CN105705486B - 用于自烷烃和发烟硫酸制备烷基磺酸的新型引发剂 - Google Patents
用于自烷烃和发烟硫酸制备烷基磺酸的新型引发剂 Download PDFInfo
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- CN105705486B CN105705486B CN201480061403.5A CN201480061403A CN105705486B CN 105705486 B CN105705486 B CN 105705486B CN 201480061403 A CN201480061403 A CN 201480061403A CN 105705486 B CN105705486 B CN 105705486B
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- compound
- sulfonic acid
- acid
- reactor
- alkyl sulfonic
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/63—Esters of sulfonic acids
- C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
- C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/42—Peroxy compounds containing sulfur atoms
- C07C409/44—Peroxy compounds containing sulfur atoms with sulfur atoms directly bound to the —O—O— groups, e.g. persulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/26—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/42—Separation; Purification; Stabilisation; Use of additives
- C07C303/44—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13193349.1 | 2013-11-18 | ||
| EP13193349 | 2013-11-18 | ||
| PCT/EP2014/074747 WO2015071455A1 (en) | 2013-11-18 | 2014-11-17 | Novel initiator for preparing alkanesulfonic acids from alkane and oleum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105705486A CN105705486A (zh) | 2016-06-22 |
| CN105705486B true CN105705486B (zh) | 2019-03-01 |
Family
ID=49674152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480061403.5A Active CN105705486B (zh) | 2013-11-18 | 2014-11-17 | 用于自烷烃和发烟硫酸制备烷基磺酸的新型引发剂 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10329251B2 (enExample) |
| EP (1) | EP3071549B1 (enExample) |
| JP (1) | JP6412570B2 (enExample) |
| KR (1) | KR102106763B1 (enExample) |
| CN (1) | CN105705486B (enExample) |
| MY (1) | MY179376A (enExample) |
| SG (1) | SG11201607264XA (enExample) |
| WO (1) | WO2015071455A1 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015071365A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane |
| JP6412570B2 (ja) | 2013-11-18 | 2018-10-24 | グリロ‐ヴェルケ アーゲー | アルカンおよび発煙硫酸からアルカンスルホン酸を製造するための新規な開始剤 |
| MX2019004519A (es) | 2016-11-28 | 2019-10-14 | Grillo Werke Ag | Sulfonacion de alcano libre de disolvente. |
| SG11201905997SA (en) * | 2017-02-07 | 2019-08-27 | Grillo Werke Ag | Method for the production of alkane sulfonic acids |
| US10899703B2 (en) | 2017-03-10 | 2021-01-26 | Veolia North American Regeneration Services, LLC | Radical initiators and chain extenders for converting methane gas into methane-sulfonic acid |
| US10995063B2 (en) | 2017-03-10 | 2021-05-04 | Veolia North America Regeneration Services, Llc | Integrated processing system with continuous acid loop for converting methane to methane-sulfonic acid |
| TW201841881A (zh) * | 2017-04-18 | 2018-12-01 | 德商巴斯夫歐洲公司 | 純化烷烴磺酸酐的方法及使用純化的烷烴磺酸酐製造烷烴磺酸的方法 |
| KR102495410B1 (ko) * | 2017-05-11 | 2023-02-06 | 알케마 인코포레이티드 | 정제된 형태의 메탄설폰산을 회수하기 위한 방법 및 시스템 |
| KR102629665B1 (ko) * | 2017-05-30 | 2024-01-25 | 바스프 에스이 | 알칸설폰산의 제조 방법 |
| TW201904938A (zh) | 2017-06-30 | 2019-02-01 | 德商葛里洛沃克股份有限公司 | 用於生產烷磺酸的調節劑 |
| CA3090041A1 (en) | 2018-02-07 | 2019-08-15 | Basf Se | Process for the manufacturing of alkanesulfonic acids |
