CN106084957B - A kind of fast light Chinese painting color of environmental protection and preparation method thereof - Google Patents
A kind of fast light Chinese painting color of environmental protection and preparation method thereof Download PDFInfo
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- CN106084957B CN106084957B CN201610714969.4A CN201610714969A CN106084957B CN 106084957 B CN106084957 B CN 106084957B CN 201610714969 A CN201610714969 A CN 201610714969A CN 106084957 B CN106084957 B CN 106084957B
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- sorghum
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/04—Alginic acid; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of fast light Chinese painting colors of environmental protection and preparation method thereof, belong to art painting articles for use field.The pigment is composed of the following components：Red sorghum pigment, famille rose, sodium alginate, polyoxyethylene carboxylate, modified sorghum starch, 2 hydroxyl, 4 methoxy benzophenone, glycerine, Zhu's fat, carboxymethyl cellulose, dimethyl silicone polymer, deionized water.The present invention is using the red sorghum pigment that sorghum discarded object sorghum husk is raw material extraction as the main base-material of pigment, and a small amount of carmine and Zhu's fat is combined as auxiliary base-material, other auxiliaries of arranging in pairs or groups again form, and at low cost, light resistance is good, permeability is strong, chromaticness is distinct, and fine and smooth uniform, stability is high, water and oil-resistant is good, safety and environmental protection.
Description
Technical field
The invention belongs to art painting articles for use fields, are related to a kind of Chinese painting color, are specifically a kind of fast light traditional Chinese Painting face of environmental protection
Material and preparation method thereof.
Background technology
Chinese painting color is also Chinese painting colour, is the sole pigment for drawing traditional Chinese Painting.Traditional Chinese painting colour, main point
Into coloring earth, vegetable pigment and chemical fusion pigment three categories.Vegetable pigment primary color has dark blue, kermes, gamboge etc., tool
Have it is nontoxic, to skin without anaphylaxis and carcinogenicity, the advantages of biodegradability and good Environmental compatibility, but there are yield
It is low, reproducibility is poor low with firmness, light fugitive is shone, the shortcomings of temperature tolerance is poor；Raw mineral materials mainly has cinnabar, orpiment, stone
Green etc., covering power is strong, and stability is good, non-discolouring, but imbibition poor performance, water proofing property are poor；Chemical fusion pigment have daybreak, it is dark red,
Bright red, chrome yellow, sky blue etc., containing organic pigment, tinting strength, tinting power is good, and easily diffusion and processing grinding, patience is good, easy to use, but can take off
Color.In order to improve the light resistance of pigment, current main settling mode is to add in organic light stabilizer in combination, because light is stablized
Agent belongs to pure organic compound, there are volatile, bloom, migration, extracted out by solvent the shortcomings of, this not only affect its efficiency performance
Persistence, while also cause pollute environment.
The content of the invention
The technical problems to be solved by the invention are for deficiencies of the prior art, and it is fast light to provide a kind of environmental protection
Chinese painting color and preparation method thereof.
In order to achieve the above object, the present invention uses following technical scheme.
A kind of fast light Chinese painting color of environmental protection, is made of by weight following components：27-33 parts of red sorghum pigment, famille rose
1-3 parts, 35-45 parts of sodium alginate, 0.1-1 parts of polyoxyethylene carboxylate, modified 15-17 parts of sorghum starch, 2- hydroxyl -4- first
0.1-0.5 parts of oxygroup benzophenone, 3-5 parts of glycerine, 1-3 parts of Zhu's fat, 0.1-0.5 parts of carboxymethyl cellulose, poly dimethyl silicon
2-4 parts of oxygen alkane, 5-15 parts of deionized water.
