CN106752573A - A kind of exterior wall anti-pollution latex paint and preparation method thereof - Google Patents
A kind of exterior wall anti-pollution latex paint and preparation method thereof Download PDFInfo
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- CN106752573A CN106752573A CN201611129769.9A CN201611129769A CN106752573A CN 106752573 A CN106752573 A CN 106752573A CN 201611129769 A CN201611129769 A CN 201611129769A CN 106752573 A CN106752573 A CN 106752573A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
A kind of exterior wall anti-pollution latex paint and preparation method thereof, the emulsion paint is made up of sodium carboxymethylcellulose, titanium dioxide, titanium valve high, bunt gypsum powder, talcum powder, diatomite, mica powder, nano zine oxide, defoamer, dispersant, anti-flooding agent, antifreezing agent, antioxidant, nanometer anti-soil auxiliary agent, deionized water, acrylic acid ester emulsion and additive；The present invention is when emulsion paint is prepared in addition to adding convenient source, be additionally added wolf tail grass extract, the additive that modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium potassium are made, make the additive being made after it is added in emulsion paint, the stain resistance and surface flatness of emulsion paint can be significantly increased, and making the softer brilliant white of emulsion paint color, quality is finer and smoother.
Description
Technical field
The present invention relates to the emulsion paint used in building decoration field, specifically a kind of exterior wall anti-pollution latex paint and its
Preparation method.
Background technology
Emulsion paint is the principal item in wall covering, with water as decentralized medium, relative to solvent based coating, in the absence of having
Machine solvent volatilization pollution environment, makes it have the advantages such as environmental protection, energy-conservation, meets coatings industry " pollution-free, province's energy, resource-saving "
Development premise, as most potential coating variety.But in today of atmospheric environment increasingly bad luck, wall covering plays protection
While wall function, while lasting dicoration then seems even more important, because the outward appearance and effect of building can be directly affected
Really, metope is various by what is exposed to wind and rain and artificially leave as the emulsion paint of wall covering due to being chronically exposed under air
The marking is easy to make emulsion paint speckle with spot, it is impossible to keep the persistence of metope neat and tidy, influences attractive in appearance.
Bunt gypsum is the waste residue of generation in salt-making process, and current bunt gypsum is arbitrarily stacked and do not only take up a large amount of soils, and
Be placed on it is outdoor by the easily pollution environment that is in contact with the material in air, can using bunt gypsum as applying filler in latex
In paint manufacture.
The content of the invention
It is an object of the invention to provide a kind of exterior wall anti-pollution latex paint and preparation method thereof, the latex made by the method
Paint, not only color quality is fine and smooth relative to existing emulsion paint more brilliant white, and stain resistance is also greatly improved.
The present invention for realize technical scheme that above-mentioned technical purpose used for：A kind of exterior wall anti-pollution latex paint, according to weight
Amount ratio, the emulsion paint is by 4-6 parts of sodium carboxymethylcellulose, 110-130 portions of titanium dioxide, 30-50 portions of titanium valve high, 150-160 portions of salt
Land plaster, 40-60 part talcum powder, 50-70 parts of diatomite, 8-10 parts of mica powder, 3-4 parts of nano zine oxide, 2-3 parts of defoamer,
3-4 parts of dispersant, 1-2 parts of anti-flooding agent, 1.5-2.6 parts of antifreezing agent, 2-3 parts of antioxidant, 1-2 parts of nanometer anti-soil auxiliary agent, 140-
150 parts of deionized waters, 80-100 parts of acrylic acid ester emulsion and 10-12 parts of additives are made, and the additive is extracted by wolf tail grass
Thing, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium compare 8-10 according to weight:4-6:The ratio of 1-3 mixes 1h and obtains
Arrive, the wolf tail grass extract is that wolf tail grass plant is immersed in 20-25h in the treatment fluid that temperature is 60-70 DEG C, then pull out,
The juice for obtaining is drained and squeezes, the preparation method of the modified Honegsukle flower P.E is：What is obtained from honeysuckle plant is new
Fresh leaves are ground, and 30-35h is soaked in temperature is 60-70 DEG C for the treatment of fluid, then pulled out, are drained, squeezing the juice for obtaining and be evaporated
Honeysuckle extract powder is obtained, then the surface modifier of the extract powder and its weight 3-5% is mixed to get modified honeysuckle extraction
Thing, surface modifier used compares 3-4 by KH550, ethanol, acetone and barium hydroxide according to weight:80:2-3:The ratio of 1-2 is mixed
Conjunction is formed, and the treatment fluid is by 20-24 parts of hydrogen peroxide, 8-10 parts of sodium acid carbonate, 0.2-0.4 parts of sodium glutamate and 5-7
The ethanol composition of part.
