CN104559154A - 环保型阻燃pa6材料及其制备方法 - Google Patents
环保型阻燃pa6材料及其制备方法 Download PDFInfo
- Publication number
- CN104559154A CN104559154A CN201410833271.5A CN201410833271A CN104559154A CN 104559154 A CN104559154 A CN 104559154A CN 201410833271 A CN201410833271 A CN 201410833271A CN 104559154 A CN104559154 A CN 104559154A
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- Prior art keywords
- retardant
- flame
- environmental
- protection flame
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 48
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000000463 material Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims description 11
- -1 polysiloxane Polymers 0.000 claims abstract description 15
- 239000012745 toughening agent Substances 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 11
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 239000012757 flame retardant agent Substances 0.000 claims description 7
- UIJZMGNMUGZMIL-UHFFFAOYSA-N [2,2-bis(hydroxymethyl)-3-phosphonooxypropyl] dihydrogen phosphate 1,3,5-triazine-2,4,6-triamine Chemical compound Nc1nc(N)nc(N)n1.OCC(CO)(COP(O)(O)=O)COP(O)(O)=O UIJZMGNMUGZMIL-UHFFFAOYSA-N 0.000 claims description 6
- 229920000578 graft copolymer Polymers 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 2
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 2
- KCYYUKIMMZGXFU-UHFFFAOYSA-N N1=C(N)N=C(N)N=C1N.P(=O)(O)OP(=O)O.OCC(CO)(CO)CO Chemical compound N1=C(N)N=C(N)N=C1N.P(=O)(O)OP(=O)O.OCC(CO)(CO)CO KCYYUKIMMZGXFU-UHFFFAOYSA-N 0.000 abstract 1
- 229910001377 aluminum hypophosphite Inorganic materials 0.000 abstract 1
- 229920002292 Nylon 6 Polymers 0.000 description 39
- 230000000052 comparative effect Effects 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | |
PA6树脂 | 100kg | 100kg | 100kg | 100kg | 100kg | 100kg |
MPP | 7kg | 5kg | 6kg | 7kg | 9kg | 6kg |
MCA | 7kg | 8kg | 7kg | 9kg | 9kg | 7kg |
次磷酸铝 | 9kg | 11kg | 14kg | 12kg | 15kg | 18kg |
聚硅氧烷 | 2.0kg | 1.5kg | 1.3kg | 1.8kg | 1.5kg | 1.5kg |
聚四氟乙烯 | 0.5kg | 0.5kg | 0.4kg | 0.4kg | 0.8kg | 1.0kg |
相容增韧剂 | 5kg | 5kg | 5kg | 5kg | 8kg | 8kg |
测试性能 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
拉伸强度/MPa | 51.26 | 50.82 | 48.43 | 49.31 | 48.17 | 46.49 |
悬臂梁抗缺口冲击强度/KJ·m-2 | 6.88 | 6.91 | 5.57 | 6.12 | 7.76 | 7.26 |
弯曲强度/MPa | 75.68 | 71.82 | 74.93 | 73.64 | 69.65 | 67.24 |
弯曲模量/MPa | 2178 | 2166 | 2437 | 2417 | 2189 | 2085 |
氧指数/% | 31.2 | 31.6 | 31.5 | 31.4 | 32.7 | 33.2 |
垂直燃烧 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
微卡软化温度/℃ | 186 | 189 | 188 | 191 | 187 | 187 |
