CN101497845A - Method for producing cigarette flavor by maillard reaction with red date extract as raw material - Google Patents
Method for producing cigarette flavor by maillard reaction with red date extract as raw material Download PDFInfo
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- CN101497845A CN101497845A CNA2008100468355A CN200810046835A CN101497845A CN 101497845 A CN101497845 A CN 101497845A CN A2008100468355 A CNA2008100468355 A CN A2008100468355A CN 200810046835 A CN200810046835 A CN 200810046835A CN 101497845 A CN101497845 A CN 101497845A
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- Prior art keywords
- fructus jujubae
- maillard reaction
- reaction
- jujubae extract
- raw material
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 69
- 239000000284 extract Substances 0.000 title claims abstract description 56
- 239000002994 raw material Substances 0.000 title claims description 23
- 239000000796 flavoring agent Substances 0.000 title claims description 18
- 235000019634 flavors Nutrition 0.000 title claims description 18
- 235000019504 cigarettes Nutrition 0.000 title abstract description 44
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 241000208125 Nicotiana Species 0.000 claims abstract description 45
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 45
- 238000000034 method Methods 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 25
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 26
- 229940024606 amino acid Drugs 0.000 claims description 21
- 235000001014 amino acid Nutrition 0.000 claims description 21
- 150000001413 amino acids Chemical class 0.000 claims description 21
- 229910021529 ammonia Inorganic materials 0.000 claims description 15
- 238000010992 reflux Methods 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000376 reactant Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 6
- 230000001143 conditioned effect Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 5
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 claims description 5
- -1 Xie Ansuan Chemical compound 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000004475 Arginine Substances 0.000 claims description 3
- 239000004471 Glycine Substances 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 3
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 229960002989 glutamic acid Drugs 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 claims description 2
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 2
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 claims description 2
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 claims description 2
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims description 2
- 235000003704 aspartic acid Nutrition 0.000 claims description 2
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 2
- 238000005352 clarification Methods 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 238000013467 fragmentation Methods 0.000 claims description 2
- 238000006062 fragmentation reaction Methods 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 claims description 2
- 235000014347 soups Nutrition 0.000 claims description 2
- 239000006228 supernatant Substances 0.000 claims description 2
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 abstract description 25
- 239000002304 perfume Substances 0.000 abstract description 20
- 239000000779 smoke Substances 0.000 abstract description 14
- 241001247821 Ziziphus Species 0.000 abstract description 11
- 238000002360 preparation method Methods 0.000 abstract description 4
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000000047 product Substances 0.000 description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 19
- 239000003546 flue gas Substances 0.000 description 19
- 235000013599 spices Nutrition 0.000 description 19
- 230000000694 effects Effects 0.000 description 12
- 238000012360 testing method Methods 0.000 description 9
- 239000000706 filtrate Substances 0.000 description 8
- 238000005303 weighing Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 150000001720 carbohydrates Chemical class 0.000 description 3
- 235000009508 confectionery Nutrition 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002240 furans Chemical class 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 150000003505 terpenes Chemical class 0.000 description 3
- 235000007586 terpenes Nutrition 0.000 description 3
- 229930091371 Fructose Natural products 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
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- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
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- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000009923 sugaring Methods 0.000 description 1
Landscapes
- Fats And Perfumes (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The invention discloses a method for producing tobacco perfume by adopting red jujube extract through the Maillard reaction, which relates to a preparation method of tobacco perfume. The preparation method comprises the following steps: (1) preparing the red jujube extract; (2) adding one or a plurality of types of aminophenol or amines in the red jujube extract, adding H2O and solvent which are placed in a reaction kettle to be mixed into a homogeneous reaction system, adjusting the pH value of the reaction system, putting reagent into a return pipe, leading the reagent to perform the Maillard reaction under the conditions of mixing, heating and normal pressure, and obtaining the tobacco perfume by the return reaction. The method enables the perfume material in the red jujube extract to mutually serve the perfume material produced in the Maillard reaction, thereby forming the tobacco perfume with rich and special fragrance and multiple type, having strong fruity coordinating with the smoke gas of a cigarette, increasing the smoke gas concentration, leading the smoke gas to be soft and exquisite, hiding the mixed gas and obviously improving the tobacco quality.
