CN105733331B - 一种糊精基无后增稠性广告画颜料的制备方法 - Google Patents

一种糊精基无后增稠性广告画颜料的制备方法 Download PDF

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CN105733331B
CN105733331B CN201610300399.4A CN201610300399A CN105733331B CN 105733331 B CN105733331 B CN 105733331B CN 201610300399 A CN201610300399 A CN 201610300399A CN 105733331 B CN105733331 B CN 105733331B
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CN105733331A (zh
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吴光辉
刘志雷
王春霞
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Nanchang Lanpo Pen & Painting Materials Co ltd
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06—Artists' paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
    • C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
    • C08B30/18—Dextrin, e.g. yellow canari, white dextrin, amylodextrin or maltodextrin; Methods of depolymerisation, e.g. by irradiation or mechanically
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09D103/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates

Abstract

本发明涉及一种糊精基无后增稠性广告画颜料的制备方法。利用一定比例的盐酸、磷酸、柠檬酸炒制的糊精粉，溶解到水中并加入甘油，恒温处理后，添加颜料、填料、杀菌剂等制备了一种广告画颜料，该广告画颜料与目前的糊精基广告画颜料相比，消除了后增稠现象，并且绘画流畅，光泽度饱满，具有广阔的市场前景。

Description

一种糊精基无后增稠性广告画颜料的制备方法
技术领域
本发明涉及一种糊精基无后增稠性广告画颜料的制备方法，属于有机材料技术领域。
背景技术
广告画是为了介绍、推销商品，或者因政治、军事、文化、社会等方面的需要而含有告白意味的一种绘画，大量应用于商业活动。主要刊登在报章、杂志以及张贴于墙壁上，也有绘在铁皮和木板而立于交通要道口或公共场所等。
目前广告画颜料的成膜物质主要有糊精基、桃胶基、阿拉伯胶基、树胶基等，其中糊精基的成本最低，便于大规模生产，但相比桃胶、阿拉伯胶和树胶，目前市场上糊精粉制备的广告画颜料具有明显的后增稠性，即在研磨、搅拌、晃动等情况下，广告画颜料具有明显的切力变稀的现象，静置会变粘稠，严重影响绘画时的笔触感。
为了克服上述缺点，本专利利用在多种酸的共同作用下炒制的具有独特性能的糊精粉，制备了无后增稠性的糊精基广告画颜料，制作工艺简单，成本低，产品笔触感好，干膜光泽度高。
发明内容
本发明的目的是提供一种糊精基无后增稠性广告画颜料的制备方法，为了实现上述目的，本发明所采用的技术方案是：
取6~15kg水，向其中加入200~1000mL质量分数为36%的盐酸、200~600mL质量分数为85%的磷酸以及10~100g的柠檬酸，溶解混合均匀。将溶解混合均匀的酸液喷洒于350kg玉米淀粉中，搅拌均匀。转移至炒锅中，1.5~2小时升温至100~130℃，恒温3~6小时，放料，降温，过筛得糊精粉。将其转移至胶水制备器中，加入500~700kg水，45~55kg甘油，45~55℃下搅拌均匀。再向浆料中加入硫酸钡130~150kg，碳酸钙190~230kg，杀菌剂3~6kg，颜料2~15kg，搅拌均匀后，三辊机研磨3~5遍，得到产品。
所述的杀菌剂可以是百菌清、多菌灵、卡松、布罗波尔中的一种或者几种组合。
所述的颜料可以是土黄、土红、赭石、桔黄、中黄、淡黄、橄榄绿、粉绿、群青、钴蓝、湖蓝、深红、青莲、紫罗兰、柠檬黄、玫瑰红、钛白粉、碱性玫瑰精、铁黄、酞青绿、橡胶大红等一种或者几种的组合。
本发明的优点：本发明在多种酸的条件下炒制糊精粉，并通过合适工艺制备了无后增稠性的糊精基广告画颜料，制作工艺简单，成本低，产品笔触感好，干膜光泽度高，相比目前市场上的产品具有更好的性能。
具体实施方式
下面结合实施例对本发明做进一步详细的阐明，但本发明的内容并不仅仅局限于下面的实施例。
实施例1
取15kg水，向其中加入900mL质量分数为36%的盐酸、300mL质量分数为85%的磷酸、100g的柠檬酸，溶解混合均匀。将溶解混合均匀的酸液喷洒于350kg玉米淀粉中，搅拌均匀。转移至炒锅中，1.5小时升温至110℃，恒温5小时，放料，降温，过筛得糊精粉，将其转移至胶水制备器中，加入500kg水，45kg甘油，45℃下搅拌均匀。再向浆料中加入硫酸钡130kg，碳酸钙190kg，卡松类杀菌剂3kg，百菌清3kg，赭石颜料2kg，搅拌均匀后，三辊机研磨3遍，得到产品。
实施例2
取10kg水，向其中加入500mL质量分数为36%的盐酸、500mL质量分数为85%的磷酸、60g的柠檬酸，溶解混合均匀。将溶解混合均匀的酸液喷洒于350kg玉米淀粉中，搅拌均匀。转移至炒锅中，2小时升温至120℃，恒温4小时，放料，降温，过筛得糊精粉，将其转移至胶水制备器中，加入600kg水，55kg甘油， 55℃下搅拌均匀。再向浆料中加入硫酸钡150kg，碳酸钙230kg，卡松类杀菌剂5kg，钛白粉颜料15kg，搅拌均匀后，三辊机研磨5遍，得到产品。
实施例3
取6kg水，向其中加入300mL质量分数为36%的盐酸、600mL质量分数为85%的磷酸，20g的柠檬酸，溶解混合均匀。将溶解混合均匀的酸液喷洒于350kg玉米淀粉中，搅拌均匀。转移至炒锅中，2小时升温至130℃，恒温3小时，放料，降温，过筛得糊精粉，将其转移至胶水制备器中，加入550kg水，50kg甘油，50℃下搅拌均匀。再向浆料中加入硫酸钡140kg，碳酸钙210kg，百菌清3kg，多菌灵2kg，柠檬黄颜料5kg，搅拌均匀后，三辊机研磨4遍，得到产品。
实施例1-实施例3性能测试：见表1。
表1实施例1-实施例3性能测试结果
实施例 静置1月后增稠情况 光泽度 笔触感 霉菌箱3个月
1 无 4 5 无霉菌
2 无 4 5 无霉菌
3 无 4 5 无霉菌
注：指标的衡量数字1、2、3、4、5分别代表差、较差、中等、较好、好。

