CN105408370B - 一种方法 - Google Patents
一种方法 Download PDFInfo
- Publication number
- CN105408370B CN105408370B CN201480041956.4A CN201480041956A CN105408370B CN 105408370 B CN105408370 B CN 105408370B CN 201480041956 A CN201480041956 A CN 201480041956A CN 105408370 B CN105408370 B CN 105408370B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- group
- alkyl
- polymerization
- independently
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13177881.3 | 2013-07-24 | ||
| EP13177881.3A EP2829556B1 (en) | 2013-07-24 | 2013-07-24 | Process |
| PCT/EP2014/065710 WO2015011134A1 (en) | 2013-07-24 | 2014-07-22 | Process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105408370A CN105408370A (zh) | 2016-03-16 |
| CN105408370B true CN105408370B (zh) | 2018-03-30 |
Family
ID=48856536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480041956.4A Expired - Fee Related CN105408370B (zh) | 2013-07-24 | 2014-07-22 | 一种方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20160168285A1 (enExample) |
| EP (1) | EP2829556B1 (enExample) |
| CN (1) | CN105408370B (enExample) |
| BR (1) | BR112016001425B1 (enExample) |
| ES (1) | ES2607378T3 (enExample) |
| SA (1) | SA516370421B1 (enExample) |
| WO (1) | WO2015011134A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3736572B1 (en) * | 2016-04-05 | 2024-07-24 | Université de Strasbourg | Intra-droplet surface engineering to capture a molecular target |
| KR102499596B1 (ko) | 2018-05-09 | 2023-02-14 | 보레알리스 아게 | 프로필렌 폴리머를 제조하는 공정 |
| CN117255734A (zh) | 2021-04-30 | 2023-12-19 | 博里利斯股份公司 | 包含聚丙烯和烃树脂的聚合物组合物 |
| EP4234629B1 (en) | 2022-02-28 | 2024-10-30 | Borealis AG | Nucleated bimodal polypropylene |
| EP4249388B1 (en) | 2022-03-23 | 2024-06-19 | Borealis AG | Living hinge of an alpha-nucleated propylene copolymer |
| EP4253453A1 (en) | 2022-04-01 | 2023-10-04 | Borealis AG | Blown film |
| EP4286156A1 (en) | 2022-06-03 | 2023-12-06 | Borealis AG | Pet-free package with pp-evoh-pe-multilayer structure |
| EP4450538A1 (en) | 2023-04-21 | 2024-10-23 | Borealis AG | Blown film |
| EP4450539B1 (en) | 2023-04-21 | 2025-10-29 | Borealis GmbH | Blown film |
| CN121175162A (zh) | 2023-05-23 | 2025-12-19 | 博里利斯有限责任公司 | 用于生产聚烯烃的粒料的方法和由此生产的粒料 |
| EP4624518A1 (en) | 2024-03-28 | 2025-10-01 | Borealis GmbH | Process for producing blown films based on ssc c2c3 random copolymer |
| WO2025242653A1 (en) | 2024-05-22 | 2025-11-27 | Borealis Gmbh | Polyolefin compositions for blown films |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102471396A (zh) * | 2009-08-13 | 2012-05-23 | 科聚亚公司 | 控制聚α烯烃粘度的方法 |
| CN102666605A (zh) * | 2009-12-22 | 2012-09-12 | 博里利斯股份公司 | 催化剂 |
| CN102781972A (zh) * | 2010-03-08 | 2012-11-14 | Lg化学株式会社 | 负载型茂金属催化剂、制备该催化剂的方法以及使用该催化剂制备聚烯烃的方法 |
| WO2013007650A1 (en) * | 2011-07-08 | 2013-01-17 | Borealis Ag | Catalysts |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| US4740550A (en) | 1986-06-18 | 1988-04-26 | Shell Oil Company | Multistage copolymerization process |
| US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| US5416228A (en) | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
| JP3153000B2 (ja) | 1992-06-11 | 2001-04-03 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
| FI104826B (fi) | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
| FI971565A7 (fi) | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
| DE19709866A1 (de) | 1997-03-11 | 1998-09-17 | Basf Ag | Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen |
| GB9708487D0 (en) | 1997-04-25 | 1997-06-18 | Bp Chem Int Ltd | Novel catalysts for olefin polymerisation |
