CN105801086A - Iron-imitating chinaware made of waste grey bricks and preparing method thereof - Google Patents
Iron-imitating chinaware made of waste grey bricks and preparing method thereof Download PDFInfo
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C04B33/24—Manufacture of porcelain or white ware
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
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- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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Abstract
The invention relates to the technical field of ceramics, in particular to an iron-imitating chinaware made of waste grey bricks and a preparing method thereof. A ceramic body of the iron-imitating chinaware made of the waste grey bricks is prepared from waste grey brick powder, fourth-class soil , low-temperature stone, pyrophyllite, ferric oxide, rutile and lapis lazuli, and glaze is prepared from feldspar, waste gray bricks, quartz, plant ash, ferric oxide, zirconium silicate, heavy calcium carbonate, cobaltous oxide and manganese dioxide. The surface of the iron-imitating chinaware is grayish brown close to that of forged ironware, and the glaze is smooth and fine, can refract colorful light spots under different lights, has rough and quaint art effects and can be directly used for producing daily or art ceramics; the problems that ceramic production cost is increased continuously and ceramic products are similar can be solved, and the iron-imitating chinaware is easy to popularize in ceramic production places, provides a new path for disposing building waste and meets the requirement of sustainable development.
Description
Technical field
The present invention relates to ceramic technology field, be specifically related to a kind of imitative ferrum porcelain utilizing discarded ash brick to prepare and preparation method thereof.
Background technology
Along with urban construction, long-living substantial amounts of waste and old construction material in removal overshoot, urban environment is not only exerted heavy pressures on by it, but also limit the sustainable development of urban economy and environment, the grey brick building a house or paving the way exactly that wherein quantity is maximum, existing ash brick cannot again again with, through direct landfill disposal after therefore generally broken.
21 century is the century of environmental protection, along with the enforcement of China's strategy of sustainable development, environmental conservation is had higher requirement, and is also the main development direction of ceramic industry environmental protection to the comprehensive regeneration of building waste.China is as Production of Ceramics state maximum in the world, if being fully utilized by building waste, not only can solve problem of resource waste, solving huge environmental crisis, it is also possible to realize society and economic sustainable development.In addition if able at the pottery being simultaneously manufactured high added value reducing Ceramic Material cost, be of great significance for having Production of Ceramics enterprise.
Summary of the invention
For overcoming deficiency of the prior art, the present invention provides a kind of imitative ironware pottery utilizing discarded ash brick to prepare and preparation technology.
For achieving the above object, the technical solution used in the present invention is as follows:
Utilize imitative ironware pottery prepared by discarded ash brick, it is characterised in that
The blank of described imitative ironware pottery is prepared from by the raw material of following weight portion: discarded ash brick powder 20-50 part, Fourth Shift's soil 20-30 part, low fire stons 10-20 part, pyrophillite 10-15 part, ferrum oxide 5-10 part, rutile 1-5 part, lazurite 1-5 part；
The glaze of described imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 30-40, discarded ash brick powder 10-30 part, quartz 10-20, plant ash 5-10, ferrum oxide 5-10, Zirconium orthosilicate. 5-10, dry powder 5-10, cobalt oxide 1-5, manganese dioxide 1-5.
Optimizing, the blank of imitative ironware pottery is prepared from by the raw material of following weight portion: discarded ash brick clay 30 parts, 28 parts of Fourth Shift's soil, low fire stons 15 parts, pyrophillite 12 parts, ferrum oxide 8 parts, rutile 4 parts, lazurite 3 parts.
Optimizing, the glaze of imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 33, discarded 16 parts of brick powder of ash, quartz 16, plant ash 5, ferrum oxide 7, Zirconium orthosilicate. 8, dry powder 8, cobalt oxide 3, manganese dioxide 4.
Optimizing, the blank of imitative ironware pottery is prepared from by the raw material of following weight portion: discarded 46 parts of brick powder of ash, 23 parts of Fourth Shift's soil, low fire stons 12 parts, pyrophillite 10 parts, ferrum oxide 6 parts, rutile 2 parts, lazurite 1 part.
