CN105482532A - Anti-aging traditional Chinese painting pigment and preparation method thereof - Google Patents
Anti-aging traditional Chinese painting pigment and preparation method thereof Download PDFInfo
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- CN105482532A CN105482532A CN201511025355.7A CN201511025355A CN105482532A CN 105482532 A CN105482532 A CN 105482532A CN 201511025355 A CN201511025355 A CN 201511025355A CN 105482532 A CN105482532 A CN 105482532A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses an anti-aging traditional Chinese painting pigment. The anti-aging traditional Chinese painting pigment is prepared from a color matrix, a dispersing agent, salicylic acid phenyl ester, a colloid, a light stabilizer, acrylic resin, a surfactant, a waterborne wetting agent, benzisothiazolone and deionized water, wherein a mixture of carrageenan and locust bean gum is adopted as the colloid. According to the anti-aging traditional Chinese painting pigment and a preparation method thereof, the anti-aging property of the pigment is improved by mainly adding the light stabilizer and adopting melamine resin with the anti-aging and antibacterial effects as a wall material of the pigment; by adding the mixture of the carrageenan and the locust bean gum which generate the synergistic effect, the moisture retention of the pigment can be improved.
Description
Technical field
The present invention relates to a kind of Chinese painting color, specifically, the present invention relates to a kind of ageing-resistant Chinese painting color and preparation method thereof.
Background technology
Traditional Chinese Painting one word originates from Han dynasty, and people from Han dynasty thinks that China occupies person among the world, so be called China, is called " Chinese painting " by the drawing of China, is called for short " traditional Chinese Painting ".Mainly refer to and to be drawn on thin,tough silk, rice paper, silks and the scroll painting of in addition mounting.Traditional Chinese Painting is the traditional drawing form of Han nationality, is to dip in water, ink with writing brush, color to be drawn on thin,tough silk or paper.Instrument and material have writing brush, ink, a kind of can be reflective novel Chinese painting color, rice paper, thin,tough silk etc., subject matter can divide personage, scenery with hills and waters, birds and flowers etc., and skill and technique can divide tool to resemble and enjoyable.Chinese painting, in content and artistic creation, embodies the understanding of ancients to aspects such as nature, society and politics associated therewith, philosophy, religion, morals, literature and art.
Traditional Chinese painting color, is mainly divided into mineral color, vegetable pigment and chemical fusion pigment three major types.The main color of vegetable pigment has dark blue, kermes, gamboge etc.Raw mineral materials mainly contains cinnabar, orpiment, malachite green etc.Also many in current Chinese painting color, but there is corresponding problem, as shortcomings such as light fugitive photographs, mainly at present in combination, add organic photostabilizer at settling mode, because photostabilizer belongs to pure organic compound, there is volatile, bloom, migration, by shortcomings such as solvent extractions, this not only have impact on the persistence that its usefulness plays, and also causes contaminate environment simultaneously; Therefore can add the reagent with anti-ultraviolet aging in pigment, to improve the ageing resistance of pigment, also the wall material of capsule be adopted simultaneously and there is uvioresistant performance material, to improve the ageing resistance of pigment.Therefore how to make Chinese painting color obtain emphasis that lasting ultraviolet resistance and light stability are current researches.
Summary of the invention
The object of this invention is to provide a kind of permanent seal cooling Chinese painting color and preparation method thereof, it mainly adopts to add photostabilizer and adopt has the wall material that ageing-resistant and melmac that is anti-microbial effect is pigment, improve the ageing-resistant performance of pigment, by adding the mixture of carrageenin and Viscogum BE, both produce synergy, can improve the moisture retention of pigment.
