CN1280359C - Water-soluble ink compositions, their manufacturing method and use - Google Patents
Water-soluble ink compositions, their manufacturing method and use Download PDFInfo
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- CN1280359C CN1280359C CN 200410029880 CN200410029880A CN1280359C CN 1280359 C CN1280359 C CN 1280359C CN 200410029880 CN200410029880 CN 200410029880 CN 200410029880 A CN200410029880 A CN 200410029880A CN 1280359 C CN1280359 C CN 1280359C
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Abstract
The present invention relates to water-soluble ink which is made of various active components of dye, protective glue, a flatting agent, a dispersing agent, an emulsifier and water absorption resin, etc. The present invention also relates to the making method of the water-soluble ink and the application of the water-soluble ink in print industry, watercolor, Indian ink and paper rinse. The water-soluble ink of the present invention can overcome the phenomena of oxidation and decolorization when colorful paper or colorful rice paper meets water or ultraviolet irradiation and can overcome a decolorizing phenomenon when traditional Chinese paintings and watercolor paintings meet water. Characters, etc. which are written by the water-soluble ink have the advantages of bright ink mark, proper color, fluent writing, moderate concentration, moderate fragrance, rapid dryness after writing, etc., and the influence of the water-soluble ink on environment can be reduced.
Description
[technical field]
The present invention relates to a kind of Chinese Painting and Calligraphy articles for use and manufacture method thereof, and their application, more specifically, the present invention relates to a kind of water miscible ink composite and manufacture method thereof, and their application.
[background technology]
Chinese painting and calligraphy are a kind of China historical deep pool original creation art form far away, and it has strong national characters.Though many calligraphy treasures were gone through over thousands of year, still perfect so far harmless, this has proved absolutely the system China ink technology of Ancient Chinese for exquisiteness, and very important effect is played in historical development.
The China ink of China was gone through more than 1700 year, and development forms the existing China ink that black factory produces of respectively making gradually, the ink marks light of existing China ink, shading color just, write smoothly, concentration is moderate, and is strong and brisk in taste, writes the back and easily do, suitable taking off mounted etc.
At present, calligraphy and painting is taken off after doing when mounting, and the China ink on profit water process China and Mexico word runs into water can be washed away, and this phenomenon is referred to as to fly China ink.One secondary good calligraphy and painting needs to mount the Shi Xiaoxin paper and just can take off and mount through taking off, but also tends to occur flying black phenomenon, so and so, the individual mounts with regard to more being difficult to take off.The calligraphy and drawing fan in the whole nation reaches the tens of thousands of people, and the annual calligraphy and drawing works that produce are just countless, and these vast as the open sea works are difficult to finish by paper teacher paper entirely, have therefore seriously hindered the development of calligraphy and drawing literature and art cause.So people press for a kind of prepared Chinese ink that flies black phenomenon of eliminating at present.
In addition, China scientific research personnel carries out excessive quantity research to various prepared Chinese ink.It is also very many to relate to the application for a patent for invention that is the theme with prepared Chinese ink, and for example CN1079760A has described that a kind of study is imitative opens up the stone inscription calligraphy ink, and this China ink is made up of sugar, gelatine, starch, black dyes, water, essence and copper bronze.CN1218819A discloses that a kind of light ink is two to collude word prepared Chinese ink, and it is made up of water/tealeaves, AES, sodium alkyl benzene sulfonate, PP, essence, prepared Chinese ink, AL-70 and PK-904.But about eliminating the prepared Chinese ink patent application that flies black phenomenon and other reference but seldom.
In printing, paper bleachinges and dyeing, in the watercolor field, the decolouring phenomenon takes place under UV-light, decolouring occurring when meeting water also is frequent visible, but patent application and other reference of relevant these chemistry of elimination or physical decolorization are considerably less.
Therefore, the inventor sums up the water soluble oils ink formulations that makes new advances through a large amount of experimental study, has proposed the black technology of system, thus for obtain high-quality printing, watercolor, prepared Chinese ink, paper is bleachinged and dyeing that an effective way is provided.
