CN102618112A - Ink-jet aqueous dye-based ink capable of improving fastness to ozone on microporous photographic paper - Google Patents

Ink-jet aqueous dye-based ink capable of improving fastness to ozone on microporous photographic paper Download PDF

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Publication number
CN102618112A
CN102618112A CN2012100366358A CN201210036635A CN102618112A CN 102618112 A CN102618112 A CN 102618112A CN 2012100366358 A CN2012100366358 A CN 2012100366358A CN 201210036635 A CN201210036635 A CN 201210036635A CN 102618112 A CN102618112 A CN 102618112A
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weight
ink
aqueous dye
jet aqueous
ozone
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CN102618112B (en
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田巍伟
刘金德
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Fortuna Imatek Co., Ltd.
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FORTUNA IMATEK Co Ltd
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Abstract

The invention relates to ink-jet aqueous dye-based ink capable of improving fastness to ozone on microporous photographic paper. The ink-jet aqueous dye-based ink is characterized in that the fastness of the aqueous dye-based ink to the ozone on microporous photographic paper is improved by means of mixing special pigment with the nano-particle size with dye, and a series of experiments finds that the fastness of the dye-based ink to the ozone can be obviously improved by the method. A formula system of the ink includes the dye with the weight percent ranging from 2% to 5%, the special pigment with the weight percent ranging from 0.5% to 3%, humectant with the weight percent ranging from 5% to 40%, viscosity regulator with the weight percent ranging from 1% to 10%, fungicide with the weight percent ranging from 0% to 1%, chelator with the weight percent ranging from 0% to 1%, buffering agent with the weight percent ranging from 0% to 1%, from 0 to 5% of surfactant and the balance deionized water. The ink-jet aqueous dye-based water has the advantages that the fastness of the aqueous dye-based ink to the ozone on a microporous medium can be obviously improved, influence on the glossiness of the dye-based ink on the media is low, and excellent printing smoothness, printing stability, restarting performance after a machine is stopped and storage stability are realized.

