CN104945990A - Biological environment-friendly pigment with long quality guarantee period for artistic design - Google Patents

Biological environment-friendly pigment with long quality guarantee period for artistic design Download PDF

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Publication number
CN104945990A
CN104945990A CN201510370895.2A CN201510370895A CN104945990A CN 104945990 A CN104945990 A CN 104945990A CN 201510370895 A CN201510370895 A CN 201510370895A CN 104945990 A CN104945990 A CN 104945990A
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China
Prior art keywords
pigment
hollow glass
glass microbead
guarantee period
carbon fiber
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CN201510370895.2A
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Chinese (zh)
Inventor
马新攀
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Henan Hang Zhi Patent Services Co Ltd
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Henan Hang Zhi Patent Services Co Ltd
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Priority to CN201510370895.2A priority Critical patent/CN104945990A/en
Publication of CN104945990A publication Critical patent/CN104945990A/en
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Abstract

The invention discloses a biological environment-friendly pigment with long quality guarantee period for artistic design. The biological environment-friendly pigment comprises the following components in parts by weight: 50-70 parts of vegetable gum, 60-80 parts of pigment powder, 10-15 parts of functional auxiliary agents, 3-5 parts of EM bacteria and 4-6 parts of antioxidants 1010. The biological environment-friendly pigment disclosed by the invention is free of containing formaldehyde, long in quality guarantee time, firm in pigment structural layer, firm in coating adhesion, good in moisture-proof effect and long in quality guarantee period.