The manyleaf meadowure rhizome and root rhizome extract of laurel alcohol ether phosphate potassium weight 8%-10%, the horse are additionally added in the additive
It is juice of the rhizome obtained from manyleaf meadowure rhizome and root plant after grinding, squeezing, filter that tail connects rhizome extract.
The antioxidant is tributyl phosphite.
The defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether.
The dispersant is ethylene-acrylic acid copolymer.
The modified Honegsukle flower P.E is added thereto to the sodium carbonate and juice of juice weight 8% in preparation process successively
The calcium chloride of liquid weight 7%.
Above-mentioned exterior wall anti-pollution latex paint preparation method, is first according to requirement and weighs each raw material, then by load weighted titanium valve high,
The powder of titanium dioxide, bunt gypsum powder, diatomite, mica powder and talcum powder mixed grinding into fineness no more than 40 microns, and successively
It is added thereto to sodium carboxymethylcellulose, nano zine oxide, defoamer, dispersant, anti-flooding agent, antifreezing agent, antioxidant and receives
Rice anti-soil auxiliary agent, then will go to be slowly added to after acrylic acid ester emulsion, deionized water, additive are well mixed, after stirring i.e.
Product is obtained, the additive is by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight
Compare 8-10:4-6:The ratio of 1-3 mixes 1h and obtains.
The additive is by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight ratio
8-10:4-6:The ratio of 1-3 mixes 1h and obtains under conditions of being 40 DEG C -50 DEG C in temperature.
In the present invention, following operation can be used modified honeysuckle is prepared：
Originally preparation method of modified honeysuckle is：Honeysuckle is shredded first, squeezes the juice for obtaining fresh blade, then juice
Filtered at a temperature of 40 DEG C -50 DEG C, addition has the second of juice weight 30%-40% in juice at a temperature of 50 DEG C -60 DEG C
The ammoniacal liquor of alcohol and 20%-30% stands 1-2h after stirring, the mass concentration of the ammoniacal liquor is 20%, is then being added thereto to
Potassium hydroxide and surfactant mix 1h so as to obtain modified honeysuckle, wherein the potassium hydroxide for adding, surface-active
The weight ratio of the juice obtained after agent and squeezing is 7-9：1-2：90-100.
