CN106189484A - Aqueous fluorescent pigment and manufacture method thereof for water color ink - Google Patents
Aqueous fluorescent pigment and manufacture method thereof for water color ink Download PDFInfo
- Publication number
- CN106189484A CN106189484A CN201610650508.5A CN201610650508A CN106189484A CN 106189484 A CN106189484 A CN 106189484A CN 201610650508 A CN201610650508 A CN 201610650508A CN 106189484 A CN106189484 A CN 106189484A
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- CN
- China
- Prior art keywords
- fluorescent pigment
- color ink
- parts
- water color
- auxiliary agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of aqueous fluorescent pigment for water color ink and manufacture method thereof.Including antioxidant, polyacrylic resin, ethanol, fluorescent pigment, deionized water and other auxiliary agents.The present invention is formed by plurality of raw materials rational proportion, and other auxiliary agents include wetting agent, dispersant and light stabilizer.Vector resin used in the present invention is polyacrylic resin, strong coloring force, environmental protection, and strong with the compatibility of water.Therefore the aqueous fluorescent pigment for water color ink of the present invention has simultaneously that environmental protection sun-proof, heat resistance be good, strong covering power, bright in colour pure, strong coloring force, stability strong and water color ink is compatible strong and the advantage such as environmental protection.
Description
Technical field
The present invention relates to field of fluorescent pigment, particularly relate to a kind of aqueous fluorescent pigment for water color ink.
Background technology
Fluorescent pigment chemically becomes to be grouped into be said and is divided into inorganic fluorescent pigment and organic fluorescent pigment.From performance,
Inorganic pigment sun-proof, heat resistance are good, strong covering power, but chromatograph is the most complete, and tinting strength, tinting power is low, and colour brightness is poor, part
Slaine and oxide toxicity are bigger.Organic pigment various structures, chromatograph is complete, bright in colour pure, strong coloring force, but resistance to
Light, against weather and poor chemical stability, expensive, organic pigment carrier used is not environmentally.The invention so we are eager
The fluorescent pigment of a kind of performance environmental protection the most again, most importantly when water color ink, this fluorescent pigment is held concurrently with water color ink
Capacitive is especially good, not precipitated and separated, does not repels between chemical composition.
Prepare fluorescent pigment at present and mainly have block resin comminuting method, emulsion polymerization, emulsifying-solidification method, wherein block
Resin comminuting method is the traditional method preparing fluorescent pigment, and first method equipment is simple, low cost.Latter two method can be straight
Connect and obtain globular polymer microgranule, and solvent resistant, impervious color, without aspects such as formaldehyde with or without alternative advantage, in recent years
Obtain increasingly being widely applied.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of aqueous fluorescent pigment for water color ink, the present invention's
It is good that aqueous fluorescent pigment for water color ink has environmental protection sun-proof, heat resistance simultaneously, strong covering power, bright in colour pure,
The advantages such as strong coloring force, stability are strong and strong with water color ink compatibility.
The aqueous fluorescent pigment for water color ink of the present invention, including antioxidant, polyacrylic resin, ethanol, glimmering
Delustering pigment, deionized water and other auxiliary agents；
Described antioxidant is 4-8 part；
Described polyacrylic resin is 10-15 part；
Described ethanol is 5-10 part；
Described fluorescent pigment is 8-12 part；
Described deionized water is 24-29 part；
Other auxiliary agents described are 2-3 part；
Described number is mass fraction.
Preferably:
Described antioxidant is 6 parts；
Described polyacrylic resin is 13 parts；
Described ethanol is 7 parts；
Described fluorescent pigment is 10 parts；
Described deionized water is 26 parts；
Other auxiliary agents described are 2 parts；
Described number is mass fraction.
Saying further, other described auxiliary agents include wetting agent, dispersant and light stabilizer；
Described wetting agent is 25-30 part；
Described dispersant is 10-20 part；
Described light stabilizer 25-35 part.
Preferably:
Described wetting agent is 27 parts；
Described dispersant is 15 parts；
Described light stabilizer 25 parts；
Described number is mass fraction.
Saying further, the described polyacrylic resin contained by the aqueous fluorescent pigment for water color ink is carrier
Resin.
