CN106084957A - A kind of fast light Chinese painting color of environmental protection and preparation method thereof - Google Patents
A kind of fast light Chinese painting color of environmental protection and preparation method thereof Download PDFInfo
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- CN106084957A CN106084957A CN201610714969.4A CN201610714969A CN106084957A CN 106084957 A CN106084957 A CN 106084957A CN 201610714969 A CN201610714969 A CN 201610714969A CN 106084957 A CN106084957 A CN 106084957A
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- sorghum
- pigment
- starch
- environmental protection
- red
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/04—Alginic acid; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of fast light Chinese painting color of environmental protection and preparation method thereof, belong to art painting articles for use field.This pigment is composed of the following components: red sorghum pigment, carmine, sodium alginate, polyoxyethylene carboxylate, modified sorghum starch, 2 hydroxyl 4 methoxy benzophenones, glycerol, Zhu's fat, carboxymethyl cellulose, polydimethylsiloxane, deionized water.The present invention be using Sorghum vulgare Pers. garbage sorghum husk be raw material extract red sorghum pigment as the main base material of pigment, and combine a small amount of carmine and Zhu's fat as auxiliary base material, other auxiliaries of arranging in pairs or groups again form, low cost, and light resistance is good, permeability is strong, chromaticness is distinct, and fine and smooth uniform, stability is high, water and oil-resistant is good, safety and environmental protection.
Description
Technical field
The invention belongs to art painting articles for use field, relate to a kind of Chinese painting color, specifically a kind of environmental protection fast light traditional Chinese Painting face
Material and preparation method thereof.
Background technology
Chinese painting color is also Chinese painting colour, is used to the sole pigment of picture traditional Chinese Painting.Traditional Chinese painting colour, mainly divides
Become coloring earth, vegetable pigment and chemical fusion pigment three major types.Vegetable pigment primary color has dark blue, kermes, Resina garciniae etc., tool
Have nontoxic, to skin without the good advantage of anaphylaxis and carcinogenecity, biodegradability and Environmental compatibility, but there is yield
Low, reproducibility is poor and firmness is low, light fugitive is according to shortcomings such as, temperature tolerance differences；Raw mineral materials mainly has Cinnabaris, orpiment, stone
Green etc., covering power is strong, and steadiness is good, invariant color, but imbibition poor performance, water proofing property is poor；Chemical fusion pigment have daybreak, dark red,
Bright red, chrome yellow, sky blue etc., containing organic pigment, tinting strength, tinting power is good, and easily diffusion and processing are ground, and patience is good, easy to use, but can take off
Color.In order to improve the light resistance of pigment, current main settling mode is to add organic light stabilizer in combination, because light is stable
Agent belongs to pure organic compound, exist volatile, bloom, migration, by shortcomings such as solvent extractions, this not only have impact on its usefulness and plays
Persistency, the most also cause polluting environment simultaneously.
Summary of the invention
The technical problem to be solved is for deficiencies of the prior art, it is provided that a kind of environmental protection is fast light
Chinese painting color and preparation method thereof.
In order to achieve the above object, the present invention is by the following technical solutions.
A kind of fast light Chinese painting color of environmental protection, is made up of by weight following components: red sorghum pigment 27-33 part, carmine
1-3 part, sodium alginate 35-45 part, polyoxyethylene carboxylate 0.1-1 part, modified sorghum starch 15-17 part, 2-hydroxyl-4-first
Epoxide benzophenone 0.1-0.5 part, glycerol 3-5 part, Zhu's fat 1-3 part, carboxymethyl cellulose 0.1-0.5 part, poly dimethyl silicon
Oxygen alkane 2-4 part, deionized water 5-15 part.