| FR3077817B1 (fr) | 2018-02-14 | 2020-02-28 | Arkema France | Procede de synthese industrielle en continu d'acide alcane-sulfonique |
| TWI714964B (zh) | 2018-02-16 | 2021-01-01 | 巴斯夫歐洲公司 | 用於烷磺酸之合成的催化劑 |
| CA3153432A1 (en) * | 2018-03-10 | 2019-11-07 | Veolia North America Regeneration Services, Llc | Compounds, processes, and machinery for converting methane gas into methane-sulfonic acid |
| US11634385B2 (en) | 2018-05-25 | 2023-04-25 | Grillo-Werke Ag | Process for the preparation of haloalkanesulfonic acids from sulfur trioxide and a haloalkane |
| WO2020048965A1 (en) * | 2018-09-04 | 2020-03-12 | Basf Se | Method for the production of alkane sulfonic acids |
| WO2020064573A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| WO2020064466A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalyst for the synthesis of alkanesulfonic acids |
| SG11202102866QA (en) | 2018-09-25 | 2021-04-29 | Basf Se | Cations as catalyst in the production of alkane sulfonic acids |
| WO2020126855A1 (en) | 2018-12-21 | 2020-06-25 | Basf Se | Mixture comprising methanesulfonic acid and sulfuric acid |
| SG11202110017TA (en) | 2019-03-21 | 2021-10-28 | Basf Se | Method for the purification of alkanes |
| CA3135452A1 (en) * | 2019-04-18 | 2020-10-22 | Basf Se | Process for the production of anhydrous methanesulfonic acid from methane and so3 |
| EP3763701A1 (en) | 2019-07-10 | 2021-01-13 | Grillo-Werke AG | Improved process for the purification of methane sulfonic acid |
| ES2966787T3 (es) | 2019-07-10 | 2024-04-24 | Basf Se | Procedimiento para reducir la concentración de SO3 en una mezcla de reacción que comprende ácido metano sulfónico y SO3 |
| CA3148005A1 (en) * | 2019-08-07 | 2021-02-11 | Basf Se | Process for the production of alkanesulfonic acids |
| MY208992A (en) * | 2019-08-07 | 2025-06-16 | Basf Se | Recovery of water-free methanesulfonic acid from the bottom stream of a distillation column |
| EP3782981A1 (en) | 2019-08-20 | 2021-02-24 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| US12503429B2 (en) | 2019-10-01 | 2025-12-23 | Basf Se | Process for manufacturing alkanesulfonic acids |
| US12479795B2 (en) | 2019-10-02 | 2025-11-25 | Basf Se | Process for manufacturing alkanesulfonic acids |
| CN111302978A (zh) * | 2020-04-17 | 2020-06-19 | 凯瑞环保科技股份有限公司 | 一种烷基磺酸的合成装置及合成方法 |
| WO2022046543A1 (en) * | 2020-08-24 | 2022-03-03 | University Of Kansas | Alkane multi-sulfonic acids, compositions thereof, and related methods |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304360A (en) * | 1990-10-27 | 1994-04-19 | Interox Chemicals Limited | Peroxoacid manufacture |
| WO2005069751A2 (en) * | 2003-06-21 | 2005-08-04 | Richards Alan K | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
| CN1732141A (zh) * | 2002-11-05 | 2006-02-08 | 艾伦·K·理查兹 | 使用自由基路线和链反应,在最小废物的情况下,使甲烷和其它轻质烷烃无水转化成甲醇和其它衍生物 |
| WO2007136425A2 (en) * | 2006-05-19 | 2007-11-29 | Richards, Alan, K. | Manufacture of dimethyl ether or olefins from methane, using di(methyl-sulfonyl) peroxide as radical initiator |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2493038A (en) | 1946-05-31 | 1950-01-03 | Houdry Process Corp | Reaction of methane with sulfur trioxide |
| US2619507A (en) | 1951-01-05 | 1952-11-25 | Dow Chemical Co | Di(methanesulfonyl) peroxide and its preparation |
