CN104498184A - Preparation method for tobacco flavor by utilizing fragrant honey in Maillard reaction - Google Patents
Preparation method for tobacco flavor by utilizing fragrant honey in Maillard reaction Download PDFInfo
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- CN104498184A CN104498184A CN201410667168.8A CN201410667168A CN104498184A CN 104498184 A CN104498184 A CN 104498184A CN 201410667168 A CN201410667168 A CN 201410667168A CN 104498184 A CN104498184 A CN 104498184A
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- maillard reaction
- honey
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- 235000012907 honey Nutrition 0.000 title claims abstract description 49
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 44
- 241000208125 Nicotiana Species 0.000 title claims abstract description 43
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 239000000796 flavoring agent Substances 0.000 title abstract description 9
- 235000019634 flavors Nutrition 0.000 title abstract description 8
- 239000003205 fragrance Substances 0.000 claims abstract description 32
- 150000001413 amino acids Chemical class 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000000419 plant extract Substances 0.000 claims abstract description 6
- 239000000284 extract Substances 0.000 claims description 25
- 229940024606 amino acid Drugs 0.000 claims description 14
- 235000001014 amino acid Nutrition 0.000 claims description 14
- 241000628997 Flos Species 0.000 claims description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims description 7
- 239000008103 glucose Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229930091371 Fructose Natural products 0.000 claims description 6
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 6
- 239000005715 Fructose Substances 0.000 claims description 6
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 claims description 6
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 4
- 235000017784 Mespilus germanica Nutrition 0.000 claims description 4
- 244000182216 Mimusops elengi Species 0.000 claims description 4
- 235000000560 Mimusops elengi Nutrition 0.000 claims description 4
- 235000007837 Vangueria infausta Nutrition 0.000 claims description 4
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- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 claims description 3
- 235000000604 Chrysanthemum parthenium Nutrition 0.000 claims description 3
- ODKSFYDXXFIFQN-BYPYZUCNSA-N L-arginine Chemical compound OC(=O)[C@@H](N)CCCN=C(N)N ODKSFYDXXFIFQN-BYPYZUCNSA-N 0.000 claims description 3
- 229930064664 L-arginine Natural products 0.000 claims description 3
- 235000014852 L-arginine Nutrition 0.000 claims description 3
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 3
- 240000007890 Leonurus cardiaca Species 0.000 claims description 3
- 235000000802 Leonurus cardiaca ssp. villosus Nutrition 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- 239000004473 Threonine Substances 0.000 claims description 3
- 239000008101 lactose Substances 0.000 claims description 3
- 229960002898 threonine Drugs 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 claims description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 2
- 235000004279 alanine Nutrition 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 3
- 235000019504 cigarettes Nutrition 0.000 description 35
- 239000002304 perfume Substances 0.000 description 26
- 239000000047 product Substances 0.000 description 24
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
- 238000003756 stirring Methods 0.000 description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 239000003546 flue gas Substances 0.000 description 12
- 235000013599 spices Nutrition 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 238000001816 cooling Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000010992 reflux Methods 0.000 description 7
- 239000000376 reactant Substances 0.000 description 6
- 239000000779 smoke Substances 0.000 description 6
- 235000009508 confectionery Nutrition 0.000 description 5
- DYLPEFGBWGEFBB-OSFYFWSMSA-N (+)-β-cedrene Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(=C)CC2 DYLPEFGBWGEFBB-OSFYFWSMSA-N 0.000 description 4
- 244000126002 Ziziphus vulgaris Species 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000006757 chemical reactions by type Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000000391 smoking effect Effects 0.000 description 3
- ITYNGVSTWVVPIC-DHGKCCLASA-N (-)-allo-Aromadendrene Chemical compound C([C@@H]1[C@H]2C1(C)C)CC(=C)[C@@H]1[C@H]2[C@H](C)CC1 ITYNGVSTWVVPIC-DHGKCCLASA-N 0.000 description 2
- JSNRRGGBADWTMC-UHFFFAOYSA-N (6E)-7,11-dimethyl-3-methylene-1,6,10-dodecatriene Chemical compound CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 description 2
