CN101624282A - Formulation of recrystallized ceramic and manufacturing method thereof - Google Patents

Formulation of recrystallized ceramic and manufacturing method thereof Download PDF

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Publication number
CN101624282A
CN101624282A CN200810132835A CN200810132835A CN101624282A CN 101624282 A CN101624282 A CN 101624282A CN 200810132835 A CN200810132835 A CN 200810132835A CN 200810132835 A CN200810132835 A CN 200810132835A CN 101624282 A CN101624282 A CN 101624282A
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ceramic
carry out
recrystallized ceramic
formulation
recrystallized
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王文祥
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Tangshan Taiming Industry Co Ltd
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Tangshan Taiming Industry Co Ltd
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Priority to CN200810132835A priority Critical patent/CN101624282A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to the field of ceramic processing, and particularly provides a formulation of recrystallized ceramic and a manufacturing method thereof. The formulation of the recrystallized ceramic comprises the following components: 98 to 0 percent of waste ceramic, 0 to 40 percent of quartz, 0 to 30 percent of feldspar, and 0 to 25 percent of kaolin. The formulation of the recrystallized ceramic and the manufacturing method thereof use non-degradable waste ceramic materials as raw materials to form a new ceramic material by designing, combining, matching and reprocessing so as to effectively utilize wastes, reduce the production cost, and protect the resource and environment with great social benefit.