Description

A kind of ink-jet aqueous dye ink that improves anti-ozone fastness on microporous type printing paper
Technical field
The present invention relates to a kind of aqueous dye ink, particularly a kind of aqueous dye ink that higher anti-ozone fastness is arranged on microporous type printing paper.
Background technology
Aqueous dye ink is printed on the micropore printing paper, if without overlay film or with the method for glass capsulation, it is easy to take place look and becomes or fade under physical environment.Here said physical environment comprises outdoor and indoor environment, and wherein outdoor environment causes that the factor of fading comprises illumination and gas, and fading of indoor environment mainly caused by gas, especially ozone.At micropore is on the printing paper, and it is comparatively typical to fade with cyan, and what cyan was selected for use in the ink-jet field basically all is sun blue 199 and two kinds of dyestuffs of acid blue 9, is main with sun blue 199 particularly.The ozone resistance of this dyestuff on microporous type printing paper is poor.
There are a lot of technician to study in the ink-jet industry to how improving the ozone resistance of cyan dye ink on microporous medium; Also there are a lot of document patents that this respect is reported abroad; Mainly contain this several schemes: the one, in ink system, add chemical assistant, like ascorbic acid derivates; The 2nd, to medium, apply one deck resin coating later in ink printed, be used for covering dyestuff, stop ozone to get into micropore and dyestuff reaction; Thereby reach ozone proof purpose, the 3rd, in ink system, add the pigment that hangs down particle diameter, the particle diameter of this kind pigment is very low; Generally in the 30-90 nanometer, and the dispersion liquid system is stable, the more important thing is and will have good consistency with dyestuff; In addition, form and aspect and glossiness do not receive very big the influence yet.Also have a lot of experts that some other influence factor has also been carried out systematic research.
These three kinds of methods respectively have relative merits, and first method is convenient and easy, but ozone resistance is had only very little raising, does not have special obvious effects.Second method improves ozone resistance clearly, but the technology more complicated will try every possible means after printing finishes image, is carrying out coating processes or printing general transparent resin ink again to protect dyestuff.The third method is the scheme of relatively good operation, and the present invention has just adopted the third method, and prescription is optimized, and the pigment of the low particle diameter of selecting for use is the Fuji FMC blue 605 of Japanese fuji company.
Summary of the invention
The ink-jet aqueous dye ink that the purpose of this invention is to provide a kind of raising anti-ozone fastness on microporous type printing paper.
The objective of the invention is to reach through following technical scheme:
A kind of ink-jet aqueous dye ink that improves anti-ozone fastness on microporous type printing paper is characterized in that mainly being made up of following proportioning component:
1-5 weight % dyestuff; 0.5-3 weight % special pigment; The wetting Agent for Printing Inks of 5-40 weight %; 1-10 weight % viscosity modifier; 0-1 weight % sterilant; 0-1 weight % sequestrant; 0-1 weight %pH buffer reagent; The 0-5% tensio-active agent; Surplus is a deionized water.
A kind of optimal technical scheme is characterized in that: said dyestuff is a sun blue 199, and is directly yellow 132, REACTIVE Red 195 or directly black 168.
A kind of optimal technical scheme is characterized in that: said special pigment be median size in the 30-90 nanometer, Fuji FMC blue 605.
A kind of optimal technical scheme is characterized in that: said wetting Agent for Printing Inks is a glycerine, terepthaloyl moietie, Diethylene Glycol butyl ether, or the mixing of their arbitrary proportions.
A kind of optimal technical scheme is characterized in that: said viscosity modifier is a USP Kosher, TriMethylolPropane(TMP), Macrogol 200, PEG 400, Polyethylene Glycol-600, the perhaps mixing of their arbitrary proportions.A kind of optimal technical scheme is characterized in that: said sterilant is GXL (20% 1, the dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone).
A kind of optimal technical scheme is characterized in that: said sequestrant is EDTA (YD 30 (Ethylene Diamine Tetraacetic Acid)).
A kind of optimal technical scheme is characterized in that: said pH buffer reagent is Tris (Tutofusin tris).
A kind of optimal technical scheme is characterized in that: said tensio-active agent is the mixing of BYK DYNWET 800 or KFBS (perfluoro butyl potassium sulfonate) or its arbitrary proportion.