Beneficial effect：The present invention compared with prior art, possesses advantages below：
1）The present invention in addition to adding convenient source, is additionally added by wolf tail grass extract, modified gold and silver when emulsion paint is prepared
The additive that flower extract and laurel alcohol ether phosphate potassium are made, the tannin in wolf tail grass extract in additive is to dicalcium powder
Condensation is served, the polymerization between coarse whiting powder particles is improve, after dicalcium powder is added to emulsion paint preparation process
The cementitiousness of emulsion paint film can be improved, the hardness and compactness of paint film are improved, together in a large amount of fine, soft fur holes compacted on film
When, tannin can reduce coating surface tension force, can reduce adsorptivity of the film to pollutant, dicalcium powder is added to emulsion paint
Emulsion paint surface coating intensity is enhanced after in preparation process, so as to improve the contaminated resistance of emulsion paint；In modified honeysuckle
Hydroxyl and coupling agent KH550 combine to form network-like structure, be added in emulsion paint and crosslink therewith, film consistency increases
Plus, so as to effectively prevent the infiltration of pollutant, the combination of paint film and substrate surface is also increased, improve the resistance to of emulsion paint and be stained with
Dirty ability, also makes the softer brilliant white of emulsion paint color, and quality is finer and smoother；
2）The present invention sequentially adds sodium carbonate and calcium chloride by modified Honegsukle flower P.E in preparation process, and both are in reaction
The calcium carbonate generated in system reacts to each other or is complexed in a generation with the fractions of additive, so as to change generation fine particle calcium carbonate
Surface nature, so when it is added in emulsion paint, the contaminated resistance of emulsion paint can be increased substantially；
3）In the present invention, wolf tail grass, honeysuckle are immersed in the treatment fluid of special composition soak respectively, cell membrane can made
Into destruction, so as in expressing process, the active ingredient contained in cell can be extracted as far as possible；
4）In the present invention, additive can also add manyleaf meadowure rhizome and root rhizome extract, wherein the oxidizing component for containing can be certain
Suppress the growth of bacterium in degree, so as to improve the anti-microbial property and pollution resistance of emulsion paint.
Specific embodiment
With reference to specific embodiment, the present invention is further elaborated, and raw material used is in following embodiment
The conventional raw material in this area or from can be commercially available on the market.
Embodiment 1
The present invention for realize technical scheme that above-mentioned technical purpose used for：A kind of exterior wall anti-pollution latex paint, according to weight ratio,
The emulsion paint by 4 parts of sodium carboxymethylcelluloses, 110 parts of titanium dioxides, 30 parts of titanium valves high, 150 parts of bunt gypsum powder, 40 parts of talcum powder,
50 parts of diatomite, 8 parts of mica powders, 3 parts of nano zine oxides, 2 parts of defoamers, 3 parts of dispersants, 1 part of anti-flooding agent, 1.5 parts it is antifreeze
Agent, 2 parts of antioxidant, 1 part of nanometer anti-soil auxiliary agent, 140 parts of deionized waters, 80 parts of acrylic acid ester emulsions and 10 parts of additives are made,
The additive compares 8 by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight:4:1
Ratio mixes 1h and obtains, and the wolf tail grass extract is immersed in 20h in the treatment fluid that temperature is 60 DEG C for wolf tail grass plant,
Then pull out, drain and squeeze the juice that obtains, the preparation method of the modified Honegsukle flower P.E is：From honeysuckle plant
The fresh blade for obtaining is ground, and 30h is soaked in temperature is 60 DEG C for the treatment of fluids, is then pulled out, is drained, squeezing the juice steaming for obtaining
It is dry to obtain honeysuckle extract powder, then the surface modifier of the extract powder and its weight 3% is mixed to get modified honeysuckle extraction
Thing, surface modifier used compares 3 by KH550, ethanol, acetone and barium hydroxide according to weight:80:2:1 ratio is mixed,
The treatment fluid by 20 parts hydrogen peroxide, 8 parts of sodium acid carbonate, 0.2 part of sodium glutamate and 5 parts of ethanol constitutes；
The preparation method of above-mentioned exterior wall anti-pollution latex paint is to be first according to above-mentioned requirements to weigh each raw material, then by load weighted height
The powder of titanium valve, titanium dioxide, bunt gypsum powder, diatomite, mica powder and talcum powder mixed grinding into fineness no more than 40 microns, and
Sodium carboxymethylcellulose, nano zine oxide, defoamer, dispersant, anti-flooding agent, antifreezing agent, antioxidant are added thereto to successively
With nanometer anti-soil auxiliary agent, will finally go to be slowly added to after acrylic acid ester emulsion, deionized water, additive are well mixed, stirring is equal
Product is obtained after even, the additive is pressed by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium
Compare 8 according to weight:4:1 ratio mixes 1h and obtains.
