CN105585901B - Color type fragrance fluorescent ink and preparation method thereof - Google Patents
Color type fragrance fluorescent ink and preparation method thereof Download PDFInfo
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- CN105585901B CN105585901B CN201610127544.3A CN201610127544A CN105585901B CN 105585901 B CN105585901 B CN 105585901B CN 201610127544 A CN201610127544 A CN 201610127544A CN 105585901 B CN105585901 B CN 105585901B
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- color type
- fluorescent ink
- type fragrance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides a kind of color type fragrance fluorescent ink, and by weight percentage, the component of the ink includes：Fluorescence mill base 40 60%, moisturizer 13 20%, essence 0.5 0.8%, essence sustained release agent 0.1 0.18%, cosolvent 0.1 0.2%, antifoaming agent 0.01 0.2%, preservative 0.1 0.2%, surplus is water.The present invention also provides the preparation methods of above-mentioned color type fragrance fluorescent ink.The color type fragrance fluorescent ink of the present invention adds essence sustained release agent in the ink, extend the fragrance time of essence in the ink, and cosolvent is added to solve the problems, such as to be added reduction fluorescence water-based ink stability after essence, the fragrance of the fluorescent chemicals and different flavor that make different colours has good suitability, so that the color type fragrance fluorescent ink of the present invention has very high stability.
Description
Technical field
The present invention relates to a kind of formula of new fluorescence water-based ink, more particularly to a kind of color type fragrance fluorescent ink and
Preparation method.
Background technology
Fluorescence water-based ink refers to the water-based ink for having fluorescent effect, mainly by preparing fluorescent ink mill base
The visible fluorescence pigment compounds with photoexcitation are added in process, fluorescent chemicals pigment can absorb luminous energy and generate
Then atomic energy level transition discharges the energy transmitting fluorescent photon of absorption, to have fluorescent effect.
Fluorescence water-based ink can be applied in fluorescence marking pen, not covered again while books emphasis can be marked
Lid script writing, therefore be well received by consumers.And color type fluorescent ink has the property such as water-fast, acid and alkali-resistance and weatherability
Can, but the very difficult dispersion in water-based system of the fluorescent chemicals of color type, and if the fluorescence concentration after scattered
The phenomenon that making an exception in liquid and add other compounds, being extremely easy to cause coagulation occurs.Therefore, for the fluorescence chemical combination of different colours
Object, which adds rational essence, just seems particularly significant.
Therefore, this field needs a kind of side that for the good fluorescence mill base of dispersion stabilization can match suitable essence
Method, and can finally obtain the fluorescence water-based ink of different colours matching diverse fragrant flavour.
Invention content
It is an object of the invention to overcome the shortage of prior art, the fluorescent chemicals addition for different colours is suitable fragrant
Essence makes ink correspond to fruit aroma with it, to obtain a kind of sufficiently stable color type odor type fluorescence water-based ink.
On the one hand, the present invention provides a kind of color type fragrance fluorescent ink, by weight percentage, the component of the ink
Including：
In an embodiment of the color type fragrance fluorescent ink of the present invention, the fluorescence mill base is blue-fluorescence color
One kind in slurry, yellow fluorescence mill base, fluorescent orange mill base and pink colour fluorescence mill base.
In the another embodiment of the color type fragrance fluorescent ink of the present invention, the moisturizer is glycerine, the third two
The mixture of alcohol or glycerine and propylene glycol.
In the another embodiment of the color type fragrance fluorescent ink of the present invention, the essence is daily cosmetics grade
Other soluble perfume.
In the another embodiment of the color type fragrance fluorescent ink of the present invention, the essence sustained release agent is macromolecular
Polymer, the macromolecule polyalcohol is with OH- ,-SH ,-NH2,-CHO ,-COOH and-H3PO2In any one or more base
Group.