- 239000001169 1-methyl-4-propan-2-ylcyclohexa-1,4-diene Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 240000007472 Leucaena leucocephala Species 0.000 description 2
- 235000010643 Leucaena leucocephala Nutrition 0.000 description 2
- UIDUJXXQMGYOIN-UHFFFAOYSA-N aromadendrin Natural products CC1(C)C2C1CCC(C)C1C2C(C)CC1 UIDUJXXQMGYOIN-UHFFFAOYSA-N 0.000 description 2
- DYLPEFGBWGEFBB-UHFFFAOYSA-N beta-Cedren Natural products C1C23C(C)CCC3C(C)(C)C1C(=C)CC2 DYLPEFGBWGEFBB-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000007823 ocimene derivatives Chemical class 0.000 description 2
- 150000007875 phellandrene derivatives Chemical class 0.000 description 2
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 description 2
- XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- 239000001674 (E)-1-(2,6,6-trimethyl-1-cyclohexenyl)but-2-en-1-one Substances 0.000 description 1
- JSNRRGGBADWTMC-QINSGFPZSA-N (E)-beta-Farnesene Natural products CC(C)=CCC\C(C)=C/CCC(=C)C=C JSNRRGGBADWTMC-QINSGFPZSA-N 0.000 description 1
- BGTBFNDXYDYBEY-UHFFFAOYSA-N 1-(2,6,6-trimethylcyclohexen-1-yl)but-2-en-1-one Chemical compound CC=CC(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-UHFFFAOYSA-N 0.000 description 1
- 241000271566 Aves Species 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- POIARNZEYGURDG-UHFFFAOYSA-N beta-damascenone Natural products CC=CC(=O)C1=C(C)C=CCC1(C)C POIARNZEYGURDG-UHFFFAOYSA-N 0.000 description 1
- YSNRTFFURISHOU-UHFFFAOYSA-N beta-farnesene Natural products C=CC(C)CCC=C(C)CCC=C(C)C YSNRTFFURISHOU-UHFFFAOYSA-N 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000009923 sugaring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/022—Refining
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/305—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances of undetermined constitution characterised by their preparation
- A24B15/306—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances of undetermined constitution characterised by their preparation one reactant being an amino acid or a protein, e.g. Maillard's reaction
Abstract
The invention relates to a preparation method for flavors and fragrances, in particular to a preparation method for a tobacco flavor by utilizing fragrant honey in the Maillard reaction. According to the invention, during the Maillard reaction for preparing the tobacco flavor, the honey with fragrance partially or totally replaces reducing sugar and takes part in the Maillard reaction with amino acid and natural plant extracts together so as to prepare Maillard reactant-like tobacco flavor with fragrant aroma. The preparation method for tobacco flavor by utilizing fragrant honey in the Maillard reaction provided by the invention has wide raw material sources; the reactant-like flavor prepared by using the method has richer and fuller aroma, higher quality of aroma and good improvement of the quality of tobacco.
Description
Technical field
The present invention relates to a kind of preparation method of essence and flavoring agent, refer to a kind of method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using particularly.
Background technology
Society, smoking becomes the one custom of many people, after the idea that Smoking is harmful to your health plants the popular feeling deeply, is the objectionable impurities reduced in cigarette, and " the safe cigarette " of producing low tar low nicotine becomes the problem that production of cigarettes manufacturers compares care.For reaching above-mentioned solution target, in cigarette product, the consumption of the subsidiary material such as tobacco sheet inherently increases, but cigarette cigarette also can be caused to inhale taste for this and satisfaction is not enough, cigarette is fragrant the impact such as to weaken.Thus production of cigarettes producer is while meticulously allocating cigarette tobacco leaf formulation, and the way of additional various spices also can be adopted to make up the deficiency of cigarette fragrance.
At present, the tobacco aromatics using of China's cigarettes plus, generally speaking can be divided into three major types: a class is natural extract class spices, utilizes that contain in its natural perfume material or the potential natural constituents coordinated with cigarette perfume to carry out cigarette perfuming; Another kind of is exactly synthetic perfume, and what utilization was synthesized coordinates with cigarette perfume, have the perfume monomer of certain effect to carry out perfuming to cigarette perfume; 3rd class is exactly Maillard reaction class spices.Comparatively front two verieties of response class tobacco aromatics using are obviously on the low side, and Maillard reaction is one of important reaction that tobacco characteristic chicken flavor is formed, and therefore develop Maillard reaction class spices and carry out cigarette perfuming and just seem particularly necessary.
