring bromine insect amide and imidacloprid, Acetamiprid, Nitenpyram mixture measure to the synergy of planthopper.
Synergy mensure is carried out using rice-stem dipping method.By ring bromine insect amide active compound, imidacloprid, Acetamiprid, alkene pyridine worm
Amine active compound, is configured to the medicinal liquid of 5 series concentration, standby.
Select the planthopper of indoor feeding（Nilaparvata lugens）3 age nymphs are standby.Choice experiment room is cultivated
The consistent tillering stage rice seedlings of stalwartness, even root take, clean, be cut into the band root rice stem of about 10cm length, dry in the air to table in shady place
Face no washmarking, stand-by.
Ready rice stem is impregnated in the medicinal liquid preparing 30s, taking-up is dried, encase root with wet absorbent cotton and protect
Wet, outsourcing preservative film, it is placed in test tube, 3 plants of every test tube.Often process 4 repetitions, and set process without medicament as comparison.
With pest sucking device, test worm is moved in test tube, 15, every test tube, mouth of pipe gauze covers.
After process test worm as（25±1）DEG C, relative humidity be 60%～80%, the illumination photoperiod be L:D=（16:8）H bar
Raise under part and observe.After process, 48h investigation test worm death condition, records total borer population and dead borer population.According to survey result, calculate
Each mortality rate processing.Obtain virulence regression equation, the lethal concentration of 50, correlation coefficient etc., and obtain common poison system with the abundant method of Sun Yun
Number（CTC value）.
The synergy to planthopper for the Pesticidal combination of the insect amide of bromine containing ring being provided using the co-toxicity coefficient method evaluation present invention,
Regression equation is asked to the preventive effect niqueMin of planthopper with the logarithm of drug concentration and medicament, and calculates the LC of medicament pair50Value,
Then try to achieve co-toxicity coefficient.The synergy to planthopper for the compound drug, co-toxicity coefficient are evaluated with co-toxicity coefficient>120 are expressed as
Potentiation, co-toxicity coefficient is expressed as summation action, co-toxicity coefficient between 80～120<80 are expressed as antagonism.
Table 1-1 ring bromine insect amide and the toxicity test result to planthopper for the imidacloprid mixture
Table 1-2 ring bromine insect amide and the toxicity test result to planthopper for the Acetamiprid mixture
Table 1-3 ring bromine insect amide and the toxicity test result to planthopper for the Nitenpyram mixture
Toxicity Determination result shows：Ring bromine insect amide presses 1 with nicotinic insecticide imidacloprid, Acetamiprid, Nitenpyram:50
～50:1 uses with, has higher virulence to planthopper, shows as potentiation.
2nd, the ring bromine insect amide and Diacloden mixture joint toxicity measuring to yellow thrips.
Toxicity Determination is carried out using infusion process.By ring bromine insect amide active compound, Diacloden active compound, it is configured to 5 series
The medicinal liquid of concentration, standby.
Select the consistent palm thrips of indoor cultivation, age（Thrips palmi）, with pest sucking device, test worm is moved into for 20
Volume is medication immersion worm 10s in the leaching worm box of 50mL, blots unnecessary medicinal liquid in leaching worm box with filter paper.Put into the Fructus Benincasae chiehquae of long 3cm
Leaf, sealed membrane will soak the sealing of worm box, after be placed in temperature and be 26 DEG C, cultivate in the illumination box of humidity 70%.Often process repetition 4
Secondary, often repeat to soak worm 20, be processed as compareing with clear water.Number of dead and live insects is checked, matched group mortality rate is less than 20% after 24h
Test as efficiency test.
According to survey result, calculate the mortality rate of each process.Obtain virulence regression equation, the lethal concentration of 50, correlation coefficient
Deng, and obtain co-toxicity coefficient with the abundant method of Sun Yun（CTC value）.