In the another embodiment of the color type fragrance fluorescent ink of the present invention, the cosolvent is selected from alkyl phenol
The surfactant of polyethenoxy ether class.
In the another embodiment of the color type fragrance fluorescent ink of the present invention, the antifoaming agent is polyethers, poly- has
The one of which of organic siloxane and organic silicon modified by polyether oxygen alkane.
In the another embodiment of the color type fragrance fluorescent ink of the present invention, the preservative is 1,2- benzisoxas
Thiazole -3- ketone or isothiazolinone.
On the other hand, the present invention provides the preparation method of above-mentioned color type fragrance fluorescent ink, including：
(a) moisturizer and water are added in reaction kettle simultaneously, are then stirred at room temperature 0.5-1 hours, are then added
Fluorescence mill base is further continued for stirring 1 hour；
(b) under stirring conditions, cosolvent, essence and essence sustained release agent are sequentially added, it is small to stir 2-4 at room temperature
When, antifoaming agent defoaming is then added, preservative is eventually adding and color type fragrance fluorescent ink is made.
Compared with current technology, the advantages of color type fragrance fluorescent ink of the invention, is：
Essence sustained release agent is added in the ink, extends the fragrance time of essence in the ink, and add cosolvent to solve
The problem of reducing fluorescence water-based ink stability after addition essence, make the fluorescent chemicals of different colours and the fragrance of different flavor
With good suitability, so that the color type fragrance fluorescent ink of the present invention has very high stability；In addition, by sweet
Oil and propylene glycol compounding are used as moisturizer, can also preferably promote the interval writing quality of fluorescence water-based ink.
Specific implementation mode
Technical scheme of the present invention is described further below according to specific embodiment.Protection scope of the present invention is unlimited
In following embodiment, these examples are enumerated merely for exemplary purpose without limiting the invention in any way.
The color type fragrance fluorescent ink of the present invention, by weight percentage, component includes：Fluorescence mill base 40-60%,
Moisturizer 13-20%, essence 0.5-0.8%, essence sustained release agent 0.1-0.18%, cosolvent 0.1-0.2%, antifoaming agent 0.01-
0.2%, preservative 0.1-0.2%, surplus is water.
Fluorescence mill base used in the present invention is that blue-fluorescence mill base, yellow fluorescence mill base, fluorescent orange mill base and pink colour are glimmering
One kind in photochromic slurry.
Moisturizer used in the present invention is the mixture of glycerine, propylene glycol or glycerine and propylene glycol.
Essence used in the present invention is the soluble perfume of daily cosmetics rank, the aqueous essence of daily cosmetics rank
It is to belong to compound essence, and compound essence, according to the difference of its odor type, the ingredient of component is also different, can be by tens of kinds extremely
It is hundreds of composition and compound.Therefore, because the complicated component of essence, is extremely easy to cause the steady of the fluorescence mill base of color type
Qualitative variation is mainly manifested in shortening for its storage time, the reduction of writing quality and the time that especially interval is write
That shortens is very severe.
Essence sustained release agent used in the present invention is macromolecule polyalcohol, with OH- ,-SH ,-NH2,-CHO ,-COOH and-
H3PO2In any one or more group.
Cosolvent used in the present invention is the surfactant selected from alkyl phenol polyoxyethylene ether class.
Antifoaming agent used in the present invention is the one of which of polyethers, polysiloxane and organic silicon modified by polyether oxygen alkane.
Preservative used in the present invention is 1,2- benzisothiazole-3-ketones or isothiazolinone.
Water used in the present invention is deionized water.
The present invention is arranged in pairs or groups according to the chemical composition composition analysis of different fluorescent pigment compounds and diverse fragrant flavour essence
It uses, and in addition addition essence sustained release agent, cosolvent etc. maintain its original stability and accordingly the fragrance of raising essence is held
The long time.It is used to filling finished product fluorescence marking pen by the final finished fluorescent ink of different proportioning allotments and carries out writing
The detection of energy.
Final laboratory test results discovery, the interval writing quality for the color type fragrance fluorescent ink allocated, such as
Intermittent writing time is more preferable compared with the fluorescent ink of same pigment type fluorescence color paste deployment.Therefore, illustrate provided by the present invention
Color type fragrance fluorescent ink be sufficiently stable.
Unless otherwise defined, term used herein is the normally understood meaning of those skilled in the art.
The present invention is described in further detail by the following examples.
Embodiment
Embodiment 1
First glycerine and deionized water are added in reaction kettle simultaneously, are then stirred at room temperature 0.5-1 hours.Then plus
Enter blue-fluorescence concentrate and is stirred 1 hour with identical rotating speed again.
Under stirring conditions, BrijC20 polyoxyethylene ether, the aqueous blueberry flavor of daily use chemicals grade and essence sustained release are sequentially added
Agent ethenyl cage model polysilsesquioxane stirs 2-4 hours at room temperature, then reduces mixing speed and adds antifoaming agent poly- two
Methylsiloxane defoams, and is eventually adding preservative 1, and the color type fragrance that blue blue berry flavor is made in 2- benzisothiazole-3-ketones is glimmering
Light ink.The filling fluorescence marking pen of filling fluorescence marking pen can write for the first time just write for 120 days normally in normal circumstances,
And interval, which writes experiment, to be carried out in the environment of 25 DEG C of temperature, humidity 50%, and longest is writeed for the first time to remain able to for 72 hours normal
It writes.And it can all give out pure and fresh blueberry fragrance on paper during writing and after writing.
Embodiment 2
First glycerine, propylene glycol and deionized water are added in reaction kettle simultaneously, it is small that 0.5-1 is then stirred at room temperature
When.Then yellow fluorescence mill base is added to stir 1 hour with identical rotating speed again.
Under stirring conditions, it is slow that 100 Myrj 45s, the aqueous flavoring banana essence of daily use chemicals grade and essence are sequentially added
Agent amino cage modle polysilsesquioxane is released, is stirred 2-4 hours at room temperature, mixing speed is then reduced and adds the poly- second of antifoaming agent
Alkenyl siloxane defoams, and is eventually adding the color type fragrance fluorescent ink that yellow banana taste is made in preservative isothiazolinone.It fills
The fluorescence marking pen of dress can write for the first time just write within 120 days normally in normal circumstances, and it is in temperature that interval, which writes experiment,
25 DEG C, carry out in the environment of humidity 50%, longest writes for the first time to remain able within 72 hours normally write.And during writing with
And it can all give out pure and fresh banana fragrance on the paper after writing.
In conclusion the final products color type fragrance fluorescent ink stability of present invention gained is good, it can be in high temperature 50
Placed in the environment of DEG C 60 days, room temperature 2 years or more remain able to normally write, filling fluorescence marking pen can be common
Write for the first time can just to write for 120 days under environment it is normal, and interval write experiment be in the environment of 25 DEG C of temperature, humidity 50% into
Row, longest write for the first time to remain able within 72 hours normally write.And it can all be dissipated on paper during writing and after writing
Pure and fresh fruit aroma is sent out, therefore the color type fragrance fluorescent ink of the present invention has very high stability.
Those skilled in the art should be noted that embodiment described in the invention is only exemplary, can be
Various other replacements, changes and improvements are made in the scope of the present invention.Thus, the present invention is not limited to the above embodiments, and only
It is defined by the claims.
Claims (6)
1. a kind of color type fragrance fluorescent ink, which is characterized in that by weight percentage, the component of the ink includes：
The wherein described essence is the soluble perfume of daily cosmetics rank, and the essence sustained release agent is the poly- sesquialter of ethenyl cage model
Siloxanes or amino cage modle polysilsesquioxane, the cosolvent are the surfactant of alkyl phenol polyoxyethylene ether class.
2. color type fragrance fluorescent ink as described in claim 1, which is characterized in that the fluorescence mill base is blue-fluorescence color
One kind in slurry, yellow fluorescence mill base, fluorescent orange mill base and pink colour fluorescence mill base.
3. color type fragrance fluorescent ink as described in claim 1, which is characterized in that the moisturizer be glycerine, propylene glycol,
Or the mixture of glycerine and propylene glycol.
4. color type fragrance fluorescent ink as described in claim 1, which is characterized in that the antifoaming agent is polyethers, poly- organic
The one of which of siloxanes and organic silicon modified by polyether oxygen alkane.
5. color type fragrance fluorescent ink as described in claim 1, which is characterized in that the preservative is 1,2- benzisothias
Azoles -3- ketone or isothiazolinone.
6. the preparation method of the color type fragrance fluorescent ink as described in any one of claim 1 to 5, which is characterized in that packet
It includes：
(a) moisturizer and water are added in reaction kettle simultaneously, are then stirred at room temperature 0.5-1 hours, fluorescence is then added
Mill base is further continued for stirring 1 hour；
(b) under stirring conditions, cosolvent, essence and essence sustained release agent are sequentially added, is stirred 2-4 hours at room temperature, with
After add antifoaming agent defoaming, be eventually adding preservative and color type fragrance fluorescent ink be made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610127544.3A CN105585901B (en) | 2016-03-07 | 2016-03-07 | Color type fragrance fluorescent ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610127544.3A CN105585901B (en) | 2016-03-07 | 2016-03-07 | Color type fragrance fluorescent ink and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN105585901A CN105585901A (en) | 2016-05-18 |
| CN105585901B true CN105585901B (en) | 2018-09-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610127544.3A Active CN105585901B (en) | 2016-03-07 | 2016-03-07 | Color type fragrance fluorescent ink and preparation method thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141868A (en) * | 2017-06-30 | 2017-09-08 | 四川马可视觉网络科技有限公司 | Fluorescence smell poster paint |
| CN107254245A (en) * | 2017-07-03 | 2017-10-17 | 四川马可视觉网络科技有限公司 | Insect prevention fluorescence poster paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1030780A (en) * | 1988-09-01 | 1989-02-01 | 孙国华 | A kind of water-based inks and its production and use |
| CN101054491A (en) * | 2007-04-30 | 2007-10-17 | 山西大学 | Yellow fluorescence ink and erasing liquor thereof |
| CN104212237A (en) * | 2014-08-20 | 2014-12-17 | 中山艺展装饰工程有限公司 | Anion-releasing health type ink |
| CN104263078A (en) * | 2014-09-28 | 2015-01-07 | 华东理工大学 | Highly stable pigment-type aromatic fluorescent neutral ink and preparation method thereof |
| CN104371424A (en) * | 2014-12-01 | 2015-02-25 | 西安交通大学 | Upconversion fluorescent ink for inkjet printer and preparation method of upconversion fluorescent ink |
-
2016
- 2016-03-07 CN CN201610127544.3A patent/CN105585901B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1030780A (en) * | 1988-09-01 | 1989-02-01 | 孙国华 | A kind of water-based inks and its production and use |
| CN101054491A (en) * | 2007-04-30 | 2007-10-17 | 山西大学 | Yellow fluorescence ink and erasing liquor thereof |
| CN104212237A (en) * | 2014-08-20 | 2014-12-17 | 中山艺展装饰工程有限公司 | Anion-releasing health type ink |
| CN104263078A (en) * | 2014-09-28 | 2015-01-07 | 华东理工大学 | Highly stable pigment-type aromatic fluorescent neutral ink and preparation method thereof |
| CN104371424A (en) * | 2014-12-01 | 2015-02-25 | 西安交通大学 | Upconversion fluorescent ink for inkjet printer and preparation method of upconversion fluorescent ink |
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| CN105585901A (en) | 2016-05-18 |
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