摩擦系数 | 0.182 | 0.181 | 0.192 | 0.191 | 0.162 | 0.160 |
抗滴落性能 | V-0 | V-0 | V-0 | V-0 | V-0 | V-0 |
实施例1 | 对比例1 | 对比例2 | 对比例3 | |
PA6树脂 | 100kg | 100kg | 100kg | 100kg |
MPP | 7kg | 7kg | 7kg | 7kg |
MCA | 7kg | 7kg | 7kg | 7kg |
次磷酸铝 | 9kg | 9kg | 9kg | 9kg |
聚硅氧烷 | 2.0kg | - | 2.0kg | - |
聚四氟乙烯 | 0.5kg | 0.5kg | - | - |
相容增韧剂 | 5kg | 5kg | 5kg | 5kg |
测试性能 | 实施例1 | 对比例1 | 对比例2 | 对比例3 |
拉伸强度/MPa | 51.26 | 52.55 | 51.87 | 53.26 |
悬臂梁抗缺口冲击强度/KJ·m-2 | 6.88 | 7.03 | 6.75 | 7.15 |
弯曲强度/MPa | 75.68 | 77.21 | 77.69 | 78.25 |
弯曲模量/MPa | 2178 | 2353 | 2429 | 2517 |
氧指数/% | 31.2 | 30.1 | 30.5 | 27.7 |
垂直燃烧 | V-0 | V-0 | V-0 | V-1 |
微卡软化温度/℃ | 186 | 167 | 172 | 158 |
摩擦系数 | 0.182 | 0.569 | 0.436 | 0.832 |
抗滴落性能 | V-0 | V-0 | V-1 | V-1 |
Claims (7)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710266329.6A CN107201028B (zh) | 2014-12-29 | 2014-12-29 | 环保型阻燃pa6材料 |
CN201410833271.5A CN104559154B (zh) | 2014-12-29 | 2014-12-29 | 环保型阻燃pa6材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410833271.5A CN104559154B (zh) | 2014-12-29 | 2014-12-29 | 环保型阻燃pa6材料及其制备方法 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710266329.6A Division CN107201028B (zh) | 2014-12-29 | 2014-12-29 | 环保型阻燃pa6材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104559154A true CN104559154A (zh) | 2015-04-29 |
CN104559154B CN104559154B (zh) | 2017-04-12 |
Family
ID=53076271
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710266329.6A Expired - Fee Related CN107201028B (zh) | 2014-12-29 | 2014-12-29 | 环保型阻燃pa6材料 |
CN201410833271.5A Expired - Fee Related CN104559154B (zh) | 2014-12-29 | 2014-12-29 | 环保型阻燃pa6材料及其制备方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710266329.6A Expired - Fee Related CN107201028B (zh) | 2014-12-29 | 2014-12-29 | 环保型阻燃pa6材料 |
Country Status (1)
Country | Link |
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CN (2) | CN107201028B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104861595A (zh) * | 2015-06-08 | 2015-08-26 | 江苏理工学院 | 无卤阻燃pbt材料及其制备方法 |
CN106987117A (zh) * | 2017-05-06 | 2017-07-28 | 广东威林工程塑料股份有限公司 | 一种复配磷氮系阻燃聚酰胺及其制备方法 |
CN107216542A (zh) * | 2015-07-17 | 2017-09-29 | 江苏理工学院 | 无卤阻燃聚丙烯材料 |
CN109734898A (zh) * | 2019-01-10 | 2019-05-10 | 军事科学院系统工程研究院军需工程技术研究所 | 一种新型P-N-Si协效阻燃共聚聚酰胺6及其制备方法 |
CN111229573A (zh) * | 2020-03-09 | 2020-06-05 | 今创集团股份有限公司 | 抗菌抗病毒加硬耐磨防锈的车辆扶手、抓手表面处理方法 |