[summary of the invention]
[problem that will solve]
The purpose of this invention is to provide a kind of water-soluble ink composition.
Another object of the present invention provides a kind of production method of described water-soluble ink composition.
Another object of the present invention is the application of described water-soluble ink composition in printing, watercolor, prepared Chinese ink, paper are bleachinged and dyeing.
[technical scheme]
The inventor through testing many times, analyze and studying, has invented solubility printing ink at last, and has proposed the system ink technique on the basis of summing up forefathers' practice.
Solubility printing ink of the present invention mainly contains dyestuff, protection glue, flow agent, dispersion agent, emulsifying agent, absorbent resin etc.
In the present invention, described dyestuff is a kind of painted quite securely material of pollutant that makes, and natural dyestuff and synthetic dyestuff are arranged.
Described flow agent can reduce the surface tension of system effectively, improves mobile, levelling property, increases surperficial smooth, the gloss of paint film, improves anti-scratch damage, resistance to marring.Enhancement is wetting to ground, prevents that shrinkage cavity from producing.In the colored paint system, prevent the generation of loose colour, grow diming phenomenon.Simultaneously, splendid with other component compatibility in the printing ink, it is excessive to add, and also can not produce the shrinkage cavity phenomenon as organosilicon, but overcoating.
Described dispersion agent can effectively reduce the interfacial tension between dyestuff and the base-material, and dyestuff is had good wetting action, improves the viscosity that dispersion efficiency also can reduce grinding system fast and effectively, has good dispersion stabilization.Described dispersion agent all has fabulous compatibility to various ink component.
Described protection glue can improve the viscosity of emulsion water; The macromolecular chain of protection glue can adsorb several latex particles.Therefore, can prevent that emulsion from use, storage process layering, precipitation taking place.Its add-on should be controlled, and add-on too much makes the emulsion viscosity increase, and the water-based ink viscosity that makes is big, is unfavorable for using; Add-on is very few, and emulsion viscosity is low, and layering, precipitation easily take place during storage, also produces the sagging disadvantage.
Described emulsifying agent is a kind of tensio-active agent, and it mainly acts on is to reduce interfacial tension.The unsettled major cause of ink system is that water oil is immiscible, and their surface tension is separately formed the interfacial tension of intersection, and interfacial tension is shunk the water-oil interface liquid phase gradually, causes agglomeration separation separately at last.The tensio-active agent that possesses emulsifying effect; generally all be made of polar group and nonpolar group on chemical structure, polar group possess hydrophilic property matter soluble in water is so be called hydrophilic group; nonpolar group is soluble in oil; so be called oleophilic group, behind the adding emulsifying agent, hydrophilic group is soluble in water in oil-water system; oleophilic group is dissolved in the oil; so just between oil-water two-phase, form the interfacial film of one deck densification, reduced interfacial tension, simultaneously drop is shielded.
Described absorbent resin is the water-soluble polymer with ionization group (mainly being carboxyl formula salt) substantially on its structure, and with its intermolecular powder or particulate state super absorbent resin that becomes network-like structure with linking agent crosslinked (or replacing block and graft copolymer).It has the spatial reticulated structure, contains the strongly hydrophilic group, and the osmotic pressure by its tridimensional network and intramolecularly outside electrolyte ion concentration are produced has the intensive association to water.
The present invention carries out according to following technical proposals:
A kind of water soluble oils ink composition is characterized in that it contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 50-600 weight part;
(B) one or more are selected from the water-fast additive 53-600 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(C) protection glue 0-9 weight part;
(D) flow agent 8-42 weight part;
(E) dispersion agent 8-38 amount part;
(F) emulsifying agent 2-14 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 5-120 weight part;
(H) absorbent resin 0-3 weight part;
(I) spices 0-1 weight part;
(K) water 15-900 weight part.
