CN104607237B - 一种含改性珍珠陶土和zsm-8的复合催化剂及其制备方法 - Google Patents
一种含改性珍珠陶土和zsm-8的复合催化剂及其制备方法 Download PDFInfo
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- CN104607237B CN104607237B CN201510078088.3A CN201510078088A CN104607237B CN 104607237 B CN104607237 B CN 104607237B CN 201510078088 A CN201510078088 A CN 201510078088A CN 104607237 B CN104607237 B CN 104607237B
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- zsm
- preparation
- dried
- clay
- catalyst
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- 239000003054 catalyst Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000002131 composite material Substances 0.000 title claims abstract description 6
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 18
- 239000004927 clay Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Inorganic materials [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 claims description 9
- 229940084478 ganite Drugs 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000010009 beating Methods 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000012265 solid product Substances 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000002779 inactivation Effects 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000000320 mechanical mixture Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
Description
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510078088.3A CN104607237B (zh) | 2015-02-15 | 2015-02-15 | 一种含改性珍珠陶土和zsm-8的复合催化剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510078088.3A CN104607237B (zh) | 2015-02-15 | 2015-02-15 | 一种含改性珍珠陶土和zsm-8的复合催化剂及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104607237A CN104607237A (zh) | 2015-05-13 |
| CN104607237B true CN104607237B (zh) | 2017-01-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510078088.3A Active CN104607237B (zh) | 2015-02-15 | 2015-02-15 | 一种含改性珍珠陶土和zsm-8的复合催化剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104607237B (zh) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2794101A1 (en) * | 2011-12-20 | 2014-10-29 | Saudi Basic Industries Corporation | Improved performance of ga- and zn-exchanged zsm-5 zeolite catalyst for conversion of oxygenates to aromatics |
| CN102527427A (zh) * | 2012-01-06 | 2012-07-04 | 厦门大学 | 卤代甲烷制丙烯的改性分子筛催化剂及其制备方法 |
| CN102963908B (zh) * | 2012-11-29 | 2015-02-18 | 中国科学院过程工程研究所 | 一种无模板剂制备zsm-5分子筛的方法 |
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2015
- 2015-02-15 CN CN201510078088.3A patent/CN104607237B/zh active Active
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| Publication number | Publication date |
|---|---|
| CN104607237A (zh) | 2015-05-13 |
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Effective date of registration: 20160921 Address after: Wenzhou Yongzhong street of Longwan District of Zhejiang province 325024 City Banqiao Road No. 44 Applicant after: Wenzhou Ou Lin coating Co., Ltd. Address before: Zhao Shi Shi Xin Cun Jiyang street 311899 Zhejiang city in Shaoxing Province, Zhuji City, No. 580 Applicant before: Li Yuhua |
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Effective date of registration: 20171204 Address after: 311800 Zhejiang city of Shaoxing province Zhuji city Jiyang Street East Road No. 98 Patentee after: Li Liangjun Address before: Wenzhou Yongzhong street of Longwan District of Zhejiang province 325024 City Banqiao Road No. 44 Patentee before: Wenzhou Ou Lin coating Co., Ltd. |
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Effective date of registration: 20181126 Address after: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang. Patentee after: Huzhou You Yan Intellectual Property Service Co., Ltd. Address before: 311800 No. 98 East Road, Jiyang Street, Zhuji City, Shaoxing City, Zhejiang Province Patentee before: Li Liangjun |
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Effective date of registration: 20211223 Address after: 362600 No. 352, xinqiong village, Dapu Town, Yongchun County, Quanzhou City, Fujian Province Patentee after: Dong Chunmin Address before: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang. Patentee before: Huzhou You Yan Intellectual Property Service Co.,Ltd. |
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Effective date of registration: 20220124 Address after: Liu'an Development Zone, Yongchun County, Quanzhou City, Fujian Province (east side of Taoxi bridge) Patentee after: Yongchun County Product Quality Inspection Institute Fujian fragrance product quality inspection center, national incense burning product quality supervision and Inspection Center (Fujian) Address before: 362600 No. 352, xinqiong village, Dapu Town, Yongchun County, Quanzhou City, Fujian Province Patentee before: Dong Chunmin |
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