CN103160153A - Formaldehyde-free art paint and preparation method thereof - Google Patents
Formaldehyde-free art paint and preparation method thereof Download PDFInfo
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- CN103160153A CN103160153A CN2013101270681A CN201310127068A CN103160153A CN 103160153 A CN103160153 A CN 103160153A CN 2013101270681 A CN2013101270681 A CN 2013101270681A CN 201310127068 A CN201310127068 A CN 201310127068A CN 103160153 A CN103160153 A CN 103160153A
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Abstract
The invention belongs to the technical field of a drawing paint, and particularly discloses a formaldehyde-free art paint and a preparation method thereof. The paint is prepared from gelatin, paint powder, a functional agent, and a corrosion remover formed by BCM (bis-chloromethyl) and chlorothalonil. The formaldehyde-free art paint is prepared by the procedures of gelatin treatment, adding the functional agent, adding the paint powder, adding the corrosion remover formed by BCM and chlorothalonil, and packaging. The formaldehyde-free art paint has the characteristics of being long in quality guarantee period, and effectively preventing aspergillus and penicillium from corroding the drawing in a humid environment.
Description
Technical field
The invention belongs to the drawing pigment technical field, relate to concretely a kind of formaldehydeless art painting pigment and preparation method thereof.
Background technology
Art painting pigment is by consisting of for functional aids such as rot-resistant formaldehyde and wetting Agent for Printing Inks, flow agent, frostproofer and the agent of anti-cracking pigment powder, vegetable jelly and comprising of adding.Its preparation technology is at first vegetable jelly to be soaked and dissolve, filter, bleach and precipitate; Then add formaldehyde and other auxiliary agents in the vegetable jelly after precipitation; At last the pigment powder is added to grind in above-mentioned colloid and can prepare drawing pigment.There is following defective in the drawing pigment that has above-mentioned technique to prepare: one, this pigment has used formaldehyde to cook sanitas, because formaldehyde is a kind of volatile toxic substance, not only can be to workman's Body composition injury in preparation engineering, and the picture of drawing in a humid environment, formaldehyde very easily discharges volatilization, makes the easy moldy metamorphism of the picture of preserving; They are two years old, although formaldehyde is a kind of good sanitas, the growth of bacterium is drawn up have good effect, but the effect that the bacterium of the phycomycetes on the dry film of the aspergillus tubigensis in fungi contained and residual in fruit tree glue, phycomycete and wet environment, Penicillium notatum and picture is not drawn up, therefore not only use the pigment of formaldehyde not only to guarantee the quality the time shorter (18 months), and used the bright and new degree preservation and effect of the picture that the pigment that contains formol draws also can be desirable.
Summary of the invention
Purpose of the present invention just is to provide a kind of formaldehydeless art painting pigment formaldehyde, that guarantee the quality time length that do not contain.
Another object of the present invention just is to provide the method for preparing above-mentioned formaldehydeless art painting pigment.
For realizing above-mentioned the first purpose, the technical solution adopted in the present invention is:
A kind of formaldehydeless art painting pigment is characterized in that: by
The vegetable jelly of 100 weight parts, the pigment powder of 90-105 weight parts, the BCM of the functional agent of 10-15 weight parts and 0.5-0.6 weight part and the m-tetrachlorophthalodinitrile of 0.3-0.45 weight part consist of.
Wherein, described functional agent is made of 1.5-3.0 weight part wetting Agent for Printing Inkss, 7.5-9.0 weight part frostproofers, the anti-cracking agent of 0.8-1.5 weight parts and 0.8-1.5 weight part flow agents.