Preferably, water soluble oils ink composition of the present invention contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 60-70 weight part;
(B) one or more are selected from the water-fast additive 47-61 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 10-15 weight part;
(E) dispersion agent 9-14 weight part;
(F) emulsifying agent 8-12 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 6-9 weight part;
(K) water 15-21 weight part
Use this water soluble oils ink composition can prepare the printing ink of excellent performance, can be used for the printing of various paper, packing bag, carton etc.
Especially, water soluble oils ink composition of the present invention contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 350-450 weight part;
(B) one or more are selected from the water-fast additive 68-82 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 15-20 weight part;
(E) dispersion agent 10-14 weight part;
(F) emulsifying agent 4-6 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 23-27 weight part;
(I) spices 0.1-0.8 weight part;
(K) water 660-760 weight part.
Use this water soluble oils ink composition can prepare the prepared Chinese ink of excellent performance, can be used on various paper, writing.
Especially, water soluble oils ink composition of the present invention contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 450-550 weight part;
(B) one or more are selected from the water-fast additive 335-395 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 29-35 weight part;
(E) dispersion agent 27-33 weight part;
(F) emulsifying agent 5-9 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 85-95 weight part;
(H) absorbent resin 1.5-2.1 weight part;
(K) water 700-900 weight part.
Use this water soluble oils ink composition can prepare the watercolor of excellent performance, can be used for the watercolor painting field.
Especially, water soluble oils ink composition of the present invention contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 350-450 weight part;
(B) one or more are selected from the water-fast additive 80-204 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 31-41 weight part;
(E) dispersion agent 18-22 weight part;
(F) emulsifying agent 6-10 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 95-106 weight part;
(H) absorbent resin 1.5-2.1 weight part;
(K) water 720-820 weight part.
Use this water soluble oils ink composition can prepare the paper bleaching and dyeing agent of excellent performance, can be used for bleachinging and dyeing of rice paper, other various paper, obtain coloury ticker tape.
In described water soluble oils ink composition of the present invention, foregoing polyethylene series emulsion and polyacrylic acid series emulsion are the various polyethylene emulsions and the ACRYLIC EMULSION of selling in the market.Described flow agent is selected from for example HX-3070, HX-3080, HX-3180, HX-3181, HX-3380 type flow agent (production of Fanyu, Guangzhou China auxiliary agent company limited); Described dispersion agent is selected from citric acid, glycerine, isopropylidene glycerol-4-methanol or polyethylene imine based; Described emulsifying agent is selected from SAD, 51-100-04,191 type water-based inks with (Sam Wing International Ltd.'s product solds) such as emulsifying agents; Described absorbent resin is selected from polyacrylate(s), polyvinyl alcohol, acetate ethylene copolymer class, polyurethanes, polyethylene oxide class, starch graft copolymer class of super absorbent resin type etc.; Described protection glue for example is selected from AP-01 type sodium methacrylate high molecular polymer protection glue (Beijing moral becomes industry and trade company limited product sold) etc.
Above-mentioned water soluble oils ink composition can also contain at normally used in the art various additives, tinting material for example, and it can be selected from Acid Black 10B, shellac, tartrate or natural gum; Defoamer, it can be selected from vegetables oil, mineral oil or animal oil, and they can be each vegetable oil, mineral oil and the animal oil of selling on the market, for example Viscotrol C, oleum lini, sesame oil, peanut oil, soybean oil, paraffin oil, tallow etc.; SYNTHETIC OPTICAL WHITNER oxalic acid; Stablizer, it can be selected from Weibull or urea; The UV light absorber gallic acid; The scavenging agent ferrous sulfate; Wetting Agent for Printing Inks, it can be selected from maltose alcohol, polyoxyethylene alkyl phenyl ether or dodecylbenzene sulfonate; The thickening material borax; Softening agent lactic acid; Sterilant, it is selected from acetate, phenylic acid, caustic soda or soda ash; Colour protecting agent saltpetre; Catalyzer, it is selected from Semen Lini oil or tung oil and starter Sodium Hydrogen Carbonate.Those skilled in the art can determine to add the amount of one or more described additives and interpolation thereof according to actual needs.Therefore, it should be understood that these additives also should be in protection scope of the present invention.
