CN105753469A - 添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料及其制备方法 - Google Patents

添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料及其制备方法 Download PDF

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CN105753469A
CN105753469A CN201610060238.2A CN201610060238A CN105753469A CN 105753469 A CN105753469 A CN 105753469A CN 201610060238 A CN201610060238 A CN 201610060238A CN 105753469 A CN105753469 A CN 105753469A
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蒲永平
姚谋腾
高淑雅
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Shaanxi University of Science and Technology
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Abstract

一种添加MgO的0.475NBT?0.525BCTZ高储能密度陶瓷材料的制备方法，将BCTZ陶瓷粉体、NBT陶瓷粉体和氧化镁粉体按照化学式0.475NBT?0.525BCTZ?x wt％MgO配料，混合均匀后经造粒、成型后，在1150?1180℃下保温2?6h烧结成瓷，得到高储能密度陶瓷材料；其中，x取值范围为3?7。本发明的制备工艺简单，操作简单、成本低，为大规模、低成本制备新型高储能密度陶瓷材料提供了基础。

Description

添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料及其制备方法
技术领域
本发明属于电子陶瓷领域，涉及一种MgO添加0.475NBT-0.525BCTZ高储能密度陶瓷材料及其制备方法。
背景技术
电容器作为一种重要的储能器件，是电子设备中大量使用的电子元器件之一。而陶瓷电容器具有使用温度范围宽、寿命长、性能可靠等优点而被广泛使用。电容储能容易保持，不需要超导体。电容储能还有很重要的一点就是能够提供瞬间大功率，非常适合于激光器，闪光灯等应用场合。电容器储存的能量大小由其尺寸和介质材料的储能密度决定。为了减小其尺寸，提高其能量的存储量，开发具有高储能密度的陶瓷介质材料可以有效解决这一问题。陶瓷电容器具有使用温度范围宽、寿命长、性能可靠等优点而被广泛使用。其中铁电陶瓷材料具有介电常数大，非线性效应强等优点，单位体积铁电陶瓷材料的储能密度J可由下式计算：
J＝∫EdP
其中P为极化强度，E为其击穿强度。
铁电陶瓷材料的储能密度由其最小极化强度(Pr)、最大极化强度(Pm)和击穿强度(Eb)共同决定。被广泛研究的Ba0.4Sr0.6TiO3陶瓷的储能密度仅仅为～0.37J/cm3，储能密度较低。
发明内容
本发明的目的是提供一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料及其制备方法，该方法制得的陶瓷材料储能密度高达1.04J/cm3，并且制备方法简单，易于实现。
为实现上述目的，本发明采用如下的技术方案：
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，将BCTZ陶瓷粉体、NBT陶瓷粉体和氧化镁粉体按照化学式0.475NBT-0.525BCTZ-xwt％MgO配料，混合均匀后经造粒、成型后，在1150-1180℃下保温2-6h烧结成瓷，得到高储能密度陶瓷材料；其中，x取值范围为3-7。
所述混合均匀是通过球磨实现的。
所述球磨是以去离子水作为球磨介质。
所述球磨的时间为6-8h。
混合均匀后在70℃-90℃下烘干。
所述BCTZ陶瓷粉体通过以下方法制得：按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，制得BCTZ陶瓷粉体。
所述NBT陶瓷粉体通过以下方法制得：按照化学式Na0.5Bi0.5TiO3，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，制得NBT陶瓷粉体。
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料，化学式为0.475NBT-0.525BCTZ-xwt％MgO，其中，x取值范围为3-7，该材料的密度为1.04J/cm3。
与现有技术相比，本发明具有的有益效果：0.475NBT-0.525BCTZ具有较高的最大极化强度(Pm～25.22μC/cm3)，但是其击穿强度较低(Eb～94.73kV/cm)，使其具有较低的储能密度(0.86J/cm3)，因此本发明通过添加MgO来提高其击穿强度，从而制得高储能密度陶瓷材料。由于MgO在陶瓷中的扩散速率较慢，使得过量的MgO在晶界处积累，可以有效抑制晶粒生长，细化陶瓷材料的晶粒，使得陶瓷材料具有均匀的微观形貌。其次MgO的击穿强度高达1000kV/cm，添加MgO还可以有效降低陶瓷材料的介电损耗。因此，本发明向0.475NBT-0.525BCTZ添加适量的MgO来提高其击穿强度，从而获得具有高储能密度的陶瓷材料。本发明采用传统固相法制备的0.475NBT-0.525BCTZ-xwt％MgO陶瓷材料的储能密度高达1.04J/cm3。本发明的制备方法设备简单、操作简单、成本低、可大规模生产，为大规模、低成本制备高储能密度陶瓷材料提供了基础。