For realizing above-mentioned the second purpose, the technical solution adopted in the present invention is:
The preparation method of above-mentioned formaldehydeless art painting pigment comprises the following steps:
The first step vegetable jelly is processed
Vegetable jelly is soaked dissolve, filter, bleach and precipitate;
Adding of second step functional aid
To comprise that wetting Agent for Printing Inks, frostproofer, the agent of anti-cracking and flow agent consist of ground and mixed in the colloid that functional agent joins precipitation;
Adding of the 3rd step pigment powder
The pigment powder of required color is joined in above-mentioned colloid, after grind;
Adding of the 4th step sanitas
Add the sanitas that is consisted of by BCM and m-tetrachlorophthalodinitrile in the colloid that grinds, be in harmonious proportion and be prepared into drawing pigment;
The 5th step packing.
a kind of formaldehydeless art painting pigment provided by the present invention and preparation method thereof compared with prior art, have the following advantages: one, because adopting BCM and the compound formation of m-tetrachlorophthalodinitrile, the anticorrosion auxiliary agent that consists of this art painting pigment replaced formaldehyde, therefore can not produce virulent gas in the production of this art painting pigment and use procedure, and the sanitas of BCM and the compound formation of m-tetrachlorophthalodinitrile not only has the good effect of drawing up to the growth of bacterium, but also to fungi contained and residual in fruit tree glue, phycomycete has the good effect of drawing up, make the quality guaranteed period of this drawing pigment reach more than 48 months, its two, due to the stable performance of the sanitas of BCM and the compound formation of m-tetrachlorophthalodinitrile, preventing effectively therefore that drawing aspergillus tubigensis, Penicillium notatum in wet environment consist of drawing corrodes, and makes drawing can access long preservation, and guarantees its bright and new degree, they are three years old, due in preparation technology, the BCM and the m-tetrachlorophthalodinitrile that consist of sanitas are to add in last step, and the add-on that not only can control sanitas in pigment effectively reduces preparation cost, and prevent in its effective constituent process of lapping destroyedly, effectively improved the utilising efficiency of sanitas.
Embodiment
The specific embodiment for preparing above-mentioned formaldehydeless art painting pigment is:
Embodiment 1
The solid peach gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 0.8 weight part of frostproofer, 0.8 weight part of wetting Agent for Printing Inks, 7.5 weight parts of 1.6 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 100 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.5 weight part and 0.45 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
Embodiment 2
The solid apple natural gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 1.0 weight parts of frostproofer, 1.1 weight parts of wetting Agent for Printing Inks, 8.2 weight parts of 1.8 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 95 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.50 weight part and 0.45 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
Embodiment 3
The solid peach gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 1.5 weight parts of frostproofer, 1.5 weight parts of wetting Agent for Printing Inks, 9.0 weight parts of 3.0 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 98 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.60 weight part and 0.30 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
Embodiment 4
The solid apple natural gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 1.5 weight parts of frostproofer, 1.5 weight parts of wetting Agent for Printing Inks, 8.4 weight parts of 2.5 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 1.4 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.53 weight part and 0.35 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
Embodiment 5
The solid peach gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 1.5 weight parts of frostproofer, 1.4 weight parts of wetting Agent for Printing Inks, 7.5 weight parts of 2.5 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 102 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.56 weight part and 0.42 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
Embodiment 6
The solid peach gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 1.0 weight parts of frostproofer, 1.0 weight parts of wetting Agent for Printing Inks, 7.8 weight parts of 2.2 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 100 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.58 weight part and 0.35 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
Embodiment 7
The solid peach gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 0.9 weight part of frostproofer, 1.4 weight parts of wetting Agent for Printing Inks, 7.9 weight parts of 2.8 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 96 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.52 weight part and 0.38 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
Embodiment 8
The solid peach gum of getting 100 weight parts dissolves, filters foreign material are removed by immersion, then obtains peach gum through bleaching and precipitation operation; The flow agent of getting anti-cracking agent, 1.1 weight parts of frostproofer, 0.8 weight part of wetting Agent for Printing Inks, 7.6 weight parts of 2.4 weight parts joins ground and mixed in the peach gum body of precipitation; The pigment powder of 97 weight parts of required color is joined in above-mentioned colloid, after grind; The sanitas that will be made of the m-tetrachlorophthalodinitrile of the BCM of 0.56 weight part and 0.42 weight part again joins to transfer in the colloid of grinding and namely is prepared into drawing pigment; Packing.