Description
Technical field
The present invention relates to a kind of preparation method of tobacco aromatics using, especially is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract.
Background technology
In the prior art, the general two big classes that adopt of the tobacco aromatics using of cigarettes plus: a class is a natural extract spices, utilizes natural component that contain in the natural perfume or potential and flue gas coordination; Another kind of is exactly synthetic perfume, utilizes synthetic and flue gas to coordinate, and flue gas is had the perfume monomer of certain effect.This two big class spices separately or the tobacco aromatics using made of allotment, though technology is simple, because fragrance dullness,, effect single to the effect of flue gas are not fine.The research of China on tobacco aromatics using is relatively backward always, the spices dependence on import of the overwhelming majority, and therefore, the tobacco aromatics using that development effectiveness is good is necessary.Response class spices (being the Maillard reaction thing) is the spices that the very important and utmost point has using value on tobacco and the food always, the fragrance that reaction produces is also different according to sugared source, ammonia source difference, a large amount of heterocycle perfume compounds that reaction produces have the improvement effect to cigarette smoke.
The domestic people of having reacts glucose and amino acid simply, generates the Maillard reaction thing, and this spices kind is few, fragrance is single, improves limited to tobacco sucking quality.Chinese patent (CN1162008A) discloses " a kind of method of producing tobacco aromatics using ", it is a raw material with the tobacco, after the raw material pulverizing, adds the water boiling sterilization, insert fermented bacterium, 20～70 ℃ of bottom fermentations 2 hours～3 days, add solvent extraction subsequently, obtain product through separating to purify again, this method, complex process, length consuming time, and raw material sources instability.Chinese patent (CN1415717A and CN1175623A) discloses " being the method for raw material production spices with the tobacco extract " and has reached " preparation method of tobacco reacting substance perfume and utilization ", they all are raw material with the tobacco extract, add sugar and amino acid generation Maillard reaction, though this method has been utilized Maillard reaction, but because the kind of institute's sugaring is single, some sugared cost is very high, and its fragrance is difficult to reach promising result, equally its raw material sources instability.U.S. Pat 3,920,026 discloses " tobacco flavor enriches agent ", utilizes reducing sugar and amino acid to make tobacco aromatics using under certain condition, same, because the kind of sugar is more single, some sugared cost is very high, is difficult to reach promising result.
In a word, up to the present, utilize Maillard reaction to prepare the method for tobacco aromatics using, or complex process, the cost height, raw material sources instability, or fragrance dullness act on singlely, and effect is undesirable.Therefore, provide a kind of effective, the Maillard reaction tobacco aromatics using that cost is low is very important.
Summary of the invention
At the above-mentioned deficiency of prior art, it is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract that the technical problem to be solved in the present invention provides a kind of.Method of the present invention organically combines the fragrance of natural jujube extract itself and the fragrance of Maillard reaction, the fragrance matter that fragrance matter in the Fructus Jujubae extract and Maillard reaction are produced sets off mutually, thereby it is abundant, unique to form fragrance, numerous in variety, have strong fruital note, with the spices of cigarette smoke coordination, increase flue gas concentration, make the soft exquisiteness of flue gas, cover assorted gas, significantly improve cigarette quality.
Technical scheme of the present invention: with the Fructus Jujubae extract is that raw material carries out according to the following steps by the method for Maillard reaction to produce tobacco flavor:
(1) produces Fructus Jujubae extract;
(2) in Fructus Jujubae extract, add one or more amino acid or Ammonia material, add H
2O and solvent place reactor to stir into the reaction system of homogeneous, the pH value of conditioned reaction system, and the return line of packing into makes reactant generation Maillard reaction under stirring, heating, condition of normal pressure, and the back flow reaction products therefrom is tobacco aromatics using.
