CN104667904A - 催化剂及其制备方法和果糖的制备方法 - Google Patents
催化剂及其制备方法和果糖的制备方法 Download PDFInfo
- Publication number
- CN104667904A CN104667904A CN201510067512.4A CN201510067512A CN104667904A CN 104667904 A CN104667904 A CN 104667904A CN 201510067512 A CN201510067512 A CN 201510067512A CN 104667904 A CN104667904 A CN 104667904A
- Authority
- CN
- China
- Prior art keywords
- catalyst
- preparation
- fructose
- attapulgite clay
- metal oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 66
- 229930091371 Fructose Natural products 0.000 title claims abstract description 65
- 239000005715 Fructose Substances 0.000 title claims abstract description 65
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 47
- 239000008103 glucose Substances 0.000 claims abstract description 47
- 239000004927 clay Substances 0.000 claims abstract description 37
- 229960000892 attapulgite Drugs 0.000 claims abstract description 36
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 36
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 32
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 32
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 26
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 11
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 25
- 238000001994 activation Methods 0.000 claims description 13
- 229910001960 metal nitrate Inorganic materials 0.000 claims description 11
- GJKFIJKSBFYMQK-UHFFFAOYSA-N lanthanum(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GJKFIJKSBFYMQK-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000001354 calcination Methods 0.000 claims description 6
- 238000006317 isomerization reaction Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000007725 thermal activation Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 238000003672 processing method Methods 0.000 claims description 4
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 238000006555 catalytic reaction Methods 0.000 abstract description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 2
- 229940010698 activated attapulgite Drugs 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 5
- 108700040099 Xylose isomerases Proteins 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910003023 Mg-Al Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229960001545 hydrotalcite Drugs 0.000 description 3
- 229910001701 hydrotalcite Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- PJVXUVWGSCCGHT-ZPYZYFCMSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3s,4r,5r)-1,3,4,5,6-pentahydroxyhexan-2-one Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO PJVXUVWGSCCGHT-ZPYZYFCMSA-N 0.000 description 1
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 1
- NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 108010051210 beta-Fructofuranosidase Proteins 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000012970 cakes Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 1
- CQGVSILDZJUINE-UHFFFAOYSA-N cerium;hydrate Chemical compound O.[Ce] CQGVSILDZJUINE-UHFFFAOYSA-N 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000021433 fructose syrup Nutrition 0.000 description 1
- 150000002303 glucose derivatives Chemical class 0.000 description 1
- 230000009229 glucose formation Effects 0.000 description 1
- 235000019534 high fructose corn syrup Nutrition 0.000 description 1
- RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 description 1
- 235000011073 invertase Nutrition 0.000 description 1
- 239000001573 invertase Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Catalysts (AREA)
Abstract
Description
编号 | 葡萄糖转化率(%) | 果糖选择性(%) | 果糖产率(%) |
F1 | 39.9 | 77.1 | 30.8 |
F2 | 45.9 | 79.0 | 36.3 |
F3 | 42.8 | 72.1 | 30.9 |
F4 | 46.1 | 75.7 | 34.9 |
F5 | 52.4 | 48.1 | 25.2 |
D1 | 17.9 | 22.7 | 4.1 |
D2 | 29.6 | 46.8 | 13.9 |
D3 | 26.4 | 77.9 | 20.6 |
D4 | 31.7 | 61.5 | 19.5 |
D5 | 27.5 | 13.2 | 3.6 |
D6 | 7.5 | 29.6 | 2.2 |
D7 | 36.7 | 43.6 | 16.1 |
D8 | 10.9 | 18.7 | 2.1 |
D9 | 6.7 | 30.6 | 2.1 |
D10 | 30.1 | 40.5 | 12.2 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510067512.4A CN104667904B (zh) | 2015-02-09 | 2015-02-09 | 果糖的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510067512.4A CN104667904B (zh) | 2015-02-09 | 2015-02-09 | 果糖的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104667904A true CN104667904A (zh) | 2015-06-03 |
CN104667904B CN104667904B (zh) | 2017-11-07 |
Family
ID=53303803