The characteristics of ink-jet aqueous dye ink of the present invention are significantly to improve the anti-ozone fastness on the microporous type medium; And it is little to the glossiness influence of dye ink on medium; Startability of have good printing fluency, print stability, shutdown being started shooting again and good stability in storage.
Through accompanying drawing and embodiment the present invention is further specified below, but and do not mean that restriction protection domain of the present invention.
Description of drawings
Fig. 1 is 1-13 shadow tone test segment, is ink of the present invention after the time 30 minute identical with traditional ink ozone ageing, the change curve of colour density.
Table 1 is the preceding form and aspect of the microporous type medium ozone ageing of ink printed of the present invention and the data of colour density
Figure DEST_PATH_269065DEST_PATH_IMAGE001
Table 1
Table 2 is the form and aspect of microporous type medium ozone ageing after 30 minutes and the data of colour density of ink printed of the present invention
Figure DEST_PATH_527746DEST_PATH_IMAGE002
Table 2
Table 3 is the data of the colour density of the form and aspect before the microporous type medium ozone ageing of ink printed of conventional formulation
Figure DEST_PATH_186259DEST_PATH_IMAGE003
Table 3
Table 4 is the form and aspect of microporous type medium ozone ageing after 30 minutes and the data of colour density of the ink printed of conventional formulation
Figure DEST_PATH_759060DEST_PATH_IMAGE004
Table 4
From Fig. 1 and table 1, table 2, the data of table 3 and table 4 can find out that ink of the present invention is significantly improved than traditional dye ink in the ozone resistance of microporous type medium, the variation of the colour density of form and aspect is all little than traditional.
Embodiment
Embodiment 1
The ink-jet aqueous dye ink of raising of the present invention anti-ozone fastness on microporous type printing paper, its proportioning is following:
2.0 the dyestuff sun blue 199 of weight %;
2.0 weight % special pigment Fuji FMC blue 605;
The glycerine of 25 weight %, terepthaloyl moietie, the Diethylene Glycol butyl ether is with the mixed solution of 10:5:10 (weight) ratio composition;
2 weight % TriMethylolPropane(TMP)s;
0.02 weight %GXL;
0.02 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.1 weight %BYK800;
1.0 weight %KFBS
67.76 weight % deionized water.
The preparation method:
With 25 weight % glycerine, terepthaloyl moietie, Diethylene Glycol butyl ether; Mixed solution so that 10:5:10 (weight) ratio is formed is put into reaction kettle, adds 2 weight % TriMethylolPropane(TMP)s again, 0.02 weight %GXL (20% 1; The dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone); 0.02 weight %EDTA (YD 30 (Ethylene Diamine Tetraacetic Acid)), 0.1 weight %Tris (Tutofusin tris), 0.1 weight %BYK800 (polyether modified siloxane); 1.0 weight %KFBS; 67.76 weight % deionized water, stirring at low speed to solution is clarified, and adds 2.0 weight % dyestuff sun blue 199 and 2.0 weight % special pigment Fuji FMC blue 605 again.After 2 hours, filter the degassing in high-speed stirring, packing gets ink 1.
Embodiment 2
The ink-jet aqueous dye ink of raising of the present invention anti-ozone fastness on microporous type printing paper, its proportioning is following:
3.0 the dyestuff sun blue 199 of weight %;
1.0 weight % special pigment Fuji FMC blue 605;
The glycerine of 20 weight %, terepthaloyl moietie, the Diethylene Glycol butyl ether is with the mixed solution of 5:5:10 (weight) ratio composition;
5 weight % TriMethylolPropane(TMP)s;
0.02 weight %GXL;
0.02 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.2 weight %BYK800;
1.0 weight %KFBS
69.66 weight % deionized water.
The preparation method:
With the glycerine of 20 weight %, terepthaloyl moietie, Diethylene Glycol butyl ether; Mixed solution so that 5:5:10 (weight) ratio is formed is put into reaction kettle, adds 5 weight % TriMethylolPropane(TMP)s again, 0.02 weight %GXL (20% 1; The dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone); 0.02 weight %EDTA (YD 30 (Ethylene Diamine Tetraacetic Acid)), 0.1 weight %Tris (Tutofusin tris), 0.2 weight %BYK800 (polyether modified siloxane); 1.0 weight %KFBS; 69.66 weight % deionized water, stirring at low speed to solution is clarified, and adds 3.0 weight % dyestuff sun blue 199 and 1.0 weight % special pigment Fuji FMC blue 605 again.After 2 hours, filter the degassing in high-speed stirring, packing gets ink 2.
Embodiment 3
The ink-jet aqueous dye ink of raising of the present invention anti-ozone fastness on microporous type printing paper, its proportioning is following:
3.5 the dyestuff sun blue 199 of weight %;
0.5 weight % special pigment Fuji FMC blue 605;