Glucose and amino acid react by the domestic people of having simply, and generate Maillard reaction thing, this spices kind fragrance is single, limited to smoking property of cigarette quality improving.Chinese patent (CN1415717A and CN1175623A) discloses " taking tobacco extract as the method for raw material production spices " and " preparation method of tobacco reacting substance perfume and utilization ", they are all raw material with tobacco extract, add sugar and amino acid generation Maillard reaction, although this method make use of Maillard reaction, but because the kind of institute's sugaring is single, merely add this perfume of tobacco and burnt odor, perfume quantity is abundant not enough, and aroma quality is also difficult to reach promising result.CN101654637A patent discloses and utilizes reducing sugar and amino acid in Fructus Pruni extract to react the preparation carrying out Maillard reaction tobacco aromatics using, although it has cover the effect such as assorted gas, reduction stimulation, but due to the quantitative limitation of reducing sugar in Fructus Pruni extract, the amount of the Maillard reaction thing generated is also less, and perfume quantity and aroma quality need further lifting.CN103146481A patent also discloses the research utilizing reducing sugar and amino acid to carry out Maillard reaction to prepare tobacco aromatics using, its preparation method has the features such as the simple yield of technique is high, production process is pollution-free, easy to operate, but its response class balsamic tolerance generated is abundant not, aroma quality is not high.
In sum, domesticly in the preparation carrying out Maillard reaction and carry out tobacco aromatics using, carry out some explored and research, these actions mainly concentrate on the direction such as reducing sugar and the selection of amino acid whose kind, reducing sugar and amino acid whose addition, also there is not research work to pass through interpolation and carry out Maillard reaction preparation feedback class tobacco aromatics using with fragrance of a flower honey (it both can provide reducing sugar to carry out Maillard reaction, can increase again fragrance of a flower component and enriched and improve perfume quantity and aroma quality).
Summary of the invention
Object of the present invention is exactly the present situation for Maillard reaction class tobacco aromatics using, a kind of method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using provided, its response class spices prepared, perfume quantity is abundanter, aroma quality is higher, has good improvement to cigarette quality.
Utilize the partly or entirely alternative sugar required for Maillard reaction of the reducing sugar in fragrance of a flower honey, jointly react with amino acid, natural plant extracts, preparation feedback class tobacco aromatics using.Not only containing the reducing sugar participating in reaction in fragrance of a flower honey, the fragrance of a flower component also containing many invigoratings, can increase the perfume quantity of cigarette, can promote again the aroma quality of cigarette, thus reach the cigarette effect of killing two birds with one stone.This method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using, its raw material sources are extensive, and its response class spices prepared, perfume quantity is abundanter, and aroma quality is higher, has good improvement to cigarette quality.
The present invention seeks to realize like this: it is when utilizing Maillard reaction to prepare tobacco aromatics using, by the sugar required for part or all of for fragrance of a flower honey alternative reaction, jointly participate in reaction with amino acid, natural plant extracts, acquisition can enrich perfume quantity, promotes the tobacco aromatics using of aroma quality.
Wherein said fragrance of a flower honey is one or more in Flos Robiniae Pseudoacaciae honey, rape flower honey, jujube flower honey, Motherwort Herb honey or medlar honey.Wherein said reducing sugar be in glucose, fructose, lactose, semi-lactosi or maltose one or more.Wherein said amino acid be in L-PROLINE, L-glycine, ALANINE, L-threonine, Pidolidone and L-arginine one or more.The extract that wherein said extract is is solvent with water or ethanol, the one in preferred Fructus Fici medicinal extract, Radix Glycyrrhizae extractum, yunyan extract, black cloth woods extract, Fructus Pruni extract.
Not only containing a large amount of glucose and fructose in fragrance of a flower honey, and wherein also include the larger fragrance matter of a lot of threshold values, and as: in rape flower honey, aroma substance has bata-phenethyl alcohol, ocimene, aromadendrene, β-heerabolene, β-times phellandrene, β-cedrene etc.Glucose 42.2g in 100g rape flower honey, fructose 34.25g.
The kind of nectariferous plant is different, and honey has the special fragrance do not suited.Commercially available Tongrentang commodity " Flos Robiniae Pseudoacaciae honey " and " rape flower honey ", its main component is that fructose and glucose (both account for 60-85% at content total), also contain a small amount of volatile aroma oil, natural perfume etc. outward.According to the literature, analyzed by GC-MS, in Flos Robiniae Pseudoacaciae honey, detect aroma substance and relative content is respectively bata-phenethyl alcohol 0.26%, β-damascone 0.09%, phenylacetic aldehyde 0.07%; In rape flower honey, aroma substance and relative content thereof are respectively bata-phenethyl alcohol 0.18%, ocimene 0.03%, aromadendrene 0.03%, β-heerabolene 0.38%, β-0.08%, β-farnesene 0.12% such as times phellandrene 0.13%, β-cedrene.
Choose appropriate fragrance of a flower honey, as the one in Flos Robiniae Pseudoacaciae honey, rape flower honey, jujube flower honey, medlar honey etc. and Fructus Fici medicinal extract, Radix Glycyrrhizae extractum, yunyan extract, black cloth woods extract, Fructus Pruni extract, add a certain amount of amino acid.Add corresponding propylene glycol and ammoniacal liquor as required, above-mentioned all compounds are dosed in reactor, stir into uniform reaction system, open the water coolant of reflux, be heated to 90-120 DEG C.
In order to make reaction system thermally equivalent, while heating, must stir, stir and use adjustable speed agitator, its rotating speed is between 100-400rpm.
Reaction times is different according to different reaction systems, and general control is at 1-5 hour.
After reaction terminates, reaction product is put into storage tank, obtains tobacco aromatics using product of the present invention by naturally cooling.
Embodiment
Illustrate content of the present invention further below in conjunction with example, but these embodiments do not limit the scope of application of the present invention.
Embodiment 1
Take 100g Fructus Fici extract and 40g propylene glycol, put into there-necked flask, it is (commercially available to add 8g Flos Robiniae Pseudoacaciae honey, Tongrentang) and 5.6g L-PROLINE, start to stir, connect reflux condensing tube, after being heated to 90 DEG C with oil bath, add 10ml strong aqua, constant temperature 4 hours, stirring velocity is 180rpm, then stops heating, pour out reactant after naturally cooling, be product of the present invention.The Maillard reaction thing obtained shows very strong baking perfume and fruital, the stronger acacia fragrance of a flower, by this product with 0.8 ‰ amount join in blank pipe tobacco and carry out cigarette effect and smoke panel test, find that this product can make the soft exquisiteness of flue gas, cover assorted gas, remarkable increase flue gas concentration, improves flue gas aroma quality.
Embodiment 2
Take 100g yunyan extract and 40g propylene glycol, put into there-necked flask, it is (commercially available to add 4g Flos Robiniae Pseudoacaciae honey, Tongrentang) and 4g fructose, and 6g L-PROLINE, start to stir, connect reflux condensing tube, after being heated to 100 DEG C with oil bath, add 15ml strong aqua, constant temperature 3 hours, stirring velocity is 200rpm, then stop heating, pour out reactant after naturally cooling, be product of the present invention.The Maillard reaction thing obtained shows very strong baking perfume and this perfume of tobacco, the stronger acacia fragrance of a flower, by this product with 0.7 ‰ amount join in blank pipe tobacco and carry out cigarette effect and smoke panel test, find that this product can make flue gas sweet, soft exquisiteness, remarkable increase flue gas concentration, makes flue gas elegance comfortable, significantly improves cigarette quality.
Embodiment 3
Take 90g Radix Glycyrrhizae extractum, put into there-necked flask, it is (commercially available to add 4g medlar honey, Tongrentang) and 4g maltose, and 6g L-arginine, start to stir, connect reflux condensing tube, after being heated to 120 DEG C with oil bath, add 10ml 1N NaOH solution, constant temperature 5 hours, stirring velocity is 300rpm, then stop heating, pour out reactant after naturally cooling, be product of the present invention.It is fragrant and fragrant and sweet that the Maillard reaction produce product obtained show very strong bake bread, by this product with 0.6 ‰ amount join in blank pipe tobacco and carry out cigarette effect and smoke panel test, find that this product makes flue gas soft smooth and easy, sweet flue gas, remarkable increase flue gas plumpness, conglobation property is better, significantly improves its aroma quality, improves cigarette quality.
Embodiment 4
Take 90g black cloth woods extract and 36g propylene glycol, put into there-necked flask, it is (commercially available to add 4g jujube flower honey, Tongrentang) and 4g glucose, and 6g amino acid (mass ratio of L-PROLINE, L-glycine, Pidolidone is 2:1:1), start to stir, connect reflux condensing tube, after being heated to 90 DEG C with oil bath, add 15ml strong aqua, constant temperature 3.5 hours, stirring velocity is 300rpm, then stop heating, pour out reactant after naturally cooling, be product of the present invention.The Maillard reaction produce product obtained show very strong baking perfume and plum fruital, stronger jujube flower is fragrant, by this product with 0.6 ‰ amount join in blank pipe tobacco and carry out cigarette effect and smoke panel test, find that this product fragrance is clear, obviously cover assorted gas, make flue gas soft smooth and easy, cigarette perfume (or spice) is plentiful, and aroma quality obviously promotes.
