CN105567354B - 水煤浆分散剂及其制备方法 - Google Patents
水煤浆分散剂及其制备方法 Download PDFInfo
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- CN105567354B CN105567354B CN201410538211.0A CN201410538211A CN105567354B CN 105567354 B CN105567354 B CN 105567354B CN 201410538211 A CN201410538211 A CN 201410538211A CN 105567354 B CN105567354 B CN 105567354B
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- acid
- humic
- obtains
- water slurry
- dispersing agent
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- 239000002270 dispersing agent Substances 0.000 title claims abstract description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 239000003245 coal Substances 0.000 title claims abstract description 38
- 239000002002 slurry Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000007613 slurry method Methods 0.000 title 1
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000004021 humic acid Substances 0.000 claims abstract description 44
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920001732 Lignosulfonate Polymers 0.000 claims abstract description 22
- 239000003999 initiator Substances 0.000 claims abstract description 22
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 20
- 229930006000 Sucrose Natural products 0.000 claims abstract description 20
- 239000003112 inhibitor Substances 0.000 claims abstract description 20
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 20
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 20
- 239000005720 sucrose Substances 0.000 claims abstract description 20
- -1 sucrose ester Chemical class 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 36
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 239000011260 aqueous acid Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 14
- 238000010792 warming Methods 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- 235000010265 sodium sulphite Nutrition 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 230000035484 reaction time Effects 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- 230000033228 biological regulation Effects 0.000 claims description 7
- 239000012153 distilled water Substances 0.000 claims description 7
- 229950007687 macrogol ester Drugs 0.000 claims description 7
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 229920005610 lignin Polymers 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- 150000005208 1,4-dihydroxybenzenes Chemical group 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 3
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 3
- 229940120693 copper naphthenate Drugs 0.000 claims description 3
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical group [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 235000019394 potassium persulphate Nutrition 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims 2
- 241000158728 Meliaceae Species 0.000 claims 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 235000019357 lignosulphonate Nutrition 0.000 abstract 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 239000003250 coal slurry Substances 0.000 description 15
- 230000006872 improvement Effects 0.000 description 9
- 238000001556 precipitation Methods 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 4
- 235000019256 formaldehyde Nutrition 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002509 fulvic acid Substances 0.000 description 1
- 229940095100 fulvic acid Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Description
Claims (10)
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CN105567354A CN105567354A (zh) | 2016-05-11 |
CN105567354B true CN105567354B (zh) | 2017-05-24 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105542886A (zh) * | 2014-11-03 | 2016-05-04 | 太原市天鼎恒砼外加剂科技发展有限公司 | 水煤浆分散剂及其制备方法 |
CN108531231A (zh) * | 2018-04-24 | 2018-09-14 | 常州五荣化工有限公司 | 一种低金属敏感型水煤浆分散剂的制备方法 |
CN108913242B (zh) * | 2018-07-05 | 2020-11-24 | 义乌市君胜科技有限公司 | 一种水煤浆分散剂 |
CN110804122A (zh) * | 2019-11-19 | 2020-02-18 | 安徽鑫固环保股份有限公司 | 一种蔗糖酯合成疏型水煤浆分散剂的新方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102051242A (zh) * | 2010-12-17 | 2011-05-11 | 贵阳超群实业有限公司 | 一种油水煤浆及制备方法 |
CN103045317A (zh) * | 2012-12-26 | 2013-04-17 | 中国东方电气集团有限公司 | 一种木质素系水煤浆分散剂及其制备方法 |
EP2749547A1 (en) * | 2012-12-04 | 2014-07-02 | Services Pétroliers Schlumberger | Additive for well cementing applications |
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2014
- 2014-10-13 CN CN201410538211.0A patent/CN105567354B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102051242A (zh) * | 2010-12-17 | 2011-05-11 | 贵阳超群实业有限公司 | 一种油水煤浆及制备方法 |
EP2749547A1 (en) * | 2012-12-04 | 2014-07-02 | Services Pétroliers Schlumberger | Additive for well cementing applications |
CN103045317A (zh) * | 2012-12-26 | 2013-04-17 | 中国东方电气集团有限公司 | 一种木质素系水煤浆分散剂及其制备方法 |
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Address after: 030027 Shanxi Province, Taiyuan Jiufeng Jiancaoping District Binfeng garden road block A room 252 Applicant after: TAIYUAN CITY TIANDINGHENG CONCRETE ADMIXTURES TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 030027 Shanxi Province, Taiyuan Jiufeng Jiancaoping District Binfeng garden road block A room 252 Applicant before: TAIYUAN TIANDING HENGQUAN ADMIXTURE TECHNOLOGY DEVELOPMENT Co.,Ltd. |
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Address after: 030027 Room 252, Building A, Binfengyuan, Jiufeng Road, Jiancaoping District, Taiyuan City, Shanxi Province Patentee after: Shanxi Tiandingheng Concrete Admixture Technology Development Co.,Ltd. Address before: 030027 Room 252, Building A, Binfengyuan, Jiufeng Road, Jiancaoping District, Taiyuan City, Shanxi Province Patentee before: TAIYUAN CITY TIANDINGHENG CONCRETE ADMIXTURES TECHNOLOGY DEVELOPMENT Co.,Ltd. |
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