Work is combined to yellow thrips using the Pesticidal combination that co-toxicity coefficient method evaluates the insect amide of bromine containing ring that the present invention provides
With regression equation being asked to the preventive effect niqueMin of yellow thrips with the logarithm of drug concentration and medicament, and calculating medicament pair
LC50Value, then tries to achieve co-toxicity coefficient.The synergy to yellow thrips for the compound drug, co-toxicity coefficient are evaluated with co-toxicity coefficient>
120 are expressed as potentiation, and co-toxicity coefficient is expressed as summation action, co-toxicity coefficient between 80～120<80 are expressed as antagonism makees
With.
Table 2 ring bromine insect amide and the toxicity test result to yellow thrips for the Diacloden mixture
Toxicity Determination result shows：Ring bromine insect amide presses 1 with Diacloden:50～50:1 uses with, yellow thrips is had higher
Virulence, show as potentiation.
3rd, ring bromine insect amide and thiacloprid, the joint toxicity measuring to Herba Spinaciae aphid for the clothianidin mixture.
Toxicity Determination is carried out using dip method.By ring bromine insect amide active compound, thiacloprid, clothianidin active compound, it is configured to 5
The medicinal liquid of individual series concentration, standby.
Select the consistent black peach aphid of indoor cultivation, age（Myzus persicae）Nymph, target insect is immersed medicinal liquid 10s
Afterwards, draw unnecessary medicinal liquid with filter paper, test worm is transferred under normal condition and raises, often process and be repeated 4 times, often repeat to soak worm 10
Head, is processed as compareing with clear water.Number of dead and live insects is checked, the test that matched group mortality rate is less than 20% is efficiency test after 24h.
According to survey result, calculate the mortality rate of each process.Obtain virulence regression equation, the lethal concentration of 50, correlation coefficient
Deng, and obtain co-toxicity coefficient with the abundant method of Sun Yun（CTC value）.
Work is combined to Herba Spinaciae aphid using the Pesticidal combination that co-toxicity coefficient method evaluates the insect amide of bromine containing ring that the present invention provides
With regression equation being asked to the preventive effect niqueMin of Herba Spinaciae aphid with the logarithm of drug concentration and medicament, and calculating medicament pair
LC50Value, then tries to achieve co-toxicity coefficient.The synergy to Herba Spinaciae aphid for the compound drug, co-toxicity coefficient are evaluated with co-toxicity coefficient>
120 are expressed as potentiation, and co-toxicity coefficient is expressed as summation action, co-toxicity coefficient between 80～120<80 are expressed as antagonism makees
With.
Table 3-1 ring bromine insect amide and the toxicity test result to Herba Spinaciae aphid for the thiacloprid mixture
Table 3-2 ring bromine insect amide and the toxicity test result to Herba Spinaciae aphid for the clothianidin mixture
Toxicity Determination result shows：Ring bromine insect amide presses 1 with thiacloprid, clothianidin:50～50:1 uses with, to Herba Spinaciae aphid
There is higher virulence, show as potentiation.
4th, ring bromine insect amide and the dinotefuran mixed joint toxicity measuring to tea lesser leafhopper.
Toxicity Determination is carried out using infusion process.By ring bromine insect amide active compound, MTI-446 active compound, it is configured to 5 series
The medicinal liquid of concentration, standby.
Select the consistent tea lesser leafhopper of indoor cultivation, age（Empoasca pirisuga）Nymph, nymph is placed in cold
Hide 5～10 min in 0～4 DEG C of refrigerator, take out when its inertia, will be into the liquid for the leaching worm cage leaching gently with nymph,
Take out after 10s, suck unnecessary medicinal liquid with absorbent paper, respectively labelling, be then placed in (26 ± 1) DEG C, relative humidity is (70 ± 10) %
Phenology case in, with the feeding of the tealeaves blade of fresh clean.Each concentration processes nymph 30, is repeated 4 times, and contains respective amount to soak
0.1% Tween 80 water of acetone is comparison, 48h inspection result after medicine, and comparison mortality rate is invalid test higher than 20%, test worm
Death standard is：Touch test worm with little brush pen, 5 s nonresponders are considered as death, be otherwise considered as the worm that lives.
