CN105440232B - 一种水溶性甲醚化三聚氰胺甲醛树脂的制备工艺 - Google Patents
一种水溶性甲醚化三聚氰胺甲醛树脂的制备工艺 Download PDFInfo
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- CN105440232B CN105440232B CN201510839497.0A CN201510839497A CN105440232B CN 105440232 B CN105440232 B CN 105440232B CN 201510839497 A CN201510839497 A CN 201510839497A CN 105440232 B CN105440232 B CN 105440232B
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- CN
- China
- Prior art keywords
- water
- melamine resin
- etherified melamine
- preparation technology
- methyl
- Prior art date
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- 229920000877 Melamine resin Polymers 0.000 title claims abstract description 31
- 239000004640 Melamine resin Substances 0.000 title claims abstract description 21
- 238000005516 engineering process Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 61
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 45
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 238000009413 insulation Methods 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920002866 paraformaldehyde Polymers 0.000 claims abstract description 9
- 229930040373 Paraformaldehyde Natural products 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000010792 warming Methods 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- 229940043237 diethanolamine Drugs 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 150000007974 melamines Chemical class 0.000 description 3
- 229920003180 amino resin Polymers 0.000 description 2
- OOSUHIIJYDMCCW-UHFFFAOYSA-N cyanamide;formaldehyde Chemical compound O=C.NC#N OOSUHIIJYDMCCW-UHFFFAOYSA-N 0.000 description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000005829 trimerization reaction Methods 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IWLBIFVMPLUHLK-UHFFFAOYSA-N azane;formaldehyde Chemical compound N.O=C IWLBIFVMPLUHLK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- -1 triethylamine amine Chemical class 0.000 description 1
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- Phenolic Resins Or Amino Resins (AREA)
Abstract
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CN201510839497.0A CN105440232B (zh) | 2015-11-27 | 2015-11-27 | 一种水溶性甲醚化三聚氰胺甲醛树脂的制备工艺 |
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CN105440232A CN105440232A (zh) | 2016-03-30 |
CN105440232B true CN105440232B (zh) | 2018-02-02 |
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Families Citing this family (8)
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CN106564263B (zh) * | 2016-10-28 | 2019-12-10 | 浙江欧仁新材料有限公司 | 一种超声融合薄膜及其制备方法 |
CN106750075B (zh) * | 2016-12-08 | 2019-03-05 | 浙江亚迪纳新材料科技股份有限公司 | 一种高稳定性低粘甲基醚化脲醛树脂的制备工艺 |
CN108003310B (zh) * | 2017-12-05 | 2020-09-11 | 河南骏化发展股份有限公司 | 一种改性三聚氰胺甲醛醚化树脂的制备方法及产品 |
CN109293863A (zh) * | 2018-09-07 | 2019-02-01 | 沈阳化工大学 | 一种一锅法制备三聚氰胺甲醛树脂方法 |
CN109577104B (zh) * | 2018-12-08 | 2021-02-05 | 上海朴美家具有限公司 | 一种环保纤维板的制备方法及家具的加工工艺 |
CN109749033B (zh) * | 2018-12-14 | 2022-03-15 | 南京长江涂料有限公司 | 一种混合醇合成水溶性氨基树脂及其制备方法 |
CN112940210B (zh) * | 2021-03-15 | 2023-02-10 | 山东阳谷华泰化工股份有限公司 | 甲醚化三聚氰胺甲醛树脂的制备方法 |
CN113956415A (zh) * | 2021-11-09 | 2022-01-21 | 山东阳谷华泰化工股份有限公司 | 一种水性亚氨基甲醚化三聚氰胺甲醛树脂的制备方法 |
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CN102391616B (zh) * | 2011-08-05 | 2012-12-05 | 华南理工大学 | 水溶性改性三聚氰胺甲醛浸渍树脂及其制备方法和应用 |
CN103102466B (zh) * | 2012-12-20 | 2014-09-24 | 山东沾化奥仕化学有限公司 | 一种高亚氨基甲醚化三聚氰胺树脂的制备方法 |
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Denomination of invention: Preparation process of water-soluble methyl-etherified melamine formaldehyde resin Effective date of registration: 20191012 Granted publication date: 20180202 Pledgee: Zhumadian Rural Commercial Bank Co.,Ltd. Pledgor: HENAN JUNHUA DEVELOPMENT Co.,Ltd. Registration number: Y2019980000247 |
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