Description

Formulation of recrystallized ceramic and manufacture method thereof
Technical field
The present invention relates to field of ceramic processing, formulation of recrystallized ceramic and manufacture method thereof specifically are provided.
Background technology
At present, show that according to the relevant data statistics China's ceramic yield ranks first in the world, account for the 40%-45% of the annual total amount in the world, wherein; Household china output is 200,000,000, sanitary china output is 1.4 hundred million, floor tile output is 400,000,000 square metres, the used raw material of Production of Ceramics mainly is that silicate minerals belongs to disposable resource, and Nonrenewable resources, and it is exhausted day by day that this just causes ceramic raw material to produce required high quality raw material, meanwhile ceramic enterprise produces owing to course of processing complexity, specially waste product will occur, about about 10%-15%, they not only occupy large stretch of the arable land, go back serious environment pollution.That drains the pond to get all the fish unordered mining exactly, has suddenly in sustainable development.For this reason, the also utilization that follows of waste old ceramics will be the optimal path that solves this type of problem.
Summary of the invention
The invention provides formulation of recrystallized ceramic and manufacture method thereof, it utilizes waste old ceramics to redesign proportioning combination processing, form new porcelain kind again, and the recrystallized ceramic material has effectively utilized nondegradable waste ceramic as raw material again.Reduce production cost, protected resource and environment.
The technical solution adopted for the present invention to solve the technical problems is:
Formulation of recrystallized ceramic comprises following each component:
Useless porcelain 98-0%, quartzy 0-40%, feldspar 0-30%, kaolin 0-25%.
The ratio of described useless porcelain is 98--60%.
Also comprise following composition in the described prescription:
Stablizer 0-12%, ionogen 0.1-0.8%.
Also comprise following composition in the described prescription:
Clay 0-60%, dispersion agent 0.1-1.2%.
Also comprise following composition in the described prescription:
Clay 40-60%, wedding agent 0-25%.
Also comprise following composition in the described prescription:
Clay 0-60%, stablizer 0-12%, dispersion agent 0-1.2%, binding agent 0-5%.
The manufacture method of recrystallized ceramic may further comprise the steps:
A, become body in small, broken bits and other raw material to put in storage respectively the selected post-treatment of waste old ceramics;
B, with the above-mentioned raw materials weigh batching, after wet ball grinding reaches fineness requirement, sieve, deironing, old, stir after, be sent to moulding slip casting;
C, with above-mentioned molded blank product through repairing the blue or green base of blue or green base, check, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
The manufacture method of recrystallized ceramic may further comprise the steps:
A, become body in small, broken bits and other raw material to put in storage respectively the selected post-treatment of waste old ceramics;
B, with the above-mentioned raw materials weigh batching, after wet ball grinding reaches fineness requirement, sieve, after the deironing, mist projection granulating, be sent to the moulding pressed compact;
C, with above-mentioned molded blank product through repairing blue or green base, check blue or green base, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
The manufacture method of recrystallized ceramic may further comprise the steps:
A, waste old ceramics is selected, dry method is in small, broken bits, sieve, put in storage respectively with other raw material after the deironing;
B, with above-mentioned raw materials and water weigh batching, rub through mixing and to carry out vacuum pugging after practicing, old after, carry out the secondary vacuum pugging, be sent to the moulding base after being extruded into the mud section;
C, with above-mentioned molded blank product through repairing blue or green base, check blue or green base, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
The manufacture method of recrystallized ceramic may further comprise the steps:
A, with waste old ceramics selected after, in small, broken bits through dry method, sieve, carry out after the deironing ceramics powder oven dry;
B, above-mentioned powder and oleic acid, paraffin, stearic acid are put in storage respectively;
C, with the above-mentioned raw materials weigh batching, after stirring heating, carry out hot-injection molding;
D, with above-mentioned molded blank product through repairing blue or green base, burn till after the dewaxing and repair bique, carry out loading of kiln after the glaze spraying;
E, with above-mentioned work in-process behind twice firing, make pottery, carry out porcelain inspection, form qualified product.
The firing temperature of recrystallized ceramic is 350 ℃-1600 ℃.
The firing atmosphere of recrystallized ceramic adopts oxydizing flame to burn till or reducing flame burns till.
The present invention makes it nondegradable waste old ceramics and has obtained recycling again, has reduced production cost, and the performance of enterprises is obvious, and social benefit is huge, has protected resource and environment, for the circulation science Sustainable development of ceramic enterprise opens up a new way.
The present invention is to be main material with the waste old ceramics, and having broken in the traditional ceramics production technique with quartz, feldspar, clay is the design concept of main raw material;
In the technical process, the waste old ceramics (98--0%) of prescription non-plastic raw material adds, and has satisfied the processing requirement of the production pottery of slip casting method moulding, plastic making, pressing moulding, the moulding of hot pouring method etc. through the working method innovation;
