CN105442315A - 一种新型蚕丝柔顺剂及其制备方法 - Google Patents

一种新型蚕丝柔顺剂及其制备方法 Download PDF

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CN105442315A
CN105442315A CN201510955124.XA CN201510955124A CN105442315A CN 105442315 A CN105442315 A CN 105442315A CN 201510955124 A CN201510955124 A CN 201510955124A CN 105442315 A CN105442315 A CN 105442315A
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张莘蔓
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Abstract

本发明公开了一种新型蚕丝柔顺剂及其制备方法，属于柔顺剂加工技术领域，所述新型蚕丝柔顺剂包括以下原料：酯基季铵盐、硅烷改性聚氨酯、聚醚改性硅烷、木质素磺酸钠、烷基苯磺酸钠、淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、香茅醛、苹果酸、卡拉胶、槐豆胶、三唑酮、去离子水，所述新型蚕丝柔顺剂是经过酯基季铵盐溶解、微波反应、消泡、pH值调节等步骤制成的。本发明的新型蚕丝柔顺剂具有突出生物降解性，绿色环保；本发明制备方法简单、方便可行，新型蚕丝柔顺剂制备成本低，有力于推广应用。

Description

一种新型蚕丝柔顺剂及其制备方法
技术领域
本发明属于柔顺剂加工技术领域，具体涉及一种新型蚕丝柔顺剂及其制备方法。
背景技术
传统方式加工蚕丝被的工艺简单，品种极为单一，以传统工艺加工的蚕丝被经使用后，丝纤维易缠结、粘连，随之弹性和保暖性将会随之降低，需要经常翻拆、扯松，才能保持蚕丝被原有的优良服饰性能。
为赋予蚕丝优良的膨松、柔软、高弹等性能，需对蚕丝进行精加工，使蚕丝纤维空隙膨大，制成的蚕丝棉具有膨松、高弹性、纤维间不结板的特点。通过对蚕丝进行膨化处理，可增加蚕丝纤维膨松性、高弹性、柔软性，可有效防止丝纤维间不粘丝、缠结，提高蚕丝被的实用性。
蚕丝柔顺剂的作用就好像是为蚕丝纤维的表面均匀地上一层保护膜，蚕丝纤维表面由于吸附了柔顺剂，蚕丝纤维间的摩擦系数降低了、可移动性增强了，蚕丝纤维固有的平滑、延伸、压缩性能也得到了恢复，所以蚕丝变得更加柔软、蓬松、有弹性。在目前蚕丝进行精加工过程中需要用到蚕丝柔顺剂，但是效果并不是很好，还不能满足工厂实际生产的需求。
发明内容
本发明要解决的技术问题是提供一种新型蚕丝柔顺剂及其制备方法，以解决目前使用蚕丝柔顺剂后，蚕丝柔软、蓬松、弹性等性能差，不能满足工厂实际生产的需求等问题。本发明的新型蚕丝柔顺剂具有突出生物降解性，绿色环保；本发明制备方法简单、方便可行，新型蚕丝柔顺剂制备成本低，有力于推广应用。
为了解决以上技术问题，本发明采用以下技术方案：
一种新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐6-10份、硅烷改性聚氨酯0.3-0.5份、聚醚改性硅烷0.2-0.4份、木质素磺酸钠0.1-0.4份、烷基苯磺酸钠0.1-0.3份、淀粉接枝丙烯酸钠0.2-0.4份、聚丙烯酸钠0.2-0.3份、N-月桂酰基谷氨酸钠0.2-0.4份、木质素磺酸钙0.2-0.3份、香茅醛0.2-0.5份、苹果酸0.3-0.5份、卡拉胶0.1-0.3份、槐豆胶0.1-0.2份、三唑酮0.1-0.3份、去离子水40-70份。
优选地，所述的新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐7-9份、硅烷改性聚氨酯0.3-0.4份、聚醚改性硅烷0.2-0.3份、木质素磺酸钠0.1-0.3份、烷基苯磺酸钠0.1-0.2份、淀粉接枝丙烯酸钠0.2-0.3份、聚丙烯酸钠0.2-0.3份、N-月桂酰基谷氨酸钠0.2-0.3份、木质素磺酸钙0.2-0.3份、香茅醛0.2-0.4份、苹果酸0.3-0.4份、卡拉胶0.1-0.2份、槐豆胶0.1-0.2份、三唑酮0.1-0.3份、去离子水50-60份。