进一步的，本发明以碳酸钡，碳酸钙，碳酸钠，氧化铋，二氧化钛，氧化锆和氧化镁为原料，采用固相法，制备0.475NBT-0.525BCTZ-xwt％MgO(x＝3-7)陶瓷材料。本发明的制备方法设备简单、操作简单、成本低、可大规模生产，为大规模、低成本制备高储能密度陶瓷材料提供了基础。
附图说明
图1是添加3wt％MgO的陶瓷材料的电滞回线图。
图2是添加5wt％MgO的陶瓷材料的电滞回线图。
图3是添加7wt％MgO的陶瓷材料的电滞回线图。
具体实施方式
下面结合附图和实施例对本发明做进一步说明。
一种MgO添加0.475NBT-0.525BCTZ高储能密度陶瓷材料，其化学式为0.475NBT-0.525BCTZ-xwt％MgO，其中，x取值范围为3-7。wt％表示重量百分比。
实施例1
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：
按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-3wt％MgO配料，用去离子水作为球磨介质球磨6h混合均匀，然后在80℃下烘干，经造粒、成型后，在1170℃下保温2h烧结成瓷，得到高储能密度陶瓷材料。
实施例2
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-3wt％MgO配料，用去离子水作为球磨介质球磨6h混合均匀，然后在80℃下烘干，经造粒、成型后，在1170℃下保温4h烧结成瓷，得到高储能密度陶瓷材料。
实施例3
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-3wt％MgO配料，用去离子水作为球磨介质球磨6h混合均匀，然后在80℃下烘干，经造粒、成型后，在1170℃下保温6h烧结成瓷，得到高储能密度陶瓷材料。
实施例4
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：
按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体，NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-5wt％MgO配料，用去离子水作为球磨介质球磨6h混合均匀，然后在80℃下烘干，经造粒、成型后，在1170℃下保温2h烧结成瓷，得到高储能密度陶瓷材料。
实施例5
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：
按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-5wt％MgO配料，用去离子水作为球磨介质球磨6h混合均匀，然后在80℃下烘干，经造粒、成型后，在1170℃下保温4h烧结成瓷，得到高储能密度陶瓷材料。
实施例6
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：
按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-5wt％MgO配料，用去离子水作为球磨介质球磨6h混合均匀，然后在80℃下烘干，经造粒、成型后，在1160℃下保温6h烧结成瓷，得到高储能密度陶瓷材料。
实施例7
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：
按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-7wt％MgO配料，用去离子水作为球磨介质球磨6h混合均匀，然后在80℃下烘干，经造粒、成型后，在1170℃下保温2h烧结成瓷，得到高储能密度陶瓷材料。
实施例8
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：
按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-4wt％MgO配料，用去离子水作为球磨介质球磨8h混合均匀，然后在70℃下烘干，经造粒、成型后，在1180℃下保温4h烧结成瓷，得到高储能密度陶瓷材料。
实施例9
一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法：
按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3(BCTZ)，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，合成BCTZ陶瓷粉体；
按照化学式Na0.5Bi0.5TiO3(NBT)，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h合成NBT陶瓷粉体。
将BCTZ陶瓷粉体、NBT陶瓷粉体和MgO按照化学式0.475NBT-0.525BCTZ-6wt％MgO配料，用去离子水作为球磨介质球磨7h混合均匀，然后在90℃下烘干，经造粒、成型后，在1150℃下保温6h烧结成瓷，得到高储能密度陶瓷材料。
参见图1，为实施例1中制备的陶瓷样品的电滞回线图，从图中可以看到该样品的储能密度可达0.92J/cm3，储能效率可达70.22％。图2为实施例4中制备的陶瓷样品的电滞回线图，从图中可以看到该样品的储能密度可达1.04J/cm3，储能效率可达69.79％。图3为实施例7中制备的陶瓷样品的电滞回线图，从图中可以看到该样品的储能密度可达1.02J/cm3，储能效率可达69.38％。