Optimizing, the glaze of imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 30, discarded 28 parts of brick powder of ash, quartz 11, plant ash 8, ferrum oxide 5, Zirconium orthosilicate. 6, dry powder 6, cobalt oxide 5, manganese dioxide 1.
Optimizing, the blank of imitative ironware pottery is prepared from by the raw material of following weight portion: discarded 28 parts of brick powder of ash, 26 parts of Fourth Shift's soil, low fire stons 17 parts, pyrophillite 15 parts, ferrum oxide 6 parts, rutile 4 parts, lazurite 4 parts.
Optimizing, the glaze of imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 34, discarded 25 parts of brick powder of ash, quartz 11, plant ash 6, ferrum oxide 10, Zirconium orthosilicate. 5, dry powder 5, cobalt oxide 1, manganese dioxide 3.
Utilize the preparation technology discarding imitative ironware pottery prepared by ash brick, it is characterised in that using the imitative ironware pottery utilizing discarded grey brick to prepare described in above-mentioned any one, it specifically comprises the following steps that
Step 1, centralized collection discarded ash brick, discarded ash brick is cleaned, it is block standby to be broken into after drying；
Step 2, by bulk ash brick calcining, calcining heat is 500-800 DEG C；
Step 3, it is stand-by that the block ash brick after calcining is broken into discarded ash brick powder；
Step 4, uses the discarded ash brick powder prepared by step 3, and prepares blank and glaze respectively according to the weight portion preparation of imitative ironware ceramic batch and glaze；
Step 5, becomes base substrate by Slug preparing, direct glazing after body drying；
Step 6, furnace heating-up, reducing atmosphere burns till under being, firing temperature is 950-1200 DEG C；
Step 7, blow-on, obtain imitative ironware pottery after cooling.
Further, blank makes base substrate after filter-press dehydration, old, vacuum pugging, molding.
Further, glaze described in step 4 uses wet ball mill to make, wherein material: ball: water=1:2:0.7.
From the above-mentioned description of this invention, imitative ironware pottery prepared by utilization provided by the invention discarded ash brick, porcelain surface has the taupe close with forging ironware, and glaze paint is smooth, fine and smooth, the hot spot of colour can be reflected under different lights, there is rough, simple and unsophisticated artistic effect；The present invention is analyzed utilizing by the blue bricks that building removal is obtained, and obtains a kind of pottery realizing imitative ironware effect, and this kind of pottery is for being used directly for producing the daily or art pottery；The ceramic material of the present invention can recycle building waste, thus the problem solving the Production of Ceramics continuous height of cost fund, ceramic product homogeneity, easily promote producing the local of pottery, provide a new approach for solving construction waste, meet the requirement of sustainable development.
Detailed description of the invention
Below by way of detailed description of the invention, the invention will be further described.
For achieving the above object, the technical solution used in the present invention is as follows:
Utilizing imitative ironware pottery prepared by discarded ash brick, the blank of described imitative ironware pottery is prepared from by the raw material of following weight portion: discarded ash brick powder 20-50 part, Fourth Shift's soil 20-30 part, low fire stons 10-20 part, pyrophillite 10-15 part, ferrum oxide 5-10 part, rutile 1-5 part, lazurite 1-5 part；
The glaze of described imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 30-40, discarded ash brick powder 10-30 part, quartz 10-20, plant ash 5-10, ferrum oxide 5-10, Zirconium orthosilicate. 5-10, dry powder 5-10, cobalt oxide 1-5, manganese dioxide 1-5.
Specific embodiment one:
The blank of imitative ironware pottery is prepared from by the raw material of following weight portion: discarded ash brick clay 30 parts, 28 parts of Fourth Shift's soil, low fire stons 15 parts, pyrophillite 12 parts, ferrum oxide 8 parts, rutile 4 parts, lazurite 3 parts；
Glaze is prepared from by the raw material of following weight portion: Anhydrite 33, discarded 16 parts of brick powder of ash, quartz 16, plant ash 5, ferrum oxide 7, Zirconium orthosilicate. 8, dry powder 8, cobalt oxide 3, manganese dioxide 4.