The invention still further relates to a kind of manufacture method of water soluble oils ink composition of the present invention, it is characterized in that this method comprises the steps:
At first, with following component in weight part: one or more are selected from the dyestuff 50-600 weight part of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner; Protection glue 0-6 weight part; Flow agent 9-14 weight part; Dispersion agent 6-12 weight part; Emulsifying agent 2-14 weight part; Water 18-575 weight part fully mixes, and obtains a kind of highly filled water-based ink;
Secondly, above-mentioned water-based ink is sent into the water-based ink that grinding machine for grinding disperses to obtain a kind of good distribution;
Then, get above-mentioned dispersive water-based ink 400-600 weight part, polyacrylic acid series emulsion 100-250 weight part, polyethylene emulsion 50 weight parts, methyl alcohol, ethanol and/or ethylene glycol 40-50 weight part, flow agent 7-20 weight part, dispersion agent 7-20 weight part, absorbent resin 0-1 weight part, spices 0-1 weight part and water 2-280 weight part and in high speed dispersor, disperse, filter and obtain product of the present invention.
In ink composition manufacture method of the present invention, can use any mixing equipment known to those skilled in the art to carry out the mixing of material, disperse and filter.Preferably, for example can adopt mechanical stirrer or colloidal mill to mix.Can adopt three-roll grinder to grind disperses.Mix with the dispersive temperature and also have no particular limits.
At last, the invention still further relates to above-mentioned water soluble oils ink composition at printing-ink, prepared Chinese ink, watercolor and bleaching and dyeing application in the paper.
[beneficial effect]
Water soluble oils ink composition of the present invention is applied to print field, can eliminate printing ink to air, river, phreatic pollution.
Water soluble oils ink composition of the present invention is applied to the field of bleachinging and dyeing of paper such as rice paper, can overcome the oxidative decoloration phenomenon that ticker tape or colorized rice paper occur when meeting water or being subjected to uviolizing.
Water soluble oils ink composition of the present invention is applied to the watercolor field, can overcome the decolouring phenomenon that traditional Chinese Painting and watercolor painting occur when meeting water.
Use water soluble oils ink composition of the present invention to be applied to the prepared Chinese ink field, use literal that this prepared Chinese ink writes etc. to have the ink marks light, shading color just writes smoothly, and concentration is moderate, and is strong and brisk in taste, writes advantages such as back Yi Gan.
Compare with prior ink, prepared Chinese ink of the present invention has been eliminated fully and has been flown black phenomenon.The works that use the various prepared Chinese ink sold on the present market to write must be taken off the shop of mounting to specialty, take off teacher of the mount'sing paper by senior, and profit water excessive also can appearance flies black phenomenon in the paper process, makes works become substandard products, even becomes waste product.Use prepared Chinese ink of the present invention to write works,, the black phenomenon that flies of black word also can not occur even take off the personnel of mounting and paper by amateur.
[embodiment]
Embodiment 1
At first, join following component in the stainless steel reactor of a band anchor stirrer in weight part: carbon black powder 65 weight parts, SAD type emulsifying agent 10 weight parts, citric acid dispersion agent 8 weight parts, HX-3070 flow agent 9 weight parts, water 18 weight parts, adopt mechanical stirrer that they are mixed earlier, transfer to three roller colloidal mills ground and mixed 120 minutes more then, obtain a kind of water-based ink of highly filled good distribution;
Then, getting above-mentioned dispersive water-based ink 600 weight parts, polyacrylic acid series emulsion 250 weight parts, polyethylene series emulsion 50 weight parts, methyl alcohol 40 weight parts, HX-3070 flow agent 20 weight parts, citric acid dispersion agent 20 weight parts and water 2 weight parts disperses in high speed dispersor, filtration obtains water soluble oils graphite product of the present invention, ink product promptly of the present invention.