The glycerine of 25 weight %, terepthaloyl moietie, the Diethylene Glycol butyl ether is with the mixed solution of 10:5:10 (weight) ratio composition;
2 weight % TriMethylolPropane(TMP)s;
0.02 weight %GXL;
0.02 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.1 weight %BYK800;
1.0 weight %KFBS
67.76 weight % deionized water.
The preparation method:
With 25 weight % glycerine, terepthaloyl moietie, Diethylene Glycol butyl ether; Mixed solution so that 10:5:10 (weight) ratio is formed is put into reaction kettle, adds 2 weight % TriMethylolPropane(TMP)s again, 0.02 weight %GXL (20% 1; The dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone); 0.02 weight %EDTA (YD 30 (Ethylene Diamine Tetraacetic Acid)), 0.1 weight %Tris (Tutofusin tris), 0.1 weight %BYK800 (polyether modified siloxane); 1.0 weight %KFBS; 67.76 weight % deionized water, stirring at low speed to solution is clarified, and adds 3.5 weight % dyestuff sun blue 199 and 0.5 weight % special pigment Fuji FMC blue 605 again.After 2 hours, filter the degassing in high-speed stirring, packing gets ink 3.
Embodiment 4
The ink-jet aqueous dye ink of raising of the present invention anti-ozone fastness on microporous type printing paper, its proportioning is following:
1.0 the dyestuff sun blue 199 of weight %;
3.5 weight % special pigment Fuji FMC blue 605;
The glycerine of 25 weight %, terepthaloyl moietie, the Diethylene Glycol butyl ether is with the mixed solution of 10:5:10 (weight) ratio composition;
2 weight % TriMethylolPropane(TMP)s;
0.1 weight %GXL;
0.1 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.3 weight %BYK800;
0.8 weight %KFBS
67.1 weight % deionized water.
The preparation method:
With 25 weight % glycerine, terepthaloyl moietie, Diethylene Glycol butyl ether; Mixed solution so that 10:5:10 (weight) ratio is formed is put into reaction kettle, adds 2 weight % TriMethylolPropane(TMP)s again, 0.1 weight %GXL (20% 1; The dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone); 0.1 weight %EDTA (YD 30 (Ethylene Diamine Tetraacetic Acid)), 0.1 weight %Tris (Tutofusin tris), 0.3 weight %BYK800 (polyether modified siloxane); 0.8 weight %KFBS; 67.1 weight % deionized water, stirring at low speed to solution is clarified, and adds 1.0 weight % dyestuff sun blue 199 and 3.5 weight % special pigment Fuji FMC blue 605 again.After 2 hours, filter the degassing in high-speed stirring, packing gets ink 4.
Embodiment 5
The ink-jet aqueous dye ink of raising of the present invention anti-ozone fastness on microporous type printing paper, its proportioning is following:
0.5 the dyestuff sun blue 199 of weight %;
3.5 weight % special pigment Fuji FMC blue 605;
The glycerine of 25 weight %, terepthaloyl moietie, the Diethylene Glycol butyl ether is with the mixed solution of 10:5:10 (weight) ratio composition;
2 weight % TriMethylolPropane(TMP)s;
0.02 weight %GXL;
0.02 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.1 weight %BYK800;
1.0 weight %KFBS
67.76 weight % deionized water.
The preparation method:
With 25 weight % glycerine, terepthaloyl moietie, Diethylene Glycol butyl ether; Mixed solution so that 10:5:10 (weight) ratio is formed is put into reaction kettle, adds 2 weight % TriMethylolPropane(TMP)s again, 0.02 weight %GXL (20% 1; The dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone); 0.02 weight %EDTA (YD 30 (Ethylene Diamine Tetraacetic Acid)), 0.1 weight %Tris (Tutofusin tris), 0.1 weight %BYK800 (polyether modified siloxane); 1.0 weight %KFBS; 67.76 weight % deionized water, stirring at low speed to solution is clarified, and adds 0.5 weight % dyestuff sun blue 199 and 3.5 weight % special pigment Fuji FMC blue 605 again.After 2 hours, filter the degassing in high-speed stirring, packing gets ink 5.
Need to prove that the inventor is limit all similar prescriptions of the present invention not.Those of ordinary skills also can reach identical goal of the invention according to technical scheme of the present invention with essentially identical prescription, also belong to protection scope of the present invention.
Testing method:
1. ozone resistance: the color lump of ink of the present invention being printed the shadow tone of different concns gradient on the microporous type medium; Test data parameters such as form and aspect and colour density for before aging; It is aging after 30 minutes to put into the ozone ageing case then, tests the variation of form and aspect and colour density again.
2. print performance: respectively get dye ink of the present invention and install on Epson desktop printer and print test, carry out the printing of various patterns.
3. startability: stamping machine has been adorned shutdown after 10 pages of the ink printed, directly printing of week back start.
Stability in storage: with dye ink 1 of the present invention put into 60 ℃ with-20 ℃ of conditions under test physical and chemical performance and print performance after aging January.