Above for the present embodiment basic embodiment, can more than on the basis of further improved, optimized and limited：
Such as, the additive by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight ratio
8:4:1 ratio mixes 1h and obtains under conditions of being 40 DEG C in temperature；
And for example, the manyleaf meadowure rhizome and root rhizome extract of laurel alcohol ether phosphate potassium weight 8%, the horse hair are additionally added in the additive
Even rhizome extract is juice of the rhizome obtained from manyleaf meadowure rhizome and root plant after grinding, squeezing, filter；
For another example, the antioxidant is tributyl phosphite；
For another example, the defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether；
For another example, the dispersant is ethylene-acrylic acid copolymer；
Finally, the modified Honegsukle flower P.E is added thereto to the sodium carbonate and juice of juice weight 8% in preparation process successively
The calcium chloride of liquid weight 7%.
Embodiment 2
The present invention for realize technical scheme that above-mentioned technical purpose used for：A kind of exterior wall anti-pollution latex paint, according to weight ratio,
The emulsion paint by 6 parts of sodium carboxymethylcelluloses, 130 parts of titanium dioxides, 50 parts of titanium valves high, 160 parts of bunt gypsum powder, 60 parts of talcum powder,
70 parts of diatomite, 10 parts of mica powders, 4 parts of nano zine oxides, 3 parts of defoamers, 4 parts of dispersants, 2 parts of anti-flooding agents, 2.6 parts it is antifreeze
Agent, 3 parts of antioxidant, 2 parts of nanometer anti-soil auxiliary agents, 150 parts of deionized waters, 100 parts of acrylic acid ester emulsions and 12 parts of additives are made,
The additive compares 10 by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight:6:3
Ratio mixes 1h and obtains, and the wolf tail grass extract is immersed in 25h in the treatment fluid that temperature is 70 DEG C for wolf tail grass plant,
Then pull out, drain and squeeze the juice that obtains, the preparation method of the modified Honegsukle flower P.E is：From honeysuckle plant
The fresh blade for obtaining is ground, and 35h is soaked in temperature is 70 DEG C for the treatment of fluids, is then pulled out, is drained, squeezing the juice steaming for obtaining
It is dry to obtain honeysuckle extract powder, then the surface modifier of the extract powder and its weight 5% is mixed to get modified honeysuckle extraction
Thing, surface modifier used compares 4 by KH550, ethanol, acetone and barium hydroxide according to weight:80:3:2 ratio is mixed,
The treatment fluid by 24 parts hydrogen peroxide, 10 parts of sodium acid carbonate, 0.4 part of sodium glutamate and 7 parts of ethanol constitutes；
Above-mentioned exterior wall anti-pollution latex paint preparation method, is first according to requirement and weighs each raw material, then by load weighted titanium valve high, titanium white
The powder of powder, bunt gypsum powder, diatomite, mica powder and talcum powder mixed grinding into fineness no more than 40 microns, and successively to it
Middle addition sodium carboxymethylcellulose, nano zine oxide, defoamer, dispersant, anti-flooding agent, antifreezing agent, antioxidant and nanometer are anti-
Dirty auxiliary agent, then will go to be slowly added to after acrylic acid ester emulsion, deionized water, additive are well mixed, obtained after stirring
Product, the additive compares 10 by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight:
6:3 ratio mixes 1h and obtains.
Above for the present embodiment basic embodiment, can more than on the basis of further improved, optimized and limited：
Such as, the additive by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight ratio
10:6:3 ratio mixes 1h and obtains under conditions of being 50 DEG C in temperature；
And for example, the manyleaf meadowure rhizome and root rhizome extract of laurel alcohol ether phosphate potassium weight 10%, the horse hair are additionally added in the additive
Even rhizome extract is juice of the rhizome obtained from manyleaf meadowure rhizome and root plant after grinding, squeezing, filter；
For another example, the antioxidant is tributyl phosphite；
For another example, the defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether；
For another example, the dispersant is ethylene-acrylic acid copolymer；
Finally, the modified Honegsukle flower P.E is added thereto to the sodium carbonate and juice of juice weight 8% in preparation process successively
The calcium chloride of liquid weight 7%.
