CN104903429A - 润滑剂组合物 - Google Patents

润滑剂组合物 Download PDF

Info

Publication number
CN104903429A
CN104903429A CN201380054637.2A CN201380054637A CN104903429A CN 104903429 A CN104903429 A CN 104903429A CN 201380054637 A CN201380054637 A CN 201380054637A CN 104903429 A CN104903429 A CN 104903429A
Authority
CN
China
Prior art keywords
weight
lubricant compositions
osp
additive
derived
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201380054637.2A
Other languages
English (en)
Inventor
M·R·格里夫斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of CN104903429A publication Critical patent/CN104903429A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24—Polyethers
    • C10M145/26—Polyoxyalkylenes
    • C10M145/34—Polyoxyalkylenes of two or more specified different types
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/003—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C10M2207/2825—Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/043—Ammonium or amine salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/30—Anti-misting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/50—Emission or smoke controlling properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明提供一种润滑剂组合物，其包含75到95重量％聚α-烯烃基础油；和7.5到25重量％油溶性聚亚烷基二醇(OSP)添加剂，其中所述聚亚烷基二醇在40℃下具有15cSt到50cSt的粘度并且包含衍生自环氧丙烷的单元和衍生自环氧丁烷的单元；其中所述润滑剂组合物展现至少160kg的四球EP熔接负荷结果和在75℃下小于3分钟的空气释放值。

