CN109266091A - A kind of ink process - Google Patents

A kind of ink process Download PDF

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Publication number
CN109266091A
CN109266091A CN201811098102.6A CN201811098102A CN109266091A CN 109266091 A CN109266091 A CN 109266091A CN 201811098102 A CN201811098102 A CN 201811098102A CN 109266091 A CN109266091 A CN 109266091A
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CN
China
Prior art keywords
ink
guarantees
low temperature
surfactant
bayscriptblack
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811098102.6A
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Chinese (zh)
Inventor
谢春裕
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Zhuhai Roewe Color Printing Supplies Co Ltd
Original Assignee
Zhuhai Roewe Color Printing Supplies Co Ltd
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Publication date
Application filed by Zhuhai Roewe Color Printing Supplies Co Ltd filed Critical Zhuhai Roewe Color Printing Supplies Co Ltd
Priority to CN201811098102.6A priority Critical patent/CN109266091A/en
Publication of CN109266091A publication Critical patent/CN109266091A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder

Abstract

The invention discloses a kind of ink process, including ink, it is 5wt%-7wt%, 1 that wherein used major ingredient includes: BayscriptBlack-SP water soluble dyestuffs by weight percentage, 5- pentanediol is 3wt%-5wt%, diethylene glycol (DEG) 7wt%-10wt%, glycerol 3wt%-5wt%, polyethylene glycol 400 3wt%-5wt%, surfactant 485 are 0.1wt%-0.5wt%, fungicide PreventolD7 is 0.05wt%-0.15wt% and distilled water is 60wt%-65wt%, and the present invention also provides a kind of ink processing technologys;The present invention uses online nano particle size instrument monitoring technology means, qualitatively judges, dynamic analysis finished product, the dissolution of detection ink and filtering accuracy, guarantee that drop mass, the ink of preparation print on medical PET film, there is good picture quality, there is no color mutually to seep, striped and spot etc..

Description

A kind of ink process
Technical field
The present invention relates to technical field of ink, in particular to a kind of ink process.
Background technique
Medical imaging technology in recent years increasingly to digital development, the way of output can by " hard output " and " soft output " Lai Medical assistance diagnostic imaging, this is a kind of more popular point-score." hard output " refers to image passing through various printing device It is printed upon on film;" soft output " refers to presenting image by display come auxiliary diagnosis;
Really continuous tone output equipment type is at present and few at present, and common color inkjet printer or household swash Optical printer and non-continuous tone output equipment.And in radiating medical image field, it is required to the output of continuous toned image at present Equipment, i.e. each print point (Dot) can show any one of 4096 grades of grayscale shade of gray.Half tone image, phase For consecutive image, such as the printed matter image that linked network is printed, image hierarchy and color are expressed by the size or density of site Color variation.From microcosmic, the variations in detail of this kind of image is discontinuous, referred to as half tone image.Current non-continuous tone Printer, including color inkjet printer, household laser printer etc., each smallest point printed can not have been shown Whole grayscale level.
Therefore, it is necessary to solve the above problems to invent a kind of ink process.
Summary of the invention
The purpose of the present invention is to provide a kind of ink process, by using online nano particle size instrument monitoring technology means, It qualitatively judges, dynamic analysis finished product, the dissolution of detection ink and filtering accuracy guarantee that drop mass, the ink of preparation exist It is printed on medical PET film, there is good picture quality, mutually seeped without color, striped and spot etc., ink viscosity temperature is bent Line is suitble to printer printing, has stable physico-chemical parameter, does not fluctuate significantly, mentioned above in the background art to solve Problem.