Embodiment 3
The present invention for realize technical scheme that above-mentioned technical purpose used for：A kind of exterior wall anti-pollution latex paint, according to weight ratio,
The emulsion paint by 5 parts of sodium carboxymethylcelluloses, 120 parts of titanium dioxides, 40 parts of titanium valves high, 155 parts of bunt gypsum powder, 50 parts of talcum powder,
60 parts of diatomite, 9 parts of mica powders, 3.5 parts of nano zine oxides, 2.5 parts of defoamers, 3.5 parts of dispersants, 1.5 parts of anti-flooding agents, 2
Part antifreezing agent, 2.5 parts of antioxidant, 1.5 parts of nanometer anti-soil auxiliary agents, 145 parts of deionized waters, 90 parts of acrylic acid ester emulsions and 11 parts add
Plus agent is made, the additive is by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight
Than 9:5:2 ratio mixes 1h and obtains, and the wolf tail grass extract is immersed in the place that temperature is 65 DEG C for wolf tail grass plant
22h in reason liquid, then pulls out, drains and squeeze the juice that obtains, and the preparation method of the modified Honegsukle flower P.E is：From gold
The fresh blade obtained on honeysuckle flower plant is ground, and 33h is soaked in temperature is 65 DEG C for the treatment of fluids, is then pulled out, drains, is squeezed
To juice be evaporated and obtain honeysuckle extract powder, then the surface modifier of the extract powder and its weight 4% is mixed to get modified gold
Honeysuckle flower extract, surface modifier used compares 3.5 by KH550, ethanol, acetone and barium hydroxide according to weight:80:2.5:1.5
Ratio mix, the treatment fluid is by 22 parts of hydrogen peroxide, 9 parts of sodium acid carbonate, 0.3 part of sodium glutamate and 6 parts
Ethanol is constituted；
Above-mentioned exterior wall anti-pollution latex paint preparation method, is first according to requirement and weighs each raw material, then by load weighted titanium valve high, titanium white
The powder of powder, bunt gypsum powder, diatomite, mica powder and talcum powder mixed grinding into fineness no more than 40 microns, and successively to it
Middle addition sodium carboxymethylcellulose, nano zine oxide, defoamer, dispersant, anti-flooding agent, antifreezing agent, antioxidant and nanometer are anti-
Dirty auxiliary agent, then will go to be slowly added to after acrylic acid ester emulsion, deionized water, additive are well mixed, obtained after stirring
Product, the additive compares 9 by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight:
5:2 ratio mixes 1h and obtains.
Above for the present embodiment basic embodiment, can more than on the basis of further improved, optimized and limited：
Such as, the additive by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium according to weight ratio
9:5:2 ratio mixes 1h and obtains under conditions of being 45 DEG C in temperature；
And for example, the manyleaf meadowure rhizome and root rhizome extract of laurel alcohol ether phosphate potassium weight 9%, the horse hair are additionally added in the additive
Even rhizome extract is juice of the rhizome obtained from manyleaf meadowure rhizome and root plant after grinding, squeezing, filter；
For another example, the antioxidant is tributyl phosphite；
For another example, the defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether；
For another example, the dispersant is ethylene-acrylic acid copolymer；
Finally, the modified Honegsukle flower P.E is added thereto to the sodium carbonate and juice of juice weight 8% in preparation process successively
The calcium chloride of liquid weight 7%.