The technical solution used in the present invention is a kind of ageing-resistant Chinese painting color, comprises the component of following weight part:
Color base: 5 ~ 15 parts; Dispersion agent: 0.2 ~ 5 part;
Salicylic acid phenyl ester: 1 ~ 5 part; Colloid: 7 ~ 25 parts;
Photostabilizer: 0.2 ~ 3 part; Acrylic resin: 2 ~ 12 parts;
Tensio-active agent: 3 ~ 8 parts; Aqueous wetting agent: 1 ~ 5 part;
BIT: 2 ~ 6 parts; Deionized water: 5 ~ 30 parts.
Preferably, described colloid is the mixture of carrageenin and Viscogum BE, and the weight part ratio of described carrageenin and Viscogum BE is 1:1 ~ 4.
Preferably, described photostabilizer is photomask agent, UV light absorber, quencher, radical scavenger or peroxide decomposer.
Preferably, described dispersion agent is polyether glycol.
Preferably, described tensio-active agent be sodium alkyl benzene sulfonate, tetradecyl sodium sulfonate, alkylpolyoxyethylene sodium sulfate, sodium soap, alkyl ether phosphates ester ammonium salt, succsinic acid two (2-Ethyl-butyl) sodium sulfonate, sodium metnylene bis-naphthalene sulfonate, surfactant AS, thunder rice side A, triethanolamine oleate, fatty alcohol-polyoxyethylene ether phosphate monoester, lipid acid sodium phosphate salt, polyol ester, lauryl alcohol list or bis phosphoric acid acid potassium salt, alkyl glycoside one or more.
Preferably, described aqueous wetting agent propylene glycol, glycerine, polyoxyethylene glycol, sorbyl alcohol, triglycerin, 3,4-glycol ether METHYLPYRROLIDONEs or its combination.
Another object of the present invention is to provide a kind of preparation method of ageing-resistant Chinese painting color, comprises the steps:
Step 1): take each component by proportioning, deionized water is divided into two parts by weight, a deionized water is added in heating container, then after adding photostabilizer, acrylic resin, aqueous wetting agent stir dissolving, being then heated to 80 ~ 90 DEG C, adding colloid, heating holding temperature while stirring and to dissolve completely to it at 80 ~ 90 DEG C and become hydrosol;
Step 2): get another part of deionized water, add dispersion agent be mixed with concentration be 30% ~ 40% solution, add color base, salicylic acid phenyl ester, rare paste is become to grind, along with the carrying out of grinding progressively adds step 1) in the hydrosol for preparing, until pigment fineness reaches 5 ~ 10 μm, form prepared Chinese ink base paste;
Step 3): in step 2) add BIT in the prepared Chinese ink base paste that obtains, tensio-active agent, continuation stir and make it fully dissolve, be filled in metal tube after cooling, ageing-resistant Chinese painting color can be obtained.
The present invention at least comprises following beneficial effect:
(1) advantage of the present invention is that employing comprises colloid, aqueous wetting agent, dispersion agent, micro encapsulation pigmented and various adjuvant component and carries out reasonable coordination, make colo(u)rant dispersion even, there is not flocculation of reuniting, obtained pigment stability is good, mildew resistance is good, moisture retention is good, act synergistically between colloid mixture, the moisture retention of pigment can be improved.
(2) the present invention adopts in component adding tube stablizer and adopts the microcapsule wall material of melmac as color base of ageing-resistant and anti-microbial effect, reduce ultraviolet to the destruction of color base, improve the ageing-resistant performance of pigment, avoid current photostabilizer to add in the composition with simple function component, easily be heated, the impact of solvent etc. and moving, thus cause photostabilizer to be lost to the external world, affect quality product, contaminate environment, solves the problem such as migration loss of ordinary method uvioresistant, photostabilizer.
Embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technique means adopted in embodiment is well known to those skilled in the art, the raw material adopted also be can business obtain.The various process do not described in detail and method are ordinary methods as known in the art.