Described amino acid or Ammonia material are L-Ala, proline(Pro), Xie Ansuan, arginine, Serine, phenylalanine, L-glutamic acid, aspartic acid, glycine, tyrosine, Secondary ammonium phosphate.
The add-on of described amino acid or Ammonia material is 2～30% of a Fructus Jujubae extract weight.
Described solvent is propylene glycol, glycerol, ethylene glycol, and its add-on is 0～20% of a Fructus Jujubae extract weight.
The pH value of described reaction system is 2～11.
Described reflux temperature is 70～120 ℃;
Described mixing speed is between 100～1000 rev/mins.
The reaction times of back flow reaction was controlled between 1-7 hour.
The acidic cpd that the pH value of conditioned reaction system adopts is one or more in hydrochloric acid, acetic acid, the citric acid etc., and basic cpd is one or more among strong aqua, NaOH, the KOH.
Producing Fructus Jujubae extract carries out according to the following steps:
(1) commercially available have a nuclear red date dry fruit, and moisture content is 20% ± 2%, rejects mouldy, septic red date, cleans then, drains;
(2) put into reactor after the red date flattening that will choose, clean, drains, the fragmentation, require broken getting final product, size is not limit, and presses red date: the mixed of 75% edible ethanol=1:4, stirring heating reflux extraction is 6 hours under 90 ± 5 ℃ of temperature, is cooled to room temperature;
(3) supernatant is extracted in the clarification in 5 hours of the solution left standstill after will lowering the temperature; After lower floor's soup compound was centrifugal, the reject dregs merged clear liquid;
(4) clear liquid is poured in the concentration kettle concentrated, concentrate recovered alcohol in 80 ± 2 ℃ of temperature, vacuum tightness under greater than the condition of 0.95Mpa, the enriched material degree Beaume stops to concentrate when being 25 ° of B é, and gained dark-brown thick liquid is Fructus Jujubae extract.
Method of the present invention has the following advantages:
1. how to improve traditional Maillard reaction fragrance dullness, and the shortcoming that adding cigarette fragrance stings is a difficult point of the present invention.Fructus Jujubae extract itself contains a lot of fragrance matters, contains saturated and unsaturated aldehyde, ketone, alcohol, acid, ester, hydrocarbon, terpenes and furans and lactone compound, these materials to cigarette flavouring is arranged, cover assorted, improve mouthfeel and fall the effect of thorn; The present invention selects the natural jujube extract for use, by testing repeatedly, groping, some nitrogenous compounds, solvent and reaction conditions have been chosen, the fragrance of natural jujube extract itself and the fragrance of Maillard reaction are organically combined, the fragrance matter that fragrance matter in the Fructus Jujubae extract and Maillard reaction are produced sets off mutually, thereby it is abundant, unique to form fragrance, numerous in variety, has strong fruital note, spices with cigarette smoke is coordinated increases flue gas concentration, makes the soft exquisiteness of flue gas, cover assorted gas, significantly improve cigarette quality.
2. contain the rich saccharide material in the Fructus Jujubae extract, as glucose, fructose and sucrose, also contain a spot of maltose, semi-lactosi, numerous in variety, the content height accounts for about 50% of its total amount, provides the basis for rich and varied Maillard reaction takes place;
3. the glucide in the red date is compared with pure glucide, has the low characteristics of cost;
4. by adding different nitrogenous sources such as ammoniacal liquor, ammonia salt, amino acid generation Maillard reaction, can make the different spices of effect.
5. contain in the Fructus Jujubae extract materials such as rich saccharide and amino acid participate in behind the Maillard reactions product than traditional single Maillard reaction thing to cause perfumery much more, enriched the fragrance of cigarette like this, promoted quality of cigarette.