To achieve the above object, the invention provides the following technical scheme: a kind of ink process, including ink, wherein being made Major ingredient includes: that BayscriptBlack-SP water soluble dyestuffs are 5wt%-7wt%, 1,5- pentanediol by weight percentage For 3wt%-5wt%, diethylene glycol (DEG) 7wt%-10wt%, glycerol 3wt%-5wt%, polyethylene glycol 400 3wt%- 5wt%, surfactant 485 are 0.1wt%-0.5wt%, fungicide PreventolD7 is 0.05wt%-0.15wt% and steaming Distilled water is 60wt%-65wt%;Specific processing technology are as follows:
Step 1: being mixed, and by BayscriptBlack-SP water soluble dyestuffs, 1,5-PD, diethylene glycol (DEG), glycerol, gathers Ethylene glycol 400, surfactant 485, fungicide PreventolD7 and distilled water proportionally mix, and are subsequently poured into reaction kettle In stir evenly, be added pigment stir to being completely dissolved, obtain ink;
Step 2: then filtering is filtered ink using negative pressure of vacuum, absolutely smart using 0.1um polyethersulfone millipore filter Filter is spent, guarantees filtering accuracy, eliminates the bubble in ink;
Step 3: ink is added in ink degassing device for defoaming, eliminates bubble and dissolved gas in ink, guarantees Ink printed smoothness stability, using online nano particle size instrument monitoring technology means, qualitatively judge, dynamic analysis produce at Product, the dissolution of detection ink and filtering accuracy, guarantee drop mass;
Step 4: ion concentration analysis, using ion electrode analytic approach, that detects ink contains salt ionic concentration, guarantees ink Salt-free, the lower salt content of water guarantee that drop mass is stablized;
Step 5: ink is carried out high/low temperature degradation by high/low temperature degradation under high and low temperature environment;
Step 6: stability analysis, first carry out sun-proof performance test to ink using ultraviolet light irradiation, to ink Anti- UV UV stable is analyzed;Second, carry out resistance to ozone stable test;
Step 7: using refinement treatment to dyestuff with ink is prepared, and reaches the subsequent preparation ink of ability after requirement, carries out It is subsequent to continue to process.
Preferably, reaction kettle first carries out major ingredient high-speed stirred 1-2 hours in the step 1, then stirs at low speed again 40-60 minutes.
Technical effect and advantage of the invention:
1, the present invention uses online nano particle size instrument monitoring technology means, qualitatively judges, dynamic analysis finished product, inspection Ink dissolution and filtering accuracy are surveyed, guarantees that drop mass, the ink of preparation print on medical PET film, there is figure well Image quality amount is mutually seeped, striped and spot etc. without color;
2, using the surfactant matched with ink system of a new generation, high speed dispersion forms stable ink point Granular media ensure that the high/low temperature deterioration and storage stability of product, replace sodium that can improve solubility with organic amine, and can The permeability of ink enhancing paper and the cohesion of dyestuff, ink viscosity temperature curve is set to be suitble to printer printing, there is stable object Change parameter, does not fluctuate significantly;
3, it prepares ink and refinement treatment is used to dyestuff, reach the subsequent preparation ink of ability after requirement, it is pure to improve pigment Degree reduces harmful ion concentration, extends service life of meeting and discussing, and researches and develops from source and synthesizes salt-free, less salt, the wide dyestuff of colour gamut, Product printing, storage stability are improved, raising printing is bright in luster, and fastness and other performances, the dyestuff for selecting counter ion can help Control the property of ink;
4, ink filter is filtered using negative pressure of vacuum, and the filtering of 0.1um polyethersulfone millipore filter absolute precision guarantees filtering essence Degree eliminates the bubble in ink, by ink degassing device, eliminates the bubble and dissolved gas in ink, ensure that ink is beaten The smooth stability of bleeding off;
5, using ion electrode analytic approach, that detects ink contains salt ionic concentration, guarantees salt-free, the lower salt content of ink, Guarantee that drop mass is stablized, ink prepared by the present invention passes through room temperature 30 days, 60 DEG C of 7 days high temperature and -20 DEG C of low temperature of aging in 7 days Test has stable physico-chemical parameter, does not fluctuate significantly, stability is stronger.
Detailed description of the invention
Fig. 1 is ink viscosity variation with temperature curve synoptic diagram of the invention.
Fig. 2 is the contrast test situation schematic diagram of printer of the invention several inks on plain copying paper.
Fig. 3 is the contrast test situation schematic diagram of printer of the invention several inks on color jet-ink paper.
