FR3002943B1 - Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. - Google Patents

Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.

Info

Publication number
FR3002943B1
FR3002943B1 FR1352157A FR1352157A FR3002943B1 FR 3002943 B1 FR3002943 B1 FR 3002943B1 FR 1352157 A FR1352157 A FR 1352157A FR 1352157 A FR1352157 A FR 1352157A FR 3002943 B1 FR3002943 B1 FR 3002943B1
Authority
FR
France
Prior art keywords
impregnating
substrate
fibrous substrate
meth
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1352157A
Other languages
English (en)
French (fr)
Other versions
FR3002943A1 (fr
Inventor
Pierre Gerard
Michel Glotin
Jean Pierre Cauchois
Claire Quinten
Marius Mihaluta
Qing Lin
Michel Ferriol
Marianne Cochez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institut National Polytechnique de Lorraine
Arkema France SA
Institut de Soudure
Original Assignee
POLE DE PLASTURGIE de l EST
Institut National Polytechnique de Lorraine
Arkema France SA
Pole De Plasturgie De L'Est
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1352157A priority Critical patent/FR3002943B1/fr
Application filed by POLE DE PLASTURGIE de l EST, Institut National Polytechnique de Lorraine, Arkema France SA, Pole De Plasturgie De L'Est filed Critical POLE DE PLASTURGIE de l EST
Priority to US14/774,186 priority patent/US10131768B2/en
Priority to MX2015012080A priority patent/MX380319B/es
Priority to CN201480026478.XA priority patent/CN105377972A/zh
Priority to CN202210267124.0A priority patent/CN115369653A/zh
Priority to EP14715352.2A priority patent/EP2970635B1/fr
Priority to PCT/FR2014/050538 priority patent/WO2014140465A1/fr
Priority to JP2015562278A priority patent/JP6499978B2/ja
Priority to CA2905866A priority patent/CA2905866C/en
Publication of FR3002943A1 publication Critical patent/FR3002943A1/fr
Application granted granted Critical
Publication of FR3002943B1 publication Critical patent/FR3002943B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
    • B29C70/021—Combinations of fibrous reinforcement and non-fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2505/00—Use of metals, their alloys or their compounds, as filler
    • B29K2505/02—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)
FR1352157A 2013-03-11 2013-03-11 Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne. Active FR3002943B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR1352157A FR3002943B1 (fr) 2013-03-11 2013-03-11 Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.
MX2015012080A MX380319B (es) 2013-03-11 2014-03-10 Jarabe (met) acrilico liquido de impregnacion de un sustrato fibroso, proceso de impregnacion de un sustrato fibroso, material compuesto obtenido despues de la polimerizacion de tal sustrato pre-impregnado.
CN201480026478.XA CN105377972A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍纤维基材的方法、在聚合预浸渍基材后获得的复合材料
CN202210267124.0A CN115369653A (zh) 2013-03-11 2014-03-10 用于浸渍纤维基材的液体(甲基)丙烯酸类浆料、浸渍方法及所获得的复合材料
US14/774,186 US10131768B2 (en) 2013-03-11 2014-03-10 Liquid (meth)acrylic syrup for impregnating a fibrous substrate, method of impregnating a fibrous substrate, composite material obtained following polymerisation of the pre-impregnated substrate
EP14715352.2A EP2970635B1 (fr) 2013-03-11 2014-03-10 Sirop (meth) acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
PCT/FR2014/050538 WO2014140465A1 (fr) 2013-03-11 2014-03-10 Sirop (meth) acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
JP2015562278A JP6499978B2 (ja) 2013-03-11 2014-03-10 繊維性基材を含浸するための液体（メタ）アクリルシロップ、繊維性基材を含浸する方法、このプレ含浸基材の重合の後に得られた複合材料
CA2905866A CA2905866C (en) 2013-03-11 2014-03-10 Liquid (meth)acrylic syrup for impregnating a fibrous substrate, method of impregnating a fibrous substrate, composite material obtained following polymerisation of the pre-impregnated substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1352157A FR3002943B1 (fr) 2013-03-11 2013-03-11 Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.

Publications (2)

Publication Number Publication Date
FR3002943A1 FR3002943A1 (fr) 2014-09-12
FR3002943B1 true FR3002943B1 (fr) 2015-03-27

Family

ID=48521282

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1352157A Active FR3002943B1 (fr) 2013-03-11 2013-03-11 Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.

