CN105705486B - 用于自烷烃和发烟硫酸制备烷基磺酸的新型引发剂 - Google Patents
用于自烷烃和发烟硫酸制备烷基磺酸的新型引发剂 Download PDFInfo
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- CN105705486B CN105705486B CN201480061403.5A CN201480061403A CN105705486B CN 105705486 B CN105705486 B CN 105705486B CN 201480061403 A CN201480061403 A CN 201480061403A CN 105705486 B CN105705486 B CN 105705486B
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- compound
- sulfonic acid
- acid
- reactor
- alkyl sulfonic
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/63—Esters of sulfonic acids
- C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
- C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/42—Peroxy compounds containing sulfur atoms
- C07C409/44—Peroxy compounds containing sulfur atoms with sulfur atoms directly bound to the —O—O— groups, e.g. persulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/26—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/42—Separation; Purification; Stabilisation; Use of additives
- C07C303/44—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13193349.1 | 2013-11-18 | ||
| EP13193349 | 2013-11-18 | ||
| PCT/EP2014/074747 WO2015071455A1 (en) | 2013-11-18 | 2014-11-17 | Novel initiator for preparing alkanesulfonic acids from alkane and oleum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105705486A CN105705486A (zh) | 2016-06-22 |
| CN105705486B true CN105705486B (zh) | 2019-03-01 |
Family
ID=49674152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480061403.5A Active CN105705486B (zh) | 2013-11-18 | 2014-11-17 | 用于自烷烃和发烟硫酸制备烷基磺酸的新型引发剂 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10329251B2 (enExample) |
| EP (1) | EP3071549B1 (enExample) |
| JP (1) | JP6412570B2 (enExample) |
| KR (1) | KR102106763B1 (enExample) |
| CN (1) | CN105705486B (enExample) |
| MY (1) | MY179376A (enExample) |
| SG (1) | SG11201607264XA (enExample) |
| WO (1) | WO2015071455A1 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3068760B1 (en) | 2013-11-13 | 2023-06-07 | Grillo Chemie GmbH | Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane |
| MY179376A (en) | 2013-11-18 | 2020-11-05 | Basf Se | Novel initiator for preparing alkanesulfonic acids from alkane and oleum |
| ES2965853T3 (es) * | 2016-11-28 | 2024-04-17 | Basf Se | Sulfonación de alcanos sin disolventes |
| CN110267938A (zh) * | 2017-02-07 | 2019-09-20 | 格里洛工厂股份有限公司 | 烷烃磺酸的生产方法 |
| US10995063B2 (en) | 2017-03-10 | 2021-05-04 | Veolia North America Regeneration Services, Llc | Integrated processing system with continuous acid loop for converting methane to methane-sulfonic acid |
| US10899703B2 (en) * | 2017-03-10 | 2021-01-26 | Veolia North American Regeneration Services, LLC | Radical initiators and chain extenders for converting methane gas into methane-sulfonic acid |
| TW201841881A (zh) * | 2017-04-18 | 2018-12-01 | 德商巴斯夫歐洲公司 | 純化烷烴磺酸酐的方法及使用純化的烷烴磺酸酐製造烷烴磺酸的方法 |
| JP7062686B2 (ja) * | 2017-05-11 | 2022-05-06 | アーケマ・インコーポレイテッド | 精製された形態でメタンスルホン酸を回収するための方法及びシステム |
| ES2971628T3 (es) | 2017-05-30 | 2024-06-06 | Basf Se | Procedimiento para la producción de ácidos alcanosulfónicos |
| TW201904938A (zh) | 2017-06-30 | 2019-02-01 | 德商葛里洛沃克股份有限公司 | 用於生產烷磺酸的調節劑 |