It is a further object to provide a kind of preparation methods of the fast light Chinese painting color of environmental protection, include the following steps：
(1) red sorghum pigment is prepared
Sorghum seed is taken, with the isolated sorghum husk of hulling machine and sorghum rice, sorghum husk is selected to extract red sorghum pigment for raw material；
Specifically first sorghum husk is added in digester, adds 60% pH3 ethanol solutions, addition is sorghum husk quality
20-30 times, 40-60min is impregnated under conditions of 50-60 DEG C, then microwave radiation processing, microwave power 550-650W, microwave
Ethyl alcohol is distilled off in processing time 60-90s, after precipitation to be crystallized, is separated by filtration to obtain red sorghum pigment；
(2) modified sorghum starch is prepared
Sorghum rice is extracted to obtain sorghum starch using wet grinding, acylation modification is carried out to sorghum starch, obtains modified height
Fine strain of millet starch；The acylation modification is first by sorghum starch and water by 1：The mass ratio of 2-3 is mixed and made into starch milk, then thereto
The succinic anhydride for accounting for starch quality 5% is added in, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, is protected
It holds temperature and adjusts pH value of starch milk to 6.5 for 35 DEG C of reaction 100min, then with the hydrochloric acid solution that mass concentration is 5%, be dehydrated, gas
Drying is flowed, crosses 200-500 mesh sieves to get modified sorghum starch；
(3) pigment is allocated
First red sorghum pigment, famille rose, sodium alginate, carboxymethyl cellulose, deionized water are mixed, are heated to 65-75
DEG C, stir evenly, obtain mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerine,
Dimethyl silicone polymer mixes, and is heated to 35-45 DEG C, stirs evenly, obtains mixture B, and modified sorghum starch and Zhu's fat are mixed
It closes, sequentially adds mixture B, mixture A thereto, fully mix thoroughly, be down to room temperature, it is filling.
The advantageous effects of the present invention：The present invention is the red sorghum pigment for raw material extraction by sorghum discarded object sorghum husk
As the main base-material of pigment, and combine a small amount of carmine and Zhu's fat and formed as auxiliary base-material, then other auxiliaries of arranging in pairs or groups, cost
Low, light resistance is good, and permeability is strong, and chromaticness is distinct, and fine and smooth uniform, stability is high, and water and oil-resistant is good, safety and environmental protection.
Specific embodiment
With reference to embodiment further make detailed elaboration to technical scheme, but the not all present invention in pairs
Scope limits.
Embodiment 1
A kind of fast light Chinese painting color of environmental protection, is made of by weight following components：27 parts of red sorghum pigment, it is 1 part carmine,
35 parts of sodium alginate, 0.1 part of polyoxyethylene carboxylate, modified 15 parts of sorghum starch, ESCALOL 567
0.1 part, 3 parts of glycerine, 1 part of Zhu's fat, 0.1 part of carboxymethyl cellulose, 2 parts of dimethyl silicone polymer, 5 parts of deionized water.
The preparation method of the fast light Chinese painting color of environmental protection, includes the following steps：
(1) red sorghum pigment is prepared
Sorghum seed is taken, with the isolated sorghum husk of hulling machine and sorghum rice, sorghum husk is selected to extract red sorghum pigment for raw material；
Specifically first sorghum husk is added in digester, adds 60% pH3 ethanol solutions, addition is the 20 of sorghum husk quality
Times, 40min is impregnated under conditions of 50 DEG C, then microwave radiation processing, microwave power 550W, microwave treatment time 60s, distillation
Ethyl alcohol is removed, after precipitation to be crystallized, is separated by filtration to obtain red sorghum pigment；
(2) modified sorghum starch is prepared
Sorghum rice is extracted to obtain sorghum starch using wet grinding, acylation modification is carried out to sorghum starch, obtains modified height
Fine strain of millet starch；The acylation modification is first by sorghum starch and water by 1：2 mass ratio is mixed and made into starch milk, then adds thereto
Enter to account for the succinic anhydride of starch quality 5%, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, keep
Temperature is 35 DEG C of reaction 100min, then adjusts pH value of starch milk to 6.5 with the hydrochloric acid solution that mass concentration is 5%, is dehydrated, air-flow
It is dry, 200 mesh sieves are crossed to get modified sorghum starch；
(3) pigment is allocated
First red sorghum pigment, famille rose, sodium alginate, carboxymethyl cellulose, deionized water are mixed, are heated to 75 DEG C,
It stirs evenly, obtains mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerine, poly- two
Methylsiloxane mixes, and is heated to 45 DEG C, stirs evenly, obtains mixture B, modified sorghum starch and Zhu's fat is mixed, Xiang Qi
In sequentially add mixture B, mixture A, fully mix thoroughly, be down to room temperature, it is filling.
Embodiment 2
A kind of fast light Chinese painting color of environmental protection, is made of by weight following components：33 parts of red sorghum pigment, it is 3 parts carmine,
45 parts of sodium alginate, 1 part of polyoxyethylene carboxylate, modified 17 parts of sorghum starch, ESCALOL 567 0.5
Part, 5 parts of glycerine, 3 parts of Zhu's fat, 0.5 part of carboxymethyl cellulose, 4 parts of dimethyl silicone polymer, 15 parts of deionized water.
