CN103360031B - Raw material of Longquan celadon product preparation technology using celadon waste and method thereof - Google Patents
Raw material of Longquan celadon product preparation technology using celadon waste and method thereof Download PDFInfo
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- CN103360031B CN103360031B CN201310287167.6A CN201310287167A CN103360031B CN 103360031 B CN103360031 B CN 103360031B CN 201310287167 A CN201310287167 A CN 201310287167A CN 103360031 B CN103360031 B CN 103360031B
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- celadon
- waste material
- longquan
- longquan celadon
- glaze
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- 239000002699 waste material Substances 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 36
- 239000002994 raw material Substances 0.000 title claims abstract description 17
- 238000005516 engineering process Methods 0.000 title abstract description 7
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000002689 soil Substances 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 7
- 229910052573 porcelain Inorganic materials 0.000 claims description 7
- 239000010433 feldspar Substances 0.000 claims description 6
- 235000019362 perlite Nutrition 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- 235000015895 biscuits Nutrition 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000005245 sintering Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 238000010304 firing Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- 239000002002 slurry Substances 0.000 abstract description 2
- 230000003796 beauty Effects 0.000 abstract 1
- 238000011068 loading method Methods 0.000 description 9
- 239000000919 ceramic Substances 0.000 description 5
- 238000000280 densification Methods 0.000 description 3
- 235000011194 food seasoning agent Nutrition 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to the technical field of material science and aims at providing a raw material of a Longquan celadon product preparation technology using celadon waste and a method thereof. The raw material of a Longquan celadon product preparation technology using celadon waste comprises Longquan celadon blank and Longquan celadon glaze. The method for realizing Longquan celadon product preparation by use of the raw material comprises a step of high-temperature firing. According to the method provided by the invention, the whole preparation flow is simple, no special requirements are imposed on the technology, and the Longquan celadon waste can be processed in bulk without occupying land, thereby saving the raw material of Longquan celadon and reducing the preparation cost; through ultrafine processing, the liquidity, plasticity and body bonding strength of the waste-containing grouting slurry are improved; and by introducing the celadon waste, the characteristics (particularly beauty) of the celadon product are maintained.
Description
Technical field
The invention relates to materials science field, particularly utilize celadon waste material to prepare raw material and the method thereof of Longquan celadon product process.
Background technology
Longquan celadon is described as " flower of celadon ", and it is verdant sparkling and crystal-clear, moist as beautiful, on Chinese culture impact to dark.2009, Longquan celadon went through to list in " mankind's non-material cultural heritage masterpiece register ", and in 2010 World Expos, perfect eternal porcelain rhythm of deducing, poem draw the south of the River, and dragon's fountain industry celadon is worth just extensively for people just accept.But, Longquan celadon due to uniqueness raw material and burn technology for making, adopt twice firing, easily produce cracking, distortion, problem that apparent aesthetic feeling is not strong in process of production, large shaped celadon product qualification rate is only about 40%, causes a large amount of useless ceramics and useless blank.In addition, celadon Mineral resources are very rare, and this brings serious challenge to the Sustainable development of celadon.
The recycling of related ceramic waste material has some research reports, as Authorization Notice No. CN100548923C patent of invention relates to a kind of processing method utilizing ceramic polished waste residue or ceramic waste material to produce ultra-thin ceramic polished tile, but due to the singularity of Longquan celadon raw material and technique, there is not yet the open report that Longquan celadon waste recovery utilizes.
Summary of the invention
Main purpose of the present invention is to overcome deficiency of the prior art, provides the celadon waste material that utilizes that a kind of simple flow, cost are low, product performance are high to prepare raw material and the method thereof of Longquan celadon product process.For solving the problems of the technologies described above, solution of the present invention is:
The raw material utilizing celadon waste material to prepare Longquan celadon product process is provided, comprise Longquan celadon blank and Longquan celadon glaze, described Longquan celadon blank is according to weight percent meter, composed of the following components: porcelain stone 30 ~ 40%, Zijin soil 40 ~ 50%, perlite 8 ~ 12%, base substrate waste material 3 ~ 5%, burns till waste material 6 ~ 8%; Described Longquan celadon glaze is according to weight percent meter, composed of the following components: quartz 15 ~ 25%, feldspar 40 ~ 45%, Zijin soil 18 ~ 25%, Wingdale 10 ~ 15%, useless glaze 3 ~ 6%.
