CN104812764B - 用于合成n‑(膦酰基甲基)甘氨酸的方法 - Google Patents

用于合成n‑(膦酰基甲基)甘氨酸的方法 Download PDF

Info

Publication number
CN104812764B
CN104812764B CN201380037316.1A CN201380037316A CN104812764B CN 104812764 B CN104812764 B CN 104812764B CN 201380037316 A CN201380037316 A CN 201380037316A CN 104812764 B CN104812764 B CN 104812764B
Authority
CN
China
Prior art keywords
acid
methods according
compound
diketopiperazine
diketopiperazines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380037316.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN104812764A (zh
Inventor
塞巴斯蒂安·伯克尔
弗雷德里克·布鲁尼尔
帕特里克·诺特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Technology LLC
Original Assignee
Straitmark Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Straitmark Holding AG filed Critical Straitmark Holding AG
Publication of CN104812764A publication Critical patent/CN104812764A/zh
Application granted granted Critical
Publication of CN104812764B publication Critical patent/CN104812764B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00Preparation of nitrogen-containing organic compounds
    • C12P13/04Alpha- or beta- amino acids

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Genetics & Genomics (AREA)
  • General Engineering & Computer Science (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380037316.1A 2012-07-17 2013-07-17 用于合成n‑(膦酰基甲基)甘氨酸的方法 Active CN104812764B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12176756.0 2012-07-17
EP12176756 2012-07-17
PCT/EP2013/065125 WO2014012991A1 (en) 2012-07-17 2013-07-17 Method for the synthesis of n-(phosphonomethyl)glycine

Publications (2)

Publication Number Publication Date
CN104812764A CN104812764A (zh) 2015-07-29
CN104812764B true CN104812764B (zh) 2017-06-09

Family

ID=49034052

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380037316.1A Active CN104812764B (zh) 2012-07-17 2013-07-17 用于合成n‑(膦酰基甲基)甘氨酸的方法

Country Status (9)

Country Link
US (1) US9676799B2 (enExample)
EP (1) EP2875037B1 (enExample)
CN (1) CN104812764B (enExample)
BR (1) BR112015000995B1 (enExample)
ES (1) ES2609488T3 (enExample)
IN (1) IN2015DN01080A (enExample)
PL (1) PL2875037T3 (enExample)
RU (1) RU2674021C9 (enExample)
WO (1) WO2014012991A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113457654B (zh) * 2021-06-02 2023-06-09 江西省科学院应用化学研究所 一种碳基固体酸催化剂及其制备方法、使用方法
CN114031637B (zh) * 2021-11-05 2024-06-11 安徽东至广信农化有限公司 一种草甘膦连续水解的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH620223A5 (en) * 1975-01-16 1980-11-14 Chinoin Gyogyszer Es Vegyeszet Process for the preparation of N-phosphonomethylglycine
US4400330A (en) * 1982-07-29 1983-08-23 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4804499A (en) * 1985-09-23 1989-02-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
CN1239473A (zh) * 1997-02-13 1999-12-22 孟山都公司 制备氨基羧酸的方法
CN102015737A (zh) * 2008-04-25 2011-04-13 斯特瑞马克控股公司 制造氨基亚烷基膦酸的方法
CN102448974A (zh) * 2009-05-28 2012-05-09 施里特马克控股公司 制备膦酰基烷基亚氨基二乙酸的方法

