CN105132165A - Preparation method of barley syrup Maillard reaction-type tobacco spice - Google Patents
Preparation method of barley syrup Maillard reaction-type tobacco spice Download PDFInfo
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- CN105132165A CN105132165A CN201510444166.7A CN201510444166A CN105132165A CN 105132165 A CN105132165 A CN 105132165A CN 201510444166 A CN201510444166 A CN 201510444166A CN 105132165 A CN105132165 A CN 105132165A
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- Manufacture Of Tobacco Products (AREA)
- Seasonings (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention discloses a preparation method of a barley syrup Maillard reaction-type tobacco spice, wherein the preparation method includes the steps of: 1) diluting the barley syrup in water for later use; 2) performing ultrasonic pretreatment to the diluted barley syrup solution to obtain an ultrasonic treated liquid; 3) adding amino acid accounting for 1-8% of the mass of the ultrasonic treated liquid, mixing the liquid uniformly, regulating the pH value of the initial mixed liquid with an alkali liquid to 8-12, filling a reflux tube with the mixed liquid with temperature controlled to be 100-120 DEG C and performing a Maillard reaction under continuous stirring for 2-5 times, and finally filtering and pressure-reduced concentrating a reaction product to obtain the barley syrup Maillard reaction-type tobacco spice. The tobacco spice is prepared with the barley syrup as a raw material, so that the method is abundant in raw material source and is simple and convenient in operations. The tobacco spice can improve the fragrance of tobacco well and softens and fines tobacco smoke, covers up foreign odors, has a comfortable after taste, and has the effect of improving the quality of tobacco.
Description
Technical field
The present invention relates to cigarette flavors field, specifically a kind of preparation method of orgeat Maillard reaction type tobacco aromatics using.
Background technology
Essence and flavoring agent is the soul of cigarette product, plays keying action to the quality of cigarette products.That disputes on along with the reduction of tar content in cigarette and smoking and health problem becomes increasingly conspicuous, and tobacco industry is faced with one, and to have challenging problem be exactly while reduction tar, makes the fragrance that cigarette keeps enough again.At present, many cigar mills are when meticulously allocating cigarette composition, and great majority adopt again additional various sweetener, to make up the deficiency of cigarette fragrance.
Maillard reaction is also called " nonenzymatic browning reaction ", refers to that reducing sugar compounds and ammonium salt, amino acid or protein finally generate macromole melanoidin material that is brown or even black, so react also known as carbonyl amine through complex reaction.Maillard reaction, while generation color and luster, is attended by the generation of fragrance matter, Maillard reaction is widely used in the production of food flavor(ing) and tobacco flavour both at home and abroad.The category of traditional flavor deployment and production technique has been broken in the application of this technology in essence field, is a brand-new essence and flavoring agent production technology.Because Maillard reaction type tobacco aromatics using contains abundant fragrance matter, the heterogeneous ring compounds such as such as pyrazine, furans, pyrroles, pyrone, these aroma components burn and suck the harmony fragrant with cigarette of major part in process at cigarette, have and increase the effect that cigarette is fragrant, promote aroma quality, cover assorted gas.Therefore, the applied research of Maillard reaction in cigarette compensating aroma technology extremely tobacco scientific worker is paid close attention to, one of heat subject becoming tobacco industry.The fragrance that Maillard reaction produces often by the impact of sugared source and nitrogenous source kind, also with temperature, time, solvent, pH value etc. because have much relations.Glucose and amino acid are simply carried out Maillard reaction by the domestic people of having, preparation feedback type tobacco aromatics using, and this product fragrance is more dull, and note is abundant not, improve limited to tobacco suction quality.Therefore, be necessary to find that a kind of effect is good, the approach of technique simple possible to be to prepare Maillard reaction type tobacco aromatics using.
Orgeat, the barley (feed barley) generally referring to be unsuitable for malt is main raw material, using starch, rice, wheat or corn as auxiliary material, by adding various zymin, through saccharification, decolouring, filtration, concentrated what make take maltose as the syrup of main carbohydrate, simultaneously also containing a certain amount of alpha-amino nitrogen and soluble protein.Orgeat after concentrated, its solid content can reach more than 70%, and wherein glucose is about 5.89%, and maltose is about 48.4%, and trisaccharide maltose is about 18.53%.Due to chemical constitution and the local flavor relatively wort of orgeat, existing orgeat replaces the report of wort beer brewing completely both at home and abroad.Orgeat has wheat juice distinctive smell, containing flavour substancess such as a small amount of carbonyl compound, amino acid, by introducing amino acid, Maillard reaction can be utilized to produce fragrant technology and prepare the tobacco aromatics using that perfume quantity is enriched, flavouring essence quality is high.Have no at present with orgeat is the method that Maillard reaction type tobacco aromatics using prepared by raw material.
Summary of the invention
The object of the invention is the preparation method that a kind of orgeat Maillard reaction type tobacco aromatics using is provided for the deficiencies in the prior art.The present invention is that Maillard reaction type tobacco aromatics using prepared by raw material with orgeat, abundant raw material source, simple to operation, production cost is low, product aroma strength is high, can promote cigarette flavor matter preferably, soft fine and smooth flue gas, enriches perfume quantity, coordinate with cigarette perfume, cover assorted gas, pleasant impression is comfortable, has the effect improving cigarette smoking quality.