Contrast test
Method according to embodiment of the present invention 1-3 prepares three kinds of emulsion paints, and numbered samples 1, sample 2, sample 3 respectively；
Sample 4 is prepared with the method for the embodiment of the present invention 1, difference is that sample 4 is free of additive；
Sample 5 is prepared with the method for the perparation of specimen 1, difference is to be additionally added laurel alcohol ether phosphate in additive in sample 5
The manyleaf meadowure rhizome and root rhizome extract of potassium weight 8%-10%；
Sample 6 is prepared with the method for the embodiment of the present invention 1, difference is that the modified honeysuckle in sample 6 in additive is extracted
The sodium carbonate of juice weight 8% and the calcium chloride of juice weight 7% are added thereto to during thing preparation process successively；
Sample 7 is prepared with the method for the embodiment of the present invention 1, difference is that the preparation method of the honeysuckle that is modified in sample 7 is：It is first
First honeysuckle is shredded, the juice for obtaining fresh blade is squeezed, then juice is filtered at a temperature of 40 DEG C, in 60 DEG C of temperature
Under add in the juice there is the ethanol of juice weight 40% and 30% ammoniacal liquor to stir after stand 2h, the quality of the ammoniacal liquor is dense
It is 20% to spend, and then mixes 1h so as to obtain modified honeysuckle being added thereto to potassium hydroxide and surfactant, wherein
The weight ratio of the juice obtained after the potassium hydroxide of addition, surfactant and squeezing is 9：1：90；
With above sample, brushing thickness is the enamelled coating of 0.5mm on 7 pieces of models of phase same material respectively, is then dried, and by 7 pieces
Model is placed in following experiment condition to verify its performance, then respectively to sample 1 and sample 4 on 2 pieces of models of phase same material
Brushing thickness is 0.5mm enamelled coatings, is then dried as untreated model, compares the face of model and untreated model after treatment
Color, both colors are indiscriminate to be judged to excellent, and both color distinctions are little to be judged to, and both color distinctions are very big to be judged to
Difference：
Plank is placed on outdoor, last layer flyash is spread in plank emulsion paint aspect, with writing brush in brush 100 times above, then
The flyash in lower emulsion paint aspect is swept with writing brush, is rinsed with clear water, the change of emulsion paint surface color is contrasted, in addition again to 7
Fast plank is as follows with the experimental result that untreated plank is compared：
Sample 1 after treatment is little with the whiteness difference of untreated sample 4, in being judged to；
Sample 2 after treatment is little with the whiteness difference of untreated sample 4, in being judged to；
Sample 3 after treatment is little with the whiteness difference of untreated sample 4, in being judged to；
Sample 4 after treatment is very big with the whiteness difference of untreated sample 4, and it is poor to be judged to；
Sample 5 after treatment is little with the whiteness difference of untreated sample 1, in being judged to；
Sample 6 and the whiteness indifference of untreated sample 1 after treatment, are judged to excellent；
Sample 7 and the whiteness indifference of untreated sample 1 after treatment, are judged to excellent；
Difference by data above derived sample 1 and sample 4 is that sample 1 adds additive, is added by being added in sample 1
Plus agent, can significantly shellac varnish stain resistance, sample 5 and the difference of sample 1 are to be additionally added the moon in additive in sample 5
The manyleaf meadowure rhizome and root rhizome extract of cinnamic alcohol ether phosphate potassium weight 8%-10%, by being additionally added laruyl alcohol in additive in sample 5
The manyleaf meadowure rhizome and root rhizome extract of ether phosphate potassium weight 8%-10%, can improve the stain resistance of emulsion paint, sample 6 and sample 1
Difference be added thereto to juice weight successively when being modified Honegsukle flower P.E preparation process in additive in sample 6
8% sodium carbonate and the calcium chloride of juice weight 7%, by the method, sample 6 significantly improves the stain resistance of emulsion paint,
The difference of the sample 1 of sample 7 is that modified honeysuckle of the sample 7 in additive adds various auxiliary agents, its experimental result and sample
Product 1 are compared, and are significantly improved, therefore, based on result above, inventor judges, by above-mentioned preparation method, it is possible to increase
Some are not known the yield of composition in modified honeysuckle, and these are not known composition, after being added in emulsion paint, can make latex
Paint further lifts antifouling property.