Claims (8)

1.一种添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，其特征在于，将BCTZ陶瓷粉体、NBT陶瓷粉体和氧化镁粉体按照化学式0.475NBT-0.525BCTZ-xwt％MgO配料，混合均匀后经造粒、成型后，在1150-1180℃下保温2-6h烧结成瓷，得到高储能密度陶瓷材料；其中，x取值范围为3-7。
2.根据权利要求1所述的添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，其特征在于，所述混合均匀是通过球磨实现的。
3.根据权利要求2所述的添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，其特征在于，所述球磨是以去离子水作为球磨介质。
4.根据权利要求2或3所述的添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，其特征在于，所述球磨的时间为6-8h。
5.根据权利要求2所述的添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，其特征在于，混合均匀后在70℃-90℃下烘干。
6.根据权利要求1所述的添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，其特征在于，所述BCTZ陶瓷粉体通过以下方法制得：按照化学式Ba0.85Ca0.15Zr0.1Ti0.9O3，将碳酸钡、碳酸钙、二氧化钛和氧化锆混合均匀后在1270℃下保温2h，制得BCTZ陶瓷粉体。
7.根据权利要求1所述的添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料的制备方法，其特征在于，所述NBT陶瓷粉体通过以下方法制得：按照化学式Na0.5Bi0.5TiO3，将碳酸钠、氧化铋和二氧化钛混合均匀后在840℃下保温4h，制得NBT陶瓷粉体。
8.一种如权利要求1所述的方法制备的添加MgO的0.475NBT-0.525BCTZ高储能密度陶瓷材料，其特征在于，化学式为0.475NBT-0.525BCTZ-xwt％MgO，其中，x取值范围为3-7，该材料的密度为1.04J/cm3。
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106396677A (zh) * 2016-09-30 2017-02-15 陕西科技大学 微波烧结制备0.5NBT‑0.5BCTZ‑xwt%MgO高储能密度陶瓷材料及方法
CN106478091A (zh) * 2016-09-30 2017-03-08 陕西科技大学 添加MgO的0.45BCTZS‑0.55BNT高储能密度陶瓷材料及其制备方法
CN106915964A (zh) * 2017-02-21 2017-07-04 陕西科技大学 一种无铅高储能密度陶瓷材料及其制备方法
CN107814569A (zh) * 2017-12-12 2018-03-20 陕西科技大学 一种无铅反铁电体陶瓷及其制备方法
CN110981479A (zh) * 2020-01-10 2020-04-10 陕西科技大学 一种高击穿的铁电陶瓷及其制备方法
CN112661508A (zh) * 2021-01-20 2021-04-16 西北大学 一种低烧高储能锆钛酸锶钡基陶瓷材料及其制备方法
CN114874007A (zh) * 2022-05-10 2022-08-09 河南科技大学 锆酸钙-钛酸锶高效率储能电介质复合陶瓷的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104773755A (zh) * 2015-04-21 2015-07-15 陕西科技大学 一种通过掺杂Mg2+水热法制备(Ba,Sr)TiO3纳米粉体的方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104773755A (zh) * 2015-04-21 2015-07-15 陕西科技大学 一种通过掺杂Mg2+水热法制备(Ba,Sr)TiO3纳米粉体的方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
QIAN GOU ET AL.: "Enhanced d33 value of Bi0.5Na0.5TiO3–(Ba0.85Ca0.15)(Ti0.90Zr0.10)O3 lead-free ceramics", 《JOURNAL OF ALLOYS AND COMPOUNDS》 *
SHA QIAO ET AL.: "Effect of Ba0.85Ca0.15Ti0.90Zr0.10O3 content on the microstructure and electrical properties of Bi0.51(Na0.82K0.18) 0.50TiO3 ceramics", 《CERAMICS INTERNATIONAL》 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN106478091A (zh) * 2016-09-30 2017-03-08 陕西科技大学 添加MgO的0.45BCTZS‑0.55BNT高储能密度陶瓷材料及其制备方法
CN106915964A (zh) * 2017-02-21 2017-07-04 陕西科技大学 一种无铅高储能密度陶瓷材料及其制备方法
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