Description

润滑剂组合物
技术领域
本发明涉及一种润滑剂组合物。
背景技术
齿轮油的两个重要性能特性为其极压性能和其空气释放特性。高度需要组合极低空气释放值与高极压值的调配齿轮液。
行业中的一个趋势为由OEM设计具有较小储液槽的齿轮箱并且因此每个齿轮箱需要较少润滑剂量。在齿轮操作期间，随着温度增加，这对齿轮润滑剂施加额外压力，因为可用于散热的流体较少。另外，齿轮润滑剂可能夹带空气并且重要的是将此空气快速释放。润滑剂通常夹带10体积％的空气。夹带的空气可能造成摩擦控制较差、氧化提高、噪音、振动和空蚀。为此，需要空气释放值较低的流体。此外，重要的是齿轮润滑剂具有极好的极压特性以防止在齿轮齿啮合时在高接触压力下熔接。
大部分可商购的工业齿轮润滑剂的粘度在ISO-150到1000(即40℃下的150到1000cSt)范围内。其空气释放值＞5分钟并且通常在75℃下在10至20分钟范围内。
发明内容
在一个实施例中，本发明提供一种润滑剂组合物，其包含75到95重量％聚α-烯烃基础油；和7.5到25重量％油溶性聚亚烷基二醇(OSP)添加剂，其中聚亚烷基二醇在40℃下具有15cSt到50cSt的粘度且包含衍生自环氧丙烷的单元和衍生自环氧丁烷的单元；其中润滑剂组合物展现至少160kg的四球EP熔接负荷结果和在75℃下小于3分钟的空气释放值。
具体实施方式
已发现含有7.5到20重量％含量的某些油溶性聚亚烷基二醇(OSP)作为添加剂的用聚α-烯烃(PAO)调配的齿轮润滑剂也可以具有低空气释放值并且也具有良好极压特性。
润滑剂组合物包含75到95重量％聚α-烯烃基础油；和7.5到25重量％油溶性聚亚烷基二醇(OSP)添加剂，其中OSP在40℃下具有15cSt到50cSt的动态粘度并且包含衍生自环氧丙烷的单元和衍生自环氧丁烷的单元；其中润滑剂组合物展现至少160kg的四球EP熔接负荷结果和在75℃下小于3分钟的空气释放值。
75到92.5重量％PAO的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，PAO可以在75、78、81、85、91或92重量％的下限到76、80、84、88或92.5重量％的上限范围内变化。举例来说，润滑剂组合物中的PAO的量可以是75到92.5重量％，或在替代方案中，润滑剂组合物中的PAO的量可以是80到90重量％，或在替代方案中，润滑剂组合物中的PAO的量可以是85到92.5重量％。
可以使用在所属领域中众所周知的任何聚α-烯烃基础油。示例性商业聚α-烯烃基础油包括可以商品名称SPECTRASYN获自埃克森美孚化学公司(ExxonMobil ChemicalCompany)、以SYNFLUID获自雪佛龙菲利浦(Chevron Phillips)和以SYNTON获自科聚亚(Chemtura)的那些基础油。
润滑剂组合物中的7.5到25重量％OSP的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，OSP可以在7.5、10、12.5、15、17.5、20、22.5或24重量％的下限到8、11、13、16、18.5、21、23.5或25重量％的上限范围内变化。举例来说，润滑剂组合物中的OSP的量可以是从7.5到25重量％，或在替代方案中，润滑剂组合物中的OSP的量可以是10到20重量％，或在替代方案中，润滑剂组合物中的OSP的量可以是15到20重量％。
OSP在40℃下具有15cSt到50cSt的动态粘度。15到50cSt的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，动态粘度可以从15、20、25、30、35、40或45cSt的下限到17.5、22.5、27.5、32.5、37.5、42.5、47.5或50cSt的上限。举例来说，OSP的粘度可以在15到50cSt范围内，或在替代方案中，OSP的粘度可以在25到50cSt范围内，或在替代方案中，OSP的粘度可以在25到45cSt范围内，或在替代方案中，OSP的粘度可以在15到35cSt范围内，或在替代方案中，OSP的粘度可以在18到46cSt范围内。
润滑剂组合物展现至少160kg的四球EP熔接负荷。至少160kg的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，四球EP熔接负荷可以160、170、180、190或200kg为下限。
润滑剂组合物在75℃下展现小于3分钟的空气释放值。小于3分钟的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，75℃下的空气释放值可以3、2.5、2、1.5或1分钟为上限。
在替代实施例中，OSP具有400到1100g/mol的分子量。所有个别值和子范围为本文所披露并且包括在本文中；举例来说，OSP的分子量可以在400、500、600、700、800、900或1000g/mol的下限到450、550、650、750、850、950、1050或1100g/mol的上限范围内变化。举例来说，OSP的分子量可以在400到1100g/mol范围内，或在替代方案中，OSP的分子量可以在500到1000g/mol范围内，或在替代方案中，OSP的分子量可以在400到800g/mol范围内，或在替代方案中，OSP的分子量可以在600到1000g/mol范围内。
在替代实施例中，本发明提供一种润滑剂组合物，其根据前述实施例中的任一实施例，但是OSP包含30到70重量％衍生自环氧丙烷的单元和70到30重量％衍生自环氧丁烷的单元。30到70重量％衍生自环氧丙烷的单元的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，衍生自环氧丙烷的单元的量可以在30、40、50或60重量％的下限到35、45、55、65或70重量％的上限范围内。举例来说，衍生自环氧丙烷的单元的量可以在30到70重量％范围内，或在替代方案中，衍生自环氧丙烷的单元的量可以在40到60重量％范围内，或在替代方案中，衍生自环氧丙烷的单元的量可以在40到70重量％范围内，或在替代方案中，衍生自环氧丙烷的单元的量可以在45到55重量％范围内，或在替代方案中，衍生自环氧丙烷的单元的量可以是50重量％。30到70重量％衍生自环氧丁烷的单元的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，衍生自环氧丁烷的单元的量可以在30、40、50或60重量％的下限到35、45、55、65或70重量％的上限范围内。举例来说，衍生自环氧丁烷的单元的量可以在30到70重量％范围内，或在替代方案中，衍生自环氧丁烷的单元的量可以在40到60重量％范围内，或在替代方案中，衍生自环氧丁烷的单元的量可以在30到60重量％范围内，或在替代方案中，衍生自环氧丁烷的单元的量可以在45到55重量％范围内，或在替代方案中，衍生自环氧丁烷的单元的量可以是50重量％。