Description

A kind of biological environmental production pigment for artistic design long quality-guarantee period
Technical field
The present invention relates to art painting technical field, particularly a kind of biological environmental production pigment for artistic design long quality-guarantee period.
Background technology
Pigment (Pigment) is used for painted powdery substance.Do not dissolve in the media such as water, grease, resin, organic solvent, but can disperse in these media equably and medium can be made painted, and there is certain opacifying power.The pigment basic demand particle of the fine arts is more fine and smooth better, and color is more bright-coloured better, more sustained look better (stability will be got well).The watercolors of watercolors, except white, are nearly all transparent.Such needs that could meet watercolor cover dye.Gouache color be at first add in watercolors white powder, make color opaque and invention.Because watercolors are transparent, so once draw wrong very difficult amendment.And gouache color just can be revised very easily due to opaque.The performance that the raw materials such as gum arabic further improve it was with the addition of again afterwards in gouache color.Gum arabic can allow gouache color do rear surface one deck gloss, but needing the flat special occasions (such as draw design sketch and to paint such situation for animation) be coated with, glue can form irregular blotches in color table face, or allow uneven color, so there is the special pigment that comes unstuck.Oil colour is with oil dilution pigment.Chinese painting color is very abundant, has all kinds, extracts from breeze to plant extract to animal, and type is complicated.As long as there is red green blue tricolor just can recall other all colors in theory, but the colour purity recalled is always not high enough, so the art painting manufacturer in modern times is just the color of various form and aspect and lightness, produce highly purified pigment to meet various needs.From 12 the most basic looks to common 24 looks even 48 looks to 60 polychromes, also do not comprise special metallic color.
Pigment is material conventional in artistic design, and its kind is more.Water-base pigment is a kind of novel environment friendly pigment, and compare with conventional pigment, it has nontoxic, the advantage such as odorlessness, environmental protection, and it more meets the theory of health environment-friendly to compare conventional pigment, also becomes a kind of trend of pigment.Existing water-base pigment is scribbled after paper, and the illumination of existence chance is mostly shone for a long time and easily come off, and not resistance to steam and humidity etc., containing defects such as the inadequate environmental protection of objectionable impurities.Chinese patent CN201010204605 discloses a kind of artistic creation pigment, and this pigment possesses the advantage of easily cleaning, but there is illumination shines for a long time and easily come off, and not resistance to steam and the defect such as moist, be not easy for paper scribble.
Summary of the invention
Object of the present invention be just to provide a kind of containing formaldehyde, long, the pigment structure layer of shelf lives firmly, with the biological environmental production pigment for artistic design long quality-guarantee period that coating adhesion is firm, moisture effect is good.
The invention provides a kind of biological environmental production pigment for artistic design long quality-guarantee period, pigment formula ratio is according to the mass fraction: the vegetable jelly of 50-70 weight part, the pigment powder of 60-80 weight part, the antioxidant 1010 of the functional agent of 10-15 weight part, the EM bacterium of 3-5 weight part and 4-6 weight part.
Described functional agent comprises hollow glass microbead, carbon fiber and polyvinyl acetate.
Described hollow glass microbead, carbon fiber and polyvinyl acetate are by mass fraction ratio: the hollow glass microbead of 30-40 weight part, the carbon fiber of 70-90 weight part, the polyvinyl acetate of 10-15 weight part.
Described hollow glass microbead adopts the hollow glass microbead of 300 order granularities.
Described hollow glass microbead adopts the hollow glass microbead of 300 order granularities and the hollow glass microbead of 500 order granularities, and the hollow glass microbead of described 300 order granularities and the hollow glass microbead of 500 order granularities are by mass fraction ratio: the wherein hollow glass microbead of 300 order granularities: the hollow glass microbead of 100 parts and 500 order granularities: 300 parts.
The length of described carbon fiber is 12-15 micron.
The preparation method of the above-mentioned biological environmental production pigment for artistic design, comprises the following steps:
The process of the first step vegetable jelly:
Vegetable jelly is carried out immersion dissolve, filter, bleach and precipitate;
Adding of second step functional aid:
By comprising hollow glass microbead, EM bacterium, carbon fiber and polyvinyl acetate form functional agent and antioxidant 1010 joins ground and mixed in the colloid of precipitation;
Adding of 3rd step pigment powder:
The pigment powder of required color is joined in above-mentioned colloid, after grind, carry out mediation and be prepared into drawing pigment.
The present invention has the following advantages: one, owing to not adding formaldehyde in material of the present invention, therefore virulent gas can not be produced in the production and use procedure of this art painting pigment, and EM bacterium not only has good effect of drawing up to the growth of bacterium, but also to fungi, phycomycete etc. contained and residual in fruit tree glue, there is good effect of drawing up, the present inventor finds the EM bacterium of adding aforementioned proportion, makes the quality guaranteed period of this drawing pigment reach 200 months; Due to the stable performance of EM bacterium, therefore effectively prevent drawing aspergillus tubigensis, Penicillium notatum in wet environment to form drawing and corrode, drawing can be preserved for a long time, and ensure its bright and new degree.Its two, the present inventor finds, in use vegetable jelly rubber, there is the problem that properties-correcting agent is single, can not play the synergy of properties-correcting