Embodiment 5
Take 90g Fructus Pruni extract and 36g propylene glycol, put into there-necked flask, it is (commercially available to add 4g Motherwort Herb honey, Tongrentang) and 4g lactose, and 6g amino acid (mass ratio of L-PROLINE, L-glycine, L-threonine is 1:1:1), start to stir, connect reflux condensing tube, after being heated to 90 DEG C with oil bath, add 15ml strong aqua, constant temperature 4 hours, stirring velocity is 360rpm, then stop heating, pour out reactant after naturally cooling, be product of the present invention.The Maillard reaction produce product obtained show very strong baking perfume and fruital, the stronger fragrance of a flower, by this product with 0.65 ‰ amount join in blank pipe tobacco and carry out cigarette effect and smoke panel test, find the sweet fine and smooth flue gas of this product energy, improve mouthfeel, pleasant impression is meaningful, obviously increases perfume quantity and aroma quality, improves cigarette quality.
Embodiment 6
Take 90g yunyan extract and 38g propylene glycol, put into there-necked flask, it is (commercially available to add 6g rape flower honey, Tongrentang) and 2g semi-lactosi, and 5g L-PROLINE, add 12ml strong aqua, start to stir, connect reflux condensing tube, after being heated to 110 DEG C with oil bath, constant temperature 4 hours, stirring velocity is 340rpm, then stops heating, pour out reactant after naturally cooling, be product of the present invention.The Maillard reaction produce product obtained show very strong baking perfume and cigarette perfume, the stronger rape fragrance of a flower, by this product with 0.5 ‰ amount join in blank pipe tobacco and carry out cigarette effect and smoke panel test, find the sweet fine and smooth flue gas of this product energy, improve mouthfeel, pleasant impression is cleaner, and make cigarette perfume (or spice) fuller, graceful elegant, it significantly improves cigarette quality.
Claims (6)
1. the method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using, it is when utilizing Maillard reaction to prepare tobacco aromatics using, honey with the fragrance of a flower is partly or entirely substituted reducing sugar, participate in Maillard reaction together with amino acid, natural plant extracts, prepare the Maillard reaction thing class tobacco aromatics using with floral notes.
2. a kind of method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using according to claim 1, wherein said fragrance of a flower honey is one or more in Flos Robiniae Pseudoacaciae honey, rape flower honey, Motherwort Herb honey or medlar honey.
3. a kind of method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using according to claim 1, wherein said amino acid be in L-PROLINE, L-glycine, ALANINE, L-threonine, Pidolidone and L-arginine one or more.
4. a kind of method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using according to claim 1, wherein said reducing sugar be in glucose, fructose, lactose, semi-lactosi or maltose one or more.
5. a kind of method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using according to claim 1, the extract of wherein said natural plant extracts to be solvent be water or ethanol.
6. a kind of method utilizing fragrance of a flower honey to carry out Maillard reaction to prepare tobacco aromatics using according to claim 1, wherein said natural plant extracts is the one in Fructus Fici medicinal extract, Radix Glycyrrhizae extractum, yunyan extract, black cloth woods extract, Fructus Pruni extract.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491596A (en) * | 2003-08-22 | 2004-04-28 | 忠 陈 | Chinese herbal medicine additive in cigarette and its preparing mehtod and use |
| CN1596687A (en) * | 2004-07-19 | 2005-03-23 | 陈忠 | Tea essence for tea food and its preparation method |
| CN102757866A (en) * | 2012-06-26 | 2012-10-31 | 湖北中烟工业有限责任公司 | Method for preparing latent fragrance perfume for cigarettes through dual-frequency ultrasonic |
| CN104041936A (en) * | 2014-06-06 | 2014-09-17 | 山东中烟工业有限责任公司 | Method for extracting Chinese style mixed-fragrance cigarette juice for electronic cigarette |
-
2014
- 2014-11-20 CN CN201410667168.8A patent/CN104498184A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491596A (en) * | 2003-08-22 | 2004-04-28 | 忠 陈 | Chinese herbal medicine additive in cigarette and its preparing mehtod and use |
| CN1596687A (en) * | 2004-07-19 | 2005-03-23 | 陈忠 | Tea essence for tea food and its preparation method |
| CN102757866A (en) * | 2012-06-26 | 2012-10-31 | 湖北中烟工业有限责任公司 | Method for preparing latent fragrance perfume for cigarettes through dual-frequency ultrasonic |
| CN104041936A (en) * | 2014-06-06 | 2014-09-17 | 山东中烟工业有限责任公司 | Method for extracting Chinese style mixed-fragrance cigarette juice for electronic cigarette |
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