According to survey result, calculate the mortality rate of each process.Obtain virulence regression equation, the lethal concentration of 50, correlation coefficient
Deng, and obtain co-toxicity coefficient with the abundant method of Sun Yun（CTC value）.
The joint to tea lesser leafhopper for the Pesticidal combination of the insect amide of bromine containing ring being provided using the co-toxicity coefficient method evaluation present invention
Effect, seeks regression equation with the logarithm of drug concentration and medicament to the preventive effect niqueMin of tea lesser leafhopper, and calculates medicament
To LC50Value, then tries to achieve co-toxicity coefficient.The synergy to tea lesser leafhopper for the compound drug is evaluated with co-toxicity coefficient, altogether poison
Coefficient>120 are expressed as potentiation, and co-toxicity coefficient is expressed as summation action, co-toxicity coefficient between 80～120<80 are expressed as
Antagonism.
Table 4 ring bromine insect amide and the dinotefuran mixed toxicity test result to tea lesser leafhopper
Toxicity Determination result shows：Ring bromine insect amide presses 1 with MTI-446:50～50:1 uses with, and tea lesser leafhopper is had relatively
High virulence, shows as potentiation.
With reference to embodiment, present invention is described further.
Example of formulations 1
Weigh 100 grams of ring bromine insect amides, 50 grams of imidacloprids, 50 grams of agriculture breasts 500#, 40 grams of agriculture breasts 400#, 50 grams of agriculture breasts 600#, 300
Gram dimethylformamide, dimethylbenzene adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and stirring and dissolving is obtained 15% ring completely afterwards
Bromine insect amide imidacloprid cream.
Example of formulations 2
Weigh 40 grams of ring bromine insect amides, 120 grams of Acetamiprids, 30 grams of agriculture breasts 500#, 50 grams of TX-10,50 grams of agriculture breasts 1601#, 100 grams
Ethyl acetate, biodiesel adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and stirring and dissolving is obtained 16% ring bromine worm completely afterwards
Amide acetamiprid EC.
Example of formulations 3
Weigh 100 grams of ring bromine insect amides, 50 grams of Nitenpyrams, 50 grams of agriculture breasts 500#, 32 grams of TX-10,45 grams of agriculture breasts 1601#, 100
Gram ethyl acetate, biodiesel adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and stirring and dissolving is obtained 15% ring bromine completely afterwards
Insect amide Nitenpyram cream.
Example of formulations 4
Weigh 60 grams of ring bromine insect amides, 140 grams of Diaclodens, 2201,30 grams of phenethyl phenol polyoxyethylene groups ether phosphoric acids of 40 grams of agriculture breasts
Ester, 30 grams of sodium lignin sulfonates, 30 grams of bentonite, 15 grams of xanthan gum, 40 grams of carbamide, 12 grams of benzoic acid, 10 grams of organosilicon froth breakings
Agent（Trade name：S-29 Nanjing "four news" (new ideas applied chemistry product company produces）, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials warp
Mixing, high speed shear disperses 30min, with 20% ring bromine insect amide Diacloden suspending agent is obtained after sand mill sand milling.
Example of formulations 5
Weigh 80 grams of ring bromine insect amides, 120 grams of thiacloprids, 50 grams of TERSPERSE2020（Huntsman Corporation of the U.S. produces）, 20 grams
Agriculture breast 1601#, 15 grams of sodium naphthalene sulfonates, 10 grams of aluminium-magnesium silicates, 10 grams of aluminium-magnesium silicates, 10 grams of ethylene glycol, 10 grams of benzoic acid, 8 grams have
Machine silicon defoaming agent（Trade name：S-29 Nanjing "four news" (new ideas applied chemistry product company produces）, 8 grams of epoxychloropropane, deionized water adds to
1000 gram weight parts.Above-mentioned raw materials are blended, and high speed shear disperses 30min, with making 20% ring bromine insect amide after sand mill sand milling
Thiacloprid suspending agent.