Claims (9)

1. the ink-jet aqueous dye ink of a raising anti-ozone fastness on microporous type printing paper is characterized in that mainly containing following proportioning component and forms:
1-5 weight % dyestuff;
0.5-3 weight % special pigment;
5-40 weight % wetting Agent for Printing Inks;
1-10 weight % viscosity modifier;
0-1 weight % sterilant;
0-1 weight % sequestrant;
0-1 weight %pH buffer reagent;
The 0-5% tensio-active agent;
Surplus is a deionized water.
2. ink-jet aqueous dye ink according to claim 1 is characterized in that: said dyestuff is a sun blue 199, and is directly yellow 132, REACTIVE Red 195 or directly black 168.
3.2. ink-jet aqueous dye ink according to claim 1 is characterized in that: said special pigment be median size in the 30-90 nanometer, Fuji FMC blue 605.
4. ink-jet aqueous dye ink according to claim 1 is characterized in that: said wetting Agent for Printing Inks is a glycerine, terepthaloyl moietie, Diethylene Glycol butyl ether, or the mixing of its arbitrary proportion.
5. ink-jet aqueous dye ink according to claim 1 is characterized in that: said viscosity modifier is a USP Kosher, TriMethylolPropane(TMP), Macrogol 200, PEG 400, Polyethylene Glycol-600, or the mixing of its arbitrary proportion.
6. ink-jet aqueous dye ink according to claim 1 is characterized in that: said sterilant is GXL.
7. ink-jet aqueous dye ink according to claim 1 is characterized in that: said sequestrant is EDTA.
8. ink-jet aqueous dye ink according to claim 1 is characterized in that: said pH buffer reagent is a Tutofusin tris.
9. ink-jet aqueous dye ink according to claim 1 is characterized in that: said tensio-active agent is the mixing of BYK DYNWET 800 or KFBS (perfluoro butyl potassium sulfonate) or its arbitrary proportion.
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CN104312449A (en) * 2014-11-19 2015-01-28 湖南盈博数码科技产业发展有限公司 Colorless adhesive ink for 3D printer and preparation method of colorless adhesive ink
CN104356961A (en) * 2014-11-19 2015-02-18 湖南盈博数码科技产业发展有限公司 Colored adhesive ink for 3D printers and preparation method thereof
CN104419259A (en) * 2013-09-06 2015-03-18 北京联创佳艺影像新材料技术有限公司 Method for processing dye high in fastness to ozone and application of dye in digital ink jet industry
CN109266091A (en) * 2018-09-20 2019-01-25 珠海荣威添彩打印耗材有限公司 A kind of ink process
CN110079155A (en) * 2019-05-18 2019-08-02 北京联创佳艺影像新材料技术有限公司 A kind of high fastness aqueous dye ink
CN115960493A (en) * 2022-12-15 2023-04-14 郑州鸿盛数码科技股份有限公司 Weather-resistant cyan ink-jet ink

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CN102304306A (en) * 2011-10-17 2012-01-04 北京联创佳艺影像新材料技术有限公司 Water-based dye ink for jet printing of black and white images

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CN104419259A (en) * 2013-09-06 2015-03-18 北京联创佳艺影像新材料技术有限公司 Method for processing dye high in fastness to ozone and application of dye in digital ink jet industry
CN104312449A (en) * 2014-11-19 2015-01-28 湖南盈博数码科技产业发展有限公司 Colorless adhesive ink for 3D printer and preparation method of colorless adhesive ink
CN104356961A (en) * 2014-11-19 2015-02-18 湖南盈博数码科技产业发展有限公司 Colored adhesive ink for 3D printers and preparation method thereof
CN109266091A (en) * 2018-09-20 2019-01-25 珠海荣威添彩打印耗材有限公司 A kind of ink process
CN110079155A (en) * 2019-05-18 2019-08-02 北京联创佳艺影像新材料技术有限公司 A kind of high fastness aqueous dye ink
CN115960493A (en) * 2022-12-15 2023-04-14 郑州鸿盛数码科技股份有限公司 Weather-resistant cyan ink-jet ink
CN115960493B (en) * 2022-12-15 2023-11-10 郑州鸿盛数码科技股份有限公司 Weather-resistant cyan ink-jet ink

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