It is a further object to provide the preparation method of the fast light Chinese painting color of a kind of environmental protection, comprise the steps:
(1) prepare red sorghum pigment
Taking Sorghum vulgare Pers. seed, with hulling machine isolated sorghum husk and sorghum rice, selecting sorghum husk is that raw material extracts red sorghum pigment；
The most first adding in diffuser by sorghum husk, add the pH3 ethanol solution of 60%, its addition is sorghum husk quality
20-30 times, under conditions of 50-60 DEG C, soak 40-60min, then microwave radiation processing, microwave power 550-650W, microwave
Process time 60-90s, is distilled off ethanol, after precipitation to be crystallized, filters isolated red sorghum pigment；
(2) prepare modified sorghum starch
Sorghum rice uses wet grinding extract and obtains sorghum starch, sorghum starch is carried out acylation modification, obtain modified high
Fine strain of millet starch；Described acylation modification is first by the mass ratio of 1:2-3, sorghum starch and water to be mixed and made into starch milk, the most wherein
Add the succinic anhydrides accounting for starch quality 5%, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, protect
Holding temperature is 35 DEG C of reaction 100min, then with the hydrochloric acid solution regulation pH value of starch milk that mass concentration is 5% to 6.5, dehydration, gas
Fluidized drying, crosses 200-500 mesh sieve, obtains modified sorghum starch；
(3) allocate pigment
First by red sorghum pigment, carmine, sodium alginate, carboxymethyl cellulose, deionized water mixing, it is heated to 65-75
DEG C, stir, obtain mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerol,
Polydimethylsiloxane mixes, and is heated to 35-45 DEG C, stirs, obtain mixture B, modification sorghum starch and Zhu's fat is mixed
Close, be sequentially added into mixture B, mixture A wherein, fully mix thoroughly, be down to room temperature, fill.
The Advantageous Effects of the present invention: the present invention be by Sorghum vulgare Pers. garbage sorghum husk be raw material extract red sorghum pigment
As the main base material of pigment, and combine a small amount of carmine and Zhu's fat as auxiliary base material, then other auxiliaries of arranging in pairs or groups form, cost
Low, light resistance is good, and permeability is strong, and chromaticness is distinct, and fine and smooth uniform, stability is high, and water and oil-resistant is good, safety and environmental protection.
Detailed description of the invention
Further technical scheme is made detailed elaboration below in conjunction with embodiment, but the not all in pairs present invention
Scope limits.
Embodiment 1
A kind of fast light Chinese painting color of environmental protection, is made up of by weight following components: red sorghum pigment 27 parts, carmine 1 part,
Sodium alginate 35 parts, polyoxyethylene carboxylate 0.1 part, modified sorghum starch 15 parts, ESCALOL 567
0.1 part, glycerol 3 parts, Zhu's fat 1 part, carboxymethyl cellulose 0.1 part, polydimethylsiloxane 2 parts, deionized water 5 parts.
The preparation method of described environmental protection is fast light Chinese painting color, comprises the steps:
(1) prepare red sorghum pigment
Taking Sorghum vulgare Pers. seed, with hulling machine isolated sorghum husk and sorghum rice, selecting sorghum husk is that raw material extracts red sorghum pigment；
The most first adding in diffuser by sorghum husk, add the pH3 ethanol solution of 60%, its addition is the 20 of sorghum husk quality
Times, under conditions of 50 DEG C, soak 40min, then microwave radiation processing, microwave power 550W, microwave treatment time 60s, distillation
Remove ethanol, after precipitation to be crystallized, filter isolated red sorghum pigment；
(2) prepare modified sorghum starch
Sorghum rice uses wet grinding extract and obtains sorghum starch, sorghum starch is carried out acylation modification, obtain modified high
Fine strain of millet starch；Described acylation modification is first by the mass ratio of 1:2, sorghum starch and water to be mixed and made into starch milk, adds the most wherein
Enter to account for the succinic anhydrides of starch quality 5%, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, keep
Temperature is 35 DEG C of reaction 100min, then with the hydrochloric acid solution regulation pH value of starch milk that mass concentration is 5% to 6.5, dehydration, air-flow
It is dried, crosses 200 mesh sieves, obtain modified sorghum starch；
(3) allocate pigment
First by red sorghum pigment, carmine, sodium alginate, carboxymethyl cellulose, deionized water mixing, it is heated to 75 DEG C,
Stir, obtain mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerol, poly-two
Methylsiloxane mixes, and is heated to 45 DEG C, stirs, obtains mixture B, modification sorghum starch and Zhu's fat is mixed, Xiang Qi
In be sequentially added into mixture B, mixture A, fully mix thoroughly, be down to room temperature, fill.
Embodiment 2
A kind of fast light Chinese painting color of environmental protection, is made up of by weight following components: red sorghum pigment 33 parts, carmine 3 parts,
Sodium alginate 45 parts, polyoxyethylene carboxylate 1 part, modified sorghum starch 17 parts, ESCALOL 567 0.5
Part, glycerol 5 parts, Zhu's fat 3 parts, carboxymethyl cellulose 0.5 part, polydimethylsiloxane 4 parts, deionized water 15 parts.