Embodiment 2
At first, join following component in the stainless steel reactor of a band anchor stirrer in weight part: oil smoke ink powder 400 weight parts, SAD type emulsifying agent 5 weight parts, citric acid dispersion agent 6 weight parts, HX-3070 flow agent 14 weight parts, water 575 weight parts, adopt mechanical stirrer that they are mixed earlier, transfer to three roller colloidal mills ground and mixed 120 minutes more then, obtain a kind of water-based ink of highly filled good distribution;
Then, getting above-mentioned dispersive water-based ink 500 weight parts, polyacrylic acid series emulsion 100 weight parts, polyethylene series emulsion 50 weight parts, ethylene glycol 50 weight parts, HX-3070 flow agent 7 weight parts, citric acid dispersion agent 12 weight parts and water 280 weight parts disperses in high speed dispersor, filtration obtains water soluble oils graphite product of the present invention, prepared Chinese ink product promptly of the present invention.
The prepared Chinese ink of selling with the prepared Chinese ink and the existing market of present embodiment compares test.Under same condition, write simultaneously, take off simultaneously and mount, moisten paper upper wall, holder paper to take off the means of mounting equally.Test-results shows that with the word that the prepared Chinese ink of existing market sale is write, chance water many places occur and flies black phenomenon, therefore completely destroy original works, and, fly black phenomenon behind the chance water with the word that the prepared Chinese ink of present embodiment is write, still kept the style of former calligraphy work.Prepared Chinese ink quality of the present invention really reaches: scribbling sketch place is dripping bold and unconstrained, and it is simple and honest to amass China ink place deepness, and thick ink place light is bright-coloured, and the light ink place is pure and fresh elegant, goes into sand just like rain, and the conformal magically change is write the romantic charm of drawing a picture with it and finished now the special-effect that pleasant place is selected to the greatest extent.
Embodiment 3
At first, join following component in the stainless steel reactor of a band anchor stirrer in weight part: blue powder 400 weight parts, 191 type emulsifying agents, 8 weight parts, glycerol dispersant 7 weight parts, HX-3180 flow agent 14 weight parts, AP-O1 type sodium methacrylate high molecular polymer protection glue 6 weight parts, water 300 weight parts, adopt mechanical stirrer that they are mixed earlier, transfer to three roller colloidal mills ground and mixed 120 minutes more then, obtain a kind of water-based ink of highly filled good distribution;
Then, polyacrylate resin 1 weight part and water 225 weight parts of getting above-mentioned dispersive water-based ink 400 weight parts, polyacrylic acid series emulsion 250 weight parts, polyethylene series emulsion 50 weight parts, ethylene glycol 55 weight parts, HX-3180 flow agent 12 weight parts, glycerol dispersant 7 weight parts, high-hydroscopicity disperse in high speed dispersor, filtration obtains water soluble oils graphite product of the present invention, and paper promptly of the present invention is bleachinged and dyeing product.
Adopt the color China ink of the present invention to bleaching and dyeing and make a kind of ticker tape, then with present market on ticker tape carried out simultaneous test.
Dripped distilled water about 1 minute toward two kinds of vertical paper aloft with tubing, place air then, after two kinds of paper were done in second day, the ticker tape of selling on the market tangible aberration occurred at water retting place and dipping place not.And the homemade ticker tape of the inventor any aberration do not occur at water retting place and dipping place not.From above-mentioned test as can be seen, homemade color China ink, any black phenomenon that flies does not appear in ticker tape, therefore compares prepared Chinese ink that prepared Chinese ink of the present invention and ticker tape are better than selling on the market and ticker tape with ticker tape with prior ink.
