CN105531358B - 润滑脂 - Google Patents
润滑脂 Download PDFInfo
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- CN105531358B CN105531358B CN201480051221.XA CN201480051221A CN105531358B CN 105531358 B CN105531358 B CN 105531358B CN 201480051221 A CN201480051221 A CN 201480051221A CN 105531358 B CN105531358 B CN 105531358B
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- Prior art keywords
- lubricating grease
- mass
- salt
- grease according
- calculated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004519 grease Substances 0.000 title claims abstract description 120
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 118
- -1 inorganic acid salts Chemical class 0.000 claims abstract description 61
- 239000003921 oil Substances 0.000 claims abstract description 30
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000011737 fluorine Substances 0.000 claims abstract description 28
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 28
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 18
- 239000010452 phosphate Substances 0.000 claims abstract description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 16
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000002199 base oil Substances 0.000 claims abstract description 5
- 239000000344 soap Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 16
- 239000002562 thickening agent Substances 0.000 claims description 14
- 239000003963 antioxidant agent Substances 0.000 claims description 13
- 235000011180 diphosphates Nutrition 0.000 claims description 13
- 230000003078 antioxidant effect Effects 0.000 claims description 12
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 229920000570 polyether Polymers 0.000 claims description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 10
- 229940048084 pyrophosphate Drugs 0.000 claims description 10
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 8
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 claims description 8
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 8
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical group [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 8
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 8
- 159000000000 sodium salts Chemical class 0.000 claims description 8
