CN104449003A - Novel traditional Chinese painting pigment capable of reflecting light - Google Patents
Novel traditional Chinese painting pigment capable of reflecting light Download PDFInfo
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- CN104449003A CN104449003A CN201410795980.9A CN201410795980A CN104449003A CN 104449003 A CN104449003 A CN 104449003A CN 201410795980 A CN201410795980 A CN 201410795980A CN 104449003 A CN104449003 A CN 104449003A
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- 239000000049 pigment Substances 0.000 title claims abstract description 59
- 238000010422 painting Methods 0.000 title claims abstract description 27
- 239000000084 colloidal system Substances 0.000 claims abstract description 13
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 21
- 238000000498 ball milling Methods 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 16
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 13
- 239000004925 Acrylic resin Substances 0.000 claims description 13
- 229920000178 Acrylic resin Polymers 0.000 claims description 13
- 239000001913 cellulose Substances 0.000 claims description 13
- 229920002678 cellulose Polymers 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 229910000684 Cobalt-chrome Inorganic materials 0.000 claims description 4
- 239000010952 cobalt-chrome Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- URPFLJMILYVJPZ-UHFFFAOYSA-N benzene;2-hydroxybenzoic acid Chemical group C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O URPFLJMILYVJPZ-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- -1 glycidol lipid Chemical class 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 239000001055 blue pigment Substances 0.000 claims description 2
- 239000001054 red pigment Substances 0.000 claims description 2
- 241001062009 Indigofera Species 0.000 claims 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 241000209094 Oryza Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005354 coacervation Methods 0.000 description 1
- 210000002808 connective tissue Anatomy 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to the field of art supplies and particularly relates to a novel traditional Chinese painting pigment capable of reflecting light. The formula of the pigment contains the ingredients in percentage by mass: 35-45% of pigment base, 5-7% of dispersant, 8-10% of color stabilizer and 40-50% of colloid. By applying the traditional Chinese painting pigment disclosed by the invention, the pigment can have light, and colors of traditional Chinese paintings can be richer and fuller. Meanwhile, the pigment is treated in a high-pressure high-shear microjet crusher, so that the prepared pigment is more stable and more bright in color and has a waterproof and oilproof layer.
Description
Technical field
The invention belongs to artistic drawing set field, be specifically related to a kind of novel Chinese painting color that can be reflective.
Background technology
Traditional Chinese Painting one word originates from Han dynasty, and people from Han dynasty thinks that China occupies person among the world, so be called China, is called " Chinese painting " by the drawing of China, is called for short " traditional Chinese Painting ".Mainly refer to and to be drawn on thin,tough silk, rice paper, silks and the scroll painting of in addition mounting.Traditional Chinese Painting is the traditional drawing form of Han nationality, is to dip in water, ink with writing brush, color to be drawn on thin,tough silk or paper.Instrument and material have writing brush, ink, a kind of can be reflective novel Chinese painting color, rice paper, thin,tough silk etc., subject matter can divide personage, scenery with hills and waters, birds and flowers etc., and skill and technique can divide tool to resemble and enjoyable.Chinese painting, in content and artistic creation, embodies the understanding of ancients to aspects such as nature, society and politics associated therewith, philosophy, religion, morals, literature and art.
But in currently available technology, middle a kind of novel Chinese painting color that can be reflective, according to its chromogen material processed, mainly can be divided into mineral color, vegetable pigment, metallic pigment, animal pigment, Artificial colors; Mineral pigment is tempered out from ore, and color is thick and heavy, and spreadability is strong, but its water-repellancy is poor, and simultaneously along with the raising of people's appreciation level, traditional Chinese Painting will realize the existence of more diversification.
Summary of the invention
In order to effectively solve the problem, the invention provides a kind of novel Chinese painting color that can be reflective, can make when painting and calligraphy each time, pigment all has light, has protective layer simultaneously.While traditional Chinese Painting color is enriched more, also there is protection adventitia.
Novel Chinese painting color that can be reflective, described pigment formula comprises pigmented, dispersion agent, colour stabilizer and colloid; Mass percent shared by described pigmented is 35-45%, and the mass percent shared by described dispersion agent is 5-7%, and the mass percent shared by described colour stabilizer is 8-10%, and the mass percent shared by described colloid is 40-50%.
Further, also have light particle in described pigment formula, described light particle is glass microballon, and described Glass Bead Diameter is 30 microns, and mass percent shared by glass microballon is 2-5%.
Further, protection filler is also added with in described pigment.
Further, described protection filler comprises acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose, it is 2-4% that described acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose entirety account for pigment mass per-cent, and acrylic resin: ethylene glycol monomethyl ether: Mierocrystalline cellulose is 2:1:1.
Further, described dispersion agent is polyether glycol.
Further, described colour stabilizer is salicylic acid benzene fat.
Further, described colloid adopts Racemic glycidol lipid epoxy resin.
Further, described pigmented comprises red, blue, green three kinds of colors, and application reddish yellow indigo plant makes required color; Wherein red pigment base is zunsober; Blue pigments base is Cu
3[CO
3]
2(OH)
2; Veridian base master is made up of cobalt, titanium, nickel and zinc, also has and account for the CoCr that pigmented mass percent is 0.1-1% in described veridian base
2o
4and Co
2tiO
4.
A preparation method for novel Chinese painting color that can be reflective, for above-mentioned pigment, comprises the following steps:
Step 1, by according to the pigmented of 30-40 part and the colloid proportioning Homogeneous phase mixing of 50-60 part, drop in ball grinder, adopt wet ball grinding 4 hours, when ball milling, control ball milling temperature at 30-50 DEG C, employing alcohols is ball-milling medium, and described alcohols can adopt ethanol, material ball ratio is 1:5, material: ball-milling medium is 1:0.5;
After step 2, ball milling complete, the slurry that ball milling obtains is dried, grinds after oven dry, be ground to 30-50 μm;
Step 3, dropped in stirrer by the abrasive after grinding, add the colour stabilizer of 5-8 part, carry out vacuumizing stirring, stirring velocity is 2500-3000 rev/min simultaneously, and to control whipping temp be 200-230 DEG C, continues 30 minutes, completes stirring;
Step 4, step 3 is stirred acquisition mixture in add the dispersion agent of 1-5 part, obtain the mixture with dispersion agent, and be again placed in stirrer, add aqua calcis, adjustment pH value is 8-9, and stirs, described stirring velocity 1000-1500 rev/min, whipping temp is 70-90 DEG C, stirs 50 minutes;
Step 5, after step 4 has stirred, add carbonic acid and regulate pH value be neutrality, after filter cleaner, be placed in high pressure high-shear microjet pulverizer, control pressure has been 160-170MPa, and current potential is 40-45mV, after circulation 40-50 time;
After step 6, completing steps 5, pigment is enclosed tightness system and stores.
Beneficial effect of the present invention: apply of the present invention a kind of can be reflective novel Chinese painting color, can realize, in pigment, there is light, allow the color of traditional Chinese Painting more enrich full.Simultaneously in the present invention in applying high voltage high-shear microjet pulverizer, make and the paint color that goes out is more stable and bright-coloured, also there is waterproof and oilproof layer.
Accompanying drawing explanation
Fig. 1 is the process flow sheet that the present invention makes pigment.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with drawings and Examples, the present invention is explained in further detail.Should be appreciated that specific embodiment described herein only for explaining the present invention, being not intended to limit the present invention.
On the contrary, the present invention is contained any by the substituting of making on marrow of the present invention and scope of defining of claim, amendment, equivalent method and scheme.Further, in order to make the public have a better understanding to the present invention, in hereafter details of the present invention being described, detailedly describe some specific detail sections.Do not have the description of these detail sections can understand the present invention completely for a person skilled in the art yet.
The invention provides a kind of novel Chinese painting color that can be reflective, described pigment formula comprises pigmented, dispersion agent, colour stabilizer and colloid, mass percent shared by described first pigmented is 30-40%, mass percent shared by described dispersion agent is 1-5%, mass percent shared by described colour stabilizer is 5-8%, and the mass percent shared by described colloid is 50-60%; Described dispersion agent adopts polyether glycol, and described dispersion agent can make solution generation bonding, and applies homogenizer, can realize the coacervation avoiding granules of pigments, and then avoid creating depositional phenomenon, pigment is disperseed uniformly.
Described colour stabilizer is salicylic acid benzene fat; Described colloid is Racemic glycidol lipid epoxy resin.
Described pigmented is divided into red, blue, green three kinds of colors, and the pigmented of application three kinds of colors can modulate required color; Described redness is mainly zunsober; Described blueness is mainly Cu
3[CO
3]
2(OH)
2; Described green is mainly cobalt, titanium, nickel and zinc composition, also has and account for the micro-CoCr that pigmented per-cent is 0.1-1% in described veridian base
2o
4and Co
2tiO
4, described pigment CoCr
2o
4and Co
2tiO
4infrared external reflection function can be realized, improve the vividness that pigment is overall on drawing paper, make works have more appreciation effect, described pigmented is carried out RGB three kinds of color proportionings as required and is obtained, the red green proportioning of example pigmented application goes out yellow, or pigmented is applied bluish-green proportioning and gone out cyan.
The preparation method of above-mentioned pigment,
Step 1, by according to the pigmented of 30-40 part and the colloid proportioning Homogeneous phase mixing of 50-60 part, drop in ball grinder, adopt wet ball grinding 4 hours, when ball milling, control ball milling temperature at 30-50 DEG C, employing alcohols is ball-milling medium, and described alcohols can adopt ethanol, material ball ratio is 1:5, material: ball-milling medium is 1:0.5;
After step 2, ball milling complete, the slurry that ball milling obtains is dried, grinds after oven dry, be ground to 30-50 μm;
Step 3, dropped in stirrer by the abrasive after grinding, add the colour stabilizer of 5-8 part, carry out vacuumizing stirring, stirring velocity is 2500-3000 rev/min simultaneously, and to control whipping temp be 200-230 DEG C, continues 30 minutes, completes stirring;
Step 4, step 3 is stirred acquisition mixture in add the dispersion agent of 1-5 part, the mixture with dispersion agent is placed in stirrer again, and add aqua calcis, adjustment pH value is 8-9, regulate PH under weak basic condition, can available protecting particle base, make it under the prerequisite effectively stirred, destroy particle base not too much, and stir, described stirring velocity 1000-1500 rev/min, whipping temp is 70-90 DEG C, stirs 50 minutes;
Step 5, after step 4 has stirred, add carbonic acid and regulate pH value be neutrality, after filter cleaner, be placed in high pressure high-shear microjet pulverizer, control pressure has been 160-170MPa, and current potential is 40-45mV, after circulation 40-50 time.
After step 6, completing steps 5, enclosed tightness system and stored.
After step 5 high-pressure electrolysis is stirred, pigmented is disperseed uniformly, has high vividness.In with writing brush painting and calligraphy, by electrostatic attraction adsorption pigment particle, and magnetism is very big, and application current potential reaches 40-45mV, make pigment good uniformity, and it is bright-coloured more to seem.
The second embodiment of the present invention, this embodiment described is identical with above-described embodiment part, only difference is, trace amount acid resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose is also added with in described pigment, it is 2-4% that described acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose entirety account for pigment mass per-cent, and acrylic resin: ethylene glycol monomethyl ether: Mierocrystalline cellulose is 2:1:1; After described acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose are added on pigment; before pigment applications; described pigment keeps certain temperature; between this temperature control 30-50 DEG C; writing brush by pigment painting and calligraphy after rice paper; leave standstill one end time at normal temperatures, described acrylic resin, ethylene glycol and Mierocrystalline cellulose form an anti-fog layer and adhere to the pigment having fallen to being drawn on rice paper, can available protecting pigment.