CN113278289A (zh) * | 2021-06-02 | 2021-08-20 | 华南理工大学 | 一种阻燃室温硫化硅橡胶及其制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108192340A (zh) * | 2018-01-03 | 2018-06-22 | 广东道生科技股份有限公司 | 一种高灼热丝点燃温度的mca阻燃pa6材料及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US5037869A (en) * | 1990-06-08 | 1991-08-06 | Monsanto Company | Process for preparing flame retardant polyamide molding resins containing melamine cyanurate |
CN1926192A (zh) * | 2004-01-07 | 2007-03-07 | 伊塔尔麦奇化学股份公司 | 用次磷酸铝阻燃剂处理过的聚酰胺组合物 |
JP2010163472A (ja) * | 2009-01-13 | 2010-07-29 | Mitsubishi Engineering Plastics Corp | 電離放射線照射用難燃性ポリアミド樹脂組成物 |
CN103013098A (zh) * | 2012-11-26 | 2013-04-03 | 江苏金发科技新材料有限公司 | 无卤阻燃连续长玻纤增强聚酰胺6复合材料及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013045966A1 (en) * | 2011-09-28 | 2013-04-04 | Italmatch Chemicals S.P.A. | Halogen-free flame retardant polyamides composition |
CN103450668B (zh) * | 2013-08-07 | 2016-08-10 | 上海日之升新技术发展有限公司 | 高强度碳纤维增强无卤阻燃pa6复合材料及其制备方法 |
-
2014
- 2014-12-29 CN CN201710266329.6A patent/CN107201028B/zh not_active Expired - Fee Related
- 2014-12-29 CN CN201410833271.5A patent/CN104559154B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5037869A (en) * | 1990-06-08 | 1991-08-06 | Monsanto Company | Process for preparing flame retardant polyamide molding resins containing melamine cyanurate |
CN1926192A (zh) * | 2004-01-07 | 2007-03-07 | 伊塔尔麦奇化学股份公司 | 用次磷酸铝阻燃剂处理过的聚酰胺组合物 |
JP2010163472A (ja) * | 2009-01-13 | 2010-07-29 | Mitsubishi Engineering Plastics Corp | 電離放射線照射用難燃性ポリアミド樹脂組成物 |
CN103013098A (zh) * | 2012-11-26 | 2013-04-03 | 江苏金发科技新材料有限公司 | 无卤阻燃连续长玻纤增强聚酰胺6复合材料及其制备方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104861595A (zh) * | 2015-06-08 | 2015-08-26 | 江苏理工学院 | 无卤阻燃pbt材料及其制备方法 |
CN106243638A (zh) * | 2015-06-08 | 2016-12-21 | 江苏理工学院 | 一种无卤阻燃pbt材料 |
CN106243638B (zh) * | 2015-06-08 | 2018-04-13 | 江苏理工学院 | 一种无卤阻燃pbt材料 |
CN107216542A (zh) * | 2015-07-17 | 2017-09-29 | 江苏理工学院 | 无卤阻燃聚丙烯材料 |
CN107216542B (zh) * | 2015-07-17 | 2020-01-10 | 江苏理工学院 | 无卤阻燃聚丙烯材料 |
CN106987117A (zh) * | 2017-05-06 | 2017-07-28 | 广东威林工程塑料股份有限公司 | 一种复配磷氮系阻燃聚酰胺及其制备方法 |
CN106987117B (zh) * | 2017-05-06 | 2019-10-08 | 广东威林工程塑料股份有限公司 | 一种复配磷氮系阻燃聚酰胺及其制备方法 |
CN109734898A (zh) * | 2019-01-10 | 2019-05-10 | 军事科学院系统工程研究院军需工程技术研究所 | 一种新型P-N-Si协效阻燃共聚聚酰胺6及其制备方法 |
CN109734898B (zh) * | 2019-01-10 | 2021-04-27 | 军事科学院系统工程研究院军需工程技术研究所 | 一种P-N-Si协效阻燃共聚聚酰胺6及其制备方法 |
CN111229573A (zh) * | 2020-03-09 | 2020-06-05 | 今创集团股份有限公司 | 抗菌抗病毒加硬耐磨防锈的车辆扶手、抓手表面处理方法 |
CN113278289A (zh) * | 2021-06-02 | 2021-08-20 | 华南理工大学 | 一种阻燃室温硫化硅橡胶及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN107201028A (zh) | 2017-09-26 |
CN104559154B (zh) | 2017-04-12 |
CN107201028B (zh) | 2019-08-23 |
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