In the method for the formaldehydeless art painting pigment of above-mentioned preparation: the fruit tree glue that adopts changes can be to replace such as Arab natural gum.In above-mentioned preparation technology, the wetting Agent for Printing Inks that uses, frostproofer and the agent of anti-cracking are adopted such as auxiliary agents commonly used such as water-borne coatingss and are got final product simultaneously; The paint film sanitas that the BCM of the formation sanitas that uses produces as Canada large Nuo De company, its active ingredient is benzimidazole carbamate and the same analog derivative of isothiazoline.
Claims (3)
1. formaldehydeless art painting pigment is characterized in that: by
The vegetable jelly of 100 weight parts, the pigment powder of 90-105 weight parts, the BCM of the functional agent of 10-15 weight parts and 0.5-0.6 weight part and the m-tetrachlorophthalodinitrile of 0.3-0.45 weight part consist of.
2. a kind of formaldehydeless art painting pigment as claimed in claim 1 is characterized in that: described functional agent is made of 1.5-3.0 weight part wetting Agent for Printing Inkss, 7.5-9.0 weight part frostproofers, the anti-cracking agent of 0.8-1.5 weight parts and 0.8-1.5 weight part flow agents.
3. prepare the method for the described a kind of formaldehydeless art painting pigment of the claims, comprise the following steps:
The first step vegetable jelly is processed
Vegetable jelly is soaked dissolve, filter, bleach and precipitate;
Adding of second step functional aid
To comprise that wetting Agent for Printing Inks, frostproofer, the agent of anti-cracking and flow agent consist of ground and mixed in the colloid that functional agent joins precipitation;
Adding of the 3rd step pigment powder
The pigment powder of required color is joined in above-mentioned colloid, after grind;
Adding of the 4th step sanitas
Add the sanitas that is consisted of by BCM and 0.3-0.45 m-tetrachlorophthalodinitrile in the colloid that grinds, be in harmonious proportion and be prepared into drawing pigment;
The 5th step packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2013101270681A CN103160153A (en) | 2013-04-14 | 2013-04-14 | Formaldehyde-free art paint and preparation method thereof |
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| CN2013101270681A CN103160153A (en) | 2013-04-14 | 2013-04-14 | Formaldehyde-free art paint and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945990A (en) * | 2015-06-30 | 2015-09-30 | 河南行知专利服务有限公司 | Biological environment-friendly pigment with long quality guarantee period for artistic design |
| CN105017829A (en) * | 2015-06-30 | 2015-11-04 | 河南行知专利服务有限公司 | Biological environmental-friendly pigment used for artistic designing |
| CN105038354A (en) * | 2015-06-30 | 2015-11-11 | 河南行知专利服务有限公司 | Biological environment-friendly pigment for artistic designing with strong tinting strength |
| CN106118261A (en) * | 2016-06-27 | 2016-11-16 | 董晓 | A kind of preparation method of waterproof ventilating type external-wall heat-insulation material organic interface agent |
| CN106280635A (en) * | 2016-08-09 | 2017-01-04 | 苏州冰心文化用品有限公司 | A kind of weather-proof drawing pigment of crack resistence and preparation method thereof |
| CN106833077A (en) * | 2017-03-21 | 2017-06-13 | 沈丽亚 | A kind of art painting of high gloss high coloring rate and preparation method thereof |
| CN106893409A (en) * | 2017-03-15 | 2017-06-27 | 乔苏坤 | A kind of biological environmental production pigment for artistic design |
| CN106957549A (en) * | 2017-03-28 | 2017-07-18 | 湖南文理学院 | A kind of environment-friendly type art painting pigment and preparation method thereof |
| CN107603309A (en) * | 2017-09-29 | 2018-01-19 | 江苏工程职业技术学院 | A kind of formaldehydeless art painting sole pigment and its preparation technology |