A kind of ageing-resistant Chinese painting color, comprises the component of following weight part:
Color base: 5 ~ 15 parts; Dispersion agent: 0.2 ~ 5 part;
Salicylic acid phenyl ester: 1 ~ 5 part; Colloid: 7 ~ 25 parts;
Photostabilizer: 0.2 ~ 3 part; Acrylic resin: 2 ~ 12 parts;
Tensio-active agent: 3 ~ 8 parts; Aqueous wetting agent: 1 ~ 5 part;
BIT: 2 ~ 6 parts; Deionized water: 5 ~ 30 parts.
Pigment is permanent bordeaux F5R, bronze red C, Pigment red A3B, Pigment red 2GL, Pigment red RT, Pigment red HF2B, Pigment red BP, Pigment red 5G, Pigment red FP, Pigment red RE, Pigment red B, Pigment red F3C, Pigment red PT, organic red 420, organic red 6B, organic red 5034, organic red BK, organic red 2R, organic red 2BR, organic red 2BM, organic red RN, organic red BR, organic red FB, organic red F5R, organic red F6B, organic red F4C, organic yellow GH, organic yellow 10G, organic yellow GF, organic yellow GR, organic yellow G, organic yellow 203, organic yellow F10G, organic yellow 104, organic yellow GG, organic yellow HR, organic yellow 103, organic yellow H4G, organic yellow H3G, organic yellow GRY, Pigment Yellow 73 AR, Pigment Yellow 73 HD, Pigment Yellow 73 HG, Pigment Yellow 73 H3R, Pigment Yellow 73 3R, Pigment Yellow 73 16, organic blue B, organic blue BGS, organic blue 4920, organic blue 7090, organic blue BS, organic blue BG, organic green G, organic green 8730, ferric oxide, red lead chrome yellow, zinc-chrome yellow, cadmium yellow, iron oxide yellow, barba hispanica, cobalt blue, ultramarine, chromoxide green, lead chrome green, gamboge, sodium alizarinsulfonate, indigo-blue any one or two or more.
Improve further as the present invention, described colloid is the mixture of carrageenin and Viscogum BE, and the weight part ratio of described carrageenin and Viscogum BE is 1:1 ~ 4.Act synergistically between colloid mixture, the moisture retention of pigment can be improved,
Improve further as the present invention, described photostabilizer is photomask agent, UV light absorber, quencher, radical scavenger or peroxide decomposer.Described photomask agent is titanium dioxide, carbon black or zinc oxide, UV light absorber is salicylic acid benzene fat or 2,4 dihydroxyl benzophenone, and quencher is organic nickel salt or nickel complex, radical scavenger is piperidine compounds, and peroxide decomposer is sulfo-lipid or phosphorous acid esters.
Improve further as the present invention, described dispersion agent is polyether glycol.
Improve further as the present invention, described tensio-active agent is sodium alkyl benzene sulfonate, tetradecyl sodium sulfonate, alkylpolyoxyethylene sodium sulfate, sodium soap, alkyl ether phosphates ester ammonium salt, succsinic acid two (2-Ethyl-butyl) sodium sulfonate, sodium metnylene bis-naphthalene sulfonate, surfactant AS, thunder rice help A, triethanolamine oleate, fatty alcohol-polyoxyethylene ether phosphate monoester, lipid acid sodium phosphate salt, polyol ester, lauryl alcohol list or bis phosphoric acid acid potassium salt, the auxiliary of one or more of alkyl glycoside joins use.
Improve further as the present invention, described aqueous wetting agent propylene glycol, glycerine, polyoxyethylene glycol, sorbyl alcohol, triglycerin, 3,4-glycol ether METHYLPYRROLIDONEs or its combination.Wetting Agent for Printing Inks consumption is too many, and product easily follows the string, and reduces keeping quality, and increase product and to wet the risk of viscosity, in order to make product quality more soft, rate of drying reduces, and the amount of wetting Agent for Printing Inks should be limited, preferably the wetting Agent for Printing Inks of 2 ~ 5 weight parts.