优选地，所述的新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐8份、硅烷改性聚氨酯0.4份、聚醚改性硅烷0.3份、木质素磺酸钠0.3份、烷基苯磺酸钠0.2份、淀粉接枝丙烯酸钠0.3份、聚丙烯酸钠0.2份、N-月桂酰基谷氨酸钠0.3份、木质素磺酸钙0.3份、香茅醛0.3份、苹果酸0.4份、卡拉胶0.2份、槐豆胶0.2份、三唑酮0.2份、去离子水55份。
本发明还提供一种新型蚕丝柔顺剂的制备方法，包括以下步骤：
S1：将酯基季铵盐加入去离子水中，升温下搅拌溶解酯基季铵盐，得混合液A；
S2：向步骤S1制得的混合液A中分别加入淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、卡拉胶、槐豆胶、木质素磺酸钠、烷基苯磺酸钠、三唑酮，升温至65-70℃后，在微波辐射下，加热反应得混合液B；
S3：将步骤S2制得的混合液B冷却后加入香茅醛、硅烷改性聚氨酯、聚醚改性硅烷，搅拌混合均匀得混合液C；
S4：向步骤S3制得的混合液C中加入苹果酸，调节pH值，制得新型蚕丝柔顺剂。
优选地，步骤S1中所述升温达到的温度为50-60℃。
优选地，步骤S2中所述加热反应的时间为15-20min。
优选地，步骤S3中冷却所达到的温度为30-45℃。
优选地，步骤S4中调节pH值至5.6-5.8。
本发明具有以下有益效果：
(1)本发明制备方法简单，制得的新型蚕丝柔顺剂因采用酯基季铵盐表面活性剂作为活性物质，因此具有突出生物降解性，绿色环保；
(2)本发明新型蚕丝柔顺剂的再润湿性能平均值为15.8s，与目前其它相关产品的再润湿性能(以毛细效应时间计)平均值为30-40s相比，本发明是目前现有产品效果的1.9-2.53倍，可见本发明新型蚕丝柔顺剂的再润湿性能更好；
(3)本发明新型蚕丝柔顺剂杀菌性能优，对金黄色葡萄球菌、大肠杆菌、白色念珠菌的杀菌率均达到95％以上；
(4)本发明制备方法简单、方便可行，新型蚕丝柔顺剂制备成本低，有力于推广应用。
具体实施方式
实施例1
一种新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐6份、硅烷改性聚氨酯0.3份、聚醚改性硅烷0.2份、木质素磺酸钠0.1份、烷基苯磺酸钠0.1份、淀粉接枝丙烯酸钠0.2份、聚丙烯酸钠0.2份、N-月桂酰基谷氨酸钠0.2份、木质素磺酸钙0.2份、香茅醛0.2份、苹果酸0.3份、卡拉胶0.1份、槐豆胶0.1份、三唑酮0.1份、去离子水40份。
所述新型蚕丝柔顺剂的制备方法，包括以下步骤：
S1：将酯基季铵盐加入去离子水中，升温至50℃下，搅拌溶解酯基季铵盐，得混合液A；
S2：向步骤S1制得的混合液A中分别加入淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、卡拉胶、槐豆胶、木质素磺酸钠、烷基苯磺酸钠、三唑酮，升温至65℃后，在微波功率为300W辐射下，加热反应20min，得混合液B；
S3：将步骤S2制得的混合液B冷却至45℃后加入香茅醛、硅烷改性聚氨酯、聚醚改性硅烷，搅拌混合均匀得混合液C；
S4：向步骤S3制得的混合液C中加入苹果酸，调节pH值至5.6，制得新型蚕丝柔顺剂。
实施例2
一种新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐10份、硅烷改性聚氨酯0.5份、聚醚改性硅烷0.4份、木质素磺酸钠0.4份、烷基苯磺酸钠0.3份、淀粉接枝丙烯酸钠0.4份、聚丙烯酸钠0.3份、N-月桂酰基谷氨酸钠0.4份、木质素磺酸钙0.3份、香茅醛0.5份、苹果酸0.5份、卡拉胶0.3份、槐豆胶0.2份、三唑酮0.3份、去离子水70份。
所述新型蚕丝柔顺剂的制备方法，包括以下步骤：
S1：将酯基季铵盐加入去离子水中，升温至60℃下，搅拌溶解酯基季铵盐，得混合液A；
S2：向步骤S1制得的混合液A中分别加入淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、卡拉胶、槐豆胶、木质素磺酸钠、烷基苯磺酸钠、三唑酮，升温至70℃后，在微波功率为300W辐射下，加热反应15min，得混合液B；
S3：将步骤S2制得的混合液B冷却至30℃后加入香茅醛、硅烷改性聚氨酯、聚醚改性硅烷，搅拌混合均匀得混合液C；
S4：向步骤S3制得的混合液C中加入苹果酸，调节pH值至5.8，制得新型蚕丝柔顺剂。
实施例3