| CN107603311A (en) * | 2017-10-31 | 2018-01-19 | 湖北工程学院 | A kind of easily wash type drawing pigment and preparation method thereof |
| CN107663389A (en) * | 2017-09-29 | 2018-02-06 | 江苏工程职业技术学院 | A kind of environment-friendly type drawing sole pigment and its preparation technology |
| CN110093056A (en) * | 2019-05-27 | 2019-08-06 | 河北青竹画材科技有限公司 | Aqueous formaldehydeless drawing pigment and preparation method thereof |
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| CN1330119A (en) * | 2001-06-29 | 2002-01-09 | 邹侯招 | Anti-pollution emulsoid paint for internal wall and its preparing process |
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| CN101100552A (en) * | 2007-08-10 | 2008-01-09 | 上海乐美文具有限公司 | Composition for advertisement poster pigment, advertisement poster pigment and preparation method thereof |
| CN101589120A (en) * | 2006-10-25 | 2009-11-25 | 美艺设计有限公司 | Self designed fashion wear and other articles |
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Patent Citations (4)
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| CN1330119A (en) * | 2001-06-29 | 2002-01-09 | 邹侯招 | Anti-pollution emulsoid paint for internal wall and its preparing process |
| US20050255251A1 (en) * | 2004-05-17 | 2005-11-17 | Hodge Robert L | Composition, method of making, and treatment of wood with an injectable wood preservative slurry having biocidal particles |
| CN101589120A (en) * | 2006-10-25 | 2009-11-25 | 美艺设计有限公司 | Self designed fashion wear and other articles |
| CN101100552A (en) * | 2007-08-10 | 2008-01-09 | 上海乐美文具有限公司 | Composition for advertisement poster pigment, advertisement poster pigment and preparation method thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104945990A (en) * | 2015-06-30 | 2015-09-30 | 河南行知专利服务有限公司 | Biological environment-friendly pigment with long quality guarantee period for artistic design |
| CN105017829A (en) * | 2015-06-30 | 2015-11-04 | 河南行知专利服务有限公司 | Biological environmental-friendly pigment used for artistic designing |
| CN105038354A (en) * | 2015-06-30 | 2015-11-11 | 河南行知专利服务有限公司 | Biological environment-friendly pigment for artistic designing with strong tinting strength |
| CN106118261A (en) * | 2016-06-27 | 2016-11-16 | 董晓 | A kind of preparation method of waterproof ventilating type external-wall heat-insulation material organic interface agent |
| CN106280635A (en) * | 2016-08-09 | 2017-01-04 | 苏州冰心文化用品有限公司 | A kind of weather-proof drawing pigment of crack resistence and preparation method thereof |
| CN106893409A (en) * | 2017-03-15 | 2017-06-27 | 乔苏坤 | A kind of biological environmental production pigment for artistic design |
| CN106833077A (en) * | 2017-03-21 | 2017-06-13 | 沈丽亚 | A kind of art painting of high gloss high coloring rate and preparation method thereof |
| CN106957549A (en) * | 2017-03-28 | 2017-07-18 | 湖南文理学院 | A kind of environment-friendly type art painting pigment and preparation method thereof |
| CN107603309A (en) * | 2017-09-29 | 2018-01-19 | 江苏工程职业技术学院 | A kind of formaldehydeless art painting sole pigment and its preparation technology |
| CN107663389A (en) * | 2017-09-29 | 2018-02-06 | 江苏工程职业技术学院 | A kind of environment-friendly type drawing sole pigment and its preparation technology |
| CN107603311A (en) * | 2017-10-31 | 2018-01-19 | 湖北工程学院 | A kind of easily wash type drawing pigment and preparation method thereof |
| CN107603311B (en) * | 2017-10-31 | 2020-03-03 | 湖北工程学院 | Easy-to-wash painting pigment and preparation method thereof |
| CN110093056A (en) * | 2019-05-27 | 2019-08-06 | 河北青竹画材科技有限公司 | Aqueous formaldehydeless drawing pigment and preparation method thereof |
| CN110093056B (en) * | 2019-05-27 | 2021-06-08 | 河北青竹画材科技有限公司 | Water-based formaldehyde-free painting pigment and preparation method thereof |
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Application publication date: 20130619 |