CN104854117B - 用于合成n-膦酰基甲基亚氨基二乙酸的方法 - Google Patents

用于合成n-膦酰基甲基亚氨基二乙酸的方法 Download PDF

Info

Publication number
CN104854117B
CN104854117B CN201380037544.9A CN201380037544A CN104854117B CN 104854117 B CN104854117 B CN 104854117B CN 201380037544 A CN201380037544 A CN 201380037544A CN 104854117 B CN104854117 B CN 104854117B
Authority
CN
China
Prior art keywords
acid
compound
temperature
group
hydrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380037544.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN104854117A (zh
Inventor
艾伯特·德沃
塞巴斯蒂安·伯克尔
帕特里克·诺特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Technology LLC
Original Assignee
Straitmark Holding AG
Monsanto Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Straitmark Holding AG, Monsanto Technology LLC filed Critical Straitmark Holding AG
Publication of CN104854117A publication Critical patent/CN104854117A/zh
Application granted granted Critical
Publication of CN104854117B publication Critical patent/CN104854117B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380037544.9A 2012-07-17 2013-07-17 用于合成n-膦酰基甲基亚氨基二乙酸的方法 Active CN104854117B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12176749.5 2012-07-17
EP12176749 2012-07-17
PCT/EP2013/065119 WO2014012986A1 (en) 2012-07-17 2013-07-17 Method for the synthesis of n-phosphonomethyliminodiacetic acid

Publications (2)

Publication Number Publication Date
CN104854117A CN104854117A (zh) 2015-08-19
CN104854117B true CN104854117B (zh) 2018-12-25

Family

ID=49162114

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380037544.9A Active CN104854117B (zh) 2012-07-17 2013-07-17 用于合成n-膦酰基甲基亚氨基二乙酸的方法

Country Status (7)

Country Link
US (1) US10364262B2 (https=)
EP (1) EP2875038A1 (https=)
CN (1) CN104854117B (https=)
BR (1) BR112015000988A2 (https=)
IN (1) IN2015DN01082A (https=)
RU (1) RU2015103314A (https=)
WO (1) WO2014012986A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN2015DN01082A (https=) 2012-07-17 2015-06-26 Straitmark Holding Ag
RU2694047C2 (ru) 2012-07-17 2019-07-09 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ синтеза аминоалкиленфосфоновой кислоты
US20150232493A1 (en) 2012-07-17 2015-08-20 Straitmark Holding Ag Method for the synthesis of alpha-aminoalkylenephosphonic acid
US9676799B2 (en) 2012-07-17 2017-06-13 Straitmark Holding Ag Method for the synthesis of N-(phosphonomethyl)glycine
CN113816994B (zh) * 2021-04-01 2022-05-27 南开大学 (1,1-二氰基-4-氧)-己基-3-氧化吲哚亚膦酸二乙酯及其衍生物的合成方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3796749A (en) * 1971-06-30 1974-03-12 W Michel Process for producing amino methylene phosphonic acids
EP0098034A2 (en) * 1982-06-25 1984-01-11 Geshuri Laboratories Ltd. A process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
CN1096290A (zh) * 1992-10-29 1994-12-14 汉普郡化学公司 转化羟甲基-亚氨二乙酸为磷酰甲基-亚氨二乙酸
CN102015737A (zh) * 2008-04-25 2011-04-13 斯特瑞马克控股公司 制造氨基亚烷基膦酸的方法