The preparation method of described environmental protection is fast light Chinese painting color, comprises the steps:
(1) prepare red sorghum pigment
Taking Sorghum vulgare Pers. seed, with hulling machine isolated sorghum husk and sorghum rice, selecting sorghum husk is that raw material extracts red sorghum pigment；
The most first adding in diffuser by sorghum husk, add the pH3 ethanol solution of 60%, its addition is the 30 of sorghum husk quality
Times, under conditions of 60 DEG C, soak 60min, then microwave radiation processing, microwave power 650W, microwave treatment time 90s, distillation
Remove ethanol, after precipitation to be crystallized, filter isolated red sorghum pigment；
(2) prepare modified sorghum starch
Sorghum rice uses wet grinding extract and obtains sorghum starch, sorghum starch is carried out acylation modification, obtain modified high
Fine strain of millet starch；Described acylation modification is first by the mass ratio of 1:3, sorghum starch and water to be mixed and made into starch milk, adds the most wherein
Enter to account for the succinic anhydrides of starch quality 5%, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, keep
Temperature is 35 DEG C of reaction 100min, then with the hydrochloric acid solution regulation pH value of starch milk that mass concentration is 5% to 6.5, dehydration, air-flow
It is dried, crosses 500 mesh sieves, obtain modified sorghum starch；
(3) allocate pigment
First by red sorghum pigment, carmine, sodium alginate, carboxymethyl cellulose, deionized water mixing, it is heated to 65 DEG C,
Stir, obtain mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerol, poly-two
Methylsiloxane mixes, and is heated to 35 DEG C, stirs, obtains mixture B, modification sorghum starch and Zhu's fat is mixed, Xiang Qi
In be sequentially added into mixture B, mixture A, fully mix thoroughly, be down to room temperature, fill.
Embodiment 3
A kind of fast light Chinese painting color of environmental protection, is made up of by weight following components: red sorghum pigment 27-33 part, carmine 2
Part, sodium alginate 40 parts, polyoxyethylene carboxylate 0.5 part, modified sorghum starch 16 parts, 2-hydroxyl-4-methoxyl group hexichol first
Ketone 0.3 part, glycerol 4 parts, Zhu's fat 2 parts, carboxymethyl cellulose 0.3 part, polydimethylsiloxane 3 parts, deionized water 10 parts.
The preparation method of described environmental protection is fast light Chinese painting color, comprises the steps:
(1) prepare red sorghum pigment
Taking Sorghum vulgare Pers. seed, with hulling machine isolated sorghum husk and sorghum rice, selecting sorghum husk is that raw material extracts red sorghum pigment；
The most first adding in diffuser by sorghum husk, add the pH3 ethanol solution of 60%, its addition is the 25 of sorghum husk quality
Times, under conditions of 55 DEG C, soak 50min, then microwave radiation processing, microwave power 600W, microwave treatment time 75s, distillation
Remove ethanol, after precipitation to be crystallized, filter isolated red sorghum pigment；
(2) prepare modified sorghum starch
Sorghum rice uses wet grinding extract and obtains sorghum starch, sorghum starch is carried out acylation modification, obtain modified high
Fine strain of millet starch；Described acylation modification is first by the mass ratio of 1:2.5, sorghum starch and water to be mixed and made into starch milk, the most wherein
Add the succinic anhydrides accounting for starch quality 5%, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, protect
Holding temperature is 35 DEG C of reaction 100min, then with the hydrochloric acid solution regulation pH value of starch milk that mass concentration is 5% to 6.5, dehydration, gas
Fluidized drying, crosses 350 mesh sieves, obtains modified sorghum starch；
(3) allocate pigment
First by red sorghum pigment, carmine, sodium alginate, carboxymethyl cellulose, deionized water mixing, it is heated to 70 DEG C,
Stir, obtain mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerol, poly-two
Methylsiloxane mixes, and is heated to 40 DEG C, stirs, obtains mixture B, modification sorghum starch and Zhu's fat is mixed, Xiang Qi
In be sequentially added into mixture B, mixture A, fully mix thoroughly, be down to room temperature, fill.
Claims (2)
1. the fast light Chinese painting color of environmental protection, it is characterised in that be made up of by weight following components: red sorghum pigment 27-33
Part, carmine 1-3 part, sodium alginate 35-45 part, polyoxyethylene carboxylate 0.1-1 part, modified sorghum starch 15-17 part, 2-
Hydroxyl-4-methoxy benzophenone 0.1-0.5 part, glycerol 3-5 part, Zhu's fat 1-3 part, carboxymethyl cellulose 0.1-0.5 part, poly-
Dimethyl siloxane 2-4 part, deionized water 5-15 part.