| US4680095A (en) | 1986-11-03 | 1987-07-14 | Pennwalt Corporation | Continuous preparation of dialkanesulfonyl peroxide |
| FR2610320A1 (fr) | 1987-02-03 | 1988-08-05 | Atochem | Composes peroxydes renfermant l'isotope 17o |
| US4910335A (en) | 1989-08-01 | 1990-03-20 | Pennwalt Corporation | Decolorization of alkanesulfonic and arenesulfonic acids |
| MXPA05004957A (es) | 2002-11-05 | 2006-01-30 | Alan K Richards | Procesamiento de anhidro iniciado por radicales alcanos ligeros en acido metano-(sulfronico)-sulfonico, metanol y otros compuestos. |
| US20080161591A1 (en) | 2003-06-21 | 2008-07-03 | Richards Alan K | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
| US7119226B2 (en) | 2004-04-20 | 2006-10-10 | The Penn State Research Foundation | Process for the conversion of methane |
| DK2029583T3 (da) | 2006-05-24 | 2010-09-27 | Leibniz Inst Naturstoff Forsch | Nye benzothiazinonderivater og anvendelse heraf som antibakterielle midler |
| WO2015071351A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing bis(alkanesulfonyl peroxide) |
| WO2015071365A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane |
| WO2015071371A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing bis(alkanesulfonyl) peroxide by oxidation |
| JP6412570B2 (ja) | 2013-11-18 | 2018-10-24 | グリロ‐ヴェルケ アーゲー | アルカンおよび発煙硫酸からアルカンスルホン酸を製造するための新規な開始剤 |
-
2014
- 2014-11-17 JP JP2016528892A patent/JP6412570B2/ja active Active
- 2014-11-17 CN CN201480061403.5A patent/CN105705486B/zh active Active
- 2014-11-17 KR KR1020167012178A patent/KR102106763B1/ko active Active
- 2014-11-17 EP EP14799443.8A patent/EP3071549B1/en active Active
- 2014-11-17 WO PCT/EP2014/074747 patent/WO2015071455A1/en not_active Ceased
- 2014-11-17 US US15/035,865 patent/US10329251B2/en active Active
- 2014-11-17 MY MYPI2016704208A patent/MY179376A/en unknown
- 2014-11-17 SG SG11201607264XA patent/SG11201607264XA/en unknown
-
2019
- 2019-05-03 US US16/403,112 patent/US11180448B2/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304360A (en) * | 1990-10-27 | 1994-04-19 | Interox Chemicals Limited | Peroxoacid manufacture |
| CN1732141A (zh) * | 2002-11-05 | 2006-02-08 | 艾伦·K·理查兹 | 使用自由基路线和链反应,在最小废物的情况下,使甲烷和其它轻质烷烃无水转化成甲醇和其它衍生物 |
| WO2005069751A2 (en) * | 2003-06-21 | 2005-08-04 | Richards Alan K | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
| WO2007136425A2 (en) * | 2006-05-19 | 2007-11-29 | Richards, Alan, K. | Manufacture of dimethyl ether or olefins from methane, using di(methyl-sulfonyl) peroxide as radical initiator |
Non-Patent Citations (1)
| Title |
|---|
| "K2S2O8-Initiated Sulfonation of Methane to Methanesulfonic Acid";Lisa J. Lobree等;《Ind. Eng. Chem. Res.》;20010106;第40卷;第736-742页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| SG11201607264XA (en) | 2016-10-28 |
| JP6412570B2 (ja) | 2018-10-24 |
| US20160289181A1 (en) | 2016-10-06 |
| EP3071549B1 (en) | 2017-10-18 |
| KR20160086832A (ko) | 2016-07-20 |
| KR102106763B1 (ko) | 2020-05-06 |
| US11180448B2 (en) | 2021-11-23 |
| CN105705486A (zh) | 2016-06-22 |
| WO2015071455A1 (en) | 2015-05-21 |
| JP2016540743A (ja) | 2016-12-28 |
| US20190256461A1 (en) | 2019-08-22 |
| US10329251B2 (en) | 2019-06-25 |
| MY179376A (en) | 2020-11-05 |
| EP3071549A1 (en) | 2016-09-28 |
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