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 8
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 150000001412 amines Chemical group 0.000 claims description 7
- 239000013556 antirust agent Substances 0.000 claims description 7
- 239000002585 base Substances 0.000 claims description 7
- 239000005864 Sulphur Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 150000004665 fatty acids Chemical group 0.000 claims description 6
- 229910052751 metal Chemical class 0.000 claims description 6
- 239000002184 metal Chemical class 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 5
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical group [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 3
- 239000004305 biphenyl Substances 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 3
- 238000005461 lubrication Methods 0.000 claims description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 3
- 239000001205 polyphosphate Substances 0.000 claims description 3
- 235000011176 polyphosphates Nutrition 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims description 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 2
- 150000001721 carbon Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical class OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims description 2
- AAQNGTNRWPXMPB-UHFFFAOYSA-N dipotassium;dioxido(dioxo)tungsten Chemical compound [K+].[K+].[O-][W]([O-])(=O)=O AAQNGTNRWPXMPB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012990 dithiocarbamate Substances 0.000 claims description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 150000002460 imidazoles Chemical class 0.000 claims description 2
- 125000005341 metaphosphate group Chemical group 0.000 claims description 2
- 239000002530 phenolic antioxidant Substances 0.000 claims description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims description 2
- 150000003008 phosphonic acid esters Chemical class 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 150000003377 silicon compounds Chemical class 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 235000010265 sodium sulphite Nutrition 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 150000004867 thiadiazoles Chemical class 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 4
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims 2
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 claims 1
- 150000007522 mineralic acids Chemical class 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- SJZFFCZQDPVHQI-UHFFFAOYSA-N potassium;sulfurous acid Chemical compound [K].OS(O)=O SJZFFCZQDPVHQI-UHFFFAOYSA-N 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 150000003852 triazoles Chemical class 0.000 claims 1
- 238000005829 trimerization reaction Methods 0.000 claims 1
- 210000002700 urine Anatomy 0.000 claims 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 abstract description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 14
- 238000005299 abrasion Methods 0.000 description 8
- 235000010288 sodium nitrite Nutrition 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 235000006708 antioxidants Nutrition 0.000 description 5
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 5
- 239000001177 diphosphate Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 2
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 239000004990 Smectic liquid crystal Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- SERXUJOJECNICY-UHFFFAOYSA-N [Rb].S(O)(O)=O Chemical compound [Rb].S(O)(O)=O SERXUJOJECNICY-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- SJPVUFMOBDBTHQ-UHFFFAOYSA-N barium(2+);dioxido(dioxo)tungsten Chemical compound [Ba+2].[O-][W]([O-])(=O)=O SJPVUFMOBDBTHQ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 1
- OQFRENMCLHGPRB-UHFFFAOYSA-N copper;dioxido(dioxo)tungsten Chemical compound [Cu+2].[O-][W]([O-])(=O)=O OQFRENMCLHGPRB-UHFFFAOYSA-N 0.000 description 1
- BBLSYMNDKUHQAG-UHFFFAOYSA-L dilithium;sulfite Chemical compound [Li+].[Li+].[O-]S([O-])=O BBLSYMNDKUHQAG-UHFFFAOYSA-L 0.000 description 1
- SSWAPIFTNSBXIS-UHFFFAOYSA-N dioxido(dioxo)tungsten;iron(2+) Chemical compound [Fe+2].[O-][W]([O-])(=O)=O SSWAPIFTNSBXIS-UHFFFAOYSA-N 0.000 description 1
- CRLHSBRULQUYOK-UHFFFAOYSA-N dioxido(dioxo)tungsten;manganese(2+) Chemical compound [Mn+2].[O-][W]([O-])(=O)=O CRLHSBRULQUYOK-UHFFFAOYSA-N 0.000 description 1