Example of formulations 6
Weigh 140 grams of ring bromine insect amides, 80 grams of clothianidins, 30 grams of TERSPERSE2020（Huntsman Corporation of the U.S. produces）, 30 grams
Agriculture breast 1601#, 12 grams of sodium naphthalene sulfonates, 20 grams of aluminium-magnesium silicates, 10 grams of aluminium-magnesium silicates, 15 grams of ethylene glycol, 10 grams of benzoic acid, 5 grams have
Machine silicon defoaming agent s-29（Nanjing "four news" (new ideas applied chemistry product company produces）, 10 grams of epoxychloropropane, deionized water adds to 1000 grams
Weight portion.Above-mentioned raw materials are blended, and high speed shear disperses 30min, with 22% ring bromine insect amide thiophene worm is obtained after sand mill sand milling
Amine suspending agent.
Example of formulations 7
Weigh 200 grams of ring bromine insect amides, 50 grams of MTI-446,50 grams of alkylphenol-polyethenoxy base ether sulfonic acid calcium, 30 grams of alkylnaphthalene sulphurs
Hydrochlorate formaldehyde condensation products, 30 grams of Negels, Pulvis Talci fills up to 1000 grams of weight portion.Above-mentioned raw materials are blended, super
Tiny pore is pulverized, hybrid technique step is prepared into 25% ring bromine insect amide MTI-446 wettable powder.
Example of formulations 8
Weigh 250 grams of ring bromine insect amides, 150 grams of imidacloprids, 40 grams of calcium lignosulfonates, 50 grams of alkyl naphthalene formaldehyde condensation substance sulfonic acid
Sodium, 30 grams of sodium alkyl sulfonates, potter's clay fills up to 1000 grams of weight portion.Above-mentioned raw materials are blended, ultra micro comminution by gas stream, mixing work
Skill step is prepared into 40% ring bromine insect amide imidacloprid wettable powder.
Example of formulations 9
Weigh 250 grams of ring bromine insect amides, 150 grams of Acetamiprids, 50 grams of alkyl naphthalene formaldehyde condensation substance sodium sulfonates, 30 grams of polycarboxylic acids sodium,
28 grams of sodium lauryl sulphates, attapulgite fills up to 1000 grams of weight portion.Above-mentioned raw materials are blended, ultra micro comminution by gas stream,
Hybrid technique step is prepared into 40% ring bromine insect amide acetamiprid wettable powder.
Example of formulations 10
Weigh 300 grams of ring bromine insect amides, 100 grams of Nitenpyrams, 40 grams of GY-D06（Polycarboxylate, Huntsman Corporation of the U.S. goes out
Product）, 20 grams of sodium lignin sulfonate, 30 grams of sodium lauryl sulphates, 30 grams of alkylsulfonate sodium, Pulvis Talci adds to 1000 gram weight
Part.The frequent regulation of above-mentioned raw materials fetch water dispersible granule method mix, ultra micro comminution by gas stream, mixing, granulation step produce 40%
Ring bromine insect amide Nitenpyram water dispersible granules.
Example of formulations 11
Weigh 120 grams of ring bromine insect amides, 40 grams of Diaclodens, 25 grams of GY-D06,20 grams of sodium lignin sulfonates, 20 grams of Nekal BXs
（Nekal）, 20 grams of K-12（Sodium lauryl sulphate）, fine particle calcium carbonate adds to 1000 gram weight parts.Above-mentioned raw materials are through routine
The method producing water dispersible granules mixes, ultra micro comminution by gas stream, mixing, granulation step produce 16% ring bromine insect amide thiophene worm
Piperazine water dispersible granules.
Example of formulations 12
Weigh 160 grams of ring bromine insect amides, 60 grams of thiacloprids, 15 grams of GY-D06,20 grams of sodium lignin sulfonates, 20 grams of Nekal BXs
（Nekal）, 15 grams of K-12（Sodium lauryl sulphate）, fine particle calcium carbonate adds to 1000 gram weight parts.Above-mentioned raw materials are through routine
The method producing water dispersible granules mixes, ultra micro comminution by gas stream, mixing, granulation step produce 22% ring bromine insect amide thiophene worm
Quinoline water dispersible granules.