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH275435A (de) 1949-06-30 1951-05-31 Cilag Ag Verfahren zur Herstellung einer Phosphonsäure.
NL285361A (enExample) 1961-11-13 1900-01-01
US3400148A (en) 1965-09-23 1968-09-03 Procter & Gamble Phosphonate compounds
GB1142294A (en) 1966-02-08 1969-02-05 Albright & Wilson Mfg Ltd Improvements in production of amino alkylene phosphonic acids
GB1230121A (enExample) 1967-01-27 1971-04-28
US3455675A (en) 1968-06-25 1969-07-15 Monsanto Co Aminophosphonate herbicides
DE2132511C3 (de) 1971-06-30 1974-06-27 Joh. A. Benckiser Gmbh, 6700 Ludwigshafen Verfahren zur Herstellung von Aminomethylenphosphonsäuren
DE2013371B1 (de) 1970-03-20 1971-11-04 Joh A , Benckiser GmbH, Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Amino methylenphosphonsauren
DE2017974A1 (de) 1970-04-15 1971-11-04 Joh. A. Benckiser Gmbh Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Aminoalkylenphosphonsäuren
US3799758A (en) 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions
US3969398A (en) 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
HU173170B (hu) 1974-06-27 1979-03-28 Chinoin Gyogyszer Es Vegyeszet Sposob poluchenija n-fosfonometil-glicina
US3927080A (en) 1974-09-03 1975-12-16 Monsanto Co Process for producing N-phosphonomethyl glycine
IL48619A (en) 1974-12-11 1978-04-30 Monsanto Co Process for the production of n-(phosphonomethyl)-glycine compounds
CH647528A5 (fr) 1978-10-27 1985-01-31 Bcap Biolog Chem Act Pat Procede pour la preparation de n-phosphonomethylglycine.
US4211547A (en) 1978-12-22 1980-07-08 Monsanto Company N-Phosphonomethyliminodiacetonitrile and certain derivatives thereof
JPS5775990A (en) 1980-10-27 1982-05-12 Mitsubishi Gas Chem Co Inc Preparation of n,n,n',n'-tetra(phosphonomethyl) diaminoalkane
US4422982A (en) 1982-06-30 1983-12-27 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4617415A (en) 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
US4654429A (en) 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
GB2154588B (en) 1984-02-20 1987-10-07 Sunlead Chemical Industry Co L A process for preparation of n-phosphonomethyl glycine
US4724103A (en) 1984-02-27 1988-02-09 Monsanto Company Process for preparing N,N-diacetic acid aminomethylenephosphonic acid
US4624937A (en) 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US4657705A (en) 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
HU200780B (en) 1988-02-08 1990-08-28 Nitrokemia Ipartelepek Process for producing n-phosphonomethyl iminodiacetic acid from double salt of iminodiacetic acid
HU205944B (en) 1988-02-08 1992-07-28 Nitrokemia Ipartelepek Process for producing n-phosphono-methyl-imino-diacetic acid
RO101476A2 (ro) 1988-08-11 1991-12-09 Intreprinderea Textila, Timisoara, Judetul Timis, Ro Procedeu de obtinere a unor dialchil n,n-bis-(2-hidroxietil)-aminometilfosfonati
ES2018746A6 (es) 1989-12-21 1991-05-01 Aragonesas Energ & Ind Procedimiento para la obtencion del acido n,n-diaceticoaminometilenfosfonico.
DE4026026A1 (de) 1990-08-17 1992-02-20 Hoechst Ag Acylaminomethyl-phosphinsaeuren und verfahren zur herstellung von acylaminomethanphosphonsaeuren und acylaminomethyl-phosphinsaeuren
TW263511B (enExample) 1990-10-10 1995-11-21 Hoechst Ag
JP2525977B2 (ja) 1991-10-17 1996-08-21 昭和電工株式会社 N−アシルアミノメチルホスホン酸の製造法
US5312972A (en) 1992-10-29 1994-05-17 Hampshire Chemical Corp. Conversion of hydroxymethyl-iminodiacetic acid to phosphonomethyl-iminodiacetic acid
GB9300641D0 (en) 1993-01-14 1993-03-03 Zeneca Ltd Process
US5312973A (en) 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9307235D0 (en) 1993-04-07 1993-06-02 Zeneca Ltd Process
DE4326887A1 (de) 1993-08-11 1995-02-16 Hoechst Ag Verfahren zur Herstellung von N-substituierten Aminoalkylenphosphonsäureestern
EP0833831B1 (en) 1995-06-07 2002-02-13 Monsanto Technology LLC Process for preparing n-phosphonomethyliminodiacetic acid
US5986128A (en) 1996-11-01 1999-11-16 Monsanto Company Use of monosodium iminodiacetic acid solutions in the preparation of N-phosphonomethyliminodiacetic acid
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
CA2339839A1 (en) 1998-08-12 2000-02-24 Monsanto Company Continuous process for the preparation of n-(phosphonomethyl) iminodiacetic acid
US6118022A (en) 1998-09-08 2000-09-12 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
DE19909200C1 (de) 1999-03-03 2000-03-09 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-Phosphonomethyliminodiessigsäure
DE19914375A1 (de) 1999-03-30 2000-10-05 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-Phosphonomethyliminodiessigsäure
JP3655135B2 (ja) 1999-08-23 2005-06-02 株式会社東芝 スイッチ装置
DE10019879A1 (de) 2000-04-20 2001-10-25 Degussa Verfahren zur Herstellung von 2,5-Diketopiperazinen, neue 2,5-Diketopiperazine und deren Verwendung
AU2001275182A1 (en) 2000-06-01 2001-12-11 Monsanto Technology Llc Metal-catalysed carboxymethylation in the presence of a promoter
AR032096A1 (es) 2001-01-12 2003-10-22 Basf Ag Procedimiento para elaborar acido n-fosfonometilimino-diacetico
CN1285600C (zh) 2004-11-25 2006-11-22 浙江新安化工集团股份有限公司 一种草甘膦制剂及其制备方法
EP1681294A1 (en) 2005-01-17 2006-07-19 Solutia Europe N.V./S.A. Process for the manufacture of aminopolyalkylene-phosphonic acid compounds
EP1681295A1 (en) 2005-01-17 2006-07-19 Solutia Europe N.V./S.A. Process for the manufacture of aminoakylenephosphonic acid compounds in the presence of a heterogeneous catalyst
US7799571B2 (en) 2005-04-01 2010-09-21 Monsanto Technology Llc Control of N-(phosphonomethyl)iminodiacetic acid conversion in manufacture of glyphosate
JP2007022956A (ja) 2005-07-15 2007-02-01 Mitsubishi Gas Chem Co Inc 高純度アミノメチレンホスホン酸の製造方法
CL2008003539A1 (es) 2007-11-28 2009-07-03 Procedimiento para la produccion de p4o6 que comprende mezclar o2 o una mezcla de o2 mas un gas inerte y fosforo en donde el producto obtenido se mantiene dentro de una unidad de reaccion a una temperatura entre los 1600 y 2000 k durante por lo menos 1 segundo.
EP2112156A1 (en) 2008-04-25 2009-10-28 Thermphos International B.V. Method for the Manufacture of Aminoalkylene Phosphonic Acid
MX2011004915A (es) 2008-11-12 2011-05-30 Willem J Schipper Proceso para la fabricacion de p4o6 con rendimiento elevado.
CN102639545B (zh) 2009-10-02 2016-08-03 施里特马克控股公司 制备氨基羟基二膦酸的方法
JP5687280B2 (ja) 2009-10-27 2015-03-18 ストレイトマーク・ホールディング・アーゲー ホスホノアルキルイミノ二酢酸の製造のための方法
EP2861935B1 (en) 2012-06-13 2016-02-10 Koninklijke Philips N.V. Determining a propagation velocity for a surface wave
RU2015103314A (ru) 2012-07-17 2016-09-10 Страйтмарк Холдинг Аг Способ синтеза N-фосфонометилиминодиуксусной кислоты
BR112015000966B1 (pt) 2012-07-17 2020-04-28 Monsanto Technology Llc método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato
EP2875035A1 (en) 2012-07-17 2015-05-27 Straitmark Holding AG Method for the synthesis of alpha-aminoalkylenephosphonic acid

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH620223A5 (en) * 1975-01-16 1980-11-14 Chinoin Gyogyszer Es Vegyeszet Process for the preparation of N-phosphonomethylglycine
US4400330A (en) * 1982-07-29 1983-08-23 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
US4804499A (en) * 1985-09-23 1989-02-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
CN1239473A (zh) * 1997-02-13 1999-12-22 孟山都公司 制备氨基羧酸的方法
CN102015737A (zh) * 2008-04-25 2011-04-13 斯特瑞马克控股公司 制造氨基亚烷基膦酸的方法
CN102448974A (zh) * 2009-05-28 2012-05-09 施里特马克控股公司 制备膦酰基烷基亚氨基二乙酸的方法

Also Published As

Publication number Publication date
PL2875037T4 (pl) 2017-06-30
BR112015000995B1 (pt) 2020-04-28
EP2875037B1 (en) 2016-09-07
WO2014012991A1 (en) 2014-01-23
BR112015000995A2 (pt) 2017-06-27
ES2609488T3 (es) 2017-04-20
PL2875037T3 (pl) 2017-06-30
RU2674021C2 (ru) 2018-12-04
EP2875037A1 (en) 2015-05-27
CN104812764A (zh) 2015-07-29
IN2015DN01080A (enExample) 2015-06-26
US9676799B2 (en) 2017-06-13
US20150175636A1 (en) 2015-06-25
RU2674021C9 (ru) 2019-01-24
RU2015103310A (ru) 2016-09-20

Similar Documents

Publication Publication Date Title
SU1282820A3 (ru) Способ получени @ -фосфонометилглицина
US20090137808A1 (en) Process for manufacturing bisphosphonic acids
CN104812763B (zh) 用于合成n-(膦酰基甲基)甘氨酸的方法
CN104812765B (zh) 用于合成α‑氨基亚烷基膦酸的方法
US10364262B2 (en) Method for the synthesis of N-phosphonomethyliminodiacetic acid
CN104812764B (zh) 用于合成n‑(膦酰基甲基)甘氨酸的方法
KR20000053014A (ko) 엔-포스포노메틸 이미노디아세트산의 제조시 모노소듐 이미노디아세트산 용액의 사용
EP0097522B1 (en) Preparation of n-phosphonomethylglycine
JP3547441B2 (ja) 製法
MXPA02006081A (es) Metodo y produccion de n-fosfonometilglicina.
CN100360546C (zh) 氯甲基膦酸单钠盐的一锅法制备工艺
EP0104775A1 (en) Production of N-phosphonomethylglycine
US4569802A (en) Method for preparation of N-phosphonomethylglycine
US10280189B2 (en) Method for the synthesis of aminoalkylenephosphonic acid
SE424639B (sv) Sett att framstella fosforhaltiga estrar
CS195418B1 (cs) Způsob výroby N-fosfonometylglycinu

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20180723

Address after: American Missouri

Patentee after: Monsanto Technology Co.

Address before: Swiss Swiss

Patentee before: Sterrett mark controls interest stock company

TR01 Transfer of patent right