Country Status (8)

Country Link
US (1) US10131768B2 (enExample)
EP (1) EP2970635B1 (enExample)
JP (1) JP6499978B2 (enExample)
CN (2) CN105377972A (enExample)
CA (1) CA2905866C (enExample)
FR (1) FR3002943B1 (enExample)
MX (1) MX380319B (enExample)
WO (1) WO2014140465A1 (enExample)

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FR2993581B1 (fr) * 2012-07-18 2016-01-22 Arkema France Procede d'impregnation pour un substrat fibreux, sirop (meth)acrylique liquide pour le procede d'impregnation, son procede de polymerisation et produit structure obtenu a partir de celui-ci
FR3002941B1 (fr) * 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
FR3016642B1 (fr) * 2014-01-22 2020-02-21 Arkema France Procede d'impregnation pour un substrat fibreux, sirop monomere liquide pour le procede d'impregnation, sa methode de polymerisation et article structurel obtenu
FR3019824B1 (fr) * 2014-04-15 2017-10-13 Arkema France Procede pour materiau composite avec impregnation par polymere thermoplastique, issu d'un prepolymere et d'un allongeur de chaine
FR3037066B1 (fr) 2015-06-05 2019-06-21 Arkema France Procede d'impregnation d'un substrat fibreux avec un melange (meth)acrylique comprenant une substance ignifugeante
CN105603741A (zh) * 2016-01-26 2016-05-25 吴江市震宇缝制设备有限公司 一种环保纺织缝纫纱线浆料
ES2811378T3 (es) * 2016-04-01 2021-03-11 Dsm Ip Assets Bv Bebidas que comprenden gránulos estables de luteína molida
CN106084606B (zh) * 2016-05-30 2018-06-19 敖然 连续纤维增强热塑性复合材料及其制备方法
FR3053693B1 (fr) * 2016-07-11 2018-08-17 Arkema France Composition liquide comprenant un additif a base de phosphore, son utilisation et materiau ou composition obtenu apres polymerisation de la composition
FR3073855B1 (fr) 2017-11-21 2020-12-18 Arkema France Composition liquide adaptee a des applications de composites thermoplastiques moulees a base de smc
KR20210092289A (ko) * 2018-11-19 2021-07-23 아르끄마 프랑스 개선된 표면 특성을 갖는 아크릴 복합재
FR3105228B1 (fr) * 2019-12-18 2021-11-26 Arkema France Composition comprenant un hemiperoxyacetal, son procédé de polymérisation, son utilisation et matériau de composition obtenu après polymérisation de la composition
ES2906674B2 (es) * 2020-10-15 2022-11-17 Consejo Superior Investigacion Polimeros reforzados con fibras basados en matrices termoplasticas
WO2023034838A1 (en) * 2021-08-31 2023-03-09 Trinseo Europe Gmbh Non-halogenated, self-extinguishing resin compositions and methods for producing same
US20240010828A1 (en) * 2022-07-08 2024-01-11 B/E Aerospace, Inc. Fire resistant polymer matrix composite
CN116082778B (zh) * 2023-03-02 2024-04-26 江苏盈韧新材料科技有限公司 一种阻燃天然纤维增强热塑性复合材料及其制造方法

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FR3002877B1 (fr) 2013-03-07 2015-03-27 Arkema France Procede de fabrication d'un materiau composite multicouche, materiau composite multicouche obtenu par le procede et pieces ou structures mecaniques realisees avec ledit materiau.
FR3002940B1 (fr) 2013-03-08 2016-01-22 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux et son procede de fabrication, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.
FR3002941B1 (fr) 2013-03-08 2015-04-10 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
FR3002942B1 (fr) 2013-03-11 2016-01-22 Arkema France Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne.

Also Published As

Publication number Publication date
EP2970635B1 (fr) 2017-06-07
FR3002943A1 (fr) 2014-09-12
CA2905866C (en) 2021-04-13
JP2016510086A (ja) 2016-04-04
MX380319B (es) 2025-03-12
CN105377972A (zh) 2016-03-02
EP2970635A1 (fr) 2016-01-20
CA2905866A1 (en) 2014-09-18
US10131768B2 (en) 2018-11-20
WO2014140465A1 (fr) 2014-09-18
MX2015012080A (es) 2016-07-06
US20160032080A1 (en) 2016-02-04
CN115369653A (zh) 2022-11-22
JP6499978B2 (ja) 2019-04-10

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FR3002941B1 (fr) Sirop (meth)acrylique liquide d'impregnation d'un substrat fibreux, procede d'impregnation d'un substrat fibreux, materiau composite obtenu apres polymerisation dudit substrat pre-impregne
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