Preparing the above-mentioned imitative ironware pottery utilizing discarded ash brick to prepare, its preparation technology specifically comprises the following steps that
Step 1, centralized collection discarded ash brick, discarded ash brick is cleaned, it is block standby to be broken into after drying；
Step 2, by bulk ash brick calcining, calcining heat is 700 DEG C；
Step 3, it is stand-by that the block ash brick after calcining is broken into discarded ash brick powder；
Step 4, use the discarded ash brick powder prepared by step 3, and prepare blank and glaze respectively according to the weight portion preparation of imitative ironware ceramic batch and glaze, blank makes base substrate after filter-press dehydration, old, vacuum pugging, molding, glaze uses wet ball mill to make, wherein material: ball: water=1:2:0.7；
Step 5, becomes base substrate by Slug preparing, direct glazing after body drying；
Step 6, furnace heating-up, reducing atmosphere burns till under being, firing temperature is 1000 DEG C；
Step 7, blow-on, obtain imitative ironware pottery after cooling.
Specific embodiment two:
The blank of imitative ironware pottery is prepared from by the raw material of following weight portion: discarded 46 parts of brick powder of ash, 23 parts of Fourth Shift's soil, low fire stons 12 parts, pyrophillite 10 parts, ferrum oxide 6 parts, rutile 2 parts, lazurite 1 part；
The glaze of imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 30, discarded 28 parts of brick powder of ash, quartz 11, plant ash 8, ferrum oxide 5, Zirconium orthosilicate. 6, dry powder 6, cobalt oxide 5, manganese dioxide 1.
Preparing the above-mentioned imitative ironware pottery utilizing discarded ash brick to prepare, its preparation technology specifically comprises the following steps that
Step 1, centralized collection discarded ash brick, discarded ash brick is cleaned, it is block standby to be broken into after drying；
Step 2, by bulk ash brick calcining, calcining heat is 750 DEG C；
Step 3, it is stand-by that the block ash brick after calcining is broken into discarded ash brick powder；
Step 4, use the discarded ash brick powder prepared by step 3, and prepare blank and glaze respectively according to the weight portion preparation of imitative ironware ceramic batch and glaze, blank makes base substrate after filter-press dehydration, old, vacuum pugging, molding, glaze uses wet ball mill to make, wherein material: ball: water=1:2:0.7；
Step 5, becomes base substrate by Slug preparing, direct glazing after body drying；
Step 6, furnace heating-up, reducing atmosphere burns till under being, firing temperature is 1100 DEG C；
Step 7, blow-on, obtain imitative ironware pottery after cooling.
Specific embodiment three:
The blank of imitative ironware pottery is prepared from by the raw material of following weight portion: discarded 28 parts of brick powder of ash, 26 parts of Fourth Shift's soil, low fire stons 17 parts, pyrophillite 15 parts, ferrum oxide 6 parts, rutile 4 parts, lazurite 4 parts；
The glaze of imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 34, discarded 25 parts of brick powder of ash, quartz 11, plant ash 6, ferrum oxide 10, Zirconium orthosilicate. 5, dry powder 5, cobalt oxide 1, manganese dioxide 3.
Preparing the above-mentioned imitative ironware pottery utilizing discarded ash brick to prepare, its preparation technology specifically comprises the following steps that
Step 1, centralized collection discarded ash brick, discarded ash brick is cleaned, it is block standby to be broken into after drying；
Step 2, by bulk ash brick calcining, calcining heat is 650 DEG C；
Step 3, it is stand-by that the block ash brick after calcining is broken into discarded ash brick powder；
Step 4, use the discarded ash brick powder prepared by step 3, and prepare blank and glaze respectively according to the weight portion preparation of imitative ironware ceramic batch and glaze, blank makes base substrate after filter-press dehydration, old, vacuum pugging, molding, glaze uses wet ball mill to make, wherein material: ball: water=1:2:0.7；
Step 5, becomes base substrate by Slug preparing, direct glazing after body drying；
Step 6, furnace heating-up, reducing atmosphere burns till under being, firing temperature is 980 DEG C；
Step 7, blow-on, obtain imitative ironware pottery after cooling.