在替代实施例中，本发明提供一种润滑剂组合物，其根据前述实施例中的任一实施例，但是OSP具有32cSt的粘度。
适用于润滑剂组合物的实施例的OSP通过一或多种由以下组成的群组选出的引发剂起始：醇(即单醇)、二醇和多元醇。示例性醇(即单醇)引发剂包括甲醇、乙醇、丙醇、丁醇、戊醇、己醇、新戊醇、异丁醇、癸醇、2-乙基己醇等，以及衍生自天然和石化来源的高级非环状醇，其具有11个碳原子到22个碳原子的醇。示例性二醇引发剂包括单乙二醇、单丙二醇、丁二醇、二乙二醇或二丙二醇。示例性多元醇引发剂包括新戊二醇、三羟甲基丙烷和季戊四醇。
在替代实施例中，本发明提供一种润滑剂组合物，其进一步包含至少0.05重量％的至少一种极压添加剂。至少0.05重量％抗磨添加剂的所有个别值和子范围包括在本文中并且为本文所披露；举例来说，润滑剂组合物中的抗磨添加剂的量可以0.05、0.15、0.25、0.5、0.8或1重量％为下限
示例性极压添加剂包括无灰二硫代磷酸酯、硫代磷酸三芳基酯、二苯基亚磷酸烷基酯、磷酸胺、二硫代磷酸酯和硫代磷酸三芳基酯。黄色金属钝化剂的实例包括甲苯基三唑、苯并三唑和N-烷基化甲苯三唑。抗氧化剂的实例包括辛基化二苯胺、烷基化苯基α萘胺、辛基化/丁基化二苯胺和酚类抗氧化剂。
润滑剂组合物的一些实施例可以进一步包含一或多个由以下组成的群组选出的添加剂：抗磨添加剂、黄色金属钝化剂和抗氧化剂。示例性抗磨添加剂包括二烷基二硫代磷酸锌、磷酸胺、二硫代氨基甲酸酯、烷基磷酸酯、无灰二硫代氨基甲酸酯、其组合和其掺合物。
黄色金属钝化剂的实例包括甲苯基三唑、苯并三唑和N-烷基化甲苯基三唑。抗氧化剂的实例包括辛基化二苯胺、烷基化苯基α萘胺、辛基化/丁基化二苯胺和酚类抗氧化剂。
在替代实施例中。本发明提供一种润滑剂组合物，其根据前述实施例中的任一实施例的，但是润滑剂组合物进一步包含0.25到2重量％的一或多种极压添加剂。0.25到2重量％的所有值和子范围包括在本文中并且为本文所披露；举例来说，极压添加剂的量可以在0.25、0.5、0.75、1、1.25、1.5或1.75重量％的下限到0.5、0.75、1、1.25、1.5、1.75或2重量％的上限范围内变化。举例来说，一或多种极压添加剂的量可以是0.25到2重量％，或在替代方案中，一或多种极压添加剂的量可以是0.25到1重量％，或在替代方案中，一或多种极压添加剂的量可以是1到2重量％，或在替代方案中，一或多种极压添加剂的量可以是0.75到1.75重量％，或在替代方案中，一或多种极压添加剂的量可以是0.5到1重量％。
根据本文揭示的实施例中的任一实施例的润滑剂组合物可用作齿轮油、液压油、压缩机油和/或机油或可用于其中。
在替代实施例中，本发明提供一种润滑剂组合物，其基本上由75到95重量％聚α-烯烃基础油；和7.5到25重量％油溶性聚亚烷基二醇(OSP)添加剂组成，其中提供的聚亚烷基二醇在40℃下具有15cSt到50cSt的粘度并且包含衍生自环氧丙烷的单元和衍生自环氧丁烷的单元；其中润滑剂组合物展现至少160kg的四球EP熔接负荷结果和在75℃下小于3分钟的空气释放值。
在另一替代实施例中，本发明提供一种润滑剂组合物，其包含75到95重量％聚α-烯烃基础油；和7.5到25重量％油溶性聚亚烷基二醇(OSP)添加剂，其中提供的聚亚烷基二醇在40℃下具有15cSt到50cSt的粘度并且主要由衍生自环氧丙烷的单元和衍生自环氧丁烷的单元组成；其中润滑剂组合物展现至少160kg的四球EP熔接负荷结果和在75℃下小于3分钟的空气释放值。
在另一替代实施例中，本发明提供一种润滑剂组合物，其基本上由75到95重量％聚α-烯烃基础油；和7.5到25重量％油溶性聚亚烷基二醇(OSP)添加剂组成，其中提供的聚亚烷基二醇在40℃下具有15cSt到50cSt的粘度并且基本上由衍生自环氧丙烷的单元和衍生自环氧丁烷的单元组成；其中润滑剂组合物展现至少160kg的四球EP熔接负荷结果和在75℃下小于3分钟的空气释放值。
实例
以下实例说明本发明，但并不打算限制本发明的范围。表1提供用于本发明和比较实例中的聚α-烯烃基础油、OSP添加剂、抗磨添加剂、抗氧化剂、极压添加剂和黄色金属钝化剂、其组成、特性和商业供应商的列表。
表1
本发明实例1到2的组成和所选特性显示于表2中。比较实例1到5的组成和所选特性显示于表3中。比较实例6到9的组成和所选特性显示于表4中。如本文所用，“wt％”和“重量％”为同义的。
表2
本发明实例1 本发明实例2
组分 重量％ 重量％
Spectrasyn 8 15.35 15.35
Spectrasyn 40 72 62
UCON OSP-32 10 20
Irganox L135 0.75 0.75
Vanlube 81 1 1
Durad 310M 0.75 0.75
NaLube AW6110 0.15 0.15
特性
40℃下的动态粘度，cst 190.5 136
100℃下的动态粘度，cSt 22.8 18.1
粘度指数 146 149
40℃下的密度，g/cc 0.844 0.882
在环境温度下的外观 透明 透明
75℃下的空气释放，分钟，ASTM D3427 2 2.8
1760+40rpm下的熔接负荷，kg，ASTM 2793 160 200
表3
表4
如通过前文可见，具有根据本发明组合物的前述实施例的聚α-烯烃基础油和OSP添加剂的润滑剂组合物展现极佳空气释放和极压特性。
测试方法
测试方法包括以下各项：
40℃和100℃下的动态黏度是根据ASTM D445测量的。
粘度指数是根据ASTM 2270测量的。
密度是根据ASTM D7042测量的。
空气释放是根据ASTM D3427测量的。对于通常为低粘度流体并且在40℃下在22到150cSt范围内的液压流体，在50℃下进行空气释放测量。对于较高粘度流体，在如75℃的较高温度下进行测量。
极压熔接负荷是根据ASTM D2793在1760+/-40rpm、18至36℃的温度下测量的。
除非另行说明、从上下文暗示或在所属领域中常规的，否则所有份数和百分比都是按重量计。所引用的所有申请、公开案、专利、测试程序和其它文件(包括优先权文件)以引用的方式完全并入，引用的程度为所述披露内容符合所披露的组合物和方法并且在所有权限中准许所述并入。
在不脱离本发明的精神和基本特质的情况下可以按其它形式实施本发明，并因此应参照所附权利要求书而非前文说明书作为本发明范围的指示。