agent.The present inventor finds in research process, by hollow glass microbead, polyvinyl acetate, carbon fiber and pigment be combined, pigment coated performance is greatly improved.Coated material is had wear-resisting, sound construction, coated adhesive power is strong, the advantage of long service life, linked together by carbon fiber between hollow glass microbead particle, vegetable jelly and pigment are filled in the cavity of hollow glass microbead simultaneously, carbon fiber, hollow glass microbead, adding of pigment makes to form cross network node in painting laminate structure, thus improve painting stiffness layer, creep resistance and wear resistance, life-span is extended greatly, making the tear resistance of coating compared to the coating not adding described functional agent can improve 11 times, making the bonding force of coating compared to the coating not adding described functional agent can improve 2.8 times, also find in process of the test, in pigment, such as add the functional agent of 10-15 part, wherein functional agent comprises the hollow glass microbead of 30-40 weight part, the carbon fiber of 70-90 weight part, the polyvinyl acetate of 10-15 weight part, make the hydrophobic nature of coating, water resistance, corrosion resistance nature can improve 9 times compared to the coating not adding described functional agent, and the bright and new degree of coating is apparently higher than the coating of not adding functional agent.Described hollow glass microbead, carbon fiber and polyvinyl acetate are by mass fraction ratio: the hollow glass microbead of 30-40 weight part, the carbon fiber of 70-90 weight part, the polyvinyl acetate of 10-15 weight part.Described hollow glass microbead adopts the hollow glass microbead of 300 order granularities and the hollow glass microbead of 500 order granularities, and the hollow glass microbead of described 300 order granularities and the hollow glass microbead of 500 order granularities are by mass fraction ratio: the wherein hollow glass microbead of 300 order granularities: the hollow glass microbead of 100 parts and 500 order granularities: 300 parts.The present inventor is through experimental studies have found that, select the hollow glass microbead of the granularity of said ratio, the hollow glass microbead of 500 order granularities can be centered around the hollow glass microbead week side of 300 order granularities, and polyvinyl acetate, pigment and vegetable jelly can be filled in the cavity of hollow glass microbead, carbon fiber interts in hollow glass microbead cavity not of uniform size simultaneously, more firmly structure can be formed, making the tear resistance of coating compared to the coating not adding described functional agent can improve 16 times, making the bonding force of coating compared to the coating not adding described functional agent can improve 5.8 times.The length of described carbon fiber is 12-15 micron, makes the structure of coating more firm, because hollow glass microbead is hyalosome, so pigment coloring ability of the present invention is apparently higher than prior art.
Embodiment
Embodiment 1: a kind of biological environmental production pigment for artistic design long quality-guarantee period, pigment formula ratio is according to the mass fraction: the vegetable jelly of 50 weight parts, the pigment powder of 60 weight parts, the antioxidant 1010 of the functional agent of 10 weight parts, the EM bacterium of 3 weight parts and 4 weight parts.
Described functional agent comprises hollow glass microbead, carbon fiber and polyvinyl acetate.
Described hollow glass microbead, carbon fiber and polyvinyl acetate are by mass fraction ratio: the hollow glass microbead of 30 weight parts, the carbon fiber of 70 weight parts, the polyvinyl acetate of 10 weight parts.
Described hollow glass microbead adopts the hollow glass microbead of 300 order granularities and the hollow glass microbead of 500 order granularities, and the hollow glass microbead of described 300 order granularities and the hollow glass microbead of 500 order granularities are by mass fraction ratio: the wherein hollow glass microbead of 300 order granularities: the hollow glass microbead of 100 parts and 500 order granularities: 300 parts.
The length of described carbon fiber is 12 microns.
The preparation method of the above-mentioned biological environmental production pigment for artistic design, comprises the following steps:
The process of the first step vegetable jelly:
Vegetable jelly is carried out immersion dissolve, filter, bleach and precipitate;
Adding of second step functional aid:
By comprising hollow glass microbead, EM bacterium, carbon fiber and polyvinyl acetate form functional agent and antioxidant 1010 joins ground and mixed in the colloid of precipitation;
Adding of 3rd step pigment powder:
The pigment powder of required color is joined in above-mentioned colloid, after grind, carry out mediation and be prepared into drawing pigment.
Embodiment 2: a kind of biological environmental production pigment for artistic design long quality-guarantee period, pigment formula ratio is according to the mass fraction: the vegetable jelly of 70 weight parts, the pigment powder of 80 weight parts, the antioxidant 1010 of the functional agent of 15 weight parts, the EM bacterium of 5 weight parts and 6 weight parts.
Described functional agent comprises hollow glass microbead, carbon fiber and polyvinyl acetate.
Described hollow glass microbead, carbon fiber and polyvinyl acetate are by mass fraction ratio: the hollow glass microbead of 40 weight parts, the carbon fiber of 90 weight parts, the polyvinyl acetate of 15 weight parts.
Described hollow glass microbead adopts the hollow glass microbead of 300 order granularities and the hollow glass microbead of 500 order granularities, and the hollow glass microbead of described 300 order granularities and the hollow glass microbead of 500 order granularities are by mass fraction ratio: the wherein hollow glass microbead of 300 order granularities: the hollow glass microbead of 100 parts and 500 order granularities: 300 parts.
The length of described carbon fiber is 15 microns.
The preparation method of the above-mentioned biological environmental production pigment for artistic design, comprises the following steps:
The process of the first step vegetable jelly:
Vegetable jelly is carried out immersion dissolve, filter, bleach and precipitate;