一种新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐9份、硅烷改性聚氨酯0.4份、聚醚改性硅烷0.3份、木质素磺酸钠0.3份、烷基苯磺酸钠0.2份、淀粉接枝丙烯酸钠0.3份、聚丙烯酸钠0.3份、N-月桂酰基谷氨酸钠0.3份、木质素磺酸钙0.3份、香茅醛0.4份、苹果酸0.4份、卡拉胶0.2份、槐豆胶0.2份、三唑酮0.3份、去离子水60份。
所述新型蚕丝柔顺剂的制备方法，包括以下步骤：
S1：将酯基季铵盐加入去离子水中，升温至55℃下，搅拌溶解酯基季铵盐，得混合液A；
S2：向步骤S1制得的混合液A中分别加入淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、卡拉胶、槐豆胶、木质素磺酸钠、烷基苯磺酸钠、三唑酮，升温至65℃后，在微波功率为300W辐射下，加热反应20min，得混合液B；
S3：将步骤S2制得的混合液B冷却至35℃后加入香茅醛、硅烷改性聚氨酯、聚醚改性硅烷，搅拌混合均匀得混合液C；
S4：向步骤S3制得的混合液C中加入苹果酸，调节pH值至5.7，制得新型蚕丝柔顺剂。
实施例4
一种新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐7份、硅烷改性聚氨酯0.3份、聚醚改性硅烷0.2份、木质素磺酸钠0.1份、烷基苯磺酸钠0.1份、淀粉接枝丙烯酸钠0.2份、聚丙烯酸钠0.2份、N-月桂酰基谷氨酸钠0.2份、木质素磺酸钙0.2份、香茅醛0.2份、苹果酸0.3份、卡拉胶0.1份、槐豆胶0.1份、三唑酮0.1份、去离子水50份。
所述新型蚕丝柔顺剂的制备方法，包括以下步骤：
S1：将酯基季铵盐加入去离子水中，升温至55℃下，搅拌溶解酯基季铵盐，得混合液A；
S2：向步骤S1制得的混合液A中分别加入淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、卡拉胶、槐豆胶、木质素磺酸钠、烷基苯磺酸钠、三唑酮，升温至68℃后，在微波功率为300W辐射下，加热反应18min，得混合液B；
S3：将步骤S2制得的混合液B冷却至38℃后加入香茅醛、硅烷改性聚氨酯、聚醚改性硅烷，搅拌混合均匀得混合液C；
S4：向步骤S3制得的混合液C中加入苹果酸，调节pH值至5.6，制得新型蚕丝柔顺剂。
实施例5
一种新型蚕丝柔顺剂，以重量份为单位，包括以下原料：酯基季铵盐8份、硅烷改性聚氨酯0.4份、聚醚改性硅烷0.3份、木质素磺酸钠0.3份、烷基苯磺酸钠0.2份、淀粉接枝丙烯酸钠0.3份、聚丙烯酸钠0.2份、N-月桂酰基谷氨酸钠0.3份、木质素磺酸钙0.3份、香茅醛0.3份、苹果酸0.4份、卡拉胶0.2份、槐豆胶0.2份、三唑酮0.2份、去离子水55份。
所述新型蚕丝柔顺剂的制备方法，包括以下步骤：
S1：将酯基季铵盐加入去离子水中，升温至50℃下，搅拌溶解酯基季铵盐，得混合液A；
S2：向步骤S1制得的混合液A中分别加入淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、卡拉胶、槐豆胶、木质素磺酸钠、烷基苯磺酸钠、三唑酮，升温至70℃后，在微波功率为300W辐射下，加热反应15min，得混合液B；
S3：将步骤S2制得的混合液B冷却至42℃后加入香茅醛、硅烷改性聚氨酯、聚醚改性硅烷，搅拌混合均匀得混合液C；
S4：向步骤S3制得的混合液C中加入苹果酸，调节pH值至5.8，制得新型蚕丝柔顺剂。
性能测试：
(1)采用本发明实施例3产品与市售普通柔顺剂对蚕丝进行清漂洗，其柔顺度和色强度检测结果如下表1所示。
表1柔顺度和色强度检测
(2)杀菌性能进行检测：对本发明实施例3产品的杀菌性能进行检测，其杀菌力结果为：金黄色葡萄球菌97％，大肠杆菌96％，白色念珠菌95％。
(3)按照《衣物柔顺剂再润湿性能的测定》标准中规定的试验程序，对本发明实施例1-5中的新型蚕丝柔顺剂的再润湿性能进行试验，结果如下表2所示。
表2新型蚕丝柔顺剂的再润湿性能测试
从上表可以看出本发明新型蚕丝柔顺剂的再润湿性能平均值为15.8s，而目前其它相关产品的再润湿性能(以毛细效应时间计)平均为30-40s，即本发明是目前现有产品效果的1.9-2.53倍，可见本发明新型蚕丝柔顺剂的再润湿性能好。
以上内容不能认定本发明的具体实施只局限于这些说明，对于本发明所属技术领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干简单推演或替换，都应当视为属于本发明由所提交的权利要求书确定的专利保护范围。

Claims (8)

1.一种新型蚕丝柔顺剂，其特征在于，以重量份为单位，包括以下原料：酯基季铵盐6-10份、硅烷改性聚氨酯0.3-0.5份、聚醚改性硅烷0.2-0.4份、木质素磺酸钠0.1-0.4份、烷基苯磺酸钠0.1-0.3份、淀粉接枝丙烯酸钠0.2-0.4份、聚丙烯酸钠0.2-0.3份、N-月桂酰基谷氨酸钠0.2-0.4份、木质素磺酸钙0.2-0.3份、香茅醛0.2-0.5份、苹果酸0.3-0.5份、卡拉胶0.1-0.3份、槐豆胶0.1-0.2份、三唑酮0.1-0.3份、去离子水40-70份。
2.根据权利要求1所述的新型蚕丝柔顺剂，其特征在于，以重量份为单位，包括以下原料：酯基季铵盐7-9份、硅烷改性聚氨酯0.3-0.4份、聚醚改性硅烷0.2-0.3份、木质素磺酸钠0.1-0.3份、烷基苯磺酸钠0.1-0.2份、淀粉接枝丙烯酸钠0.2-0.3份、聚丙烯酸钠0.2-0.3份、N-月桂酰基谷氨酸钠0.2-0.3份、木质素磺酸钙0.2-0.3份、香茅醛0.2-0.4份、苹果酸0.3-0.4份、卡拉胶0.1-0.2份、槐豆胶0.1-0.2份、三唑酮0.1-0.3份、去离子水50-60份。
3.根据权利要求2所述的新型蚕丝柔顺剂，其特征在于，以重量份为单位，包括以下原料：酯基季铵盐8份、硅烷改性聚氨酯0.4份、聚醚改性硅烷0.3份、木质素磺酸钠0.3份、烷基苯磺酸钠0.2份、淀粉接枝丙烯酸钠0.3份、聚丙烯酸钠0.2份、N-月桂酰基谷氨酸钠0.3份、木质素磺酸钙0.3份、香茅醛0.3份、苹果酸0.4份、卡拉胶0.2份、槐豆胶0.2份、三唑酮0.2份、去离子水55份。
4.一种根据权利要求1-3任一项所述的新型蚕丝柔顺剂的制备方法，其特征在于，包括以下步骤：
S1：将酯基季铵盐加入去离子水中，升温下搅拌溶解酯基季铵盐，得混合液A；
S2：向步骤S1制得的混合液A中分别加入淀粉接枝丙烯酸钠、聚丙烯酸钠、N-月桂酰基谷氨酸钠、木质素磺酸钙、卡拉胶、槐豆胶、木质素磺酸钠、烷基苯磺酸钠、三唑酮，升温至65-70℃后，在微波辐射下，加热反应得混合液B；
S3：将步骤S2制得的混合液B冷却后加入香茅醛、硅烷改性聚氨酯、聚醚改性硅烷，搅拌混合均匀得混合液C；
S4：向步骤S3制得的混合液C中加入苹果酸，调节pH值，制得新型蚕丝柔顺剂。
5.根据权利要求4所述的新型蚕丝柔顺剂的制备方法，其特征在于，步骤S1中所述升温达到的温度为50-60℃。
6.根据权利要求4所述的新型蚕丝柔顺剂的制备方法，其特征在于，步骤S2中所述加热反应的时间为15-20min。
7.根据权利要求4所述的新型蚕丝柔顺剂的制备方法，其特征在于，步骤S3中冷却所达到的温度为30-45℃。
8.根据权利要求4所述的新型蚕丝柔顺剂的制备方法，其特征在于，步骤S4中调节pH值至5.6-5.8。
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