And described acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose, be applied in step 5 and step 6 in preparation overshoot after, after adding acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose in pigment, again be placed in stirrer to stir, stirring velocity is 1500-1800 rev/min, stirs 20 minutes.Separately have acrylic resin, ethylene glycol monomethyl ether and cellulosic pigment solution, leaving temperature in is under the environment of 50-80 DEG C.
The third embodiment of the present invention, this embodiment described is identical with above-described embodiment part, only difference is, light particle is also added with in described pigment, described light particle is glass microballon, described Glass Bead Diameter is 30 microns, mass percent shared by described glass microballon is 2-5%, glass microballon is added in a first step in above-mentioned making pigment process, through ball milling and grinding, but glass microballon is evenly distributed in pigment, make pigment fall picture on paper after, there is reflective effect, make whole picture abundanter.
The fourth embodiment of the present invention, described embodiment is identical with above-described embodiment part, only difference is, also glossy material is added with in described pigment, described glossy material is metallic aluminium, described metallic aluminium is plated in pigmented by the mode of plating, and in above-mentioned manufacture method before step 5, pigmented is stirred, whipping appts is vacuumized, and the non-stirred space place in whipping appts, one aluminium bar is set, and aluminium bar is connected sputtering electrode, pass into shielding gas simultaneously, described shielding gas is argon gas, open sputtering electrode, regulating voltage is to 4-5Kv, electroplating time is 20-60 minute, metallic aluminium is realized to electroplate on the pigment in whipping process, there is the pigment of reflecting metal, there is very bright color and luster.
Claims (9)
1. a novel Chinese painting color that can be reflective, is characterized in that, described pigment formula comprises pigmented, dispersion agent, colour stabilizer and colloid; Mass percent shared by described pigmented is 35-45%, and the mass percent shared by described dispersion agent is 5-7%, and the mass percent shared by described colour stabilizer is 8-10%, and the mass percent shared by described colloid is 40-50%.
2. pigment according to claim 1, is characterized in that, also has light particle in described pigment formula, and described light particle is glass microballon, and described Glass Bead Diameter is 30 microns, and mass percent shared by glass microballon is 2-5%.
3. pigment according to claim 1, is characterized in that, is also added with protection filler in described pigment.
4. pigment according to claim 3, it is characterized in that, described protection filler comprises acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose, it is 2-4% that described acrylic resin, ethylene glycol monomethyl ether and Mierocrystalline cellulose entirety account for pigment mass per-cent, and acrylic resin: ethylene glycol monomethyl ether: Mierocrystalline cellulose is 2:1:1.
5. pigment according to claim 1, is characterized in that, described dispersion agent is polyether glycol.
6. pigment according to claim 1, is characterized in that, described colour stabilizer is salicylic acid benzene fat.
7. pigment according to claim 1, is characterized in that, described colloid adopts Racemic glycidol lipid epoxy resin.
8. pigment according to claim 1, is characterized in that, described pigmented comprises red, blue, green three kinds of colors, and application reddish yellow indigo plant makes required color; Wherein red pigment base is zunsober; Blue pigments base is Cu
3[CO
3]
2(OH)
2; Veridian base master is made up of cobalt, titanium, nickel and zinc, also has and account for the CoCr that pigmented mass percent is 0.1-1% in described veridian base
2o
4and Co
2tiO
4.