Adding of second step functional aid:
By comprising hollow glass microbead, EM bacterium, carbon fiber and polyvinyl acetate form functional agent and antioxidant 1010 joins ground and mixed in the colloid of precipitation;
Adding of 3rd step pigment powder:
The pigment powder of required color is joined in above-mentioned colloid, after grind, carry out mediation and be prepared into drawing pigment.
Embodiment 3: a kind of biological environmental production pigment for artistic design long quality-guarantee period, pigment formula ratio is according to the mass fraction: the vegetable jelly of 60 weight parts, the pigment powder of 70 weight parts, the antioxidant 1010 of the functional agent of 13 weight parts, the EM bacterium of 4 weight parts and 5 weight parts.
Described functional agent comprises hollow glass microbead, carbon fiber and polyvinyl acetate.
Described hollow glass microbead, carbon fiber and polyvinyl acetate are by mass fraction ratio: the hollow glass microbead of 35 weight parts, the carbon fiber of 80 weight parts, the polyvinyl acetate of 13 weight parts.
Described hollow glass microbead adopts the hollow glass microbead of 300 order granularities and the hollow glass microbead of 500 order granularities, and the hollow glass microbead of described 300 order granularities and the hollow glass microbead of 500 order granularities are by mass fraction ratio: the wherein hollow glass microbead of 300 order granularities: the hollow glass microbead of 100 parts and 500 order granularities: 300 parts.
The length of described carbon fiber is 12 microns.
The preparation method of the above-mentioned biological environmental production pigment for artistic design, comprises the following steps:
The process of the first step vegetable jelly:
Vegetable jelly is carried out immersion dissolve, filter, bleach and precipitate;
Adding of second step functional aid:
By comprising hollow glass microbead, EM bacterium, carbon fiber and polyvinyl acetate form functional agent and antioxidant 1010 joins ground and mixed in the colloid of precipitation;
Adding of 3rd step pigment powder:
The pigment powder of required color is joined in above-mentioned colloid, after grind, carry out mediation and be prepared into drawing pigment.
The present invention has the following advantages: one, owing to not adding formaldehyde in material of the present invention, therefore virulent gas can not be produced in the production and use procedure of this art painting pigment, and B EM bacterium not only has good effect of drawing up to the growth of bacterium, but also to fungi, phycomycete etc. contained and residual in fruit tree glue, there is good effect of drawing up, the present inventor finds the EM bacterium of adding aforementioned proportion, makes the quality guaranteed period of this drawing pigment reach 200 months; Due to the stable performance of EM bacterium, therefore effectively prevent drawing aspergillus tubigensis, Penicillium notatum in wet environment to form drawing and corrode, drawing can be preserved for a long time, and ensure its bright and new degree.Its two, the present inventor finds, in use vegetable jelly rubber, there is the problem that properties-correcting agent is single, can not play the synergy of properties-correcting agent.The present inventor finds in research process, by hollow glass microbead, polyvinyl acetate, carbon fiber and pigment be combined, pigment coated performance is greatly improved.Coated material is had wear-resisting, sound construction, coated adhesive power is strong, the advantage of long service life, linked together by carbon fiber between hollow glass microbead particle, vegetable jelly and pigment are filled in the cavity of hollow glass microbead simultaneously, carbon fiber, hollow glass microbead, adding of pigment makes to form cross network node in painting laminate structure, thus improve painting stiffness layer, creep resistance and wear resistance, life-span is extended greatly, making the tear resistance of coating compared to the coating not adding described functional agent can improve 11 times, making the bonding force of coating compared to the coating not adding described functional agent can improve 2.8 times, also find in process of the test, in pigment, such as add the functional agent of 10-15 part, wherein functional agent comprises the hollow glass microbead of 30-40 weight part, the carbon fiber of 70-90 weight part, the polyvinyl acetate of 10-15 weight part, make the hydrophobic nature of coating, water resistance, corrosion resistance nature can improve 9 times compared to the coating not adding described functional agent, and the bright and new degree of coating is apparently higher than the coating of not adding functional agent.Described hollow glass microbead, carbon fiber and polyvinyl acetate are by mass fraction ratio: the hollow glass microbead of 30-40 weight part, the carbon fiber of 70-90 weight part, the polyvinyl acetate of 10-15 weight part.Described hollow glass microbead adopts the hollow glass microbead of 300 order granularities and the hollow glass microbead of 500 order granularities, and the hollow glass microbead of described 300 order granularities and the hollow glass microbead of 500 order granularities are by mass fraction ratio: the wherein hollow glass microbead of 300 order granularities: the hollow glass microbead of 100 parts and 500 order granularities: 300 parts.The present inventor is through experimental studies have found that, select the hollow glass microbead of the granularity of said ratio, the hollow glass microbead of 500 order granularities can be centered around the hollow glass microbead week side of 300 order granularities, and polyvinyl acetate, pigment and vegetable jelly can be filled in the cavity of hollow glass microbead, carbon fiber interts in hollow glass microbead cavity not of uniform size simultaneously, more firmly structure can be formed, making the tear resistance of coating compared to the coating not adding described functional agent can improve 16 times, making the bonding force of coating compared to the coating not adding described functional agent can improve 6.8 times.The diameter of described carbon fiber is 6-6.6, and length is 12-15 micron, makes the structure of coating more firm, because hollow glass microbead is hyalosome, so pigment coloring ability of the present invention is apparently higher than prior art.