The preparation method of environmental protection the most according to claim 1 is fast light Chinese painting color, it is characterised in that comprise the steps:
(1) prepare red sorghum pigment
Taking Sorghum vulgare Pers. seed, with hulling machine isolated sorghum husk and sorghum rice, selecting sorghum husk is that raw material extracts red sorghum pigment；Specifically
Being first to add in diffuser by sorghum husk, add the pH3 ethanol solution of 60%, its addition is the 20-30 of sorghum husk quality
Times, under conditions of 50-60 DEG C, soaking 40-60min, then microwave radiation processing, microwave power 550-650W, during microwave treatment
Between 60-90s, ethanol is distilled off, after precipitation to be crystallized, filter isolated red sorghum pigment；
(2) prepare modified sorghum starch
Sorghum rice uses wet grinding extract and obtains sorghum starch, sorghum starch is carried out acylation modification, obtain modified Sorghum vulgare Pers. and form sediment
Powder；Described acylation modification is first by the mass ratio of 1:2-3, sorghum starch and water to be mixed and made into starch milk, is then added thereto to
Account for the succinic anhydrides of starch quality 5%, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, keep temperature
Degree is 35 DEG C of reaction 100min, then with the hydrochloric acid solution regulation pH value of starch milk that mass concentration is 5% to 6.5, dehydration, air-flow is done
Dry, cross 200-500 mesh sieve, obtain modified sorghum starch；
(3) allocate pigment
First by red sorghum pigment, carmine, sodium alginate, carboxymethyl cellulose, deionized water mixing, it is heated to 65-75 DEG C, stirs
Mix uniformly, obtain mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerol, poly-diformazan
Radical siloxane mixes, and is heated to 35-45 DEG C, stirs, obtains mixture B, modification sorghum starch and Zhu's fat is mixed, Xiang Qi
In be sequentially added into mixture B, mixture A, fully mix thoroughly, be down to room temperature, fill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610714969.4A CN106084957B (en) | 2016-08-24 | 2016-08-24 | A kind of fast light Chinese painting color of environmental protection and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610714969.4A CN106084957B (en) | 2016-08-24 | 2016-08-24 | A kind of fast light Chinese painting color of environmental protection and preparation method thereof |
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| CN106084957A true CN106084957A (en) | 2016-11-09 |
| CN106084957B CN106084957B (en) | 2018-05-22 |
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| CN201610714969.4A Expired - Fee Related CN106084957B (en) | 2016-08-24 | 2016-08-24 | A kind of fast light Chinese painting color of environmental protection and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135400A (en) * | 2018-08-01 | 2019-01-04 | 三晃树脂（佛山）有限公司 | The application of red sorghum pigment, water stain and preparation method thereof and aqueous woodware paint |
Citations (4)
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|---|---|---|---|---|
| CN102417747A (en) * | 2011-11-07 | 2012-04-18 | 吴江市冰心文教用品有限公司 | Production method of traditional Chinese painting pigment |
| CN104017436A (en) * | 2014-05-28 | 2014-09-03 | 南昌大学 | Children pigment composed of edible composition |
| US20150182992A1 (en) * | 2013-12-31 | 2015-07-02 | Johnson & Johnson Consumer Companies, Inc. | Process for forming a multilayered shaped film product |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
-
2016
- 2016-08-24 CN CN201610714969.4A patent/CN106084957B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417747A (en) * | 2011-11-07 | 2012-04-18 | 吴江市冰心文教用品有限公司 | Production method of traditional Chinese painting pigment |
| US20150182992A1 (en) * | 2013-12-31 | 2015-07-02 | Johnson & Johnson Consumer Companies, Inc. | Process for forming a multilayered shaped film product |
| CN104017436A (en) * | 2014-05-28 | 2014-09-03 | 南昌大学 | Children pigment composed of edible composition |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张海容 等: "高粱红色素萃取方法的研究", 《食品科学》 * |
| 郑茂强 等: "辛烯基琥珀酸淀粉酯的制备工艺研究", 《食品科技》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135400A (en) * | 2018-08-01 | 2019-01-04 | 三晃树脂（佛山）有限公司 | The application of red sorghum pigment, water stain and preparation method thereof and aqueous woodware paint |
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| CN106084957B (en) | 2018-05-22 |
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Address after: 300162 No. 1, unit 48, building 1, No. 48, Lin Dong Road, Hedong District, Tianjin. Applicant after: Sun Xinyu Address before: 748100 Gansu province Dingxi Longxi County Gong Chang town expressway exit 300 meters, wing Ye Hotel sixteen Bureau of China Railway Group Lan Yu project department Applicant before: Sun Xinyu |
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