Fig. 4 is the contrast test situation schematic diagram of printer of the invention several inks on photo printing paper.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of ink process according to figure 1, including ink, wherein used major ingredient wraps by weight percentage Include: BayscriptBlack-SP water soluble dyestuffs be 5wt%-7wt%, 1,5- pentanediol be 3wt%-5wt%, diethylene glycol (DEG) is 7wt%-10wt%, glycerol 3wt%-5wt%, polyethylene glycol 400 3wt%-5wt%, surfactant 485 are 0.1wt%-0.5wt%, fungicide PreventolD7 are 0.05wt%-0.15wt% and distilled water is 60wt%-65wt%; Specific processing technology are as follows:
Step 1: being mixed, and by BayscriptBlack-SP water soluble dyestuffs, 1,5-PD, diethylene glycol (DEG), glycerol, gathers Ethylene glycol 400, surfactant 485, fungicide PreventolD7 and distilled water proportionally mix, and are subsequently poured into reaction kettle In stir evenly, first to major ingredient carry out high-speed stirred 1 hour, then stir at low speed again 40 minutes, be added pigment stir to complete Dissolution, obtains ink;
Step 2: then filtering is filtered ink using negative pressure of vacuum, absolutely smart using 0.1um polyethersulfone millipore filter Filter is spent, guarantees filtering accuracy, eliminates the bubble in ink;
Step 3: ink is added in ink degassing device for defoaming, eliminates bubble and dissolved gas in ink, guarantees Ink printed smoothness stability, using online nano particle size instrument monitoring technology means, qualitatively judge, dynamic analysis produce at Product, the dissolution of detection ink and filtering accuracy, guarantee drop mass;
Step 4: ion concentration analysis, using ion electrode analytic approach, that detects ink contains salt ionic concentration, guarantees ink Salt-free, the lower salt content of water guarantee that drop mass is stablized;
Step 5: ink is carried out high/low temperature degradation by high/low temperature degradation under high and low temperature environment;
Step 6: stability analysis, first carry out sun-proof performance test to ink using ultraviolet light irradiation, to ink Anti- UV UV stable is analyzed;Second, carry out resistance to ozone stable test;
Step 7: using refinement treatment to dyestuff with ink is prepared, and reaches the subsequent preparation ink of ability after requirement, carries out It is subsequent to continue to process.
The ink bleed prepared in the present embodiment is general, and stability is general, and 50 bottles of ink have in addition been extracted in the present embodiment Water, which is laid on dyestuff, to carry out penetration testing and carries out ink viscosity test, wherein 36 bottles of ink times of penetration on dyestuff Short, ink viscosity is lower, and remaining 14 bottles of ink times of penetration on dyestuff are moderate, and ink viscosity is moderate.
Embodiment 2:
A kind of ink process according to figure 1, including ink, wherein used major ingredient wraps by weight percentage Include: BayscriptBlack-SP water soluble dyestuffs be 5wt%-7wt%, 1,5- pentanediol be 3wt%-5wt%, diethylene glycol (DEG) is 7wt%-10wt%, glycerol 3wt%-5wt%, polyethylene glycol 400 3wt%-5wt%, surfactant 485 are 0.1wt%-0.5wt%, fungicide PreventolD7 are 0.05wt%-0.15wt% and distilled water is 60wt%-65wt%; Specific processing technology are as follows:
Step 1: being mixed, and by BayscriptBlack-SP water soluble dyestuffs, 1,5-PD, diethylene glycol (DEG), glycerol, gathers Ethylene glycol 400, surfactant 485, fungicide PreventolD7 and distilled water proportionally mix, and are subsequently poured into reaction kettle In stir evenly, first to major ingredient carry out high-speed stirred 1.5 hours, then stir at low speed again 50 minutes, be added pigment stir to complete Fully dissolved obtains ink;
Step 2: then filtering is filtered ink using negative pressure of vacuum, absolutely smart using 0.1um polyethersulfone millipore filter Filter is spent, guarantees filtering accuracy, eliminates the bubble in ink;
Step 3: ink is added in ink degassing device for defoaming, eliminates bubble and dissolved gas in ink, guarantees Ink printed smoothness stability, using online nano particle size instrument monitoring technology means, qualitatively judge, dynamic analysis produce at Product, the dissolution of detection ink and filtering accuracy, guarantee drop mass;
Step 4: ion concentration analysis, using ion electrode analytic approach, that detects ink contains salt ionic concentration, guarantees ink Salt-free, the lower salt content of water guarantee that drop mass is stablized;
Step 5: ink is carried out high/low temperature degradation by high/low temperature degradation under high and low temperature environment;
Step 6: stability analysis, first carry out sun-proof performance test to ink using ultraviolet light irradiation, to ink Anti- UV UV stable is analyzed;Second, carry out resistance to ozone stable test;
Step 7: using refinement treatment to dyestuff with ink is prepared, and reaches the subsequent preparation ink of ability after requirement, carries out It is subsequent to continue to process.
Comparative example 1, the ink bleed prepared in the present embodiment is preferable, and stability is preferable, in addition in the present embodiment It has extracted 50 bottles of inks to be laid on progress penetration testing on dyestuff and carry out ink viscosity test, wherein 48 bottles of inks are in dyestuff Upper time of penetration is short, and ink viscosity is moderate, and remaining 2 bottles of ink times of penetration on dyestuff are short, and ink viscosity is lower.