Claims (5)

1. the biological environmental production pigment for artistic design long quality-guarantee period, it is characterized in that: pigment formula ratio according to the mass fraction: the vegetable jelly of 50-70 weight part, the pigment powder of 60-80 weight part, the antioxidant 1010 of the functional agent of 10-15 weight part, the EM bacterium of 3-5 weight part and 4-6 weight part.
2., as claimed in claim 1 for the biological environmental production pigment of artistic design long quality-guarantee period, it is characterized in that: described functional agent comprises hollow glass microbead, carbon fiber and polyvinyl acetate.
3., as claimed in claim 1 for the biological environmental production pigment of artistic design long quality-guarantee period, it is characterized in that: described hollow glass microbead adopts the hollow glass microbead of 300 order granularities.
4., as claimed in claim 1 for the biological environmental production pigment of artistic design long quality-guarantee period, it is characterized in that: the length of described carbon fiber is 12-15 micron.
5., as claimed in claim 1 for the preparation method of the biological environmental production pigment of artistic design long quality-guarantee period, it is characterized in that: comprise the following steps:
The process of the first step vegetable jelly:
Vegetable jelly is carried out immersion dissolve, filter, bleach and precipitate;
Adding of second step functional aid:
By comprising hollow glass microbead, EM bacterium, carbon fiber and polyvinyl acetate form functional agent and antioxidant 1010 joins ground and mixed in the colloid of precipitation;
Adding of 3rd step pigment powder:
The pigment powder of required color is joined in above-mentioned colloid, after grind, carry out mediation and be prepared into drawing pigment.
CN201510370895.2A 2015-06-30 2015-06-30 Biological environment-friendly pigment with long quality guarantee period for artistic design Pending CN104945990A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108384300A (en) * 2018-03-28 2018-08-10 黑龙江工业学院 A kind of fine arts gouache color and its manufacturing method containing nano components

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101225254A (en) * 2007-12-26 2008-07-23 宋健 Reflection acrylic paints for fine arts and method for manufacturing same
CN101531840A (en) * 2009-04-16 2009-09-16 宋阳 Colored daub painting pigment and process for preparing same
CN103160153A (en) * 2013-04-14 2013-06-19 河北青竹美术颜料有限公司 Formaldehyde-free art paint and preparation method thereof
CN104449003A (en) * 2014-12-18 2015-03-25 李泳博 Novel traditional Chinese painting pigment capable of reflecting light
JP2015089930A (en) * 2013-11-07 2015-05-11 株式会社サクラクレパス Finger pigment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101225254A (en) * 2007-12-26 2008-07-23 宋健 Reflection acrylic paints for fine arts and method for manufacturing same
CN101531840A (en) * 2009-04-16 2009-09-16 宋阳 Colored daub painting pigment and process for preparing same
CN103160153A (en) * 2013-04-14 2013-06-19 河北青竹美术颜料有限公司 Formaldehyde-free art paint and preparation method thereof
JP2015089930A (en) * 2013-11-07 2015-05-11 株式会社サクラクレパス Finger pigment
CN104449003A (en) * 2014-12-18 2015-03-25 李泳博 Novel traditional Chinese painting pigment capable of reflecting light

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
沈莲: "《机械工程材料》", 31 May 1999, 西安交通大学 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108384300A (en) * 2018-03-28 2018-08-10 黑龙江工业学院 A kind of fine arts gouache color and its manufacturing method containing nano components

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Application publication date: 20150930