The preparation method of the fast light Chinese painting color of environmental protection, includes the following steps：
(1) red sorghum pigment is prepared
Sorghum seed is taken, with the isolated sorghum husk of hulling machine and sorghum rice, sorghum husk is selected to extract red sorghum pigment for raw material；
Specifically first sorghum husk is added in digester, adds 60% pH3 ethanol solutions, addition is the 30 of sorghum husk quality
Times, 60min is impregnated under conditions of 60 DEG C, then microwave radiation processing, microwave power 650W, microwave treatment time 90s, distillation
Ethyl alcohol is removed, after precipitation to be crystallized, is separated by filtration to obtain red sorghum pigment；
(2) modified sorghum starch is prepared
Sorghum rice is extracted to obtain sorghum starch using wet grinding, acylation modification is carried out to sorghum starch, obtains modified height
Fine strain of millet starch；The acylation modification is first by sorghum starch and water by 1：3 mass ratio is mixed and made into starch milk, then adds thereto
Enter to account for the succinic anhydride of starch quality 5%, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, keep
Temperature is 35 DEG C of reaction 100min, then adjusts pH value of starch milk to 6.5 with the hydrochloric acid solution that mass concentration is 5%, is dehydrated, air-flow
It is dry, 500 mesh sieves are crossed to get modified sorghum starch；
(3) pigment is allocated
First red sorghum pigment, famille rose, sodium alginate, carboxymethyl cellulose, deionized water are mixed, are heated to 65 DEG C,
It stirs evenly, obtains mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerine, poly- two
Methylsiloxane mixes, and is heated to 35 DEG C, stirs evenly, obtains mixture B, modified sorghum starch and Zhu's fat is mixed, Xiang Qi
In sequentially add mixture B, mixture A, fully mix thoroughly, be down to room temperature, it is filling.
Embodiment 3
A kind of fast light Chinese painting color of environmental protection, is made of by weight following components：27-33 parts of red sorghum pigment, famille rose 2
Part, 40 parts of sodium alginate, 0.5 part of polyoxyethylene carboxylate, modified 16 parts of sorghum starch, 2- hydroxyl -4- methoxyl group hexichol first
0.3 part of ketone, 4 parts of glycerine, 2 parts of Zhu's fat, 0.3 part of carboxymethyl cellulose, 3 parts of dimethyl silicone polymer, 10 parts of deionized water.
The preparation method of the fast light Chinese painting color of environmental protection, includes the following steps：
(1) red sorghum pigment is prepared
Sorghum seed is taken, with the isolated sorghum husk of hulling machine and sorghum rice, sorghum husk is selected to extract red sorghum pigment for raw material；
Specifically first sorghum husk is added in digester, adds 60% pH3 ethanol solutions, addition is the 25 of sorghum husk quality
Times, 50min is impregnated under conditions of 55 DEG C, then microwave radiation processing, microwave power 600W, microwave treatment time 75s, distillation
Ethyl alcohol is removed, after precipitation to be crystallized, is separated by filtration to obtain red sorghum pigment；
(2) modified sorghum starch is prepared
Sorghum rice is extracted to obtain sorghum starch using wet grinding, acylation modification is carried out to sorghum starch, obtains modified height
Fine strain of millet starch；The acylation modification is first by sorghum starch and water by 1：2.5 mass ratio is mixed and made into starch milk, then thereto
The succinic anhydride for accounting for starch quality 5% is added in, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, is protected
It holds temperature and adjusts pH value of starch milk to 6.5 for 35 DEG C of reaction 100min, then with the hydrochloric acid solution that mass concentration is 5%, be dehydrated, gas
Drying is flowed, crosses 350 mesh sieves to get modified sorghum starch；
(3) pigment is allocated
First red sorghum pigment, famille rose, sodium alginate, carboxymethyl cellulose, deionized water are mixed, are heated to 70 DEG C,
It stirs evenly, obtains mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerine, poly- two
Methylsiloxane mixes, and is heated to 40 DEG C, stirs evenly, obtains mixture B, modified sorghum starch and Zhu's fat is mixed, Xiang Qi
In sequentially add mixture B, mixture A, fully mix thoroughly, be down to room temperature, it is filling.