Claims (11)

1.一种润滑剂组合物，其包含
75到95重量％聚α-烯烃基础油；和
7.5到25重量％油溶性聚亚烷基二醇(OSP)添加剂，其中所述聚亚烷基二醇在40℃下具有15 cSt到50 cSt的粘度并且包含衍生自环氧丙烷的单元和衍生自环氧丁烷的单元；
其中所述润滑剂组合物展现至少160 kg的四球EP熔接负荷结果和在75℃下小于3分钟的空气释放值。
2.根据权利要求1所述的润滑剂组合物，其中所述OSP添加剂具有400到1100g/mol的分子量。
3.根据前述权利要求中任一权利要求所述的润滑剂组合物，其中所述OSP添加剂包含30到70重量％衍生自环氧丙烷的单元和70到30重量％衍生自环氧丁烷的单元。
4.根据前述权利要求中任一权利要求所述的润滑剂组合物，其中所述OSP添加剂包含40到60重量％衍生自环氧丙烷的单元和60到40重量％衍生自环氧丁烷的单元。
5.根据前述权利要求中任一权利要求所述的润滑剂组合物，其中所述OSP添加剂包含50重量％衍生自环氧丙烷的单元和50重量％衍生自环氧丁烷的单元。
6.根据前述权利要求中任一权利要求所述的润滑剂组合物，其中所述OSP添加剂具有18到46 cSt的粘度。
7.根据前述权利要求中任一权利要求所述的润滑剂组合物，其中所述OSP添加剂具有32 cSt的粘度。
8.根据前述权利要求中任一权利要求所述的润滑剂组合物，其进一步包含一或多种由以下组成的群组选出的添加剂：抗磨添加剂、黄色金属钝化剂和抗氧化剂。
9.根据前述权利要求中任一权利要求所述的润滑剂组合物，其进一步包含0.25到2重量％的一或多种极压添加剂。
10.根据前述权利要求中任一权利要求所述的润滑剂组合物，其进一步包含0.5到1重量％的一或多种极压添加剂。
11.一种齿轮润滑剂，其包含根据前述权利要求中任一权利要求所述的润滑剂组合物。
CN201380054637.2A 2012-10-25 2013-10-14 润滑剂组合物 Pending CN104903429A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261718283P 2012-10-25 2012-10-25
US61/718283 2012-10-25
PCT/US2013/064752 WO2014066076A1 (en) 2012-10-25 2013-10-14 Lubricant composition