Making the imitative ironware pottery utilizing discarded ash brick to prepare prepared in aforementioned manners, porcelain surface has the taupe close with forging ironware, and glaze paint is smooth, fine and smooth, can reflect the hot spot of colour, have rough, simple and unsophisticated artistic effect under different lights；The present invention is analyzed utilizing by the blue bricks that building removal is obtained, and obtains a kind of pottery realizing imitative ironware effect, and this kind of pottery is for being used directly for producing the daily or art pottery；The ceramic material of the present invention can recycle building waste, thus the problem solving the Production of Ceramics continuous height of cost fund, ceramic product homogeneity, easily promote producing the local of pottery, provide a new approach for solving construction waste, meet the requirement of sustainable development.
Above are only some detailed description of the invention of the present invention, but the design concept of the present invention is not limited thereto, all changes utilizing this design that the present invention carries out unsubstantiality, the behavior invading scope all should be belonged to.
Claims (10)
1. utilize imitative ironware pottery prepared by discarded ash brick, it is characterised in that
The blank of described imitative ironware pottery is prepared from by the raw material of following weight portion: discarded ash brick powder 20-50 part, Fourth Shift's soil 20-30 part, low fire stons 10-20 part, pyrophillite 10-15 part, ferrum oxide 5-10 part, rutile 1-5 part, lazurite 1-5 part；
The glaze of described imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 30-40, discarded ash brick powder 10-30 part, quartz 10-20, plant ash 5-10, ferrum oxide 5-10, Zirconium orthosilicate. 5-10, dry powder 5-10, cobalt oxide 1-5, manganese dioxide 1-5.
2. the imitative ironware pottery that prepared by utilization according to claim 1 discarded ash brick, it is characterized in that, the blank of described imitative ironware pottery is prepared from by the raw material of following weight portion: discarded ash brick clay 30 parts, 28 parts of Fourth Shift's soil, low fire stons 15 parts, pyrophillite 12 parts, ferrum oxide 8 parts, rutile 4 parts, lazurite 3 parts.
3. the imitative ironware pottery that prepared by utilization according to claim 1 and 2 discarded ash brick, it is characterized in that, the glaze of described imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 33, discarded 16 parts of brick powder of ash, quartz 16, plant ash 5, ferrum oxide 7, Zirconium orthosilicate. 8, dry powder 8, cobalt oxide 3, manganese dioxide 4.
4. the imitative ironware pottery that prepared by utilization according to claim 1 discarded ash brick, it is characterized in that, the blank of described imitative ironware pottery is prepared from by the raw material of following weight portion: discarded 46 parts of brick powder of ash, 23 parts of Fourth Shift's soil, low fire stons 12 parts, pyrophillite 10 parts, ferrum oxide 6 parts, rutile 2 parts, lazurite 1 part.
5. utilizing according to claim 1 or 4 discards imitative ironware pottery prepared by ash brick, it is characterized in that, the glaze of described imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 30, discarded 28 parts of brick powder of ash, quartz 11, plant ash 8, ferrum oxide 5, Zirconium orthosilicate. 6, dry powder 6, cobalt oxide 5, manganese dioxide 1.
6. the imitative ironware pottery that prepared by utilization according to claim 1 discarded ash brick, it is characterized in that, the blank of described imitative ironware pottery is prepared from by the raw material of following weight portion: discarded 28 parts of brick powder of ash, 26 parts of Fourth Shift's soil, low fire stons 17 parts, pyrophillite 15 parts, ferrum oxide 6 parts, rutile 4 parts, lazurite 4 parts.
7. utilizing according to claim 1 or 6 discards imitative ironware pottery prepared by ash brick, it is characterized in that, the glaze of described imitative ironware pottery is prepared from by the raw material of following weight portion: Anhydrite 34, discarded 25 parts of brick powder of ash, quartz 11, plant ash 6, ferrum oxide 10, Zirconium orthosilicate. 5, dry powder 5, cobalt oxide 1, manganese dioxide 3.