The product quality in kind has reached national domestic ceramics GB/T3532--1999 standard and snitaryware GB6952--2005 standard after testing.
Use waste old ceramics, greatly reduce production cost.The business economic remarkable benefit;
Use nondegradable waste old ceramics, protected resource and environment; Social benefit is huge;
Embodiment
Below in conjunction with specific embodiment formulation of recrystallized ceramic of the present invention and manufacture method thereof are described further.
Embodiment 1:
Formulation of recrystallized ceramic comprises following each component:
Waste old ceramics 98-60%, quartzy 0-20%, feldspar 0-20%, stablizer 0-12%, kaolin 0-15%, ionogen 0.1-0.8%.
Adopt the slip casting method moulding, its technology is as follows:
A, become body in small, broken bits and other raw material to put in storage respectively the selected post-treatment of waste old ceramics;
B, with the above-mentioned raw materials weigh batching, after wet ball grinding reaches fineness requirement, sieve, deironing, old, stir after, be sent to moulding slip casting;
C, with above-mentioned molded blank product through repairing the blue or green base of blue or green base, check, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
Embodiment 2:
Formulation of recrystallized ceramic comprises following each component:
Waste old ceramics 98-60%, quartzy 0-20%, feldspar 0-20%, clay 0-60%, kaolin 0-15%, dispersion agent 0.1-1.2%.
Adopt the pressing moulding, its technology is as follows:
A, become body in small, broken bits and other raw material to put in storage respectively the selected post-treatment of waste old ceramics;
B, with the above-mentioned raw materials weigh batching, after wet ball grinding reaches fineness requirement, sieve, after the deironing, mist projection granulating, be sent to the moulding pressed compact;
C, with above-mentioned molded blank product through repairing blue or green base, check blue or green base, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
Embodiment 3:
Formulation of recrystallized ceramic comprises following each component:
Waste old ceramics 98-60%, quartzy 0-20%, feldspar 0-20%, clay 40-60%, kaolin 0-15%, wedding agent 0-25%.
Adopt plastic making, its technological process is as follows:
A, waste old ceramics is selected, dry method is in small, broken bits, sieve, put in storage respectively with other raw material after the deironing;
B, with above-mentioned raw materials and water weigh batching, rub through mixing and to carry out vacuum pugging after practicing, old after, carry out the secondary vacuum pugging, be sent to the moulding base after being extruded into the mud section;
C, with above-mentioned molded blank product through repairing blue or green base, check blue or green base, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
Embodiment 4:
Formulation of recrystallized ceramic comprises following each component:
Waste old ceramics 98-60%, quartzy 0-40%, feldspar 0-30%, clay 0-60%, kaolin 0-25%, stablizer 0-12%, dispersion agent 0-1.2%, binding agent 0-5%.
Adopt the moulding of hot pouring method, its technological process is as follows:
A, with waste old ceramics selected after, in small, broken bits through dry method, sieve, carry out after the deironing ceramics powder oven dry;
B, above-mentioned powder and oleic acid, paraffin, stearic acid are put in storage respectively;
C, with the above-mentioned raw materials weigh batching, after stirring heating, carry out hot-injection molding;
D, with above-mentioned molded blank product through repairing blue or green base, burn till after the dewaxing and repair bique, carry out loading of kiln after the glaze spraying;
E, with above-mentioned work in-process behind twice firing, make pottery, carry out porcelain inspection, form qualified product.
Recrystallized ceramic subject range; Its development relates to and is applicable to that with aluminium silicate mineral or some oxide compound etc. be main raw material, according to people's intention at high temperature by specific production technique, all kinds of ceramic enterprise of rock-like goods-pottery of making in the calcining of certain temperature and atmosphere with definite shape, will occur not meeting industrial waste products (waste old ceramics) such as grade standard, residual, inferior, waste product or old pottery in process of production is main raw material, by adding other raw materials, can cash the composition pottery arbitrarily and recycle.
Recrystallized ceramic is widely used in the production of all kinds of ceramic enterprises (pottery, stoneware, porcelain, architectural ceramics, sanitary china, floor tile etc.).Simultaneously, also can different porcelain kinds gather according to the conventional ceramic blank conversion K 2O-AI 2O 3-SiO 2System's household china phasor utilizes algebraic method or diagram method to calculate the design technology parameter that will reach.Through processes, can cash batching mutually or each other arbitrarily and make pottery,
The innovation of recrystallized ceramic, having broken in the traditional ceramics production technique with clay is main plastic raw material, non-plastic raw material only accounts for a part and satisfies the moulding process requirement, be to be main raw material (can reach 98%) with poor material (waste old ceramics), the innovation complete processing satisfies the manufacturing of pottery, and quality in kind has reached national ceramic standard after testing.The performance of enterprises is obvious, and social benefit is huge, makes it nondegradable waste old ceramics and has obtained following again also use, has protected resource and environment, has opened up a new way for ceramic enterprise follows also science sustainable development.
Above-described embodiment, the present invention's embodiment more preferably just, the common variation that those skilled in the art carries out in the technical solution of the present invention scope and replace all should be included in protection scope of the present invention.