| EP3749644B1 (en) | 2018-02-07 | 2022-03-09 | Basf Se | Process for the manufacturing of alkanesulfonic acids |
| FR3077817B1 (fr) | 2018-02-14 | 2020-02-28 | Arkema France | Procede de synthese industrielle en continu d'acide alcane-sulfonique |
| TWI714964B (zh) * | 2018-02-16 | 2021-01-01 | 巴斯夫歐洲公司 | 用於烷磺酸之合成的催化劑 |
| EP3959192A4 (en) * | 2018-03-10 | 2022-05-18 | Veolia North America Regeneration Services, LLC | COMPOUNDS, PROCESSES AND MACHINE FOR CONVERTING METHANE GAS INTO METHANESULPHONIC ACID |
| TWI799586B (zh) * | 2018-05-25 | 2023-04-21 | 德商格里洛工廠股份有限公司 | 自三氧化硫及鹵烷製備鹵代烷磺酸的方法 |
| WO2020048965A1 (en) * | 2018-09-04 | 2020-03-12 | Basf Se | Method for the production of alkane sulfonic acids |
| CN112739681A (zh) | 2018-09-25 | 2021-04-30 | 巴斯夫欧洲公司 | 作为生产链烷磺酸中的催化剂的阳离子 |
| WO2020064466A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalyst for the synthesis of alkanesulfonic acids |
| WO2020064573A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| WO2020126855A1 (en) | 2018-12-21 | 2020-06-25 | Basf Se | Mixture comprising methanesulfonic acid and sulfuric acid |
| US11479522B2 (en) * | 2019-03-21 | 2022-10-25 | Basf Se | Method for the purification of alkanes |
| EP3956302B1 (en) | 2019-04-18 | 2023-05-03 | Basf Se | Process for the production of anhydrous methanesulfonic acid from methane and so3 |
| CN114096520B (zh) | 2019-07-10 | 2024-06-18 | 巴斯夫欧洲公司 | 降低包含甲磺酸和so3的反应混合物中的so3浓度的方法 |
| EP3763701A1 (en) | 2019-07-10 | 2021-01-13 | Grillo-Werke AG | Improved process for the purification of methane sulfonic acid |
| MY207209A (en) | 2019-08-07 | 2025-02-06 | Basf Se | Process for the production of alkanesulfonic acids |
| ES2966790T3 (es) * | 2019-08-07 | 2024-04-24 | Basf Se | Recuperación de ácido metanosulfónico exento de agua a partir de la corriente inferior de una columna de destilación |
| EP3782981A1 (en) | 2019-08-20 | 2021-02-24 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| CA3156366A1 (en) * | 2019-10-01 | 2021-04-08 | Basf Se | Process for manufacturing alkanesulfonic acids |
| MX2022004064A (es) | 2019-10-02 | 2022-05-02 | Basf Se | Proceso para elaborar acidos alcansulfonicos. |
| CN111302978A (zh) * | 2020-04-17 | 2020-06-19 | 凯瑞环保科技股份有限公司 | 一种烷基磺酸的合成装置及合成方法 |
| WO2022046543A1 (en) * | 2020-08-24 | 2022-03-03 | University Of Kansas | Alkane multi-sulfonic acids, compositions thereof, and related methods |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304360A (en) * | 1990-10-27 | 1994-04-19 | Interox Chemicals Limited | Peroxoacid manufacture |
| WO2005069751A2 (en) * | 2003-06-21 | 2005-08-04 | Richards Alan K | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
| CN1732141A (zh) * | 2002-11-05 | 2006-02-08 | 艾伦·K·理查兹 | 使用自由基路线和链反应,在最小废物的情况下,使甲烷和其它轻质烷烃无水转化成甲醇和其它衍生物 |
| WO2007136425A2 (en) * | 2006-05-19 | 2007-11-29 | Richards, Alan, K. | Manufacture of dimethyl ether or olefins from methane, using di(methyl-sulfonyl) peroxide as radical initiator |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2493038A (en) * | 1946-05-31 | 1950-01-03 | Houdry Process Corp | Reaction of methane with sulfur trioxide |
| US2619507A (en) | 1951-01-05 | 1952-11-25 | Dow Chemical Co | Di(methanesulfonyl) peroxide and its preparation |