Though Fructus Jujubae extract contain much to cigarette flavouring is arranged, cover assorted, improve mouthfeel and fall the material of thorn effect, also there are shortcomings such as flavouring deficiency, pleasant impression is not good enough, utilize the sugar generation Maillard reaction in the red date can produce abundant heterogeneous ring compound, these materials can remedy these shortcomings, set off mutually.
Embodiment
Further illustrate content of the present invention below in conjunction with embodiment, but these embodiment do not limit protection scope of the present invention.
Fructus Jujubae extract contains volatile component such as saturated and unsaturated aldehyde, ketone, alcohol, acid, ester, hydrocarbon, terpenes and furans and the lactone compound useful to flue gas, contains the rich saccharide material in addition.Such as: glucose, fructose, semi-lactosi or the like.Utilize these also diversity of source sugar, by amino acid or the Ammonia material that adds one or more, and H
2O and solvent, place reactor to stir into the reaction system of homogeneous, utilize the pH value of acidity or basic cpd conditioned reaction system, load onto return line then, under agitation heat normal pressure generation Maillard reaction, the fragrance matter that fragrance matter in the Fructus Jujubae extract and Maillard reaction are produced sets off mutually, thereby makes the good tobacco aromatics using of effect.
Wherein Fructus Jujubae extract itself also is a kind of tobacco aromatics using, is raw material with it, by adding amino acid or Ammonia material, Maillard reaction takes place, and can be made into tobacco aromatics using wide in variety, better effects if.
Because reaction is carried out under heating condition, therefore must controlled temperature and installation reflux.By kind and amount and the proportioning that amino acid or Ammonia material are added in change, the amount and the kind of change solvent, thus obtain tobacco aromatics using wide in variety, to satisfy the production of cigarettes needs.
Because the reducing sugar content in the Fructus Jujubae extract is higher and wide in variety various, and contain saturated and unsaturated aldehyde, ketone, alcohol, acid, ester, hydrocarbon, terpenes and furans and lactone compound, these materials have flavouring, cover the effect of mixing and falling thorn cigarette, therefore, can be with it as the abundant sugared source of Maillard reaction, but aminoacids content wherein is low, so must be toward the amino acid or the Ammonia material that wherein add one or more.
After add amino acid or Ammonia material, can be to wherein adding certain amount of solvent as H
2O, propylene glycol, glycerol, ethylene glycol etc., its effect is to help amino acid whose dissolving and reaction.
Above-mentioned all compounds are added in the reactor, stir into uniform reaction system, the pH value with acidity or basic cpd conditioned reaction system is 2～11 then, and said acidic cpd is one or more in hydrochloric acid, acetic acid, the citric acid etc.Basic cpd is one or more among strong aqua, NaOH, the KOH, opens the water coolant of reflux, is heated to 70～120 ℃, and it adds electrically heated of thermal recovery thermal oil or steam heating.
In order to make the reaction system thermally equivalent, in heating, must stir, stir and use the adjustable speed agitator, its rotating speed should be between 100～1000 rev/mins.Make the temperature of reaction reach predetermined temperature by heating.Its temperature of reaction is different and different according to amino acid that adds or Ammonia material, generally is controlled at 70～120 ℃, is reflected under the normal pressure and carries out.
Reaction times is different and different according to amino acid that adds or Ammonia material, generally is controlled at 1-7 hour.Reaction is put into storage tank with reaction product after finishing, and naturally cooling gets product-tobacco aromatics using of the present invention.
Embodiment 1
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 30 gram L-Ala, start stirring, adding ammoniacal liquor adjusting pH again is 9.7, connects reflux condensing tube, is heated to 90 ℃ with oil bath, constant temperature 3 hours, stirring velocity is 200 rev/mins, stops heating then, pours out reactant, remove insolubles with gauze, gained filtrate is product of the present invention.Products obtained therefrom shows very strong jujube perfume (or spice), baking perfume (or spice) and nutty.This product joined with 0.8 ‰ amount please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Embodiment 2
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 15 gram L-Ala, 15 gram proline(Pro) start stirring, and adding ammoniacal liquor adjusting pH again is 9.7, connect reflux condensing tube, be heated to 95 ℃ with oil bath, constant temperature 3.5 hours, stirring velocity is 200 rev/mins, stop heating then, pour out reactant, remove insolubles with gauze, gained filtrate is product of the present invention.Products obtained therefrom shows very strong jujube perfume (or spice), burnt fragrant and sweet, this product is joined with 0.8 ‰ amount please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Embodiment 3
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 40 gram proline(Pro), start stirring, add 50 gram propylene glycol again, it is 9.7 that strong aqua is regulated pH, connect reflux condensing tube, be heated to 110 ℃ with oil bath, constant temperature 3 hours, stirring velocity is 300 rev/mins, stop heating then, pour out reactant, remove insolubles with gauze, gained filtrate is product of the present invention.Products obtained therefrom shows very strong baking perfume (or spice), Mi Xiang.This product joined with 0.8 ‰ amount please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Embodiment 4
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 30 gram arginine, start stirring, adding phosphoric acid ammonia two ammoniums adjusting pH again is 7.2, connects reflux condensing tube, is heated to 90 ℃ with oil bath, constant temperature 3 hours, stirring velocity is 200 rev/mins, stops heating then, pours out reactant, remove insolubles with gauze, gained filtrate is product of the present invention.This product shows very strong jujube perfume (or spice), baking is fragrant.This product joined with 0.8 ‰ amount please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Embodiment 5
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 10 gram proline(Pro), 10 gram glycine, 10 gram L-glutamic acid, start stirring, adding the lemon acid for adjusting pH again is 3, connects reflux condensing tube, is heated to 90 ℃ with oil bath, constant temperature 3 hours, stirring velocity is 200 rev/mins, stops heating then, pours out reactant, remove insolubles with gauze, gained filtrate is product of the present invention.This product shows very strong baking perfume (or spice).This product joined with 0.8 ‰ amount please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Embodiment 6
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 50 gram phosphoric acid ammonia, two ammoniums, pH is 7.4, start stirring, connect reflux condensing tube, be heated to 85 ℃ with oil bath, constant temperature 5 hours, stirring velocity is 200 rev/mins, and stopped reaction is poured out reactant then, use filtered through gauze, filtrate is product of the present invention.This product shows strong burnt sweet roasting fragrance breath.This product joined with 0.8 ‰ amount please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Embodiment 7
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 30 gram Xie Ansuans, start stirring, adding NaOH adjusting pH again is 11, connects reflux condensing tube, is heated to 90 ℃ of temperature with oil bath, constant temperature 4 hours, stirring velocity is 300 rev/mins, stops reacting by heating then, pours out reactant, use filtered through gauze, filtrate is product of the present invention.This product shows tangible chocolate fragrant.This product joined by 1 ‰ please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Embodiment 8
Take by weighing 500 gram Fructus Jujubae extracts, put into three-necked flask, add 20 gram L-Ala, start stirring, adding acetic acid adjusting pH again is 3, connects reflux condensing tube, is heated to 95 ℃ with oil bath, constant temperature 3.5 hours, stirring velocity is 800 rev/mins, stops heating then, pours out reactant, remove insolubles with gauze, gained filtrate is product of the present invention.Products obtained therefrom shows very strong jujube perfume (or spice), this product is joined with 0.8 ‰ amount please comment the cigarette expert to smoke panel test in the blank cigarette, the results are shown in Table 1.