Claims (12)

1, formulation of recrystallized ceramic comprises following each component:
Waste old ceramics 98-0%, quartzy 0-40%, feldspar 0-30%, kaolin 0-25%.
2, formulation of recrystallized ceramic according to claim 1 is characterized in that, the ratio of described waste old ceramics is 98-60%.
3, formulation of recrystallized ceramic according to claim 2 is characterized in that, also comprises following composition in the described prescription:
Stablizer 0-12%, ionogen 0.1-0.8%.
4, formulation of recrystallized ceramic according to claim 2 is characterized in that, also comprises following composition in the described prescription:
Clay 0-60%, dispersion agent 0.1-1.2%.
5, formulation of recrystallized ceramic according to claim 2 is characterized in that, also comprises following composition in the described prescription:
Clay 40-60%, wedding agent 0-25%.
6, formulation of recrystallized ceramic according to claim 2 is characterized in that, also comprises following composition in the described prescription:
Clay 0-60%, stablizer 0-12%, dispersion agent 0-1.2%, binding agent 0-5%.
7, the manufacture method of recrystallized ceramic may further comprise the steps:
A, become body in small, broken bits and other raw material to put in storage respectively the selected post-treatment of waste old ceramics;
B, with the above-mentioned raw materials weigh batching, after wet ball grinding reaches fineness requirement, sieve, deironing, old, stir after, be sent to moulding slip casting;
C, with above-mentioned molded blank product through repairing the blue or green base of blue or green base, check, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
8, the manufacture method of recrystallized ceramic may further comprise the steps:
A, become body in small, broken bits and other raw material to put in storage respectively the selected post-treatment of waste old ceramics;
B, with the above-mentioned raw materials weigh batching, after wet ball grinding reaches fineness requirement, sieve, after the deironing, mist projection granulating, be sent to the moulding pressed compact;
C, with above-mentioned molded blank product through repairing blue or green base, check blue or green base, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
9, the manufacture method of recrystallized ceramic may further comprise the steps:
A, waste old ceramics is selected, dry method is in small, broken bits, sieve, put in storage respectively with other raw material after the deironing;
B, with above-mentioned raw materials and water weigh batching, rub through mixing and to carry out vacuum pugging after practicing, old after, carry out the secondary vacuum pugging, be sent to the moulding base after being extruded into the mud section;
C, with above-mentioned molded blank product through repairing blue or green base, check blue or green base, glazing, repair openpore, test loading of kiln behind the openpore;
D, above-mentioned work in-process are made pottery behind once-firing (or twice firing), carry out the porcelain inspection, form qualified product.
10, the manufacture method of recrystallized ceramic may further comprise the steps:
A, with waste old ceramics selected after, in small, broken bits through dry method, sieve, carry out after the deironing ceramics powder oven dry;
B, above-mentioned powder and oleic acid, paraffin, stearic acid are put in storage respectively;
C, with the above-mentioned raw materials weigh batching, after stirring heating, carry out hot-injection molding;
D, with above-mentioned molded blank product through repairing blue or green base, burn till after the dewaxing and repair bique, carry out loading of kiln after the glaze spraying;
E, with above-mentioned work in-process behind twice firing, make pottery, carry out porcelain inspection, form qualified product.
According to the manufacture method of any described recrystallized ceramic among the claim 7-10, it is characterized in that 11, the firing temperature of described recrystallized ceramic is 350 ℃-1600 ℃.
According to the manufacture method of any described recrystallized ceramic among the claim 7-10, it is characterized in that 12, the firing atmosphere of described recrystallized ceramic adopts oxydizing flame to burn till or reducing flame burns till.
CN200810132835A 2008-07-10 2008-07-10 Formulation of recrystallized ceramic and manufacturing method thereof Pending CN101624282A (en)