Claims (8)
1. a kind of exterior wall anti-pollution latex paint, it is characterised in that：According to weight ratio, the emulsion paint by 4-6 parts of sodium carboxymethylcellulose,
110-130 parts of titanium dioxide, 30-50 parts of titanium valve high, 150-160 parts of bunt gypsum powder, 40-60 parts of talcum powder, 50-70 parts of diatomite,
8-10 parts of mica powder, 3-4 parts of nano zine oxide, 2-3 parts of defoamer, 3-4 parts of dispersant, 1-2 parts of anti-flooding agent, 1.5-2.6 parts
Antifreezing agent, 2-3 part antioxidant, 1-2 parts of nanometer anti-soil auxiliary agent, 140-150 parts of deionized water, 80-100 parts of acrylic acid ester emulsion and
10-12 parts of additive is made, and the additive is by wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium
Compare 8-10 according to weight:4-6:The ratio of 1-3 mixes 1h and obtains, and the wolf tail grass extract is immersed in for wolf tail grass plant
Temperature is 20-25h in 60-70 DEG C for the treatment of fluid, then pulls out, drains and squeezes the juice that obtains, and the modified honeysuckle carries
The preparation method for taking thing is：The fresh blade obtained from honeysuckle plant grinds, and is soaked in temperature is 60-70 DEG C for the treatment of fluid
30-35h, then pulls out, drains, squeezing the juice for obtaining and be evaporated and obtain honeysuckle extract powder, then by the extract powder and its weight
The surface modifier of 3-5% is mixed to get modified Honegsukle flower P.E, and surface modifier used is by KH550, ethanol, acetone and hydrogen
Barium monoxide compares 3-4 according to weight:80:2-3:The ratio of 1-2 is mixed, hydrogen peroxide, 8-10 of the treatment fluid by 20-24 parts
Part sodium acid carbonate, the ethanol of 0.2-0.4 part of sodium glutamate and 5-7 parts constitutes.
2. a kind of exterior wall anti-pollution latex paint according to claim 1, it is characterised in that：The moon has been additionally added in the additive
The manyleaf meadowure rhizome and root rhizome extract of cinnamic alcohol ether phosphate potassium weight 8%-10%, the manyleaf meadowure rhizome and root rhizome extract is from manyleaf meadowure rhizome and root plant
Juice of the rhizome of acquisition after grinding, squeezing, filter.
3. a kind of exterior wall anti-pollution latex paint according to claim 1, it is characterised in that：The antioxidant is the fourth of phosphorous acid three
Ester.
4. a kind of exterior wall anti-pollution latex paint according to claim 1, it is characterised in that：The defoamer is poly- for polyoxyethylene
Oxygen propyl alcohol amidogen ether.
5. a kind of exterior wall anti-pollution latex paint according to claim 1, it is characterised in that：The dispersant is ethylene-propylene
Acid copolymer.
6. a kind of exterior wall anti-pollution latex paint according to claim 1, it is characterised in that：The modified Honegsukle flower P.E exists
The sodium carbonate of juice weight 8% and the calcium chloride of juice weight 7% are added thereto to during preparation process successively.
7. exterior wall anti-pollution latex paint preparation method according to claim 1, the requirement for being first according to claim 1 is weighed respectively
Raw material, then by load weighted titanium valve high, titanium dioxide, bunt gypsum powder, diatomite, mica powder and talcum powder mixed grinding into fineness not
Powder more than 40 microns, and sodium carboxymethylcellulose, nano zine oxide, defoamer, dispersant, anti-floating is added thereto to successively
Toner, antifreezing agent, antioxidant and nanometer anti-soil auxiliary agent, then after acrylic acid ester emulsion, deionized water, additive will be gone well mixed
It is slowly added to, product is obtained after stirring, it is characterised in that：The additive is by wolf tail grass extract, modified honeysuckle
Extract and laurel alcohol ether phosphate potassium compare 8-10 according to weight:4-6:The ratio of 1-3 mixes 1h and obtains.