Table 1 smoking result
| Embodiment | Smoking result |
| 1 | Significantly increase flue gas concentration, make the soft exquisiteness of flue gas, cover assorted gas, significantly improve cigarette quality. |
| 2 | Obviously improve mouthfeel, pleasant impression is comfortable, pure and mild flue gas. |
| 3 | Significantly increase flue gas concentration, cover assorted gas, make the flue gas elegance comfortable, improved the grade of cigarette greatly. |
| 4 | Obviously increase flue gas concentration, improve mouthfeel, pleasant impression is comfortable, |
| Significantly improve cigarette quality. | |
| 5 | Significantly improve flue gas concentration, make flue gas plentiful, soft exquisiteness, cigarette perfume (or spice) is clear, significantly improves cigarette quality. |
| 6 | Obviously improve the fragrant and sweet breath of cigarette, flue gas is sent out thoroughly, very lucid and lively impression is arranged, significantly improve the cigarette quality. |
| 7 | Obviously improve cigarette flavor, withered and burnt smell is had restraining effect, the oral cavity is comfortable clean, and cigarette perfume (or spice) stays length, has obviously improved the cigarette quality |
| 8 | Obviously improve cigarette flavor, make flue gas elegant, reducing stimulates |
By above embodiment 1～8 as seen:,, Maillard reaction takes place by amino acid or the Ammonia material that adds one or more with containing the Fructus Jujubae extract that enriches reducing sugar, the tobacco aromatics using fragrance of making is abundant, and comfortable taste is covered assorted gas, fragrance remaining time is long, obviously improves quality of cigarette.
In a word, tobacco aromatics using making method of the present invention can be tobacco industry colory tobacco aromatics using is provided, and promotes the development of cigarette industry.
Claims (10)
1, a kind of is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that described method carries out according to the following steps:
(1) produces Fructus Jujubae extract;
(2) in Fructus Jujubae extract, add one or more amino acid or Ammonia material, add H
2O and solvent place reactor to stir into the reaction system of homogeneous, the pH value of conditioned reaction system, and the return line of packing into makes reactant generation Maillard reaction under stirring, heating, condition of normal pressure, and the back flow reaction products therefrom is tobacco aromatics using.
2, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that: described amino acid or Ammonia material are L-Ala, proline(Pro), Xie Ansuan, arginine, Serine, phenylalanine, L-glutamic acid, aspartic acid, glycine, tyrosine, Secondary ammonium phosphate.
3, according to claim 2 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that: the add-on of described amino acid or Ammonia material is 2～30% of a Fructus Jujubae extract weight.
4, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that: described solvent is propylene glycol, glycerol, ethylene glycol, and its add-on is 0～20% of a Fructus Jujubae extract weight.
5, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that: the pH value of described reaction system is 2～11.
6, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that: described reflux temperature is 70～120 ℃;
7, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, and it is characterized in that: described mixing speed is between 100～1000 rev/mins.
8, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, and it is characterized in that: the reaction times of back flow reaction was controlled between 1-7 hour.
9, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that: the acidic cpd that the pH value of conditioned reaction system adopts is one or more in hydrochloric acid, acetic acid, the citric acid etc., and basic cpd is one or more among strong aqua, NaOH, the KOH.
10, according to claim 1 is the method for raw material by Maillard reaction to produce tobacco flavor with the Fructus Jujubae extract, it is characterized in that: produce Fructus Jujubae extract and carry out according to the following steps:
(1) commercially available have a nuclear red date dry fruit, and moisture content is 20% ± 2%, rejects mouldy, septic red date, cleans then, drains;
(2) put into reactor after the red date flattening that will choose, clean, drains, the fragmentation, require broken getting final product, size is not limit, and presses red date: the mixed of 75% edible ethanol=1:4, stirring heating reflux extraction is 6 hours under 90 ± 5 ℃ of temperature, is cooled to room temperature;
(3) supernatant is extracted in the clarification in 5 hours of the solution left standstill after will lowering the temperature; After lower floor's soup compound was centrifugal, the reject dregs merged clear liquid;
(4) clear liquid is poured in the concentration kettle concentrated, concentrate recovered alcohol in 80 ± 2 ℃ of temperature, vacuum tightness under greater than the condition of 0.95Mpa, the enriched material degree Beaume stops to concentrate when being 25 ° of B é, and gained dark-brown thick liquid is Fructus Jujubae extract.
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