Embodiment 3:
A kind of ink process according to figure 1, including ink, wherein used major ingredient wraps by weight percentage Include: BayscriptBlack-SP water soluble dyestuffs be 5wt%-7wt%, 1,5- pentanediol be 3wt%-5wt%, diethylene glycol (DEG) is 7wt%-10wt%, glycerol 3wt%-5wt%, polyethylene glycol 400 3wt%-5wt%, surfactant 485 are 0.1wt%-0.5wt%, fungicide PreventolD7 are 0.05wt%-0.15wt% and distilled water is 60wt%-65wt%; Specific processing technology are as follows:
Step 1: being mixed, and by BayscriptBlack-SP water soluble dyestuffs, 1,5-PD, diethylene glycol (DEG), glycerol, gathers Ethylene glycol 400, surfactant 485, fungicide PreventolD7 and distilled water proportionally mix, and are subsequently poured into reaction kettle In stir evenly, first to major ingredient carry out high-speed stirred 2 hours, then stir at low speed again 60 minutes, be added pigment stir to complete Dissolution, obtains ink;
Step 2: then filtering is filtered ink using negative pressure of vacuum, absolutely smart using 0.1um polyethersulfone millipore filter Filter is spent, guarantees filtering accuracy, eliminates the bubble in ink;
Step 3: ink is added in ink degassing device for defoaming, eliminates bubble and dissolved gas in ink, guarantees Ink printed smoothness stability, using online nano particle size instrument monitoring technology means, qualitatively judge, dynamic analysis produce at Product, the dissolution of detection ink and filtering accuracy, guarantee drop mass;
Step 4: ion concentration analysis, using ion electrode analytic approach, that detects ink contains salt ionic concentration, guarantees ink Salt-free, the lower salt content of water guarantee that drop mass is stablized;
Step 5: ink is carried out high/low temperature degradation by high/low temperature degradation under high and low temperature environment;
Step 6: stability analysis, first carry out sun-proof performance test to ink using ultraviolet light irradiation, to ink Anti- UV UV stable is analyzed;Second, carry out resistance to ozone stable test;
Step 7: using refinement treatment to dyestuff with ink is prepared, and reaches the subsequent preparation ink of ability after requirement, carries out It is subsequent to continue to process.
The ink bleed prepared in the present embodiment is general, and stability is general, and 50 bottles of ink have in addition been extracted in the present embodiment Water, which is laid on dyestuff, to carry out penetration testing and carries out ink viscosity test, wherein 32 bottles of ink times of penetration on dyestuff Long, ink viscosity is higher, and remaining 18 bottles of ink times of penetration on dyestuff are moderate, and ink viscosity is moderate.
Following table is obtained according to embodiment 1-3:
Test bottle number Time of penetration is long Time of penetration is moderate Time of penetration is short
Embodiment 1 50 14 36
Embodiment 2 50 2 48
Embodiment 3 50 32 18
Test bottle number Viscosity is higher Moderate viscosity Viscosity is lower
Embodiment 1 50 14 36
Embodiment 2 50 48 2
Embodiment 3 50 32 18
As seen from the above table, 2 chinese raw materials ratio of embodiment is moderate, and mixing time and speed are moderate, keeps ink bleed high, And modest viscosity, stability are high.
Embodiment 4:
Ion concentration analysis is carried out to the ink of the preparation in embodiment 2, it is as follows to obtain analysis result:
As seen from the above table, ink salt content is lower, and drop mass is stablized.
Embodiment 5:
High/low temperature degradation, experiment condition are carried out to the ink of the preparation in embodiment 2 are as follows: minus 20 degrees, 7 days;70 Degree, 7 days, it is as follows to obtain experimental result:
Test temperature on (before degradation) December 1 is 16.5 DEG C
Test temperature on (after degradation) December 8 is 16.8 DEG C
By analyzing before and after degradation, ph value, viscosity, surface tension and the conductivity indices of ink system do not have substantially It changes, illustrates that ink system is more stable, above data illustrates that the stability of LFC ink is fine;
And ink passes through room temperature 30 days, 60 DEG C of 7 days high temperature and 7 days -20 DEG C of low temperature of degradations, with stable object Change parameter, does not fluctuate significantly, as shown in Figure 1, design parameter is as follows:
Embodiment 6:
Stability analysis is carried out to the ink of the preparation in embodiment 2
1) sun-proof performance test is carried out to ink using ultraviolet light irradiation, the anti-UV UV stable of ink is divided K/C/M/Y/LC/LM different colours are carried out colour fading test, as in Figure 2-4 by analysis;