- QLTKZXWDJGMCAR-UHFFFAOYSA-N dioxido(dioxo)tungsten;nickel(2+) Chemical compound [Ni+2].[O-][W]([O-])(=O)=O QLTKZXWDJGMCAR-UHFFFAOYSA-N 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- ZRRLFMPOAYZELW-UHFFFAOYSA-N disodium;hydrogen phosphite Chemical compound [Na+].[Na+].OP([O-])[O-] ZRRLFMPOAYZELW-UHFFFAOYSA-N 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- DJZHPOJZOWHJPP-UHFFFAOYSA-N magnesium;dioxido(dioxo)tungsten Chemical compound [Mg+2].[O-][W]([O-])(=O)=O DJZHPOJZOWHJPP-UHFFFAOYSA-N 0.000 description 1
- JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910000344 rubidium sulfate Inorganic materials 0.000 description 1
- GANPIEKBSASAOC-UHFFFAOYSA-L rubidium(1+);sulfate Chemical compound [Rb+].[Rb+].[O-]S([O-])(=O)=O GANPIEKBSASAOC-UHFFFAOYSA-L 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 239000011684 sodium molybdate Substances 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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Abstract
本发明的润滑脂特征在于：以氟系合成油为基础油，配合有选自磷酸盐、钨酸盐、硫酸盐和亚硫酸盐中的一种以上的无机酸盐。根据本发明的润滑脂，由于耐磨耗性优异、环境负荷也低，可以适合地在轴承和齿轮等中使用。
Description
技术领域
本发明涉及以氟系合成油为基础油的润滑脂。
背景技术
以氟系合成油为基础油的所谓氟系润滑脂由于油溶性差，所以烃系润滑剂中通用的各种添加剂的使用受到了限制。例如，当对氟润滑脂赋予耐磨耗性和防锈功能时，一直以来使用无机钝化剂亚硝酸钠。然而，已知亚硝酸钠在酸性条件下与仲胺反应生成N-亚硝胺。由于N-亚硝胺是环境负荷物质，所以需要能代替亚硝酸钠的添加剂。
从而，提出添加脂肪族二羧酸金属盐、单酰胺单羧酸金属盐或者单酯羧酸金属盐的至少一种作为增稠剂的氟系润滑脂的方案（参考专利文献1）。在专利文献1中，记载了根据该氟系润滑脂，可以提供耐磨耗性、耐泄露性和清净性等优异，并且成本上也能得到满足的氟系润滑脂。此外，提出添加作为增稠剂的聚四氟乙烯和作为防锈剂的癸二酸金属盐等脂肪酸金属盐的氟系润滑脂的方案（参考专利文献2）。在专利文献2中，记载了可以提供蒸发特性和防锈性优异的氟系润滑脂。
现有技术文献
专利文献
专利文献1：日本特开2001-354986号公报
专利文献2：日本特开2008-013652号公报。
发明内容
发明要解决的问题
然而，在专利文献1和专利文献2中记载的氟系润滑脂，耐磨耗性未必充分。此外，专利文献2的氟系润滑脂由于添加了有机酸金属盐，因而耐热性不充分。
本发明的目的是提供具有防锈性，并且耐磨耗性优异，环境负荷也低的氟系润滑脂。
解决课题的手段
要解决上述课题，本发明提供了如下所述的润滑脂。
（1）润滑脂，其为以氟系合成油为基础油的润滑脂，其特征在于，配合有选自磷酸盐、钨酸盐、硫酸盐和亚硫酸盐中的一种以上的无机酸盐。
（2）在上述润滑脂中，其特征在于，所述无机酸盐为碱金属盐。
（3）在上述润滑脂中，其特征在于，所述磷酸盐为正磷酸盐、磷酸氢盐、多聚磷酸盐、亚磷酸盐和偏磷酸盐的至少任一种。
（4）润滑脂，其为以氟系合成油为基础油的润滑脂，其特征在于，配合有无机酸盐，所述无机酸盐是磷酸盐和钨酸盐。
（5）在上述润滑脂中，其特征在于，所述磷酸盐为磷酸氢盐、焦磷酸盐、三聚磷酸盐和四聚磷酸盐的至少任一种。
（6）在上述润滑脂中，其特征在于，使用相同碱金属的盐。
（7）在上述润滑脂中，其特征在于，所述无机酸盐为钠盐。
（8）在上述润滑脂中，其特征在于，所述无机酸盐的配合量为以润滑脂总量基准计0.5质量%以上且15质量%以下。
（9）在上述润滑脂中，其特征在于，所述氟系合成油为全氟烷基聚醚油。
根据本发明，可以提供耐磨耗性优异的氟润滑脂。
具体实施方式
本发明的润滑脂（以下也称为“本润滑脂”）是以氟系合成油为基础油的润滑脂，其特征在于，配合有选自磷酸盐、钨酸盐、硫酸盐和亚硫酸盐中的一种以上的无机酸盐。以下进行详细地说明。
本润滑脂是所谓的氟系润滑脂，作为基础油所使用的氟系合成油只要是其分子中含有氟，可以作为润滑油使用的氟系合成油，则没有限制。特别地，非活性的、蒸汽压低的全氟烷基聚醚油可以优选用作基础油。作为全氟烷基聚醚油，优选40℃运动粘度为5 mm2/s以上且1000 mm2/s以下，更优选50 mm2/s以上且1000 mm2/s以下，进一步优选70 mm2/s以上且800 mm2/s以下。若40℃运动粘度在上述范围，则倾点和蒸发量的平衡优异。