A preparation method for ageing-resistant Chinese painting color, comprises the steps:
Step 1): take each component by proportioning, deionized water is divided into two parts by weight, a deionized water is added in heating container, then after adding photostabilizer, acrylic resin, aqueous wetting agent stir dissolving, being then heated to 80 ~ 90 DEG C, adding colloid, heating holding temperature while stirring and to dissolve completely to it at 80 ~ 90 DEG C and become hydrosol;
Step 2): get another part of deionized water, add dispersion agent be mixed with concentration be 30% ~ 40% solution, add color base, salicylic acid phenyl ester, rare paste is become to grind, along with the carrying out of grinding progressively adds step 1) in the hydrosol for preparing, until pigment fineness reaches 5 ~ 10 μm, form prepared Chinese ink base paste;
Step 3): in step 2) add BIT in the prepared Chinese ink base paste that obtains, tensio-active agent, continuation stir and make it fully dissolve, be filled in metal tube after cooling, ageing-resistant Chinese painting color can be obtained.
Table 1 lists concrete component and the content thereof of different embodiment and comparative example.
Table 1 embodiment 1 ~ 3 and the concrete component of comparative example 1 ~ 4
Color fastness to daylight adopts GB1710-79 pigment photostabilization assay method, sample is coated on tinplate, is exposed to the sun under being placed in sun-proof instrument, is that standard card carries out grading contrast.
Stability test: pigment sealing is left in 50 DEG C of baking ovens and takes out again tested viscosity and granularity after 90 days, investigate the stability of pigment.
Table 2 lists the test result of embodiment 1 ~ 3 and comparative example 1 ~ 4.
The test result of table 2 embodiment 1 ~ 3 and comparative example 1 ~ 4
Although embodiment of the present invention are open as above, but it is not restricted to listed in specification sheets and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details.
Claims (8)
1. an ageing-resistant Chinese painting color, is characterized in that, comprises the component of following weight part:
Color base: 5 ~ 15 parts; Dispersion agent: 0.2 ~ 5 part;
Salicylic acid phenyl ester: 1 ~ 5 part; Colloid: 7 ~ 25 parts;
Photostabilizer: 0.2 ~ 3 part; Acrylic resin: 2 ~ 12 parts;
Tensio-active agent: 3 ~ 8 parts; Aqueous wetting agent: 1 ~ 5 part;
BIT: 2 ~ 6 parts; Deionized water: 5 ~ 30 parts.
2. ageing-resistant Chinese painting color as claimed in claim 1, is characterized in that, described colloid is the mixture of carrageenin and Viscogum BE, and the weight part ratio of described carrageenin and Viscogum BE is 1:1 ~ 4.
3. ageing-resistant Chinese painting color as claimed in claim 1, it is characterized in that, described pigment is selected from dispersion size at the resin inclusion pigment of 0.1 ~ 20 μm, is selected from mineral dye, pigment dyestuff, high-visibility pigment, phosphorescent pigment or pearly pigment by the pigment that resin wraps up; The resin of inclusion pigment is selected from melmac.
4. ageing-resistant Chinese painting color as claimed in claim 1, is characterized in that, described photostabilizer is photomask agent, UV light absorber, quencher, radical scavenger or peroxide decomposer.
5. ageing-resistant Chinese painting color as claimed in claim 1, is characterized in that, described dispersion agent is polyether glycol.
6. ageing-resistant Chinese painting color as claimed in claim 1, it is characterized in that, described tensio-active agent be sodium alkyl benzene sulfonate, tetradecyl sodium sulfonate, alkylpolyoxyethylene sodium sulfate, sodium soap, alkyl ether phosphates ester ammonium salt, succsinic acid two (2-Ethyl-butyl) sodium sulfonate, sodium metnylene bis-naphthalene sulfonate, surfactant AS, thunder rice side A, triethanolamine oleate, fatty alcohol-polyoxyethylene ether phosphate monoester, lipid acid sodium phosphate salt, polyol ester, lauryl alcohol list or bis phosphoric acid acid potassium salt, alkyl glycoside one or more.