There is provided the raw material described in utilization to realize preparing the method for Longquan celadon goods, comprise high temperature and burn till, specifically comprise the following steps:
Steps A: will burn till waste material and carry out ultramicronising process, makes the granularity of burning till waste material between 0.5 ~ 2 μm;
Step B: the moiety of burning till waste material and other Longquan celadon blanks processed in steps A is loaded ball mill in proportion, after adding water, ball milling mixes, pouring out water after old becomes mud to do, then injection forming repaired biscuit again, work in-process are obtained after drying, again work in-process are loaded kiln, in 800 ~ 900 DEG C, carry out biscuiting;
Step C: each moiety of Longquan celadon glaze is loaded ball mill in proportion, adds 1wt% dispersion agent, pour out into glaze slip after ball milling;
Step D: carry out glazing to the work in-process of biscuiting in step B with the glaze slip obtained in step C, then loads kiln by after the work in-process drying after glazing, burns till, namely complete the making of Longquan celadon goods in reducing atmosphere with the high temperature of 1200 ~ 1250 DEG C.
In the present invention, the ultramicronising process in described steps A refers to: first roughly grind with high pressure roll mill, then carry out fine grinding with Ball-stirring mill.
Compared with prior art, the invention has the beneficial effects as follows:
1, whole manufacturing process is simple, and does not have special requirement to technique, can process in a large number and no longer land occupation, save Longquan celadon raw material usage quantity, reduce preparation cost Longquan celadon waste material;
2, by ultramicronising process, the bonding strength of the mobility of the slip casting slurry containing waste material, plasticity-and base substrate is improved;
3, the introducing of celadon waste material, maintains the characteristic of celadon product, particularly aesthetic property.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail:
Raw material for preparing Longquan celadon goods with celadon waste material comprises Longquan celadon blank and Longquan celadon glaze.
Longquan celadon blank is according to weight percent meter, composed of the following components: porcelain stone 30 ~ 40%, Zijin soil 40 ~ 50%, perlite 8 ~ 12%, and base substrate waste material 3 ~ 5% burns till waste material 6 ~ 8%.Described base substrate waste material refers to the waste material produced in celadon blank forming process.The described waste material that burns till refers in celadon sintering process because ftractureing, being out of shape the waste product produced.
Longquan celadon glaze is according to weight percent meter, composed of the following components: quartz 15 ~ 25%, feldspar 40 ~ 45%, Zijin soil 18 ~ 25%, Wingdale 10 ~ 15%, useless glaze 3 ~ 6%.Described useless glaze refers to the useless glaze that celadon glazing operation produces.
Utilize described raw material to realize preparing the method for Longquan celadon goods, concrete steps comprise:
Steps A: will burn till waste material and carry out ultramicronising process, makes the granularity of burning till waste material between 0.5 ~ 2 μm.Here ultramicronising process refers to: first roughly grind with high pressure roll mill, then carry out fine grinding with Ball-stirring mill.
Step B: the moiety of burning till waste material and other Longquan celadon blanks processed in steps A is loaded ball mill in proportion, after adding water, ball milling mixes, pouring out water after old becomes mud to do, then injection forming repaired biscuit again, work in-process are obtained after drying, again work in-process are loaded kiln, in 800 ~ 900 DEG C, carry out biscuiting.
Step C: each moiety of Longquan celadon glaze is loaded ball mill in proportion, adds 1wt% dispersion agent, pour out into glaze slip after ball milling.
Step D: carry out glazing to the work in-process of biscuiting in step B with the glaze slip obtained in step C, then loads kiln by after the work in-process drying after glazing, burns till, namely complete the making of Longquan celadon goods in reducing atmosphere with the high temperature of 1200 ~ 1250 DEG C.
The following examples can make professional and technical personnel's comprehend the present invention of this specialty, but do not limit the present invention in any way.Dispersion agent in embodiment adopts PEG1000.
Embodiment 1
Longquan celadon blank, according to weight percent meter, specifically consists of: porcelain stone 30%, Zijin soil 50%, perlite 8%, and base substrate waste material 5% burns till waste material 7%.Longquan celadon glaze, according to weight percent meter, specifically consists of: quartz 25%, feldspar 40%, Zijin soil 20%, Wingdale 10%, useless glaze 5%.