本润滑脂中的基础油比例以润滑脂总量基准计优选50质量%以上且98质量%以下，更优选65质量%以上且85%质量以下。
作为在本润滑脂中所使用的增稠剂，只要在氟系合成油中分散，是可以形成润滑脂状（半固体状）的固体，则可以使用。例如，可以列举出以聚四氟乙烯、聚三氟乙烯为代表的氟树脂、以Li皂、Ca皂、Al皂为代表的金属皂、以Li复合皂、Ca复合皂、Al复合皂为代表的复合皂、尿素化合物、氨基甲酸酯化合物、膨润土、硅化合物、对苯二甲酸钠、氰脲酸三聚氰胺（melamine cyanurate）、炭黑等。特别优选耐热性优异的聚四氟乙烯、二氧化硅、氰脲酸三聚氰胺、炭黑等。
本润滑脂中的增稠剂的比例以润滑脂总量为基准，优选1~49质量%，更优选10~40质量%。若增稠剂的比例为1质量以上，则具有充分的流动性，若在49质量%以下，则不会变得过硬。即，若增稠剂的比例在上述范围，则流动性和硬度（柔软度）的平衡优异。
在本润滑脂中，作为无机酸盐配合了选自磷酸盐、钨酸盐、硫酸盐和亚硫酸盐中的一种以上的无机酸盐。这些无机酸盐有效地提高了耐磨耗性。
作为上述磷酸盐，可以优选使用正磷酸盐、磷酸氢盐、多聚磷酸盐、亚磷酸盐和偏磷酸盐等。作为多聚磷酸盐，可以列举出焦磷酸盐（二磷酸盐）、三聚磷酸盐和四聚磷酸盐等。从效果的观点出发，这些磷酸盐中优选磷酸氢盐、焦磷酸盐（二磷酸盐）、三聚磷酸盐和四聚磷酸盐。
作为钨酸盐，可以列举出例如钨酸锂、钨酸钠、钨酸钾、钨酸铷、钨酸铯、钨酸镁、钨酸钙、钨酸锶、钨酸钡、钨酸锆、钨酸锰、钨酸铁、钨酸钴、钨酸镍、钨酸铜、钨酸银、钨酸锌、钨酸镉和钨酸铵等。
在此，如果组合使用上述磷酸盐和钨酸盐，由于其协同效果，可以显著地提高耐磨耗性。此时，作为磷酸盐，优选磷酸氢盐、焦磷酸盐（二磷酸盐）、三聚磷酸盐和四聚磷酸盐。此外，作为这些盐，优选同为碱金属盐，更优选同为钠盐。
作为硫酸盐，可以列举出例如硫酸锂、硫酸钠、硫酸钾、硫酸铷、硫酸锶、硫酸镁、硫酸钙和硫酸铵等。
作为亚硫酸盐，可以列举出例如亚硫酸锂、亚硫酸钠、亚硫酸钾、亚硫酸铷、亚硫酸锶、亚硫酸镁、亚硫酸钙和亚硫酸铵等。
在上述各无机酸盐中，从效果的观点出发，优选碱金属盐。作为碱金属盐，可以优选地列举出钠盐、钾盐和锂盐，特别优选钠盐。
上述无机酸盐的优选的配合量为0.5质量%以上且15质量%以下，更优选的配合量为0.8质量%以上且12质量%以下，还更优选的配合量为2质量%以上且8质量%以下。
此外，作为无机酸盐使用焦磷酸盐，特别是焦磷酸钠时，优选0.8质量%以上且8质量%以下左右。使用钨酸盐，特别是钨酸钠时，优选2质量%以上且12质量%以下左右。
本润滑脂进一步可以根据需要添加抗氧化剂、防锈剂、防腐蚀剂、极压剂和油性剂等在润滑脂中通用添加的添加剂。
作为抗氧化剂，可以列举出例如烷基二苯基胺（烷基的碳原子数优选为4以上且20以下）、三苯基胺、苯基-α-萘基胺、吩噻嗪（フェノチアジン）、烷基化苯基-α-萘基胺、吩噻嗪（フェニチアジン）和烷基化吩噻嗪（アルキル化フェニチアジン）等胺系抗氧化剂，2,6-二叔丁基-4-甲基苯酚和4,4'-亚甲基双(2,6-二叔丁基苯酚)等酚系抗氧化剂，或者硫系抗氧化剂。它们可以单独使用一种，也可以组合两种以上使用。
抗氧化剂的配合量虽没有特别的限定，但以润滑脂总量基准计优选0.05质量%以上且7质量%以下。
作为防锈剂，可以列举出例如脂肪酸、脂肪酸皂、脂肪酸胺盐、烷基磺酸盐、氧化石蜡和聚氧烷基醚等。
防锈剂的配合量虽没有特别的限定，但以润滑脂总量基准计优选0.1质量%以上且2质量%以下左右。
此外作为防腐蚀剂，可以列举出例如苯并三唑系、甲苯基三唑系、噻二唑系和咪唑系的各种化合物。它们可以单独使用一种，也可以组合两种以上使用。
防腐蚀剂的配合量虽没有特别的限定，但以润滑脂总量基准计优选0.01质量%以上且3质量%以下，更优选0.01质量%以上且1质量%以下。
作为极压剂，可以列举出例如硫系极压剂和磷系极压剂。作为硫系极压剂，可以列举出例如硫化烯烃、硫化油脂、硫化酯、硫代碳酸酯类、二硫代氨基甲酸酯类、多硫化物类等。作为磷系极压剂，可以列举出例如亚磷酸酯类、磷酸酯类、膦酸酯类，以及其胺盐或者金属盐。它们可以单独使用一种，也可以组合两种以上使用。
极压剂的配合量虽没有特别的限定，但以润滑脂总量基准计优选0.1质量%以上且20质量%以下。
作为油性剂，可以列举出例如脂肪族单羧酸、聚合脂肪酸、羟基脂肪酸、脂肪族单醇、脂肪族单胺、脂肪族单羧酸酰胺、多元醇与脂肪族单羧酸的偏酯。它们可以单独使用一种，也可以组合两种以上使用。
油性剂的配合量虽没有特别的限定，但以润滑脂总量基准计优选0.01质量%以上且10质量%以下的范围。
要制造（调制）本润滑脂，例如，在氟系合成油（全氟烷基聚醚油等）中以规定量添加增稠剂（含前体）、无机酸盐和其他必要的添加剂，加热、搅拌，由此进行润滑脂化，然后根据需要，用三辊等进行混炼即可。
本发明的润滑脂对在高温、苛刻的条件下使用的轴承（滚动轴承和滑动轴承等）、齿轮、销-衬套、滚珠丝杠、直线导轨和各种滑动件等有效。
实施例
以下通过列举实施例和比较例，更具体地说明本发明。尚需说明，本发明并不以任何形式限定于实施例的内容。
[实施例1~14，对比例1~3，参考例1~3]