7. ageing-resistant Chinese painting color as claimed in claim 1, is characterized in that, described aqueous wetting agent propylene glycol, glycerine, polyoxyethylene glycol, sorbyl alcohol, triglycerin, 3,4-glycol ether METHYLPYRROLIDONEs or its combination.
8. a preparation method for ageing-resistant Chinese painting color as claimed in claim 1, is characterized in that, comprise the steps:
Step 1): take each component by proportioning, deionized water is divided into two parts by weight, a deionized water is added in heating container, then after adding photostabilizer, acrylic resin, aqueous wetting agent stir dissolving, being then heated to 80 ~ 90 DEG C, adding colloid, heating holding temperature while stirring and to dissolve completely to it at 80 ~ 90 DEG C and become hydrosol;
Step 2): get another part of deionized water, add dispersion agent be mixed with concentration be 30% ~ 40% solution, add color base, salicylic acid phenyl ester, rare paste is become to grind, along with the carrying out of grinding progressively adds step 1) in the hydrosol for preparing, until pigment fineness reaches 5 ~ 10 μm, form prepared Chinese ink base paste;
Step 3): in step 2) add BIT in the prepared Chinese ink base paste that obtains, tensio-active agent, continuation stir and make it fully dissolve, be filled in metal tube after cooling, ageing-resistant Chinese painting color can be obtained.
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084957A (en) * | 2016-08-24 | 2016-11-09 | 孙鑫宇 | A kind of fast light Chinese painting color of environmental protection and preparation method thereof |
| CN106189484A (en) * | 2016-08-10 | 2016-12-07 | 苏州中亚油墨有限公司 | Aqueous fluorescent pigment and manufacture method thereof for water color ink |
| CN106893386A (en) * | 2017-04-12 | 2017-06-27 | 叶华 | A kind of self-cleaning Chinese painting color of fluorescence |
| CN107011712A (en) * | 2017-06-02 | 2017-08-04 | 中国科学院包头稀土研发中心 | A kind of new Chinese painting color containing rare earth element and preparation method thereof |
| CN107057433A (en) * | 2017-04-12 | 2017-08-18 | 叶华 | A kind of Chinese painting color |
| CN107365520A (en) * | 2017-08-29 | 2017-11-21 | 惠州海翔文教用品有限公司 | A kind of water-based water transfer pigment and preparation method thereof |
| CN107603309A (en) * | 2017-09-29 | 2018-01-19 | 江苏工程职业技术学院 | A kind of formaldehydeless art painting sole pigment and its preparation technology |
| CN107760086A (en) * | 2016-08-21 | 2018-03-06 | 赵伊 | The water-soluble etching pigment with mimeograph effect that a kind of suitable children use |
| CN107955446A (en) * | 2017-12-21 | 2018-04-24 | 温州维特利颜料科技有限公司 | A kind of pigment and its preparation process for being easy to desalination |
| CN108250819A (en) * | 2018-02-09 | 2018-07-06 | 上海马利画材销售有限公司 | A kind of Chinese painting color and preparation method thereof and purposes |
| CN113045939A (en) * | 2021-05-11 | 2021-06-29 | 河北青竹画材科技有限公司 | Solid gouache pigment and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107057433A (en) * | 2017-04-12 | 2017-08-18 | 叶华 | A kind of Chinese painting color |
| CN107011712A (en) * | 2017-06-02 | 2017-08-04 | 中国科学院包头稀土研发中心 | A kind of new Chinese painting color containing rare earth element and preparation method thereof |
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| CN108250819A (en) * | 2018-02-09 | 2018-07-06 | 上海马利画材销售有限公司 | A kind of Chinese painting color and preparation method thereof and purposes |
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Application publication date: 20160413 |