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510067512.4A Active CN104667904B (zh) | 2015-02-09 | 2015-02-09 | 果糖的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104667904B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106492874A (zh) * | 2016-09-06 | 2017-03-15 | 安徽理工大学 | 一种制备5‑羟甲基糠醛高效催化剂的配方及应用条件 |
CN109020672A (zh) * | 2018-09-23 | 2018-12-18 | 安徽乐农环保科技有限公司 | 绿色土壤修复方法 |
CN111253449A (zh) * | 2018-11-30 | 2020-06-09 | 中国石油化工股份有限公司 | 一种制备果糖的方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4008124A (en) * | 1974-06-26 | 1977-02-15 | Mitsubishi Chemical Industries Ltd. | Process for the isomerization of glucose into fructose |
CN102600821A (zh) * | 2012-03-14 | 2012-07-25 | 淮阴工学院 | 二氧化钛/凹凸棒石粘土光催化剂的制备方法及负载光催化剂的涂料 |
CN102872716A (zh) * | 2012-10-17 | 2013-01-16 | 安徽理工大学 | 一种低温等离子体协同催化剂脱除NOx的处理装置及其处理方法 |
WO2013030132A1 (fr) * | 2011-08-26 | 2013-03-07 | Centre National De La Recherche Scientifique (C.N.R.S) | Procede d'isomerisation du glucose en fructose |
CN103143346A (zh) * | 2013-03-12 | 2013-06-12 | 合肥工业大学 | 一种具有抗硫性的低温scr脱硝催化剂及其制备方法 |
CN103769116A (zh) * | 2012-10-20 | 2014-05-07 | 中国石油化工股份有限公司 | 耐硫变换催化剂及制备方法 |
-
2015
- 2015-02-09 CN CN201510067512.4A patent/CN104667904B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4008124A (en) * | 1974-06-26 | 1977-02-15 | Mitsubishi Chemical Industries Ltd. | Process for the isomerization of glucose into fructose |
WO2013030132A1 (fr) * | 2011-08-26 | 2013-03-07 | Centre National De La Recherche Scientifique (C.N.R.S) | Procede d'isomerisation du glucose en fructose |
CN102600821A (zh) * | 2012-03-14 | 2012-07-25 | 淮阴工学院 | 二氧化钛/凹凸棒石粘土光催化剂的制备方法及负载光催化剂的涂料 |
CN102872716A (zh) * | 2012-10-17 | 2013-01-16 | 安徽理工大学 | 一种低温等离子体协同催化剂脱除NOx的处理装置及其处理方法 |
CN103769116A (zh) * | 2012-10-20 | 2014-05-07 | 中国石油化工股份有限公司 | 耐硫变换催化剂及制备方法 |
CN103143346A (zh) * | 2013-03-12 | 2013-06-12 | 合肥工业大学 | 一种具有抗硫性的低温scr脱硝催化剂及其制备方法 |
Non-Patent Citations (2)
Title |
---|
罗平等: ""La-Ce-attapulgite催化分解NO的研究"", 《环境工程学报》 * |
荣峻峰等: ""改性粘土用于制备乙烯聚合催化剂的研究"", 《合成树脂及塑料》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106492874A (zh) * | 2016-09-06 | 2017-03-15 | 安徽理工大学 | 一种制备5‑羟甲基糠醛高效催化剂的配方及应用条件 |
CN109020672A (zh) * | 2018-09-23 | 2018-12-18 | 安徽乐农环保科技有限公司 | 绿色土壤修复方法 |
CN111253449A (zh) * | 2018-11-30 | 2020-06-09 | 中国石油化工股份有限公司 | 一种制备果糖的方法 |
CN111253449B (zh) * | 2018-11-30 | 2023-03-10 | 中国石油化工股份有限公司 | 一种制备果糖的方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104667904B (zh) | 2017-11-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107365287B (zh) | 一种合成2,5-呋喃二甲酸的方法 | |
CN105727930B (zh) | 一种用于丙烷脱氢制丙烯的催化剂及其制备方法与应用 | |
CN103638956A (zh) | 一种三聚甲醛或多聚甲醛和醋酸及醋酸水溶液合成丙烯酸甲酯的催化剂及其制备和应用方法 | |
CN104667904A (zh) | 催化剂及其制备方法和果糖的制备方法 | |
CN105126930B (zh) | 一种催化剂载体的制备方法及其在氯化氢催化氧化中的应用 | |
CN101966460B (zh) | 用于合成碳酸二甲酯的负载型催化剂的使用方法 | |
CN101265180B (zh) | 制取乳酸的方法 | |
CN109289831A (zh) | 具有高抗积碳性的丙烷脱氢制丙烯的催化剂及其制备方法 | |
CN102807244A (zh) | 一种制备一水软铝石的方法 | |
CN105056990B (zh) | 丙烷脱氢制丙烯催化剂及其制备方法 | |
CN103664634A (zh) | 用于1,2-丙二胺制备的负载型催化剂 | |
CN103159243A (zh) | 用普通含铝化合物生产活性氧化铝的方法 | |
CN104549224B (zh) | 不饱和腈催化剂及其制备方法 | |
CN106378131B (zh) | 一种尿素醇解法合成碳酸酯的催化剂及其制备方法 | |
CN106563492B (zh) | 一种氧化钛改性微孔分子筛择形催化剂在合成对二甲苯中的应用 | |
CN109336760A (zh) | 金属掺杂SnO2酸碱两性纳米晶催化剂在催化糖制备乳酸甲酯中的用途 | |
CN106582744B (zh) | 提高正丁烷氧化制顺酐收率的催化剂的制备方法 | |
CN107986949A (zh) | 一种医药中间体4-羟基-3-甲氧基苯基丙酮的制备方法 | |
CN108067253A (zh) | 一种糠醛加氢制备环戊酮的催化剂及其制备方法以及其用于糠醛加氢制备环戊酮的方法 | |
CN102452933A (zh) | 一种羧酸酯的制备方法 | |
CN107793282A (zh) | 制备二乙烯苯的方法 | |
CN102649730B (zh) | 由co偶联生产草酸酯的方法 | |
CN112742433B (zh) | 一种碳氮掺杂二氧化硅负载Pt催化剂及其制备方法和应用 | |
CN110124682A (zh) | 一种Ce-Co修饰氧化锰的合成方法 | |
CN116217348B (zh) | 一种1,2-二正丙氧基苯的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20200414 Address after: 515638 Kanghui Industrial Zone, Chao'an Avenue, Chao'an District, Chaozhou City, Guangdong Province Patentee after: CHAOZHOU KANGHUIHONG FOOD INDUSTRY Co.,Ltd. Address before: 241002 Anhui Province, Wuhu District of Yijiang City Jiuhua Road No. 189 Technology Service Department Patentee before: ANHUI NORMAL University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20200728 Address after: 521000 Southern Sichaoan Avenue, Anbu Town, Chaoan District, Chaozhou City, Guangdong Province Patentee after: GUANGDONG ZHENGYIPIN BIOTECHNOLOGY Co.,Ltd. Address before: 515638 Kanghui Industrial Zone, Chao'an Avenue, Chao'an District, Chaozhou City, Guangdong Province Patentee before: CHAOZHOU KANGHUIHONG FOOD INDUSTRY Co.,Ltd. |
|
TR01 | Transfer of patent right |