Embodiment 4
At first, join following component in the stainless steel reactor of a band anchor stirrer in weight part: bright red toner 500 weight parts, 51-100-04 type emulsifying agent 7 weight parts, glycerol dispersant 12 weight parts, HX-3180 flow agent 10 weight parts, AP-O1 type sodium methacrylate high molecular polymer protection glue 5 weight parts, water 466 weight parts, adopt mechanical stirrer that they are mixed earlier, transfer to three roller colloidal mills ground and mixed 120 minutes more then, obtain a kind of water-based ink of highly filled good distribution;
Then, polyacrylate resin 1 weight part and water 177 weight parts of getting above-mentioned dispersive water-based ink 550 weight parts, polyacrylic acid series emulsion 150 weight parts, polyethylene series emulsion 50 weight parts, ethylene glycol 50 weight parts, HX-3180 flow agent 12 weight parts, glycerol dispersant 10 weight parts, high-hydroscopicity disperse in high speed dispersor, filtration obtains water soluble oils graphite product of the present invention, watercolor product promptly of the present invention.
When product of the present invention was used to write, the resulting calligraphy and painting of writing was met the water phenomenon of can not decolouring.
Claims (8)
1, a kind of water soluble oils ink composition is characterized in that it contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 50-600 weight part;
(B) one or more are selected from the water-fast additive 53-600 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(C) protection glue 0-9 weight part;
(D) flow agent 8-42 weight part;
(E) dispersion agent 8-38 weight part;
(F) emulsifying agent 2-14 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 5-120 weight part;
(H) absorbent resin 0-3 weight part;
(I) spices 0-1 weight part;
(K) water 15-900 weight part;
Described flow agent is selected from HX-3070, HX-3080, HX-3180, HX-3181, HX-3380 type flow agent;
Described dispersion agent is selected from citric acid, glycerine, isopropylidene glycerol-4-methanol or polyethylene imine based;
Described emulsifying agent is selected from SAD, 51-100-04,191 type water-based inks emulsifying agents;
Described absorbent resin is selected from polyacrylate(s), polyvinyl alcohol, acetate ethylene copolymer class, polyurethanes, the polyethylene oxide class of super absorbent resin type, the resin of starch graft copolymer class;
Described protection glue is selected from AP-01 type sodium methacrylate high molecular polymer protection glue.
2, water soluble oils ink composition according to claim 1 is characterized in that it contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 60-70 weight part;
(B) one or more are selected from the water-fast additive 47-61 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 10-15 weight part;
(E) dispersion agent 9-14 weight part;
(F) emulsifying agent 8-12 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 6-9 weight part;
(K) water 15-21 weight part.
3, water soluble oils ink composition according to claim 1 is characterized in that it contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 350-450 weight part;
(B) one or more are selected from the water-fast additive 68-82 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 15-20 weight part;
(E) dispersion agent 10-14 weight part;
(F) emulsifying agent 4-6 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 23-27 weight part;
(I) spices 0.1-0.8 weight part;
(K) water 660-760 weight part.
4, water soluble oils ink composition according to claim 1 is characterized in that it contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 450-550 weight part;
(B) one or more are selected from the water-fast additive 335-395 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 29-35 weight part;
(E) dispersion agent 27-33 weight part;
(F) emulsifying agent 5-9 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 85-95 weight part;
(H) absorbent resin 1.5-2.1 weight part;
(K) water 700-900 weight part.
5, water soluble oils ink composition according to claim 1 is characterized in that it contains following component, in weight part:
(A) one or more are selected from the dyestuff of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner: the 350-450 weight part;
(B) one or more are selected from the water-fast additive 180-204 weight part of Sudan Gum-arabic, polyethylene series emulsion and/or polyacrylic acid series emulsion;
(D) flow agent 31-41 weight part;
(E) dispersion agent 18-22 weight part;
(F) emulsifying agent 6-10 weight part;
(G) methyl alcohol, ethanol and/or ethylene glycol auxiliary agent 95-106 weight part;
(H) absorbent resin 1.5-2.1 weight part;
(K) water 720-820 weight part.