Example of formulations 13
Weigh 60 grams of ring bromine insect amides, 40 grams of clothianidins, 25 grams of this disk -60#, 20 grams of triphenoethyl benzene phenol polyethenoxy ether phosphoric acids
Ester, 25 grams of Tween-60 #, 30 grams of Nongru-700 #, 40 grams of glycerol, 80 grams of solvent naphtha S-200,40 grams of toluene, 3 grams of bentonite, 4 grams
Sodium benzoate, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and high speed shearing emulsification is obtained 10% ring bromine worm acyl
Amine clothianidin aqueous emulsion.
Example of formulations 14
Weigh 80 grams of ring bromine insect amides, 60 grams of MTI-446,50 grams of Nonyl phenos（EO=10）Ether phosphate, 10 grams of agriculture breasts
700#, 1601,30 grams of Tween-60 # of 20 grams of agriculture breasts, 15 grams of epoxy soybean oils, 25 grams of glycerol, 30 grams of Ketohexamethylene, 5 grams of bentonite, 3
Gram sodium benzoate, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and high speed shearing emulsification is obtained 14% ring bromine worm
Amide MTI-446 aqueous emulsion.
Example of formulations 15
Weigh 120 grams of ring bromine insect amides, 80 grams of imidacloprids, 50 grams of Nonyl phenos（EO=10）Ether phosphate, 30 grams of agriculture breasts
700#, 1601,15 grams of Tween-60 # of 30 grams of agriculture breasts, 10 grams of epoxy soybean oils, 20 grams of glycerol, 40 grams of Ketohexamethylene, 5 grams of bentonite, 5
Gram sodium benzoate, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and high speed shearing emulsification is obtained 20% ring bromine worm
Amide imidacloprid aqueous emulsion.
Example of formulations 16
Weigh 100 grams of ring bromine insect amides, 60 grams of Acetamiprids, 1601,40 grams of agriculture breasts 500# of 30 grams of agriculture breasts, 30 grams of agriculture breasts 400#, 40
Gram toluene, 150 grams of Ketohexamethylene, 40 grams of isopropanols, 12 grams of triphenyl phosphites, through dissolving completely and mix homogeneously, deionized water
Add to 1000 gram weight parts, 16% ring bromine insect amide acetamiprid micro emulsion agent after stirring, is obtained.
Example of formulations 17
Weigh 60 grams of ring bromine insect amides, 80 grams of Nitenpyrams, 2201,30 grams of this disk-60# of 40 grams of agriculture breasts, 40 grams of polysorbate60-#, 80
Gram N-Methyl pyrrolidone, 150 grams of Ketohexamethylene, 30 grams of n-butyl alcohol, 20 grams of epoxychloropropane, through dissolving completely and mix homogeneously,
Deionized water adds to 1000 gram weight parts, and 14% ring bromine insect amide Nitenpyram microemulsion is obtained after stirring.
Example of formulations 18
Weigh 80 grams of ring bromine insect amides, 40 grams of Diaclodens, 2201,40 grams of this disk-60# of 60 grams of agriculture breasts, 50 grams of polysorbate60-#, 80 grams
N-Methyl pyrrolidone, 100 grams of Ketohexamethylene, 60 grams of n-butyl alcohol, 15 grams of epoxychloropropane, through the complete simultaneously mix homogeneously of dissolving, go
Ionized water adds to 1000 gram weight parts, and 12% ring bromine insect amide thiamethoxam micro-emulsion is obtained after stirring.
Example of formulations 19
Weigh 30 grams of ring bromine insect amides, 50 grams of thiacloprids, 50 grams of glycerol, 60 grams of agriculture breasts 2201#, 20 grams of bentonite, 20 grams of butanol,
Deionized water fills up to 1000 grams of weight portion.8% ring bromine insect amide is obtained after the blended stirring of above-mentioned raw materials, polyreaction
Thiacloprid microcapsule.