8. exterior wall anti-pollution latex paint preparation method according to claim 7, it is characterised in that：The additive is by wolf tail grass
Extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium compare 8-10 according to weight:4-6:The ratio of 1-3 is in temperature
1h is mixed under conditions of 40 DEG C -50 DEG C to obtain.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276862A (en) * | 2018-02-05 | 2018-07-13 | 合肥华盖光伏科技有限公司 | A kind of preparation method of environment friendly emulsion paint |
| CN108892986A (en) * | 2018-06-13 | 2018-11-27 | 合肥欧克斯新型建材有限公司 | A kind of energy saving and environment friendly exterior wall latex paint and preparation method thereof |
| CN108997877A (en) * | 2018-09-11 | 2018-12-14 | 杨道林 | A kind of exterior wall anti-pollution latex paint and preparation method thereof |
| CN109456639A (en) * | 2018-11-06 | 2019-03-12 | 江苏赛欧信越消泡剂有限公司 | A kind of preparation method of resistance to highly basic silicon polyethers emulsifier |
| CN110409724A (en) * | 2019-07-22 | 2019-11-05 | 安徽盛世碧美实业有限公司 | A kind of preparation method of natural green wall paper |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0739553B2 (en) * | 1987-05-08 | 1995-05-01 | 東北ポ−ル株式会社 | Substrate conditioning agent for solvent-based silicone antifouling paints for marine structures |
| EP0909800A1 (en) * | 1996-06-19 | 1999-04-21 | Daikin Industries, Limited | Coating composition, coating film, and process for the production of the film |
| CN1488684A (en) * | 2002-10-11 | 2004-04-14 | 中国科学院金属研究所 | Nano composite latex paint and preparing method thereof |
| CN102372977A (en) * | 2010-08-16 | 2012-03-14 | 南通市通州区金晨涂料厂 | Nano elastic emulsion paint |
| CN104371457A (en) * | 2014-12-05 | 2015-02-25 | 曹兴 | Elastic self-cleaning exterior wall emulsion paint |
| CN105623430A (en) * | 2014-11-05 | 2016-06-01 | 沈阳顺风新城建筑材料有限公司 | Contamination-resistant external wall emulsion paint |
-
2016
- 2016-12-09 CN CN201611129769.9A patent/CN106752573A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0739553B2 (en) * | 1987-05-08 | 1995-05-01 | 東北ポ−ル株式会社 | Substrate conditioning agent for solvent-based silicone antifouling paints for marine structures |
| EP0909800A1 (en) * | 1996-06-19 | 1999-04-21 | Daikin Industries, Limited | Coating composition, coating film, and process for the production of the film |
| CN1488684A (en) * | 2002-10-11 | 2004-04-14 | 中国科学院金属研究所 | Nano composite latex paint and preparing method thereof |
| CN102372977A (en) * | 2010-08-16 | 2012-03-14 | 南通市通州区金晨涂料厂 | Nano elastic emulsion paint |
| CN105623430A (en) * | 2014-11-05 | 2016-06-01 | 沈阳顺风新城建筑材料有限公司 | Contamination-resistant external wall emulsion paint |
| CN104371457A (en) * | 2014-12-05 | 2015-02-25 | 曹兴 | Elastic self-cleaning exterior wall emulsion paint |
Non-Patent Citations (1)
| Title |
|---|
| 段久芳: "《天然高分子材料》", 30 September 2016, 华中科技大学出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276862A (en) * | 2018-02-05 | 2018-07-13 | 合肥华盖光伏科技有限公司 | A kind of preparation method of environment friendly emulsion paint |
| CN108892986A (en) * | 2018-06-13 | 2018-11-27 | 合肥欧克斯新型建材有限公司 | A kind of energy saving and environment friendly exterior wall latex paint and preparation method thereof |
| CN108997877A (en) * | 2018-09-11 | 2018-12-14 | 杨道林 | A kind of exterior wall anti-pollution latex paint and preparation method thereof |
| CN109456639A (en) * | 2018-11-06 | 2019-03-12 | 江苏赛欧信越消泡剂有限公司 | A kind of preparation method of resistance to highly basic silicon polyethers emulsifier |
| CN110409724A (en) * | 2019-07-22 | 2019-11-05 | 安徽盛世碧美实业有限公司 | A kind of preparation method of natural green wall paper |
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