Making processes is: first will burn till waste material and use high pressure roll-in mill grinding 4 hours, then through Ball-stirring mill fine grinding 6 hours, after micronization, granularity was 2 μm.Then the moiety of burning till waste material and other Longquan celadon blanks will processed, loading ball mill in proportion, take water as ball-milling medium, ball milling 30 hours, pours out water and becomes mud to do, then injection forming repaired biscuit again after old, naturally rear loading kiln is dried, biscuiting 0.5 hour in 900 DEG C.Again each moiety of Longquan celadon glaze is loaded ball mill in proportion, add 1wt% PEG1000, ball milling poured out into glaze slip after 36 hours.Finally by the work in-process base substrate glaze slip obtained of biscuiting, carry out twice glazing, glazed thickness is about 5mm, Deng loading kiln after the seasoning of glaze layer, in reducing atmosphere, high temperature burns till, and firing temperature adopts 1200 DEG C, namely even structure densification is made, the Longquan celadon goods that glaze paint is plump, fine and smooth.
Embodiment 2
Longquan celadon blank, according to weight percent meter, specifically consists of: porcelain stone 40%, Zijin soil 40%, perlite 10%, and base substrate waste material 4% burns till waste material 6%.Longquan celadon glaze, according to weight percent meter, specifically consists of: quartz 15%, feldspar 42%, Zijin soil 25%, Wingdale 15%, useless glaze 3%.
Making processes is: first will burn till waste material and use high pressure roll-in mill grinding 4 hours, then through Ball-stirring mill fine grinding 8 hours, after micronization, granularity was 1.1 μm.Then the moiety of burning till waste material and other Longquan celadon blanks will processed, loading ball mill in proportion, take water as ball-milling medium, ball milling 30 hours, pours out water and becomes mud to do, then injection forming repaired biscuit again after old, naturally rear loading kiln is dried, biscuiting 1 hour in 800 DEG C.Again each moiety of Longquan celadon glaze is loaded ball mill in proportion, add 1wt% PEG400, ball milling poured out into glaze slip after 40 hours.Finally by the work in-process base substrate glaze slip obtained of biscuiting, carry out twice glazing, glazed thickness is about 5mm, Deng loading kiln after the seasoning of glaze layer, in reducing atmosphere, high temperature burns till, and firing temperature adopts 1230 DEG C, namely even structure densification is made, the Longquan celadon goods that glaze paint is plump, fine and smooth.
Embodiment 3
Longquan celadon blank, according to weight percent meter, specifically consists of: porcelain stone 35%, Zijin soil 42%, perlite 12%, and base substrate waste material 3% burns till waste material 8%.Longquan celadon glaze, according to weight percent meter, specifically consists of: quartz 19%, feldspar 45%, Zijin soil 18%, Wingdale 12%, useless glaze 6%.
Making processes is: first will burn till waste material and use high pressure roll-in mill grinding 6 hours, then through Ball-stirring mill fine grinding 8 hours, after micronization, granularity was 0.5 μm.Then the moiety of burning till waste material and other Longquan celadon blanks will processed, loading ball mill in proportion, take water as ball-milling medium, ball milling 24 hours, pours out water and becomes mud to do, then injection forming repaired biscuit again after old, naturally rear loading kiln is dried, biscuiting 45 minutes in 850 DEG C.Again each moiety of Longquan celadon glaze is loaded ball mill in proportion, add 1wt% PEG1000, ball milling poured out into glaze slip after 30 hours.Finally by the work in-process base substrate glaze slip obtained of biscuiting, carry out three glazings, glazed thickness is about 7mm, Deng loading kiln after the seasoning of glaze layer, in reducing atmosphere, high temperature burns till, and firing temperature adopts 1250 DEG C, namely even structure densification is made, the Longquan celadon goods that glaze paint is plump, fine and smooth.
Finally, it should be noted that above what enumerate is only specific embodiments of the invention.Obviously, the invention is not restricted to above embodiment, a lot of distortion can also be had.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention, all should think protection scope of the present invention.
Claims (2)
1. utilize celadon waste material to prepare the raw material of Longquan celadon product process, comprise Longquan celadon blank and Longquan celadon glaze, it is characterized in that, described Longquan celadon blank is according to weight percent meter, composed of the following components: porcelain stone 30 ~ 40%, Zijin soil 40 ~ 50%, perlite 8 ~ 12%, base substrate waste material 3 ~ 5%, burns till waste material 6 ~ 8%; Described Longquan celadon glaze is according to weight percent meter, composed of the following components: quartz 15 ~ 25%, feldspar 40 ~ 45%, Zijin soil 18 ~ 25%, Wingdale 10 ~ 15%, useless glaze 3 ~ 6%;
Described base substrate waste material refers to the waste material produced in celadon blank forming process; The described waste material that burns till refers in celadon sintering process because ftractureing, being out of shape the waste product produced; Described useless glaze refers to the useless glaze that celadon glazing operation produces.