Example of formulations 20
Weigh 50 grams of ring bromine insect amides, 20 grams of clothianidins, 40 grams of ethylene glycol, 60 grams of Tween-60 #, 20 grams of aluminium-magnesium silicates, 20 grams of silicon
Oil, deionized water fills up to 1000 grams of weight portion.7% ring bromine worm acyl is obtained after the blended stirring of above-mentioned raw materials, polyreaction
Amine clothianidin microcapsule.
Example of formulations 21
Weigh 70 grams of ring bromine insect amides, 30 grams of MTI-446,60 grams of propylene glycol, 80 grams of agriculture breasts 600#, 15 grams of white carbons, 20 grams pungent
Alcohol, deionized water fills up to 1000 grams of weight portion.10% ring bromine worm acyl is obtained after the blended stirring of above-mentioned raw materials, polyreaction
Amine MTI-446 microcapsule.
Example of formulations 22
Weigh 20 grams of ring bromine insect amides, 10 grams of imidacloprids, 40 grams of Negels, 40 grams of sodium alkyl sulfonates, 40 grams of polyethylene
Ketopyrrolidine, Calcium Carbonate adds to 1000 gram weight parts.Above-mentioned raw materials mix homogeneously in mixed cylinder, through extruding, pelletize, does
Dry, and screened step is obtained 3% ring bromine insect amide imidacloprid granule.
Example of formulations 23
Weigh 10 grams of ring bromine insect amides, 30 grams of Acetamiprids, 50 grams of polycarboxylic acids sodium, 40 grams of sodium naphthalene sulfonates, 25 grams of polyvinyl alcohol, Talcum
Powder adds to 1000 gram weight parts.Above-mentioned raw materials mix homogeneously in mixed cylinder, through extruding, pelletize, drying, and screened step
4% ring bromine insect amide Acetamiprid granule is obtained.
Example of formulations 24
Weigh 30 grams of ring bromine insect amides, 20 grams of Nitenpyrams, 30 grams of polycarboxylic acids sodium, 50 grams of sodium naphthalene sulfonates, 30 grams of polyvinyl alcohol, carbon
Sour calcium adds to 1000 gram weight parts.Above-mentioned raw materials mix homogeneously in mixed cylinder, through extruding, pelletize, drying, and screened step
Suddenly 5% ring bromine insect amide Nitenpyram granule is obtained.
Example of formulations 25
Weigh 50 grams of ring bromine insect amides, 50 grams of Diaclodens, 50 grams of agriculture breasts 1601#, deionized water adds to 1000 gram weight parts.Above-mentioned
Raw material is blended, and stirring and dissolving is obtained 10% ring bromine insect amide Diacloden water preparation completely afterwards.
Example of formulations 26
Weigh 80 grams of ring bromine insect amides, 40 grams of thiacloprids, 30 grams of agriculture breasts 2201#, 40 grams of Nongru-700 #, deionized water adds to 1000
Gram weight part.Above-mentioned raw materials are blended, and stirring and dissolving is obtained 12% ring bromine insect amide thiacloprid water preparation completely afterwards.
Example of formulations 27
Weigh 120 grams of ring bromine insect amides, 30 grams of clothianidins, 40 grams of sorbitan monostearates, deionized water adds to 1000 grams
Weight portion.Above-mentioned raw materials are blended, and stirring and dissolving is obtained 14% ring bromine insect amide clothianidin water preparation completely afterwards.
Biological Examples 1：Preventing and treating planthopper field control effectiveness test.
Inventor has carried out example of formulations 1 in Junichiro Koizumi village of xiangtan, hunan province in 2015 county（15% ring bromine insect amide pyrrole worm
Quinoline cream）, example of formulations 9（40% ring bromine insect amide acetamiprid wettable powder）, example of formulations 17（14% ring bromine worm acyl
Amine Nitenpyram microemulsion）Preventing and treating planthopper field control effectiveness test, demonstrates this medicament to the prevention effect of planthopper and right
The safety of Oryza sativa L..