| DK0990003T3 (da) | 1997-06-10 | 2003-01-06 | Peroxid Chemie Gmbh & Co Kg | Nye katalysatorsystemer til (co-)polymerisationsreaktioner, metallocenamidhalogenider og deres anvendelse |
| FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| WO1998058976A1 (en) | 1997-06-24 | 1998-12-30 | Borealis A/S | Process for preparing propylene polymers |
| ATE218147T1 (de) | 1997-09-05 | 2002-06-15 | Bp Chem Int Ltd | Polymerisationskatalysatoren |
| GB9721559D0 (en) | 1997-10-11 | 1997-12-10 | Bp Chem Int Ltd | Novel polymerisation catalysts |
| GB9826874D0 (en) | 1998-12-07 | 1999-01-27 | Borealis As | Process |
| JP2004502699A (ja) | 2000-06-30 | 2004-01-29 | エクソンモービル・ケミカル・パテンツ・インク | 架橋ビス(インデニル)メタロセン化合物 |
| US6877107B2 (en) | 2001-07-05 | 2005-04-05 | Softwired Ag | Method for ensuring operation during node failures and network partitions in a clustered message passing server |
| EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| DE60328582D1 (de) * | 2002-01-31 | 2009-09-10 | Mitsubishi Chem Corp | Nichtsteife propylenharzzusammensetzung |
| ES2366651T3 (es) | 2004-12-31 | 2011-10-24 | Borealis Technology Oy | Procedimiento para preparar un catalizador sólido para la polimerización de olefinas. |
| US7834205B2 (en) | 2006-04-12 | 2010-11-16 | Basell Polyolifine GmbH | Metallocene compounds |
| US7429635B2 (en) * | 2006-09-28 | 2008-09-30 | Equistar Chemicals, Lp | Preparation of ultra high molecular weight linear low density polyethylene |
| EP2203483B1 (en) * | 2007-10-25 | 2014-04-09 | Lummus Novolen Technology Gmbh | Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo-and copolymers |
| WO2010052263A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| EP2361267B1 (en) | 2008-11-07 | 2015-03-04 | Borealis AG | Process to prepare a solid catalyst composition |
| WO2010052264A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| JP5785609B2 (ja) | 2010-04-28 | 2015-09-30 | ボレアリス エージー | 触媒 |
| KR101618753B1 (ko) * | 2010-04-28 | 2016-05-09 | 보레알리스 아게 | 브릿지된 메탈로센을 포함하는 고체 미립자 촉매 |
| US20110294972A1 (en) | 2010-05-27 | 2011-12-01 | Basell Polyolefine Gmbh | Olefin Polymerization Catalysts |
| EP2402353B1 (en) | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
| CN103380151A (zh) | 2010-12-22 | 2013-10-30 | 博里利斯股份公司 | 桥连茂金属催化剂 |
-
2013
- 2013-07-24 ES ES13177881.3T patent/ES2607378T3/es active Active
- 2013-07-24 EP EP13177881.3A patent/EP2829556B1/en not_active Not-in-force
-
2014
- 2014-07-22 BR BR112016001425-1A patent/BR112016001425B1/pt not_active IP Right Cessation
- 2014-07-22 WO PCT/EP2014/065710 patent/WO2015011134A1/en not_active Ceased
- 2014-07-22 CN CN201480041956.4A patent/CN105408370B/zh not_active Expired - Fee Related
- 2014-07-22 US US14/906,640 patent/US20160168285A1/en not_active Abandoned
-
2016
- 2016-01-19 SA SA516370421A patent/SA516370421B1/ar unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102471396A (zh) * | 2009-08-13 | 2012-05-23 | 科聚亚公司 | 控制聚α烯烃粘度的方法 |
| CN102666605A (zh) * | 2009-12-22 | 2012-09-12 | 博里利斯股份公司 | 催化剂 |
| CN102781972A (zh) * | 2010-03-08 | 2012-11-14 | Lg化学株式会社 | 负载型茂金属催化剂、制备该催化剂的方法以及使用该催化剂制备聚烯烃的方法 |
| WO2013007650A1 (en) * | 2011-07-08 | 2013-01-17 | Borealis Ag | Catalysts |
Also Published As
| Publication number | Publication date |
|---|---|
| US20160168285A1 (en) | 2016-06-16 |
| CN105408370A (zh) | 2016-03-16 |
| BR112016001425A2 (enExample) | 2017-07-25 |
| BR112016001425B1 (pt) | 2021-08-31 |
| SA516370421B1 (ar) | 2016-11-03 |
| WO2015011134A1 (en) | 2015-01-29 |
| ES2607378T3 (es) | 2017-03-31 |
| EP2829556B1 (en) | 2016-11-16 |
| EP2829556A1 (en) | 2015-01-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180330 |