Claims (1)
1. a kind of fast light Chinese painting color of environmental protection, which is characterized in that be made of by weight following components：Red sorghum pigment 27-33
Part, 1-3 parts of famille rose, 35-45 parts of sodium alginate, 0.1-1 parts of polyoxyethylene carboxylate, modified 15-17 parts of sorghum starch, 2-
It is 0.1-0.5 parts of hydroxyl -4- methoxy benzophenones, 3-5 parts of glycerine, 1-3 parts of Zhu's fat, 0.1-0.5 parts of carboxymethyl cellulose, poly-
2-4 parts of dimethyl siloxane, 5-15 parts of deionized water；Its preparation process is as follows：
(1) red sorghum pigment is prepared
Sorghum seed is taken, with the isolated sorghum husk of hulling machine and sorghum rice, sorghum husk is selected to extract red sorghum pigment for raw material；Specifically
It is first to add in sorghum husk in digester, adds 60% pH3 ethanol solutions, addition is the 20-30 of sorghum husk quality
Times, 40-60min is impregnated under conditions of 50-60 DEG C, then microwave radiation processing, microwave power 550-650W, during microwave treatment
Between 60-90s, ethyl alcohol is distilled off, after precipitation to be crystallized, is separated by filtration to obtain red sorghum pigment；
(2) modified sorghum starch is prepared
Sorghum rice is extracted to obtain sorghum starch using wet grinding, acylation modification is carried out to sorghum starch, modified sorghum is obtained and forms sediment
Powder；The acylation modification is first by sorghum starch and water by 1：The mass ratio of 2-3 is mixed and made into starch milk, then adds in thereto
The succinic anhydride of starch quality 5% is accounted for, with the sodium hydroxide solution regulation system pH value that mass concentration is 5% to 8.5, keeps temperature
It spends and reacts 100min for 35 DEG C, then pH value of starch milk is adjusted to 6.5 with the hydrochloric acid solution that mass concentration is 5%, dehydration, air-flow is done
It is dry, 200-500 mesh sieves are crossed to get modified sorghum starch；
(3) pigment is allocated
First red sorghum pigment, famille rose, sodium alginate, carboxymethyl cellulose, deionized water are mixed, 65-75 DEG C is heated to, stirs
It mixes uniformly, obtains mixture A, then by polyoxyethylene carboxylate, ESCALOL 567, glycerine, poly- diformazan
Radical siloxane mixes, and is heated to 35-45 DEG C, stirs evenly, obtains mixture B, modified sorghum starch and Zhu's fat is mixed, Xiang Qi
In sequentially add mixture B, mixture A, fully mix thoroughly, be down to room temperature, it is filling.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610714969.4A CN106084957B (en) | 2016-08-24 | 2016-08-24 | A kind of fast light Chinese painting color of environmental protection and preparation method thereof |
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| CN201610714969.4A CN106084957B (en) | 2016-08-24 | 2016-08-24 | A kind of fast light Chinese painting color of environmental protection and preparation method thereof |
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| CN106084957A CN106084957A (en) | 2016-11-09 |
| CN106084957B true CN106084957B (en) | 2018-05-22 |
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| CN109135400A (en) * | 2018-08-01 | 2019-01-04 | 三晃树脂（佛山）有限公司 | The application of red sorghum pigment, water stain and preparation method thereof and aqueous woodware paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417747A (en) * | 2011-11-07 | 2012-04-18 | 吴江市冰心文教用品有限公司 | Production method of traditional Chinese painting pigment |
| CN104017436A (en) * | 2014-05-28 | 2014-09-03 | 南昌大学 | Children pigment composed of edible composition |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP6588020B2 (en) * | 2013-12-31 | 2019-10-09 | ジョンソン・アンド・ジョンソン・コンシューマー・インコーポレイテッド | Method for forming a multilayer shaped film |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417747A (en) * | 2011-11-07 | 2012-04-18 | 吴江市冰心文教用品有限公司 | Production method of traditional Chinese painting pigment |
| CN104017436A (en) * | 2014-05-28 | 2014-09-03 | 南昌大学 | Children pigment composed of edible composition |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 辛烯基琥珀酸淀粉酯的制备工艺研究;郑茂强 等;《食品科技》;20020831(第8期);第28-29页 * |
| 高粱红色素萃取方法的研究;张海容 等;《食品科学》;20060315;第27卷(第3期);第124-129页 * |
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Address after: 300162 No. 1, unit 48, building 1, No. 48, Lin Dong Road, Hedong District, Tianjin. Applicant after: Sun Xinyu Address before: 748100 Gansu province Dingxi Longxi County Gong Chang town expressway exit 300 meters, wing Ye Hotel sixteen Bureau of China Railway Group Lan Yu project department Applicant before: Sun Xinyu |
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