Say that the preparation method of the above-mentioned aqueous fluorescent pigment for water color ink is carried out as steps described below further:
One, polyacrylic resin is added in dispersion machine and disperses, then by mechanical means, particle diameter is controlled 5 microns with
Under；
Two, wetting agent, dispersant and light stabilizer are added stirring in blender so that it is mixing, the rotating speed of blender controls
20-30 per minute turns, and mixing time is 20-30 minute；
Three, antioxidant, ethanol, fluorescent pigment, deionized water and other auxiliary agents are added stirring in blender so that it is mixing,
The rotating speed of blender controls to turn at 30-40 per minute, and mixing time is 30-40 minute；
Four, the mixture that mixture material prepared for step one, step 2 prepared and step 3 prepare adds in dispersion machine
Dispersion, then adjust fineness to less than 10 microns through roll squeezer.
The invention has the beneficial effects as follows: the aqueous fluorescent pigment for water color ink of the present invention is by plurality of raw materials Reasonable
Ratio forms.The acrylic resin dispersibility used is strong, heat-resist, coloring is good, environmental protection, covering power are good and compatibility with water
Strong etc., other auxiliary agents simultaneously used include wetting agent, dispersant and light stabilizer, make the aqueous fluorescent pigment performance prepared steady
Fixed, it is difficult to layering and precipitating, is difficult to bleeding, should not fade and come off.The secondary solvent that the present invention uses is ethanol, is also that water solublity is molten
Agent, more enhances the compatibility of this aqueous fluorescent pigment and water color ink.The aqueous fluorescent face for water color ink of the present invention
The manufacturing approach apparatus of material is simple, low cost, and manufacture process is pollution-free, discharges without noxious substance, does not injure operator healthy.Therefore
It is good that the aqueous fluorescent pigment for water color ink of the present invention has environmental protection sun-proof, heat resistance simultaneously, and strong covering power, color and luster is fresh
Strong and compatible with the water color ink advantage such as strong of gorgeous pure, strong coloring force, stability, is particularly well-suited to the manufacture of water color ink,
There is the most wide utilization prospect.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of description, after describing in detail such as with presently preferred embodiments of the present invention below.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described in further detail.
Embodiment 1: a kind of aqueous fluorescent pigment for water color ink, it is characterised in that: include antioxidant, polypropylene
Acid resin, ethanol, fluorescent pigment, deionized water and other auxiliary agents；
Described antioxidant is 6 parts；
Described polyacrylic resin is 13 parts；
Described ethanol is 7 parts；
Described fluorescent pigment is 10 parts；
Described deionized water is 26 parts；
Other auxiliary agents described are 2 parts；
Described number is mass fraction.
Embodiment 2: a kind of aqueous fluorescent pigment for water color ink, it is characterised in that: include antioxidant, polypropylene
Acid resin, ethanol, fluorescent pigment, deionized water and other auxiliary agents；
Described antioxidant is 2 parts；
Described polyacrylic resin is 14 parts；
Described ethanol is 9 parts；
Described fluorescent pigment is 11 parts；
Described deionized water is 28 parts；
Other auxiliary agents described are 3 parts；
Described number is mass fraction.
Saying further, other auxiliary agents described in embodiment 1 and embodiment 2 include that wetting agent, dispersant and light are stable
Agent；
Preferably:
Described wetting agent is 27 parts；
Described dispersant is 15 parts；
Described light stabilizer 25 parts；
Described number is mass fraction.
The preparation method of the aqueous fluorescent pigment for water color ink of embodiment 1 and embodiment 2, enters as steps described below
OK:
One, polyacrylic resin is added in dispersion machine and disperses, then by mechanical means, particle diameter is controlled 5 microns with
Under；
Two, wetting agent, dispersant and light stabilizer are added stirring in blender so that it is mixing, the rotating speed of blender controls
20-30 per minute turns, and mixing time is 20-30 minute；
Three, antioxidant, ethanol, fluorescent pigment, deionized water and other auxiliary agents are added stirring in blender so that it is mixing,
The rotating speed of blender controls to turn at 30-40 per minute, and mixing time is 30-40 minute；
Four, the mixture that mixture material prepared for step one, step 2 prepared and step 3 prepare adds in dispersion machine
Dispersion, then adjust fineness to less than 10 microns through roll squeezer.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this
Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks
Territory, is the most in like manner included in the scope of patent protection of the present invention.