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH275435A (de) 1949-06-30 1951-05-31 Cilag Ag Verfahren zur Herstellung einer Phosphonsäure.
NL285361A (https=) 1961-11-13 1900-01-01
US3400148A (en) 1965-09-23 1968-09-03 Procter & Gamble Phosphonate compounds
GB1142294A (en) 1966-02-08 1969-02-05 Albright & Wilson Mfg Ltd Improvements in production of amino alkylene phosphonic acids
GB1230121A (https=) 1967-01-27 1971-04-28
US3455675A (en) 1968-06-25 1969-07-15 Monsanto Co Aminophosphonate herbicides
DE2013371B1 (de) * 1970-03-20 1971-11-04 Joh A , Benckiser GmbH, Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Amino methylenphosphonsauren
DE2017974A1 (de) 1970-04-15 1971-11-04 Joh. A. Benckiser Gmbh Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Aminoalkylenphosphonsäuren
US3799758A (en) 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions
US3969398A (en) 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
HU173170B (hu) 1974-06-27 1979-03-28 Chinoin Gyogyszer Es Vegyeszet Sposob poluchenija n-fosfonometil-glicina
US3927080A (en) 1974-09-03 1975-12-16 Monsanto Co Process for producing N-phosphonomethyl glycine
IL48619A (en) 1974-12-11 1978-04-30 Monsanto Co Process for the production of n-(phosphonomethyl)-glycine compounds
ES444490A1 (es) 1975-01-16 1977-09-16 Chinoin Gyogyszer Es Vegyeszet Procedimiento para la fabricacion de n-fosfono-metilglicina y sus intermedios.
CH647528A5 (fr) * 1978-10-27 1985-01-31 Bcap Biolog Chem Act Pat Procede pour la preparation de n-phosphonomethylglycine.
US4211547A (en) 1978-12-22 1980-07-08 Monsanto Company N-Phosphonomethyliminodiacetonitrile and certain derivatives thereof
DE3016289A1 (de) * 1980-04-28 1981-10-29 Henkel KGaA, 4000 Düsseldorf Verfahren zur herstellung von omega -amino-1-hydroxyalkyliden-1,1-bis-phosphonsaeuren
JPS5775990A (en) 1980-10-27 1982-05-12 Mitsubishi Gas Chem Co Inc Preparation of n,n,n',n'-tetra(phosphonomethyl) diaminoalkane
US4422982A (en) 1982-06-30 1983-12-27 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4400330A (en) * 1982-07-29 1983-08-23 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4654429A (en) 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
US4617415A (en) 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
GB2154588B (en) 1984-02-20 1987-10-07 Sunlead Chemical Industry Co L A process for preparation of n-phosphonomethyl glycine
US4724103A (en) 1984-02-27 1988-02-09 Monsanto Company Process for preparing N,N-diacetic acid aminomethylenephosphonic acid
US4624937A (en) 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4657705A (en) 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4804499A (en) 1985-09-23 1989-02-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
HU205944B (en) 1988-02-08 1992-07-28 Nitrokemia Ipartelepek Process for producing n-phosphono-methyl-imino-diacetic acid
HU200780B (en) 1988-02-08 1990-08-28 Nitrokemia Ipartelepek Process for producing n-phosphonomethyl iminodiacetic acid from double salt of iminodiacetic acid
RO101476A2 (ro) 1988-08-11 1991-12-09 Intreprinderea Textila, Timisoara, Judetul Timis, Ro Procedeu de obtinere a unor dialchil n,n-bis-(2-hidroxietil)-aminometilfosfonati
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
ES2018746A6 (es) 1989-12-21 1991-05-01 Aragonesas Energ & Ind Procedimiento para la obtencion del acido n,n-diaceticoaminometilenfosfonico.
DE4026026A1 (de) 1990-08-17 1992-02-20 Hoechst Ag Acylaminomethyl-phosphinsaeuren und verfahren zur herstellung von acylaminomethanphosphonsaeuren und acylaminomethyl-phosphinsaeuren
TW263511B (https=) * 1990-10-10 1995-11-21 Hoechst Ag
JP2525977B2 (ja) 1991-10-17 1996-08-21 昭和電工株式会社 N−アシルアミノメチルホスホン酸の製造法
GB9300641D0 (en) 1993-01-14 1993-03-03 Zeneca Ltd Process
US5312973A (en) 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9307235D0 (en) 1993-04-07 1993-06-02 Zeneca Ltd Process
DE4326887A1 (de) 1993-08-11 1995-02-16 Hoechst Ag Verfahren zur Herstellung von N-substituierten Aminoalkylenphosphonsäureestern
RO116964B1 (ro) 1995-06-07 2001-08-30 Monsanto Co Procedeu de preparare a acidului n-fosfonometiliminodiacetic
US5986128A (en) 1996-11-01 1999-11-16 Monsanto Company Use of monosodium iminodiacetic acid solutions in the preparation of N-phosphonomethyliminodiacetic acid
AU740288B2 (en) 1997-02-13 2001-11-01 Monsanto Company Method of preparing amino carboxylic acids
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
AU754281B2 (en) 1998-08-12 2002-11-14 Monsanto Company Continuous process for the preparation of N-(phosphonomethyl) iminodiacetic acid
US6118022A (en) 1998-09-08 2000-09-12 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
DE19909200C1 (de) 1999-03-03 2000-03-09 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-Phosphonomethyliminodiessigsäure
DE19914375A1 (de) 1999-03-30 2000-10-05 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-Phosphonomethyliminodiessigsäure
JP3655135B2 (ja) 1999-08-23 2005-06-02 株式会社東芝 スイッチ装置
DE10019879A1 (de) 2000-04-20 2001-10-25 Degussa Verfahren zur Herstellung von 2,5-Diketopiperazinen, neue 2,5-Diketopiperazine und deren Verwendung
WO2001092208A1 (en) 2000-06-01 2001-12-06 Monsanto Technology Llc Metal-catalysed carboxymethylation in the presence of a promoter
ES2225764T3 (es) 2001-01-12 2005-03-16 Basf Aktiengesellschaft Procedimiento para obtencion de acido n-fosfono-metiliminodiacetico.
CN1285600C (zh) 2004-11-25 2006-11-22 浙江新安化工集团股份有限公司 一种草甘膦制剂及其制备方法
EP1681295A1 (en) 2005-01-17 2006-07-19 Solutia Europe N.V./S.A. Process for the manufacture of aminoakylenephosphonic acid compounds in the presence of a heterogeneous catalyst
EP1681294A1 (en) 2005-01-17 2006-07-19 Solutia Europe N.V./S.A. Process for the manufacture of aminopolyalkylene-phosphonic acid compounds
AR057271A1 (es) 2005-04-01 2007-11-28 Monsanto Technology Llc Control de la conversion de acido n-(fosfonometil)iminodiacetico en la elaboracion de glifosato
JP2007022956A (ja) 2005-07-15 2007-02-01 Mitsubishi Gas Chem Co Inc 高純度アミノメチレンホスホン酸の製造方法
CL2008003539A1 (es) 2007-11-28 2009-07-03 Procedimiento para la produccion de p4o6 que comprende mezclar o2 o una mezcla de o2 mas un gas inerte y fosforo en donde el producto obtenido se mantiene dentro de una unidad de reaccion a una temperatura entre los 1600 y 2000 k durante por lo menos 1 segundo.
EP2112156A1 (en) 2008-04-25 2009-10-28 Thermphos International B.V. Method for the Manufacture of Aminoalkylene Phosphonic Acid
KR101361345B1 (ko) 2008-11-12 2014-02-10 스트라이트마르크 홀딩 아게 P4o6을 고수율로 제조하는 방법
MX2011012593A (es) 2009-05-28 2012-04-19 Metodo para la fabricacion de acidos fosfonoalquiliminodiaceticos.
ES2533799T3 (es) * 2009-10-02 2015-04-14 Straitmark Holding Ag Procedimiento de fabricación de ácidos aminohidroxi difosfónicos
US9315528B2 (en) 2009-10-27 2016-04-19 Straitmark Holding Ag Method for the manufacture of phosphonoalkyl iminodiacetic acid
US10240912B2 (en) 2012-06-13 2019-03-26 Koninklijke Philips N.V. Determining a propagation velocity for a surface wave
IN2015DN01078A (https=) 2012-07-17 2015-06-26 Straitmark Holding Ag
US20150232493A1 (en) * 2012-07-17 2015-08-20 Straitmark Holding Ag Method for the synthesis of alpha-aminoalkylenephosphonic acid
IN2015DN01082A (https=) 2012-07-17 2015-06-26 Straitmark Holding Ag