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Application Number Priority Date Filing Date Title
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102211946A (en) * 2011-03-10 2011-10-12 朱根源 Ceramic fiber honeycomb heat accumulator and manufacturing method thereof
CN102351508A (en) * 2011-06-10 2012-02-15 广东省枫溪陶瓷工业研究所 Production method for colorful ceramic permeable brick by using waste porcelain
CN104591689A (en) * 2015-02-02 2015-05-06 王占一 Method for producing recrystallized ceramic product by utilizing waste ceramic
CN104691211A (en) * 2015-02-20 2015-06-10 佛山市三水区希望火炬教育科技有限公司 Production method for wooden wheel vehicle-mounted ceramic artillery beverage bottle modeling
CN105777076A (en) * 2016-03-14 2016-07-20 景德镇市瓷海瓷业有限公司 Method for producing fine ceramic products with waste ceramic adopted as main material
CN106673437A (en) * 2017-02-06 2017-05-17 广东欣红陶瓷股份有限公司 Preparation method of high-hardness cracked glaze porcelain
CN107188536A (en) * 2017-07-03 2017-09-22 四川锦泓佳建筑装饰工程有限公司 A kind of use in toilet floor tile
CN107721435A (en) * 2017-10-12 2018-02-23 福建省德化臻南陶瓷有限公司 Ceramic made of waste old ceramics material and preparation method thereof
CN111116171A (en) * 2019-12-31 2020-05-08 泉州阳光创艺陶瓷股份有限公司 Antibacterial and mildew-proof ceramic artwork and preparation method thereof
CN115784755A (en) * 2022-11-24 2023-03-14 中国地质大学(北京) Method for preparing heat-resistant ramming mass by utilizing waste sanitary porcelain and waste silicon carbide deck

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102211946A (en) * 2011-03-10 2011-10-12 朱根源 Ceramic fiber honeycomb heat accumulator and manufacturing method thereof
CN102211946B (en) * 2011-03-10 2013-08-21 朱根源 Ceramic fiber honeycomb heat accumulator and manufacturing method thereof
CN102351508A (en) * 2011-06-10 2012-02-15 广东省枫溪陶瓷工业研究所 Production method for colorful ceramic permeable brick by using waste porcelain
CN102351508B (en) * 2011-06-10 2013-06-05 韩山师范学院 Production method for colorful ceramic permeable brick by using waste porcelain
CN104591689A (en) * 2015-02-02 2015-05-06 王占一 Method for producing recrystallized ceramic product by utilizing waste ceramic
CN104691211A (en) * 2015-02-20 2015-06-10 佛山市三水区希望火炬教育科技有限公司 Production method for wooden wheel vehicle-mounted ceramic artillery beverage bottle modeling
CN105777076A (en) * 2016-03-14 2016-07-20 景德镇市瓷海瓷业有限公司 Method for producing fine ceramic products with waste ceramic adopted as main material
CN105777076B (en) * 2016-03-14 2018-07-10 景德镇市瓷海瓷业有限公司 A kind of method that fine ceramics product is produced using waste ceramic as major ingredient
CN106673437A (en) * 2017-02-06 2017-05-17 广东欣红陶瓷股份有限公司 Preparation method of high-hardness cracked glaze porcelain
CN106673437B (en) * 2017-02-06 2019-01-22 广东欣红陶瓷股份有限公司 A kind of preparation method of high rigidity hacking glaze porcelain
CN107188536A (en) * 2017-07-03 2017-09-22 四川锦泓佳建筑装饰工程有限公司 A kind of use in toilet floor tile
CN107721435A (en) * 2017-10-12 2018-02-23 福建省德化臻南陶瓷有限公司 Ceramic made of waste old ceramics material and preparation method thereof
CN107721435B (en) * 2017-10-12 2020-11-24 福建省德化臻南陶瓷有限公司 Ceramic product made of waste ceramic material and manufacturing method thereof
CN111116171A (en) * 2019-12-31 2020-05-08 泉州阳光创艺陶瓷股份有限公司 Antibacterial and mildew-proof ceramic artwork and preparation method thereof
CN115784755A (en) * 2022-11-24 2023-03-14 中国地质大学(北京) Method for preparing heat-resistant ramming mass by utilizing waste sanitary porcelain and waste silicon carbide deck

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