Claims (6)
1. the aqueous fluorescent pigment for water color ink, it is characterised in that: include antioxidant, polyacrylic resin, second
Alcohol, fluorescent pigment, deionized water and other auxiliary agents；
Described antioxidant is 4-8 part；
Described polyacrylic resin is 10-15 part；
Described ethanol is 5-10 part；
Described fluorescent pigment is 8-12 part；
Described deionized water is 24-29 part；
Other auxiliary agents described are 2-3 part；
Described number is mass fraction.
Aqueous fluorescent pigment for water color ink the most according to claim 1, it is characterised in that: other auxiliary agents include profit
Humectant, dispersant and light stabilizer；
Described wetting agent is 25-30 part；
Described dispersant is 10-20 part；
Described light stabilizer 25-35 part；
Described number is mass fraction.
Aqueous fluorescent pigment for water color ink the most according to claim 1, it is characterised in that:
Described antioxidant is 6 parts；
Described polyacrylic resin is 13 parts；
Described ethanol is 7 parts；
Described fluorescent pigment is 10 parts；
Described deionized water is 26 parts；
Other auxiliary agents described are 2 parts；
Described number is mass fraction.
Aqueous fluorescent pigment for water color ink the most according to claim 1, it is characterised in that: other auxiliary agents include profit
Humectant, dispersant and light stabilizer；
Described wetting agent is 27 parts；
Described dispersant is 15 parts；
Described light stabilizer 25 parts；
Described number is mass fraction.
The preparation method of the aqueous fluorescent pigment for water color ink the most according to claim 1, it is characterised in that: contained
Some polyacrylic resins are vector resin.
The preparation method of the aqueous fluorescent pigment for water color ink the most according to claim 1, it is characterised in that:
One, polyacrylic resin is added in dispersion machine and disperses, then by mechanical means, particle diameter is controlled 5 microns with
Under；
Two, wetting agent, dispersant and light stabilizer are added stirring in blender so that it is mixing, the rotating speed of blender controls
20-30 per minute turns, and mixing time is 20-30 minute；
Three, antioxidant, ethanol, fluorescent pigment, deionized water and other auxiliary agents are added stirring in blender so that it is mixing,
The rotating speed of blender controls to turn at 30-40 per minute, and mixing time is 30-40 minute；
Four, the mixture that mixture material prepared for step one, step 2 prepared and step 3 prepare adds in dispersion machine
Dispersion, then adjust fineness to less than 10 microns through roll squeezer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610650508.5A CN106189484A (en) | 2016-08-10 | 2016-08-10 | Aqueous fluorescent pigment and manufacture method thereof for water color ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610650508.5A CN106189484A (en) | 2016-08-10 | 2016-08-10 | Aqueous fluorescent pigment and manufacture method thereof for water color ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106189484A true CN106189484A (en) | 2016-12-07 |
Family
ID=57514727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610650508.5A Pending CN106189484A (en) | 2016-08-10 | 2016-08-10 | Aqueous fluorescent pigment and manufacture method thereof for water color ink |
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| Country | Link |
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| CN (1) | CN106189484A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114940841A (en) * | 2022-07-13 | 2022-08-26 | 山东盛驰新材料有限公司 | Pigment for water-based ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140014617A (en) * | 2012-07-25 | 2014-02-06 | 공영미 | Thermochromic ink composite and manufacturing method thereof |
| CN103911045A (en) * | 2014-04-10 | 2014-07-09 | 哈尔滨绿科科技有限公司 | Environment-friendly fluorescent printing ink and preparation method thereof |
| CN104031472A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based electrochemical aluminum packaging composite film color layer ink |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
-
2016
- 2016-08-10 CN CN201610650508.5A patent/CN106189484A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140014617A (en) * | 2012-07-25 | 2014-02-06 | 공영미 | Thermochromic ink composite and manufacturing method thereof |
| CN103911045A (en) * | 2014-04-10 | 2014-07-09 | 哈尔滨绿科科技有限公司 | Environment-friendly fluorescent printing ink and preparation method thereof |
| CN104031472A (en) * | 2014-06-05 | 2014-09-10 | 哈尔滨绿科科技有限公司 | Water-based electrochemical aluminum packaging composite film color layer ink |
| CN105482532A (en) * | 2015-12-31 | 2016-04-13 | 苏州冰心文化用品有限公司 | Anti-aging traditional Chinese painting pigment and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114940841A (en) * | 2022-07-13 | 2022-08-26 | 山东盛驰新材料有限公司 | Pigment for water-based ink and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |
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| RJ01 | Rejection of invention patent application after publication |