9. a preparation method for novel Chinese painting color that can be reflective, for the preparation of pigment according to claim 1, is characterized in that, comprises the following steps:
Step 1, by according to the pigmented of 30-40 part and the colloid proportioning Homogeneous phase mixing of 50-60 part, drop in ball grinder, adopt wet ball grinding 4 hours, when ball milling, control ball milling temperature at 30-50 DEG C, employing alcohols is ball-milling medium, and described alcohols can adopt ethanol, material ball ratio is 1:5, material: ball-milling medium is 1:0.5;
After step 2, ball milling complete, the slurry that ball milling obtains is dried, grinds after oven dry, be ground to 30-50 μm;
Step 3, dropped in stirrer by the abrasive after grinding, add the colour stabilizer of 5-8 part, carry out vacuumizing stirring, stirring velocity is 2500-3000 rev/min simultaneously, and to control whipping temp be 200-230 DEG C, continues 30 minutes, completes stirring;
Step 4, step 3 is stirred acquisition mixture in add the dispersion agent of 1-5 part, obtain the mixture with dispersion agent, and be again placed in stirrer, add aqua calcis, adjustment pH value is 8-9, and stirs, described stirring velocity 1000-1500 rev/min, whipping temp is 70-90 DEG C, stirs 50 minutes;
Step 5, after step 4 has stirred, add carbonic acid and regulate pH value be neutrality, after filter cleaner, be placed in high pressure high-shear microjet pulverizer, control pressure has been 160-170MPa, and current potential is 40-45mV, after circulation 40-50 time;
After step 6, completing steps 5, pigment is enclosed tightness system and stores.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410795980.9A CN104449003B (en) | 2014-12-18 | 2014-12-18 | A kind of can be reflective Chinese painting color |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410795980.9A CN104449003B (en) | 2014-12-18 | 2014-12-18 | A kind of can be reflective Chinese painting color |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104449003A true CN104449003A (en) | 2015-03-25 |
| CN104449003B CN104449003B (en) | 2016-08-17 |
Family
ID=52895786
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410795980.9A Expired - Fee Related CN104449003B (en) | 2014-12-18 | 2014-12-18 | A kind of can be reflective Chinese painting color |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945990A (en) * | 2015-06-30 | 2015-09-30 | 河南行知专利服务有限公司 | Biological environment-friendly pigment with long quality guarantee period for artistic design |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
| CN107011712A (en) * | 2017-06-02 | 2017-08-04 | 中国科学院包头稀土研发中心 | A kind of new Chinese painting color containing rare earth element and preparation method thereof |
| CN108203556A (en) * | 2016-12-19 | 2018-06-26 | 江苏格罗瑞化学有限公司 | A kind of chemical industry polychrome degree pigment formula and production method |
| LU101061B1 (en) * | 2018-12-18 | 2020-06-18 | Int Lacquers S A | Process for improving the gloss of compositions for nail varnish |
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| CN101225255A (en) * | 2007-12-26 | 2008-07-23 | 宋健 | Reflection stacking acrylic paints for fine arts and method for manufacturing same |
| CN101225257A (en) * | 2007-12-26 | 2008-07-23 | 宋健 | Reflection gouache color for fine arts and method for manufacturing same |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101225255A (en) * | 2007-12-26 | 2008-07-23 | 宋健 | Reflection stacking acrylic paints for fine arts and method for manufacturing same |
| CN101225257A (en) * | 2007-12-26 | 2008-07-23 | 宋健 | Reflection gouache color for fine arts and method for manufacturing same |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945990A (en) * | 2015-06-30 | 2015-09-30 | 河南行知专利服务有限公司 | Biological environment-friendly pigment with long quality guarantee period for artistic design |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
| CN108203556A (en) * | 2016-12-19 | 2018-06-26 | 江苏格罗瑞化学有限公司 | A kind of chemical industry polychrome degree pigment formula and production method |
| CN107011712A (en) * | 2017-06-02 | 2017-08-04 | 中国科学院包头稀土研发中心 | A kind of new Chinese painting color containing rare earth element and preparation method thereof |
| CN107011712B (en) * | 2017-06-02 | 2019-04-05 | 中国科学院包头稀土研发中心 | A kind of Chinese painting color and preparation method thereof containing rare earth element |
| LU101061B1 (en) * | 2018-12-18 | 2020-06-18 | Int Lacquers S A | Process for improving the gloss of compositions for nail varnish |
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| CN104449003B (en) | 2016-08-17 |
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