CN105377972A - 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料 - Google Patents

用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料 Download PDF

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Publication number
CN105377972A
CN105377972A CN201480026478.XA CN201480026478A CN105377972A CN 105377972 A CN105377972 A CN 105377972A CN 201480026478 A CN201480026478 A CN 201480026478A CN 105377972 A CN105377972 A CN 105377972A
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China
Prior art keywords
methyl
weight
acrylic
liquid
protection
Prior art date
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Pending
Application number
CN201480026478.XA
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English (en)
Chinese (zh)
Inventor
P.热拉尔
M.格洛坦
J-P.科舒瓦（波尔普拉斯特吉德莱斯特）
C.奎因滕
M.米哈卢塔
Q.林
M.费里奥尔
M.科谢
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Institut National Polytechnique de Lorraine
Arkema France SA
Pole De Plasturgie De L'Est
Original Assignee
Institut National Polytechnique de Lorraine
Arkema France SA
Pole De Plasturgie De L'Est
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Application filed by Institut National Polytechnique de Lorraine, Arkema France SA, Pole De Plasturgie De L'Est filed Critical Institut National Polytechnique de Lorraine
Priority to CN202210267124.0A priority Critical patent/CN115369653A/zh
Publication of CN105377972A publication Critical patent/CN105377972A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
    • B29C70/021—Combinations of fibrous reinforcement and non-fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2505/00—Use of metals, their alloys or their compounds, as filler
    • B29K2505/02—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)
CN201480026478.XA 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料 Pending CN105377972A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210267124.0A CN115369653A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1352157 2013-03-11
FR1352157A FR3002943B1 (fr) 2013-03-11 2013-03-11 Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.
PCT/FR2014/050538 WO2014140465A1 (fr) 2013-03-11 2014-03-10 Sirop (meth) acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne

Related Child Applications (1)

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CN202210267124.0A Division CN115369653A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料

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Publication Number Publication Date
CN105377972A true CN105377972A (zh) 2016-03-02

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CN201480026478.XA Pending CN105377972A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料
CN202210267124.0A Pending CN115369653A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料

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Country Status (8)

Country Link
US (1) US10131768B2 (enExample)
EP (1) EP2970635B1 (enExample)
JP (1) JP6499978B2 (enExample)
CN (2) CN105377972A (enExample)
CA (1) CA2905866C (enExample)
FR (1) FR3002943B1 (enExample)
MX (1) MX380319B (enExample)
WO (1) WO2014140465A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106084606A (zh) * 2016-05-30 2016-11-09 敖然 连续纤维增强热塑性复合材料及其制备方法
CN109415470A (zh) * 2016-07-11 2019-03-01 阿肯马法国公司 包含磷基添加剂的液体组合物、其用途以及在组合物聚合后获得的材料或组合物
CN111587265A (zh) * 2017-11-21 2020-08-25 阿科玛法国公司 用于smc模塑的热塑性复合材料的应用的液体组合物
CN116082778A (zh) * 2023-03-02 2023-05-09 江苏盈美复合材料有限公司 一种阻燃天然纤维增强热塑性复合材料及其制造方法

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FR2993581B1 (fr) * 2012-07-18 2016-01-22 Arkema France Procede d'impregnation pour un substrat fibreux, sirop (meth)acrylique liquide pour le procede d'impregnation, son procede de polymerisation et produit structure obtenu a partir de celui-ci
FR3002941B1 (fr) * 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
FR3016642B1 (fr) * 2014-01-22 2020-02-21 Arkema France Procede d'impregnation pour un substrat fibreux, sirop monomere liquide pour le procede d'impregnation, sa methode de polymerisation et article structurel obtenu
FR3019824B1 (fr) * 2014-04-15 2017-10-13 Arkema France Procede pour materiau composite avec impregnation par polymere thermoplastique, issu d'un prepolymere et d'un allongeur de chaine
FR3037066B1 (fr) 2015-06-05 2019-06-21 Arkema France Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique comprenant une substance ignifugeante
CN105603741A (zh) * 2016-01-26 2016-05-25 吴江市震宇缝制设备有限公司 一种环保纺织缝纫纱线浆料
ES2811378T3 (es) * 2016-04-01 2021-03-11 Dsm Ip Assets Bv Bebidas que comprenden gránulos estables de luteína molida
KR20210092289A (ko) * 2018-11-19 2021-07-23 아르끄마 프랑스 개선된 표면 특성을 갖는 아크릴 복합재
FR3105228B1 (fr) * 2019-12-18 2021-11-26 Arkema France Composition comprenant un hemiperoxyacetal, son procédé de polymérisation, son utilisation et matériau de composition obtenu après polymérisation de la composition
ES2906674B2 (es) * 2020-10-15 2022-11-17 Consejo Superior Investigacion Polimeros reforzados con fibras basados en matrices termoplasticas
WO2023034838A1 (en) * 2021-08-31 2023-03-09 Trinseo Europe Gmbh Non-halogenated, self-extinguishing resin compositions and methods for producing same
US20240010828A1 (en) * 2022-07-08 2024-01-11 B/E Aerospace, Inc. Fire resistant polymer matrix composite

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FR3002941B1 (fr) 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
FR3002942B1 (fr) 2013-03-11 2016-01-22 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.

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US3287155A (en) * 1962-11-08 1966-11-22 Du Pont Process for impregnating glass fiber mat with methyl methacrylate polymer
CN85104029A (zh) * 1983-08-23 1986-11-19 凡塔公司 一防水、抗风雨和基本上无弹性的纺织品，生产它的方法，以及由它制造的组件
CN1902275A (zh) * 2003-12-19 2007-01-24 罗狄亚工程塑料有限责任公司 基于热塑性基质的阻燃组合物
CN101720329A (zh) * 2007-07-13 2010-06-02 科莱恩金融(Bvi)有限公司 烷基亚膦酸，烷基亚膦酸盐和烷基亚膦酸酯，它们的制备方法及它们的用途
TW201229219A (en) * 2010-10-09 2012-07-16 Clariant Finance Bvi Ltd Flame retardant-stabilizer combination for thermoplastic polymers

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106084606A (zh) * 2016-05-30 2016-11-09 敖然 连续纤维增强热塑性复合材料及其制备方法
CN109415470A (zh) * 2016-07-11 2019-03-01 阿肯马法国公司 包含磷基添加剂的液体组合物、其用途以及在组合物聚合后获得的材料或组合物
CN111587265A (zh) * 2017-11-21 2020-08-25 阿科玛法国公司 用于smc模塑的热塑性复合材料的应用的液体组合物
CN111587265B (zh) * 2017-11-21 2023-12-22 阿科玛法国公司 用于smc模塑的热塑性复合材料的应用的液体组合物
CN116082778A (zh) * 2023-03-02 2023-05-09 江苏盈美复合材料有限公司 一种阻燃天然纤维增强热塑性复合材料及其制造方法
CN116082778B (zh) * 2023-03-02 2024-04-26 江苏盈韧新材料科技有限公司 一种阻燃天然纤维增强热塑性复合材料及其制造方法

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CA2905866C (en) 2021-04-13
FR3002943B1 (fr) 2015-03-27
JP2016510086A (ja) 2016-04-04
MX380319B (es) 2025-03-12
EP2970635A1 (fr) 2016-01-20
CA2905866A1 (en) 2014-09-18
US10131768B2 (en) 2018-11-20
WO2014140465A1 (fr) 2014-09-18
MX2015012080A (es) 2016-07-06
US20160032080A1 (en) 2016-02-04
CN115369653A (zh) 2022-11-22
JP6499978B2 (ja) 2019-04-10

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