6, the manufacture method of the described water soluble oils ink composition of a kind of claim 1 is characterized in that this method comprises the steps:
At first, with following component in weight part: one or more are selected from the dyestuff 50-600 weight part of carbon black, oil smoke China ink, pine-soot ink, orange China ink, bright red toner, amaranth flour, light yellow toner, middle yellow powder, ultramarine blue toner, green flour, iron oxide yellow toner, iron oxide red toner, white powder, fuchsin toner or bright orange toner; Protection glue 0-6 weight part; Flow agent 9-14 weight part; Dispersion agent 6-12 weight part; Emulsifying agent 2-14 weight part; Water 18-575 weight part fully mixes, and obtains a kind of highly filled water-based ink;
Secondly, above-mentioned water-based ink is sent into the water-based ink that grinding machine for grinding disperses to obtain a kind of good distribution;
Then, get above-mentioned dispersive water-based ink 400-600 weight part, polyacrylic acid series emulsion 100-250 weight part, polyethylene emulsion 50 weight parts, methyl alcohol, ethanol and/or ethylene glycol 40-50 weight part, flow agent 7-20 weight part, dispersion agent 7-20 weight part, absorbent resin 0-1 weight part, spices 0-1 weight part and water 2-280 weight part and in high speed dispersor, disperse, filter and obtain product of the present invention.
7, ink composition manufacture method according to claim 6 is characterized in that using mechanical stirrer or colloidal mill to mix; Use three-roll grinder to grind.
8, according to the described water soluble oils ink composition of arbitrary claim among the claim 1-5 at printing-ink, prepared Chinese ink, watercolor and bleaching and dyeing application in the paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410029880 CN1280359C (en) | 2004-03-31 | 2004-03-31 | Water-soluble ink compositions, their manufacturing method and use |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410029880 CN1280359C (en) | 2004-03-31 | 2004-03-31 | Water-soluble ink compositions, their manufacturing method and use |
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| Publication Number | Publication Date |
|---|---|
| CN1676555A CN1676555A (en) | 2005-10-05 |
| CN1280359C true CN1280359C (en) | 2006-10-18 |
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| CN 200410029880 Expired - Fee Related CN1280359C (en) | 2004-03-31 | 2004-03-31 | Water-soluble ink compositions, their manufacturing method and use |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5353059B2 (en) | 2008-05-26 | 2013-11-27 | 株式会社リコー | Image forming method |
| CN101760122B (en) * | 2009-10-30 | 2011-11-30 | 宋健 | Aqueous polyurethane art painting and preparation method thereof |
| CN101787234A (en) * | 2010-04-01 | 2010-07-28 | 北京今鼎新翰文化艺术有限公司 | Antique tusche and new preparation method thereof |
| CN103725091B (en) * | 2013-12-31 | 2016-04-20 | 西安理工大学 | A kind of aquosity intaglio printing ink and preparation method thereof |
| CN104177912A (en) * | 2014-08-07 | 2014-12-03 | 深圳市顾康力化工有限公司 | Mildew-proof antibacterial water-based ink and preparation method thereof |
| CN104559391B (en) * | 2014-12-19 | 2018-11-06 | 天津市鸵鸟墨水有限公司 | Traditional Chinese Painting colored ink composition and preparation method thereof |
| CN104886766B (en) * | 2015-05-06 | 2017-05-17 | 湖北中烟工业有限责任公司 | Cigar processing method |
| CN105153804A (en) * | 2015-08-24 | 2015-12-16 | 蚌埠市神龙笔业有限公司 | Natural waterborne paint ink and preparation method thereof |
| CN109535835A (en) * | 2018-12-29 | 2019-03-29 | 罗旭映 | A kind of superelevation blackness prepared Chinese ink |
| CN109504178A (en) * | 2018-12-29 | 2019-03-22 | 罗旭映 | A kind of production method of superelevation blackness prepared Chinese ink |
| CN113185866B (en) * | 2021-04-01 | 2023-04-07 | 浙江工业大学 | Carbon ink prepared from waste kelp residues and preparation method thereof |
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