以规定量配合下述的表1所示的无机酸盐，调制各试验润滑脂。尚需说明，作为基础油使用40℃运动粘度为400 mm2/s的全氟聚醚，作为增稠剂配合了25质量%的聚四氟乙烯。
表1
| 无机酸盐 | 添加量（质量%） | 磨耗痕径（mm） | |
| 实施例1 | 焦磷酸钠 | 0.9 | 0.31 |
| 实施例2 | 焦磷酸钠 | 2.5 | 0.21 |
| 实施例3 | 焦磷酸钠 | 5.0 | 0.24 |
| 实施例4 | 焦磷酸钠 | 7.5 | 0.26 |
| 实施例5 | 钨酸钠 | 2.5 | 0.33 |
| 实施例6 | 钨酸钠 | 5.0 | 0.26 |
| 实施例7 | 钨酸钠 | 7.5 | 0.16 |
| 实施例8 | 钨酸钠 | 10.0 | 0.20 |
| 实施例9 | 偏磷酸钠 | 5.0 | 0.25 |
| 实施例10 | 三聚磷酸钠 | 5.0 | 0.24 |
| 实施例11 | 四聚磷酸钠 | 5.0 | 0.23 |
| 实施例12 | 焦磷酸钾 | 5.0 | 0.27 |
| 实施例13 | 磷酸氢二钠 | 5.0 | 0.22 |
| 实施例14 | 亚磷酸氢二钠 | 5.0 | 0.23 |
| 比较例1 | 无添加 | 0.0 | 0.57 |
| 比较例2 | 碳酸钙 | 5.0 | 0.33 |
| 比较例3 | 钼酸钠 | 5.0 | 0.43 |
| 参考例1 | 亚硝酸钠 | 0.9 | 0.30 |
| 参考例2 | 亚硝酸钠 | 2.5 | 0.29 |
| 参考例3 | 亚硝酸钠 | 5.0 | 0.29 |
[评价方法]
使用在DIN51834中记载的球盘（ボールオンディスク,ball on disk）试验机，在盘上涂布各试验润滑脂后，在下述条件下进行摩擦试验，得到试验开始60分钟后的磨耗痕直径的纵横平均值（单位 mm）。其结果显示在表1中。
温度：190℃
荷重：50 N
振幅：1 mm
频率：50 Hz
球径：10 mm。
[评价结果]
实施例1~14所涉及的本发明的润滑脂由于配合了规定的无机酸盐，不存在环境负荷的问题，即使与参考例的亚硝酸钠（环境负荷大）相比较，也显示出不逊色的优异耐磨耗性。
比较例1~3的润滑脂，由于没有配合本发明涉及的规定的无机酸盐，所以耐磨耗性差。
[实施例15~17]
在表2中，对于组合使用焦磷酸钠和钨酸钠的试验润滑脂，和表1中的试验润滑脂一样显示出评价了耐磨耗性的结果。
表2
[评价结果]
与作为无机酸盐单独添加了焦磷酸钠（5.0质量%）的实施例3和单独添加了钨酸钠（5.0质量%）的实施例6相比较，同样添加量（总量5.0质量%）的实施例16的磨耗痕径显著地小，可以理解为这些添加剂具有协同效果。
Claims (52)
1.润滑脂，其为以氟系合成油为基础油的润滑脂，其特征在于，配合有选自磷酸盐、钨酸盐、硫酸盐和亚硫酸盐中的一种以上的无机酸盐，所述无机酸盐为碱金属盐，所述无机酸盐的配合量以润滑脂总量基准计为0.5质量％以上且15质量％以下，所述氟系合成油为全氟烷基聚醚油，所述碱金属盐为钠盐和/或钾盐。
2.根据权利要求1所述的润滑脂，其特征在于，所述磷酸盐为正磷酸盐、磷酸氢盐、多聚磷酸盐、亚磷酸盐和偏磷酸盐的至少任一种。
3.润滑脂，其为以氟系合成油为基础油的润滑脂，其特征在于，配合有无机酸盐，所述无机酸盐为磷酸盐和钨酸盐，所述无机酸盐的配合量以润滑脂总量基准计为0.5质量％以上且15质量％以下，所述氟系合成油为全氟烷基聚醚油，所述碱金属盐为钠盐和/或钾盐。
4.根据权利要求3所述的润滑脂，其特征在于，所述磷酸盐为磷酸氢盐、焦磷酸盐、三聚磷酸盐和四聚磷酸盐的至少任一种。
5.根据权利要求3或者权利要求4所述的润滑脂，其特征在于，使用相同碱金属的盐。
6.根据权利要求3或者权利要求4所述的润滑脂，其特征在于，所述无机酸盐是钠盐。
7.根据权利要求1所述的润滑脂，其特征在于，所述全氟烷基聚醚油的40℃运动粘度为5mm2/s以上且1000mm2/s以下。
8.根据权利要求7所述的润滑脂，其特征在于，所述全氟烷基聚醚油的40℃运动粘度为50mm2/s以上且1000mm2/s以下。
9.根据权利要求8所述的润滑脂，其特征在于，所述全氟烷基聚醚油的40℃运动粘度为70mm2/s以上且800mm2/s以下。
10.根据权利要求1或权利要求3所述的润滑脂，其特征在于，所述基础油的比例以润滑脂总量基准计为50质量％以上且98质量％以下。
11.根据权利要求10所述的润滑脂，其特征在于，所述基础油的比例以润滑脂总量基准计为65质量％以上且85质量％以下。
12.根据权利要求1或权利要求3所述的润滑脂，其特征在于，添加有氟树脂、金属皂、尿素化合物、氨基甲酸酯化合物、膨润土、硅化合物、对苯二甲酸钠、氰脲酸三聚氰胺、和炭黑中的任一种增稠剂。
13.根据权利要求12所述的润滑脂，其特征在于，所述金属皂是复合皂。
14.根据权利要求12所述的润滑脂，其特征在于，所述氟树脂为聚四氟乙烯或聚三氟乙烯。
15.根据权利要求12所述的润滑脂，其特征在于，所述金属皂为Li皂、Ca皂、和Al皂中的任一种。
16.根据权利要求12所述的润滑脂，其特征在于，所述增稠剂为聚四氟乙烯、二氧化硅、氰脲酸三聚氰胺、和炭黑中的任一种。