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3796749A (en) * 1971-06-30 1974-03-12 W Michel Process for producing amino methylene phosphonic acids
EP0098034A2 (en) * 1982-06-25 1984-01-11 Geshuri Laboratories Ltd. A process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
CN1096290A (zh) * 1992-10-29 1994-12-14 汉普郡化学公司 转化羟甲基-亚氨二乙酸为磷酰甲基-亚氨二乙酸
CN102015737A (zh) * 2008-04-25 2011-04-13 斯特瑞马克控股公司 制造氨基亚烷基膦酸的方法

Also Published As

Publication number Publication date
IN2015DN01082A (https=) 2015-06-26
US10364262B2 (en) 2019-07-30
US20150166584A1 (en) 2015-06-18
EP2875038A1 (en) 2015-05-27
RU2015103314A (ru) 2016-09-10
CN104854117A (zh) 2015-08-19
WO2014012986A1 (en) 2014-01-23
BR112015000988A2 (pt) 2017-06-27

Similar Documents

Publication Publication Date Title
CN104854117B (zh) 用于合成n-膦酰基甲基亚氨基二乙酸的方法
US10464958B2 (en) Method for the synthesis of alpha-aminoalkylenephosphonic acid
US6600068B2 (en) Process for preparing ethanebis(methylphosphinic) acid
RU2674023C9 (ru) Способ синтеза n-(фосфонометил)глицина
CN104812764B (zh) 用于合成n‑(膦酰基甲基)甘氨酸的方法
US20140303394A1 (en) Synthesis of H-Phosphonate Intermediates and Their Use in Preparing the Herbicide Glyphosate
KR101178142B1 (ko) 알코올성 하이드록시기를 가지는 포스포네이트의 제조방법
JP2000355597A (ja) アルキル亜ホスホン酸の(金属)塩の製造方法ii
CN102448973A (zh) 用于制备二烷基亚磷酸盐的方法
CN104812766B (zh) 用于合成氨基亚烷基膦酸的方法
SE424639B (sv) Sett att framstella fosforhaltiga estrar
JP2007039357A (ja) 有機ホスフィン酸ハライドの製造方法

Legal Events

Date Code Title Description
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20180723

Address after: American Missouri

Applicant after: Monsanto Technology Co.

Address before: Swiss Swiss

Applicant before: Sterrett mark controls interest stock company

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant