CN104725428A - 三聚氰胺改性聚氨基环三磷腈及其制备方法 - Google Patents
三聚氰胺改性聚氨基环三磷腈及其制备方法 Download PDFInfo
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- CN104725428A CN104725428A CN201410536145.3A CN201410536145A CN104725428A CN 104725428 A CN104725428 A CN 104725428A CN 201410536145 A CN201410536145 A CN 201410536145A CN 104725428 A CN104725428 A CN 104725428A
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- phosphonitrile
- polycondensation
- hexachlorocyclotriphosphazene
- amino ring
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- DZKXDEWNLDOXQH-UHFFFAOYSA-N 1,3,5,2,4,6-triazatriphosphinine Chemical compound N1=PN=PN=P1 DZKXDEWNLDOXQH-UHFFFAOYSA-N 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000003063 flame retardant Substances 0.000 claims abstract description 53
- UBIJTWDKTYCPMQ-UHFFFAOYSA-N hexachlorophosphazene Chemical compound ClP1(Cl)=NP(Cl)(Cl)=NP(Cl)(Cl)=N1 UBIJTWDKTYCPMQ-UHFFFAOYSA-N 0.000 claims abstract description 27
- -1 phosphonitrile compound Chemical class 0.000 claims abstract description 6
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- 238000006068 polycondensation reaction Methods 0.000 claims description 53
- 239000000203 mixture Substances 0.000 claims description 43
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 42
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 41
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 35
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- 229910021529 ammonia Inorganic materials 0.000 claims description 13
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- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 claims description 3
- 238000006482 condensation reaction Methods 0.000 claims 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 23
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 19
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- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 5
- 0 CCP(*)(*=P(*C(C)(C)C)(N=P(*)(N)Cl)Cl)Cl Chemical compound CCP(*)(*=P(*C(C)(C)C)(N=P(*)(N)Cl)Cl)Cl 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical group [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
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- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 3
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- SNUILLZYFZLHJG-UHFFFAOYSA-N CN/C(/N)=N/P(C)(N)=N Chemical compound CN/C(/N)=N/P(C)(N)=N SNUILLZYFZLHJG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
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- BNBQRQQYDMDJAH-UHFFFAOYSA-N benzodioxan Chemical compound C1=CC=C2OCCOC2=C1 BNBQRQQYDMDJAH-UHFFFAOYSA-N 0.000 description 1
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105348539A (zh) * | 2015-12-17 | 2016-02-24 | 西北师范大学 | 一种有机磷氮无卤阻燃剂及其制备和应用 |
CN106633082A (zh) * | 2016-12-31 | 2017-05-10 | 华南理工大学 | 一种基于环三磷腈的大分子氮、磷膨胀阻燃剂及其制备方法 |
CN106700005A (zh) * | 2016-12-08 | 2017-05-24 | 湘潭大学 | 基于环三磷腈的有机微孔聚合物及其制备方法和应用 |
CN107344951A (zh) * | 2016-05-04 | 2017-11-14 | 青岛科技大学 | 苯基改性聚氨基环三磷腈及其制备方法 |
CN107344997A (zh) * | 2016-05-04 | 2017-11-14 | 青岛科技大学 | 苯氧基改性聚氨基环三磷腈及其制备方法 |
CN108250650A (zh) * | 2018-01-25 | 2018-07-06 | 陈昭 | 一种抗菌性hips塑料 |
CN109651589A (zh) * | 2018-12-13 | 2019-04-19 | 江南大学 | 一种含n、p阻燃水性聚氨酯的制备方法 |
CN111363154A (zh) * | 2020-03-09 | 2020-07-03 | 南华大学上虞高等研究院有限公司 | 一种含有氨基的聚磷腈微球的制备方法、应用及脱色方法 |
CN111378285A (zh) * | 2020-04-30 | 2020-07-07 | 新纳奇材料科技江苏有限公司 | 一种高强度高阻燃有机硅泡沫材料及其制备方法 |
CN111410736A (zh) * | 2020-05-06 | 2020-07-14 | 山东迈特新材料科技有限公司 | 一种赛克聚酯衍生物及其制备方法 |
CN114932601A (zh) * | 2022-05-27 | 2022-08-23 | 江苏零界智能家居有限公司 | 一种环保防潮的实木板材及其制备工艺 |
CN115627656A (zh) * | 2022-10-12 | 2023-01-20 | 江苏中凯纸业有限公司 | 高强度阻燃纱管纸及其制备方法 |
Citations (2)
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US3412045A (en) * | 1959-12-24 | 1968-11-19 | Hughes Aircraft Co | Plastic reaction products of a phosphonitrilic halide and a polyamine |
CN103992481A (zh) * | 2014-05-09 | 2014-08-20 | 苏州安鸿泰新材料有限公司 | 一种超支化聚磷腈阻燃成炭剂及其制备方法 |
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2014
- 2014-10-12 CN CN201410536145.3A patent/CN104725428B/zh active Active
Patent Citations (2)
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US3412045A (en) * | 1959-12-24 | 1968-11-19 | Hughes Aircraft Co | Plastic reaction products of a phosphonitrilic halide and a polyamine |
CN103992481A (zh) * | 2014-05-09 | 2014-08-20 | 苏州安鸿泰新材料有限公司 | 一种超支化聚磷腈阻燃成炭剂及其制备方法 |
Non-Patent Citations (1)
Title |
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朱红伟 等: ""聚氨基环磷腈的合成及其在PVA纤维中的应用"", 《合成纤维工业》 * |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105348539A (zh) * | 2015-12-17 | 2016-02-24 | 西北师范大学 | 一种有机磷氮无卤阻燃剂及其制备和应用 |
CN107344997B (zh) * | 2016-05-04 | 2020-06-09 | 青岛科技大学 | 苯氧基改性聚氨基环三磷腈及其制备方法 |
CN107344951A (zh) * | 2016-05-04 | 2017-11-14 | 青岛科技大学 | 苯基改性聚氨基环三磷腈及其制备方法 |
CN107344997A (zh) * | 2016-05-04 | 2017-11-14 | 青岛科技大学 | 苯氧基改性聚氨基环三磷腈及其制备方法 |
CN106700005B (zh) * | 2016-12-08 | 2019-01-25 | 湘潭大学 | 用于气体吸附的基于环三磷腈的有机微孔聚合物及其制备方法和应用 |
CN106700005A (zh) * | 2016-12-08 | 2017-05-24 | 湘潭大学 | 基于环三磷腈的有机微孔聚合物及其制备方法和应用 |
CN106633082B (zh) * | 2016-12-31 | 2019-08-20 | 华南理工大学 | 一种基于环三磷腈的大分子氮、磷膨胀阻燃剂及其制备方法 |
CN106633082A (zh) * | 2016-12-31 | 2017-05-10 | 华南理工大学 | 一种基于环三磷腈的大分子氮、磷膨胀阻燃剂及其制备方法 |
CN108250650A (zh) * | 2018-01-25 | 2018-07-06 | 陈昭 | 一种抗菌性hips塑料 |
CN109651589A (zh) * | 2018-12-13 | 2019-04-19 | 江南大学 | 一种含n、p阻燃水性聚氨酯的制备方法 |
CN109651589B (zh) * | 2018-12-13 | 2021-02-09 | 江南大学 | 一种含n、p阻燃水性聚氨酯的制备方法 |
CN111363154A (zh) * | 2020-03-09 | 2020-07-03 | 南华大学上虞高等研究院有限公司 | 一种含有氨基的聚磷腈微球的制备方法、应用及脱色方法 |
CN111378285A (zh) * | 2020-04-30 | 2020-07-07 | 新纳奇材料科技江苏有限公司 | 一种高强度高阻燃有机硅泡沫材料及其制备方法 |
CN111410736A (zh) * | 2020-05-06 | 2020-07-14 | 山东迈特新材料科技有限公司 | 一种赛克聚酯衍生物及其制备方法 |
CN111410736B (zh) * | 2020-05-06 | 2022-02-18 | 山东迈特新材料科技有限公司 | 一种赛克聚酯衍生物及其制备方法 |
CN114932601A (zh) * | 2022-05-27 | 2022-08-23 | 江苏零界智能家居有限公司 | 一种环保防潮的实木板材及其制备工艺 |
CN115627656A (zh) * | 2022-10-12 | 2023-01-20 | 江苏中凯纸业有限公司 | 高强度阻燃纱管纸及其制备方法 |
CN115627656B (zh) * | 2022-10-12 | 2023-08-18 | 江苏中凯纸业有限公司 | 高强度阻燃纱管纸及其制备方法 |
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