It is printer in figure in plain copying paper, color jet-ink paper, the contrast test feelings of several inks on photo printing paper Condition, following table are data analyses:
2) resistance to ozone stable test
Color fading test:
CMYK
As seen from the above table, microporous photopapers are influenced to become apparent from compared with swelling printing paper by ultraviolet light and ozone.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (2)

1. a kind of ink process, including ink, it is characterised in that: wherein used major ingredient includes: by weight percentage BayscriptBlack-SP water soluble dyestuffs be 5wt%-7wt%, 1,5- pentanediol be 3wt%-5wt%, diethylene glycol (DEG) 7wt%- 10wt%, glycerol 3wt%-5wt%, polyethylene glycol 400 3wt%-5wt%, surfactant 485 are 0.1wt%- 0.5wt%, fungicide PreventolD7 are 0.05wt%-0.15wt% and distilled water is 60wt%-65wt%;Specific processing Technique are as follows:
Step 1: it is mixed, by BayscriptBlack-SP water soluble dyestuffs, 1,5-PD, diethylene glycol (DEG), glycerol, poly- second two Alcohol 400, surfactant 485, fungicide PreventolD7 and distilled water proportionally mix, and are subsequently poured into reaction kettle and stir It mixes uniformly, pigment is added and stirs to being completely dissolved, obtains ink;
Step 2: then ink is filtered using negative pressure of vacuum, uses 0.1um polyethersulfone millipore filter absolute precision mistake by filtering Filter guarantees filtering accuracy, eliminates the bubble in ink;
Step 3: ink is added in ink degassing device for defoaming, eliminates bubble and dissolved gas in ink, guarantees ink Smooth stability is printed, using online nano particle size instrument monitoring technology means, is qualitatively judged, dynamic analysis finished product, inspection Ink dissolution and filtering accuracy are surveyed, guarantees drop mass;
Step 4: ion concentration analysis, using ion electrode analytic approach, that detects ink contains salt ionic concentration, guarantees ink Salt-free, lower salt content guarantees that drop mass is stablized;
Step 5: ink is carried out high/low temperature degradation by high/low temperature degradation under high and low temperature environment;
Step 6: stability analysis, first carry out sun-proof performance test to ink using ultraviolet light irradiation, to the anti-UV of ink UV stable is analyzed;Second, carry out resistance to ozone stable test;
Step 7: using refinement treatment to dyestuff with ink is prepared, and reaches the subsequent preparation ink of ability after requirement, carries out subsequent Continue process.
2. a kind of ink process according to claim 1, it is characterised in that: in the step 1 reaction kettle first to major ingredient into It row high-speed stirred 1-2 hours, then stirs at low speed again 40-60 minutes.
CN201811098102.6A 2018-09-20 2018-09-20 A kind of ink process Pending CN109266091A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110655830A (en) * 2019-10-30 2020-01-07 珠海格美达科技有限公司 Ink-jet printing ink and preparation method thereof
CN114456637A (en) * 2022-01-19 2022-05-10 江苏友威科技股份有限公司 Ink for printing patterns on light guide film and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN102153908A (en) * 2011-03-23 2011-08-17 北京联创佳艺影像新材料技术有限公司 Aqueous dye ink for broad-width piezoelectric printer
CN102618112A (en) * 2012-05-14 2012-08-01 北京联创佳艺影像新材料技术有限公司 Ink-jet aqueous dye-based ink capable of improving fastness to ozone on microporous photographic paper
CN106189511A (en) * 2016-08-30 2016-12-07 广东丽格科技股份有限公司 A kind of quick-drying digital jet ink of high concentration and preparation method thereof
CN107987612A (en) * 2017-11-13 2018-05-04 珠海市宇瀚数码科技有限公司 A kind of water-based kyocera Single-pass high speed ink jets printing thermal transfer ink and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153908A (en) * 2011-03-23 2011-08-17 北京联创佳艺影像新材料技术有限公司 Aqueous dye ink for broad-width piezoelectric printer
CN102618112A (en) * 2012-05-14 2012-08-01 北京联创佳艺影像新材料技术有限公司 Ink-jet aqueous dye-based ink capable of improving fastness to ozone on microporous photographic paper
CN106189511A (en) * 2016-08-30 2016-12-07 广东丽格科技股份有限公司 A kind of quick-drying digital jet ink of high concentration and preparation method thereof
CN107987612A (en) * 2017-11-13 2018-05-04 珠海市宇瀚数码科技有限公司 A kind of water-based kyocera Single-pass high speed ink jets printing thermal transfer ink and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110655830A (en) * 2019-10-30 2020-01-07 珠海格美达科技有限公司 Ink-jet printing ink and preparation method thereof
CN114456637A (en) * 2022-01-19 2022-05-10 江苏友威科技股份有限公司 Ink for printing patterns on light guide film and preparation method thereof

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Application publication date: 20190125