Publications (1)

Publication Number Publication Date
CN104903429A true CN104903429A (zh) 2015-09-09

Family

ID=49510541

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380054637.2A Pending CN104903429A (zh) 2012-10-25 2013-10-14 润滑剂组合物

Country Status (8)

Country Link
US (1) US9926510B2 (zh)
EP (1) EP2888345B1 (zh)
JP (1) JP6228219B2 (zh)
CN (1) CN104903429A (zh)
BR (1) BR112015009036A2 (zh)
CA (1) CA2887558A1 (zh)
IN (1) IN2015DN03950A (zh)
WO (1) WO2014066076A1 (zh)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105524693A (zh) * 2015-12-28 2016-04-27 芜湖市创源新材料有限公司 一种具有良好剪切稳定性的可降解合成液压油
CN105695051A (zh) * 2014-12-16 2016-06-22 现代自动车株式会社 用于车辆制动液的含有osp的组合物
CN108251193A (zh) * 2016-12-29 2018-07-06 现代自动车株式会社 具有改进的摩擦性能和燃料经济性的自动变速器油组合物及包含其的自动变速器的离合器
CN109825354A (zh) * 2019-03-22 2019-05-31 北京豪氏金洁碧润滑油有限公司 一种赛车专用润滑油及其制备方法
CN109863234A (zh) * 2016-10-24 2019-06-07 道达尔销售服务公司 润滑剂组合物
CN110016377A (zh) * 2018-01-10 2019-07-16 中国石油天然气股份有限公司 一种合成冷冻机油组合物及其制备方法和应用

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2745383T3 (es) * 2013-03-11 2020-03-02 Basf Se Uso de polialcoxilatos en composiciones lubricantes
WO2015200029A1 (en) * 2014-06-23 2015-12-30 Rohm And Haas Company Oil-free emollients in personal care compositions
WO2015200030A1 (en) * 2014-06-23 2015-12-30 Rohm And Haas Company Oil-free emollients in sunscreen compositions
KR102431118B1 (ko) 2014-07-31 2022-08-11 다우 글로벌 테크놀로지스 엘엘씨 자동차 응용에서 베이스 오일을 위한 알킬 캡핑된 유용성 중합체 점도 지수 개선 첨가제
EP3174963B1 (en) * 2014-07-31 2019-12-18 Dow Global Technologies LLC Alkyl capped oil soluble polymer viscosity index improving additives for polyalphaolefin base oils in industrial lubricant applications
FR3024461B1 (fr) * 2014-07-31 2017-12-29 Total Marketing Services Compositions lubrifiantes pour vehicule a moteur
US20160168504A1 (en) * 2014-12-10 2016-06-16 Hyundai Motor Company Low viscosity gear oil composition providing enhanced fuel efficiency
BR112017017360A2 (pt) * 2015-02-26 2018-04-10 Dow Global Technologies Llc formulação de lubrificantes com desempenho de pressão extrema e antidesgaste intensificado
WO2016137880A1 (en) * 2015-02-26 2016-09-01 Dow Global Technologies Llc Enhanced extreme pressure lubricant formulations
US10160926B2 (en) * 2016-11-25 2018-12-25 Hyundai Motor Company Axle oil composition having enhanced fuel efficiency and low viscosity
EP3935143B1 (en) * 2019-03-05 2023-11-29 Dow Global Technologies Llc Improved hydrocarbon lubricant compositions and method to make them

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471720A (zh) * 2009-07-23 2012-05-23 陶氏环球技术有限责任公司 可用作i-iv类烃油用润滑剂添加剂的聚亚烷基二醇
WO2012070007A1 (fr) * 2010-11-26 2012-05-31 Total Raffinage Marketing Composition lubrifiante pour moteur