Trial crops are Oryza sativa L., and controlling object is planthopper, in the spraying of planthopper 2 age nymph occurance peak.Test field
Gesture is flat, and soil is sandy loam, middle fertility, and irrigation and drainage facilitate.Test medicine and dosage refer to table 5.Separately set blank, often locate
4 repetitions of reason, every cell 30, totally 32 cells, the random district's groups of cell arrange.
Carry out insect population investigation, investigation in 7 and 14 days after dispenser remains borer population of living before dispenser.Every cell adopts interlacing to jump
15 points of samplings of method, investigate 30 clumps altogether by 2 clumps every.Basin is clapped and is remained, after insect population and medicine, borer population of living before recording medicine, calculates larva dead
Rate of dying and prevention effect.
Planthopper field control effectiveness test result prevented and treated by table 5
Field control effectiveness test result shows, complex preparation preventive effect of 7 days after medicine has all exceeded 90%, and 14 days after medicine, single dose
Preventive effect is respectively 69.0%, 70.7%, 73.4% and 68.1%, ring bromine insect amide and imidacloprid, Acetamiprid, Nitenpyram is described respectively
After compounding in different ratios, the preventive effect of preparation is obvious apparently higher than the preventive effect of two single doses, potentiation.
Security survey, observes during test, and all reagent agents occur to paddy growth safety, no poisoning phenomenon.
Biological Examples 2：Preventing and treating yellow thrips field control effectiveness test.
Inventor has carried out example of formulations 4 in 2015 in Hainan Province Sanya precipice city（20% ring bromine insect amide thiophene
Worm piperazine suspending agent）Preventing and treating yellow thrips field control effectiveness test, demonstrates this medicament to the prevention effect of yellow thrips and to Fructus Benincasae chiehquae
Safety.
Trial crops are Fructus Benincasae chiehquae, and controlling object is yellow thrips, in the spraying of yellow thrips 2 age nymph occurance peak.Test
Field gesture is flat, and soil is sandy loam, middle fertility, and irrigation and drainage facilitate.Test medicine and dosage refer to table 6.Separately set blank,
Often process 4 repetitions, every cell 30, totally 16 cells, the random district's groups of cell arrange.
Every cell, in 20 leaves of the fixing selection in Fructus Benincasae chiehquae middle and upper part, carries out insect population investigation before dispenser, 5 days and 10 after dispenser
Its investigation residual borer population alive.Calculate larval mortality and prevention effect.
CK0：Borer population alive before blank district dispenser, unit is head；
CK1：Borer population alive after blank district dispenser, unit is head；
PT0：Borer population alive before chemicals treatment district dispenser, unit is head；
PT1：Borer population alive after chemicals treatment district dispenser, unit is head.
Yellow thrips field control effectiveness test result prevented and treated by table 6
Field control effectiveness test result shows, complex preparation preventive effect of 10 days after medicine has all exceeded 90%, and the preventive effect of two single doses
Be respectively 69.6% and 67.5%, illustrate ring bromine insect amide and Diacloden press respectively different ratios compounding after, the preventive effect of preparation is wanted
Apparently higher than the preventive effect of two single doses, potentiation is obvious.
Security survey, observes during test, and all reagent agents grow safety to Fructus Benincasae chiehquae, and no poisoning phenomenon occurs.
Example of formulations 12 and example of formulations 20, preventing and treating cabbage aphid table of field test results is bright, 10 days preventive effects after medicine
All reach more than 90% hence it is evident that being better than ring bromine insect amide, thiacloprid, the preventive effect 68.4%, 65.3% and 72.3% of clothianidin single dose.
Example of formulations 27, prevents and treats tea lesser leafhopper, table of field test results is bright, after medicine 10 days preventive effects all reach 90% with
Above hence it is evident that being better than the preventive effect 67.4% of clothianidin single dose.