2. utilize the raw material described in claim 1 to realize preparing the method for Longquan celadon goods, comprise high temperature and burn till, it is characterized in that, specifically comprise the following steps:
Steps A: will burn till waste material and carry out ultramicronising process, makes the granularity of burning till waste material between 0.5 ~ 2 μm; Wherein, ultramicronising process refers to: first roughly grind with high pressure roll mill, then carry out fine grinding with Ball-stirring mill;
Step B: the moiety of burning till waste material and other Longquan celadon blanks processed in steps A is loaded ball mill in proportion, after adding water, ball milling mixes, pouring out water after old becomes mud to do, then injection forming repaired biscuit again, work in-process are obtained after drying, again work in-process are loaded kiln, in 800 ~ 900 DEG C, carry out biscuiting;
Step C: each moiety of Longquan celadon glaze is loaded ball mill in proportion, adds 1wt% dispersion agent, pour out into glaze slip after ball milling;
Step D: carry out glazing to the work in-process of biscuiting in step B with the glaze slip obtained in step C, then loads kiln by after the work in-process drying after glazing, burns till, namely complete the making of Longquan celadon goods in reducing atmosphere with the high temperature of 1200 ~ 1250 DEG C.
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| CN201310287167.6A CN103360031B (en) | 2013-07-08 | 2013-07-08 | Raw material of Longquan celadon product preparation technology using celadon waste and method thereof |
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| CN201310287167.6A CN103360031B (en) | 2013-07-08 | 2013-07-08 | Raw material of Longquan celadon product preparation technology using celadon waste and method thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107021625A (en) * | 2017-05-23 | 2017-08-08 | 张福利 | A kind of bluish white glaze of pottery |
| CN109437836A (en) * | 2018-12-24 | 2019-03-08 | 王晶 | A kind of celadon pen and its preparation process |
| CN112374861A (en) * | 2020-11-27 | 2021-02-19 | 于大鹏 | Method for improving strength of ceramic ware blank |
| CN112341155A (en) * | 2020-11-27 | 2021-02-09 | 于大鹏 | Method for manufacturing large-size ceramic ware |
Citations (4)
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|---|---|---|---|---|
| CN1683282A (en) * | 2005-02-23 | 2005-10-19 | 广州晟田化工材料科技有限公司 | Process for producing super thin ceramic polished brick using ceramic polished waste slag or ceramic waste material |
| CN101700971A (en) * | 2009-08-12 | 2010-05-05 | 广东长城集团股份有限公司 | Method for producing petuntse from waste ceramics |
| CN101792303A (en) * | 2009-11-02 | 2010-08-04 | 浙江大学 | Longquan celadon reinforced blank and preparation method of product thereof |
| CN102924049A (en) * | 2012-09-27 | 2013-02-13 | 浙江天丰陶瓷有限公司 | Raw material for low-temperature firing of Longquan celadon and firing method |
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2013
- 2013-07-08 CN CN201310287167.6A patent/CN103360031B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1683282A (en) * | 2005-02-23 | 2005-10-19 | 广州晟田化工材料科技有限公司 | Process for producing super thin ceramic polished brick using ceramic polished waste slag or ceramic waste material |
| CN101700971A (en) * | 2009-08-12 | 2010-05-05 | 广东长城集团股份有限公司 | Method for producing petuntse from waste ceramics |
| CN101792303A (en) * | 2009-11-02 | 2010-08-04 | 浙江大学 | Longquan celadon reinforced blank and preparation method of product thereof |
| CN102924049A (en) * | 2012-09-27 | 2013-02-13 | 浙江天丰陶瓷有限公司 | Raw material for low-temperature firing of Longquan celadon and firing method |
Non-Patent Citations (1)
| Title |
|---|
| 论陶瓷碎片再利用在环境艺术设计中体现的人文关怀;钦冯燕;《中国优秀硕士学位论文全文数据库 哲学与人文科学辑》;20110430;正文第1-3,6-10,25-26页 * |
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