8. utilize the preparation technology discarding imitative ironware pottery prepared by ash brick, it is characterised in that using utilizing described in any one in the claims 1-7 to discard imitative ironware pottery prepared by ash brick, it specifically comprises the following steps that
Step 1, centralized collection discarded ash brick, discarded ash brick is cleaned, it is block standby to be broken into after drying；
Step 2, by bulk ash brick calcining, calcining heat is 500-800 DEG C；
Step 3, it is stand-by that the block ash brick after calcining is broken into discarded ash brick powder；
Step 4, uses the discarded ash brick powder prepared by step 3, and prepares blank and glaze respectively according to the weight portion preparation of imitative ironware ceramic batch and glaze；
Step 5, becomes base substrate by Slug preparing, direct glazing after body drying；
Step 6, furnace heating-up, reducing atmosphere burns till under being, firing temperature is 950-1200 DEG C；
Step 7, blow-on, obtain imitative ironware pottery after cooling.
9. the preparation technology of the imitative ironware pottery that prepared by utilization according to claim 8 discarded ash brick, it is characterised in that: described blank makes base substrate after filter-press dehydration, old, vacuum pugging, molding.
10. the preparation technology of the imitative ironware pottery that prepared by utilization according to claim 8 discarded ash brick, it is characterised in that: glaze described in step 4 uses wet ball mill to make, wherein material: ball: water=1:2:0.7.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106747305A (en) * | 2016-12-06 | 2017-05-31 | 广州市科恩电脑有限公司 | A kind of construction waste recoverying and utilizing method |
| CN107840641A (en) * | 2017-11-07 | 2018-03-27 | 河南建筑材料研究设计院有限责任公司 | A kind of Art Stone made using mine tailing and waste residue |
| CN111978070A (en) * | 2020-09-02 | 2020-11-24 | 福建泉州顺美集团有限责任公司 | Environment-friendly ceramic prepared from Dehua stream sludge and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109290341B (en) * | 2018-10-11 | 2020-04-21 | 福建省德化县现代陶瓷有限公司 | Method for recycling waste ceramic |
| CN109231832B (en) * | 2018-11-20 | 2021-09-10 | 广西建设职业技术学院 | Glaze, glaze surface, decorative brick and manufacturing method thereof |
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| JPH10167806A (en) * | 1996-12-06 | 1998-06-23 | Matsuyama Kankyo Service:Kk | Ceramic using waste |
| CN103073263A (en) * | 2011-10-25 | 2013-05-01 | 况学成 | Method for manufacturing ceramic antique brick by using various solid wastes |
| CN103435331A (en) * | 2013-08-20 | 2013-12-11 | 澧县新鹏陶瓷有限公司 | Glazed tile produced by waste materials of red bricks, and producing method thereof |
| CN103951388A (en) * | 2014-04-23 | 2014-07-30 | 景德镇陶瓷学院 | Coal ash ceramic bottle and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106747305A (en) * | 2016-12-06 | 2017-05-31 | 广州市科恩电脑有限公司 | A kind of construction waste recoverying and utilizing method |
| CN107840641A (en) * | 2017-11-07 | 2018-03-27 | 河南建筑材料研究设计院有限责任公司 | A kind of Art Stone made using mine tailing and waste residue |
| CN107840641B (en) * | 2017-11-07 | 2020-10-27 | 河南建筑材料研究设计院有限责任公司 | Culture stone made of tailings and waste residues |
| CN111978070A (en) * | 2020-09-02 | 2020-11-24 | 福建泉州顺美集团有限责任公司 | Environment-friendly ceramic prepared from Dehua stream sludge and preparation method thereof |
Also Published As
| Publication number | Publication date |
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| CN108484111A (en) | 2018-09-04 |
| CN108484111B (en) | 2021-07-20 |
| CN105801086B (en) | 2018-04-24 |
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