From above example, ring bromine insect amide and nicotinic insecticide are according to weight than for 1:50～50:1 is carried out
Compounding, can be made into cream, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, microcapsule, granule, water
Agent, has significant preventing and treating effect to the Homopteras such as aphid, plant hopper, aleyrodid, thrips, tea lesser leafhopper, Semiptera, Thysanoptera
Really, potentiation substantially, reduces dosage and drug cost, and to crop safety, is preventing and treating Homoptera, Semiptera, tassel wing
Purpose favourable agents, therefore produce and have wide practical use.
In sum, the compositionss of the present invention are using two kinds of active components compound scheme, and its activity and insecticidal effect are not
It is the simple superposition of each composition activity, compared with existing unitary agent, in addition to there is obvious insecticidal effect, and have notable
Potentiation, cost accounting reduce, to crop safety, meet the security requirement of pesticidal preparations.
Claims (5)
1. a kind of Pesticidal combination containing ring bromine insect amide is it is characterised in that effective active composition is by the first active component ring
Bromine insect amide and the second active component nicotinic insecticide imidacloprid, Acetamiprid, Nitenpyram, Diacloden, thiacloprid, thiophene worm
One of amine, MTI-446 form, and the weight of the first active component and the second active component ratio is for 1:50～50:1, content sum
For described composition total weight 1%～80%.
2. according to claim 1 the Pesticidal combination containing ring bromine insect amide it is characterised in that the first active component and
Two active component weight are than for 1:30～30:1, content sum is the 5%～50% of described composition total weight.
3. according to claim 1 the Pesticidal combination containing ring bromine insect amide it is characterised in that described combination dosage form is
Cream, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, microcapsule, granule, water preparation.
4. the Pesticidal combination containing ring bromine insect amide does harm in preventing and treating Homoptera, Semiptera, Thysanoptera according to claim 1
Purposes on worm.
5. according to claim 5 the Pesticidal combination containing ring bromine insect amide anti-eliminate aphis, plant hopper, aleyrodid, thrips, tea
Purposes on smaller green leaf hopper.
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| CN201610818229.5A CN106386840A (en) | 2016-09-13 | 2016-09-13 | Insecticidal composition containing cyclaniliprole |
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| CN201610818229.5A CN106386840A (en) | 2016-09-13 | 2016-09-13 | Insecticidal composition containing cyclaniliprole |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107258793A (en) * | 2017-05-28 | 2017-10-20 | 陕西康禾立丰生物科技药业有限公司 | A kind of Pesticidal combination containing four Tolfenpyrads and anabasine |
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|---|---|---|---|---|
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN105454241A (en) * | 2014-08-29 | 2016-04-06 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
| CN105555777A (en) * | 2013-02-20 | 2016-05-04 | 巴斯夫欧洲公司 | Anthranilamide compounds, their mixtures and the use thereof as pesticides |
| WO2016091674A1 (en) * | 2014-12-12 | 2016-06-16 | Basf Se | Use of cyclaniliprole on cultivated plants |
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2016
- 2016-09-13 CN CN201610818229.5A patent/CN106386840A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101557710A (en) * | 2006-12-14 | 2009-10-14 | 石原产业株式会社 | Pesticidal compositions |
| CN105555777A (en) * | 2013-02-20 | 2016-05-04 | 巴斯夫欧洲公司 | Anthranilamide compounds, their mixtures and the use thereof as pesticides |
| CN105454241A (en) * | 2014-08-29 | 2016-04-06 | 深圳诺普信农化股份有限公司 | Insecticidal composition |
| WO2016091674A1 (en) * | 2014-12-12 | 2016-06-16 | Basf Se | Use of cyclaniliprole on cultivated plants |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107258793A (en) * | 2017-05-28 | 2017-10-20 | 陕西康禾立丰生物科技药业有限公司 | A kind of Pesticidal combination containing four Tolfenpyrads and anabasine |
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