| US4680095A (en) | 1986-11-03 | 1987-07-14 | Pennwalt Corporation | Continuous preparation of dialkanesulfonyl peroxide |
| FR2610320A1 (fr) | 1987-02-03 | 1988-08-05 | Atochem | Composes peroxydes renfermant l'isotope 17o |
| US4910335A (en) | 1989-08-01 | 1990-03-20 | Pennwalt Corporation | Decolorization of alkanesulfonic and arenesulfonic acids |
| EA200500779A1 (ru) | 2002-11-05 | 2006-02-24 | Алан К. Ричардс | Безводное преобразование метана и других легких алканов в метанол и другие производные |
| US20080161591A1 (en) * | 2003-06-21 | 2008-07-03 | Richards Alan K | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
| US7119226B2 (en) | 2004-04-20 | 2006-10-10 | The Penn State Research Foundation | Process for the conversion of methane |
| CN101472922B (zh) | 2006-05-24 | 2012-05-30 | e.V.汉斯-诺尔-研究院（HKI）莱布尼茨天然产物研究和感染生物学研究所 | 苯并噻嗪酮衍生物及其作为抗菌剂的应用 |
| EP3068760B1 (en) | 2013-11-13 | 2023-06-07 | Grillo Chemie GmbH | Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane |
| WO2015071351A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing bis(alkanesulfonyl peroxide) |
| WO2015071371A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing bis(alkanesulfonyl) peroxide by oxidation |
| MY179376A (en) | 2013-11-18 | 2020-11-05 | Basf Se | Novel initiator for preparing alkanesulfonic acids from alkane and oleum |
-
2014
- 2014-11-17 MY MYPI2016704208A patent/MY179376A/en unknown
- 2014-11-17 US US15/035,865 patent/US10329251B2/en active Active
- 2014-11-17 CN CN201480061403.5A patent/CN105705486B/zh active Active
- 2014-11-17 EP EP14799443.8A patent/EP3071549B1/en active Active
- 2014-11-17 SG SG11201607264XA patent/SG11201607264XA/en unknown
- 2014-11-17 WO PCT/EP2014/074747 patent/WO2015071455A1/en not_active Ceased
- 2014-11-17 KR KR1020167012178A patent/KR102106763B1/ko active Active
- 2014-11-17 JP JP2016528892A patent/JP6412570B2/ja active Active
-
2019
- 2019-05-03 US US16/403,112 patent/US11180448B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304360A (en) * | 1990-10-27 | 1994-04-19 | Interox Chemicals Limited | Peroxoacid manufacture |
| CN1732141A (zh) * | 2002-11-05 | 2006-02-08 | 艾伦·K·理查兹 | 使用自由基路线和链反应,在最小废物的情况下,使甲烷和其它轻质烷烃无水转化成甲醇和其它衍生物 |
| WO2005069751A2 (en) * | 2003-06-21 | 2005-08-04 | Richards Alan K | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
| WO2007136425A2 (en) * | 2006-05-19 | 2007-11-29 | Richards, Alan, K. | Manufacture of dimethyl ether or olefins from methane, using di(methyl-sulfonyl) peroxide as radical initiator |
Non-Patent Citations (1)
| Title |
|---|
| "K2S2O8-Initiated Sulfonation of Methane to Methanesulfonic Acid";Lisa J. Lobree等;《Ind. Eng. Chem. Res.》;20010106;第40卷;第736-742页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105705486A (zh) | 2016-06-22 |
| US10329251B2 (en) | 2019-06-25 |
| US20190256461A1 (en) | 2019-08-22 |
| JP2016540743A (ja) | 2016-12-28 |
| US20160289181A1 (en) | 2016-10-06 |
| JP6412570B2 (ja) | 2018-10-24 |
| KR102106763B1 (ko) | 2020-05-06 |
| US11180448B2 (en) | 2021-11-23 |
| MY179376A (en) | 2020-11-05 |
| EP3071549B1 (en) | 2017-10-18 |
| SG11201607264XA (en) | 2016-10-28 |
| EP3071549A1 (en) | 2016-09-28 |
| KR20160086832A (ko) | 2016-07-20 |
| WO2015071455A1 (en) | 2015-05-21 |
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