17.根据权利要求12所述的润滑脂，其特征在于，所述增稠剂的比例以润滑脂总量基准计为1质量％以上且49质量％以下。
18.根据权利要求17所述的润滑脂，其特征在于，所述增稠剂的比例以润滑脂总量基准计为10质量％以上且40质量％以下。
19.根据权利要求2所述的润滑脂，其特征在于，所述多聚磷酸盐为焦磷酸盐、三聚磷酸盐和四聚磷酸盐中的任一种。
20.根据权利要求1所述的润滑脂，其特征在于，所述磷酸盐为磷酸氢盐、焦磷酸盐、三聚磷酸盐和四聚磷酸盐中的任一种。
21.根据权利要求1或权利要求3所述的润滑脂，其特征在于，所述钨酸盐为钨酸钠和/或钨酸钾。
22.根据权利要求1所述的润滑脂，其特征在于，所述硫酸盐为硫酸钠和/或硫酸钾。
23.根据权利要求1所述的润滑脂，其特征在于，所述亚硫酸盐为亚硫酸钠和/或亚硫酸钾。
24.根据权利要求1或权利要求3所述的润滑脂，其特征在于，所述无机酸盐的配合量以润滑脂总量基准计为0.8质量％以上且12质量％以下。
25.根据权利要求24所述的润滑脂，其特征在于，所述无机酸盐的配合量以润滑脂总量基准计为2质量％以上且8质量％以下。
26.根据权利要求4或权利要求20所述的润滑脂，其特征在于，使用焦磷酸盐作为所述无机酸盐时，所述无机酸盐的配合量以润滑脂总量基准计为0.8质量％以上且8质量％以下。
27.根据权利要求26所述的润滑脂，其特征在于，所述焦磷酸盐为焦磷酸钠。
28.根据权利要求1或权利要求3所述的润滑脂，其特征在于，使用钨酸盐作为所述无机酸盐时，所述无机酸盐的配合量以润滑脂总量基准计为2质量％以上且12质量％以下。
29.根据权利要求28所述的润滑脂，其特征在于，所述钨酸盐为钨酸钠。
30.根据权利要求1或权利要求3所述的润滑脂，其特征在于，还添加有抗氧化剂、防锈剂、防腐蚀剂、极压剂、和油性剂中的任一种添加剂。
31.根据权利要求30所述的润滑脂，其特征在于，所述抗氧化剂为胺系抗氧化剂、酚系抗氧化剂、和硫系抗氧化剂中的至少任一种。
32.根据权利要求31所述的润滑脂，其特征在于，所述胺系抗氧化剂为烷基二苯基胺、三苯基胺、苯基-α-萘基胺、吩噻嗪、烷基化苯基-α-萘胺、和烷基化吩噻嗪中的至少任一种。
33.根据权利要求32所述的润滑脂，其特征在于，所述烷基二苯基胺的烷基的碳原子数为4以上且20以下。
34.根据权利要求31所述的润滑脂，其特征在于，所述酚系抗氧化剂为2,6-二叔丁基-4-甲基苯酚和4,4'-亚甲基双(2,6-二叔丁基苯酚)中的至少任一种。
35.根据权利要求30所述的润滑脂，其特征在于，所述抗氧化剂的配合量以润滑脂总量基准计为0.05质量％以上且7质量％以下。
36.根据权利要求30所述的润滑脂，其特征在于，所述防锈剂为脂肪酸、脂肪酸皂、脂肪酸胺盐、烷基磺酸盐、氧化石蜡和聚氧烷基醚中的任一种。
37.根据权利要求30所述的润滑脂，其特征在于，所述防锈剂的配合量以润滑脂总量基准计为0.1质量％以上且2质量％以下。
38.根据权利要求30所述的润滑脂，其特征在于，所述防腐蚀剂为苯并三唑系、甲苯基三唑系、噻二唑系和咪唑系的化合物中的至少任一种。
39.根据权利要求30所述的润滑脂，其特征在于，所述防腐蚀剂的配合量以润滑脂总量基准计为0.01质量％以上且3质量％以下。
40.根据权利要求30所述的润滑脂，其特征在于，所述极压剂为硫系极压剂、和磷系极压剂中的至少任一种。
41.根据权利要求40所述的润滑脂，其特征在于，所述硫系极压剂为硫化烯烃、硫化油脂、硫化酯、硫代碳酸酯类、二硫代氨基甲酸酯类、多硫化物类中的至少任一种。
42.根据权利要求40所述的润滑脂，其特征在于，所述磷系极压剂为亚磷酸酯类、磷酸酯类、膦酸酯类、以及其胺盐或者金属盐中的至少任一种。
43.根据权利要求30所述的润滑脂，其特征在于，所述极压剂的配合量以润滑脂总量基准计为0.1质量％以上且20质量％以下。
44.根据权利要求30所述的润滑脂，其特征在于，所述油性剂为脂肪族单羧酸、聚合脂肪酸、羟基脂肪酸、脂肪族单醇、脂肪族单胺、脂肪族单羧酸酰胺、和多元醇与脂肪族单羧酸的偏酯中的至少任一种。
45.根据权利要求30所述的润滑脂，其特征在于，所述油性剂的配合量以组合物总量基准计为0.01质量％以上且10质量％以下。
46.根据权利要求1或权利要求3所述的润滑脂，其特征在于，其利用于轴承、齿轮、销-衬套、滚珠丝杠和直线导轨中的任一种。
47.根据权利要求1或权利要求3所述的润滑脂，其特征在于，其利用于滑动件。
48.根据权利要求46所述的润滑脂，其特征在于，所述轴承为滚动轴承或滑动轴承。
49.润滑脂的制造方法，其特征在于，在氟系合成油中以规定量添加增稠剂、无机酸盐，加热、搅拌，由此进行润滑脂化，所述无机酸盐为碱金属盐，所述无机酸盐的配合量以润滑脂总量基准计为0.5质量％以上且15质量％以下，所述氟系合成油为全氟烷基聚醚油，所述碱金属盐为钠盐和/或钾盐。
50.根据权利要求49所述的润滑脂的制造方法，其特征在于，在添加所述增稠剂和无机酸盐的同时，添加抗氧化剂、防锈剂、防腐蚀剂、极压剂、和油性剂中的任一种添加剂。
51.根据权利要求49或50所述的润滑脂的制造方法，其特征在于，进行所述润滑脂化后，进一部进行混炼。
52.根据权利要求51所述的润滑脂的制造方法，其特征在于，所述混炼使用三辊。
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