Claims (3)

1.一种糊精基无后增稠性广告画颜料的制备方法，其特征在于方法步骤如下：
（1）取6~15kg水，向其中加入200~1000mL质量分数为36%的盐酸、200~600mL质量分数为85%的磷酸以及10~100g的柠檬酸，溶解混合均匀；
（2）将溶解混合均匀的酸液喷洒于350kg玉米淀粉中，搅拌均匀；转移至炒锅中，1.5~2小时升温至100~130℃，恒温3~6小时，放料，降温，过筛得糊精粉，将其转移至胶水制备器中，加入500~700kg水，45~55kg甘油，45~55℃下搅拌均匀；
（3）再向浆料中加入硫酸钡130~150kg，碳酸钙190~230kg，杀菌剂3~5kg，颜料2~15kg，搅拌均匀，三辊机研磨3~5遍，得到产品。
2.根据权利要求1所述的一种糊精基无后增稠性广告画颜料的制备方法，其特征在于：所述的杀菌剂或是百菌清、多菌灵、卡松、布罗波尔中的一种或者几种组合。
3.根据权利要求1所述的一种糊精基无后增稠性广告画颜料的制备方法，其特征在于：所述的颜料或是土黄、土红、赭石、桔黄、中黄、淡黄、橄榄绿、粉绿、群青、钴蓝、湖蓝、深红、青莲、紫罗兰、柠檬黄、玫瑰红、钛白粉、碱性玫瑰精、铁黄、酞青绿、橡胶大红一种或者几种的组合。
CN201610300399.4A 2016-05-09 2016-05-09 一种糊精基无后增稠性广告画颜料的制备方法 Expired - Fee Related CN105733331B (zh)

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CN109294341A (zh) * 2018-09-25 2019-02-01 南昌蓝珀笔业画材有限公司 一种绘画颜料用低变色性糊精胶水的制备方法
CN109233394A (zh) * 2018-09-26 2019-01-18 张惠柳 利用红花制备红色绘画颜料的方法
CN111944346A (zh) * 2020-08-24 2020-11-17 天长市嘉丰美术用品有限公司 一种不伤手可洗型广告画颜料及其生产工艺

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CN103160152A (zh) * 2011-12-14 2013-06-19 吴江市冰心文教用品有限公司 一种速干型红色水粉颜料及其生产方法
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CN101845246A (zh) * 2010-06-10 2010-09-29 宋健 一种易擦洗的水粉涂鸦艺术颜料和制造方法
CN103160152A (zh) * 2011-12-14 2013-06-19 吴江市冰心文教用品有限公司 一种速干型红色水粉颜料及其生产方法
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