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54159411A (en) 1978-06-07 1979-12-17 Nippon Oil & Fats Co Ltd Engine oil composition
JPH02269198A (ja) 1989-04-10 1990-11-02 Nippon Oil & Fats Co Ltd 潤滑油組成物
US7741259B2 (en) * 2005-07-01 2010-06-22 Enbio Industries, Inc. Environmentally compatible hydraulic fluid
JP2009161685A (ja) 2008-01-09 2009-07-23 Cosmo Oil Lubricants Co Ltd 潤滑油組成物
KR101628406B1 (ko) * 2008-04-28 2016-06-08 다우 글로벌 테크놀로지스 엘엘씨 폴리알킬렌 글리콜 윤활제 조성물
US8247358B2 (en) * 2008-10-03 2012-08-21 Exxonmobil Research And Engineering Company HVI-PAO bi-modal lubricant compositions
EP2619295B1 (en) * 2010-09-24 2014-10-22 Dow Global Technologies LLC Non-aromatic based antioxidants for lubricants
EP2773731A2 (en) * 2011-11-01 2014-09-10 Dow Global Technologies LLC Oil soluble polyalkylene glycol lubricant compositions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471720A (zh) * 2009-07-23 2012-05-23 陶氏环球技术有限责任公司 可用作i-iv类烃油用润滑剂添加剂的聚亚烷基二醇
WO2012070007A1 (fr) * 2010-11-26 2012-05-31 Total Raffinage Marketing Composition lubrifiante pour moteur

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
胡盛忠: "《石油工业新技术与标准规范手册-油气分析测试化验新技术及标准规范（第二卷）》", 31 March 2004, 哈尔滨地图出版社 *
钟泰岗等: "《汽车用润滑脂及添加剂》", 31 July 2006, 化学工业出版社 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105695051A (zh) * 2014-12-16 2016-06-22 现代自动车株式会社 用于车辆制动液的含有osp的组合物
CN105524693A (zh) * 2015-12-28 2016-04-27 芜湖市创源新材料有限公司 一种具有良好剪切稳定性的可降解合成液压油
CN109863234A (zh) * 2016-10-24 2019-06-07 道达尔销售服务公司 润滑剂组合物
US11499115B2 (en) 2016-10-24 2022-11-15 Total Marketing Services Lubricant composition
CN108251193A (zh) * 2016-12-29 2018-07-06 现代自动车株式会社 具有改进的摩擦性能和燃料经济性的自动变速器油组合物及包含其的自动变速器的离合器
CN108251193B (zh) * 2016-12-29 2022-05-13 现代自动车株式会社 具有改进的摩擦性能和燃料经济性的自动变速器油组合物及包含其的自动变速器的离合器
CN110016377A (zh) * 2018-01-10 2019-07-16 中国石油天然气股份有限公司 一种合成冷冻机油组合物及其制备方法和应用
CN109825354A (zh) * 2019-03-22 2019-05-31 北京豪氏金洁碧润滑油有限公司 一种赛车专用润滑油及其制备方法

Also Published As

Publication number Publication date
EP2888345A1 (en) 2015-07-01
US9926510B2 (en) 2018-03-27
US20150275124A1 (en) 2015-10-01
EP2888345B1 (en) 2020-12-09
WO2014066076A1 (en) 2014-05-01
CA2887558A1 (en) 2014-05-01
IN2015DN03950A (zh) 2015-10-02
BR112015009036A2 (pt) 2017-07-04
JP6228219B2 (ja) 2017-11-08
JP2015532943A (ja) 2015-11-16

Similar Documents

Publication Publication Date Title
CN104903429A (zh) 润滑剂组合物
CN103890154A (zh) 油溶性聚亚烷基二醇润滑剂组合物
JP5771532B2 (ja) 潤滑油組成物
JP2009500489A5 (zh)
JP2009500489A (ja) 工業潤滑油及びグリース組成物中のｈｖｉ−ｐａｏ
US10883064B2 (en) Lubricant oil composition and lubrication method
CN101466818A (zh) 润滑油组合物
KR20120114218A (ko) 윤활유 조성물
WO2013008836A1 (ja) 潤滑油組成物および機械装置
JP6219203B2 (ja) 農業機械用潤滑油組成物
CN101629119A (zh) 热稳定无锌抗磨剂
JP7296711B2 (ja) 潤滑油組成物、潤滑油組成物を備える機械装置および潤滑油組成物の製造方法
JP7074502B2 (ja) 潤滑油組成物、潤滑油組成物を備える機械装置および潤滑油組成物の製造方法
JP4829852B2 (ja) 油圧作動油組成物
JP7460445B2 (ja) 潤滑油組成物
JP2008195780A (ja) 手動変速機用潤滑油組成物
KR20230025048A (ko) 소음저감 및 내구성 향상을 위한 변속기오일 조성물
WO2023058440A1 (ja) 潤滑油組成物、潤滑方法及び変速機
WO2021145405A1 (ja) 潤滑油組成物

Legal Events

Date Code Title Description
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150909

WD01 Invention patent application deemed withdrawn after publication