The present invention is achieved through the following technical solutions: a kind of preparation method of orgeat Maillard reaction type tobacco aromatics using, the method comprises the steps:
1) by orgeat dilute with water, for subsequent use;
2) by step 1) dilution after orgeat solution carry out ultrasonic pretreatment, obtain ultrasonication liquid;
3) to step 2) add the amino acid that treatment solution mass ratio is 1 ~ 8% in the ultrasonication liquid that obtains, after mixing, the pH value of initial mixed solution is regulated to be 8 ~ 12 with alkali lye, mixed solution is transferred in flask, it is 100 ~ 120 DEG C that temperature controls, and under constantly stirring, Maillard reaction occurs, the reaction times is 2 ~ 5 hours, by reacted material after filtration, after concentrating under reduced pressure, both obtained orgeat Maillard reaction type tobacco aromatics using.
Preferably, described step 2) in supersonic treatment condition be: ultrasonic power is 200 ~ 800W, and ultrasonic temperature is 40 ~ 80 DEG C, and ultrasonic time is 30 ~ 60min.
Preferably, described step 3) in amino acid be one or more in L-Ala, aspartic acid, halfcystine, L-glutamic acid, leucine, Methionin, arginine, phenylalanine, glycine, proline(Pro), α-amino-isovaleric acid.
Preferably, described step 3) in alkali lye be the NaOH aqueous solution, the KOH aqueous solution, Na
2hPO
4the aqueous solution or Na
2cO
3the aqueous solution.
Preferably, described orgeat is commercially available prod.
The invention has the advantages that:
(1) the present invention adopts this physical refining processes of ultrasonic wave to carry out pre-treatment to raw material, under the strong hole effect that the vibration of low frequency fierceness produces, macromolecular substance protein in orgeat and polysaccharide etc. are converted into polypeptide or reductibility oligose, these materials can participate in Maillard reaction as precursor substance, impel the fragrant technology of product to generate more fragrance matter;
(2) orgeat is prepared Maillard reaction thing spices as sugared source by the present invention first, by adding amino acid, conservative control processing condition, a small amount of flavour substances that the fragrance produce Maillard reaction and orgeat itself contain organically combines, set off mutually, note is more abundant to be coordinated;
(3) the present invention has abundant raw material source, simple to operation, production cost is low, product aroma strength advantages of higher, tobacco aromatics using prepared by the present invention can promote cigarette flavor matter preferably, enrich perfume quantity, coordinate with cigarette perfume, increase flue gas concentration, soft fine and smooth flue gas, cover assorted gas, pleasant impression is comfortable, can apply as the new way of a kind of economy, High-efficient Production tobacco aromatics using.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
Be after 1:4 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 300W, temperature processes 30min under being the condition of 50 DEG C.Take 500g ultrasonication liquid, add 10g proline(Pro), after mixing, regulate the pH value of initial mixed solution to be 9 with the NaOH aqueous solution, mixed solution is moved in three-necked flask, load return line, under stirring, oil bath, condition of normal pressure, Maillard reaction occurs, it is 115 DEG C that temperature controls, and the reaction times is 3 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is brown liquid, and puffed rice fragrance is obvious, embodies comfortable nutty and roasting perfume.By products obtained therefrom according to 0.05% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: the fragrance of cigarette can be made more thoroughly to send out, fragrance is more abundant, coordinate, alleviate assorted gas, flue gas is more fine and smooth soft, and pleasant impression is comfortable.
Embodiment 2
Be after 1:6 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 600W, temperature processes 40min under being the condition of 70 DEG C.Take 500g ultrasonication liquid, add 20g aspartic acid, after mixing, use Na
2cO
3the aqueous solution regulates the pH value of initial mixed solution to be 11, mixed solution is moved in three-necked flask, load return line, Maillard reaction is there is under stirring, oil bath, condition of normal pressure, it is 110 DEG C that temperature controls, reaction times is 2 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is light brown liquid, embodies strong roasting fragrant and sweet gas.By products obtained therefrom according to 0.08% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: cigarette perfume (or spice) can be increased, promote aroma quality, alleviate assorted gas, increase flue gas concentration, pleasant impression is comfortable, improves mouthfeel.
Embodiment 3
Be after 1:5 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 400W, temperature processes 45min under being the condition of 65 DEG C.Take 500g ultrasonication liquid, add 20g L-Ala, after mixing, regulate the pH value of initial mixed solution to be 10 with the KOH aqueous solution, mixed solution is moved in three-necked flask, load return line, under stirring, oil bath, condition of normal pressure, Maillard reaction occurs, it is 115 DEG C that temperature controls, and the reaction times is 4 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is brown liquid, and what embody pleasant bakes fragrance, and is attended by burnt odor.By products obtained therefrom according to 0.1% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: can perfume quantity be enriched, promote aroma quality, with cigarette perfume coordinate, flue gas concentration has increased slightly, and the soft exquisiteness of flue gas, cover assorted gas, oral cavity is clean.
Embodiment 4
Be after 1:4 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 700W, temperature processes 50min under being the condition of 60 DEG C.Take 500g ultrasonication liquid, add 40g arginine, after mixing, use Na
2cO
3the aqueous solution regulates the pH value of initial mixed solution to be 12, mixed solution is moved in three-necked flask, load return line, Maillard reaction is there is under stirring, oil bath, condition of normal pressure, it is 100 DEG C that temperature controls, reaction times is 2 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is brown liquid, embodies strong roasting fragrant and sweet gas.By products obtained therefrom according to 0.05% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: fragrance is abundanter, promote fragrance texture, coordinates with cigarette perfume, increase flue gas concentration, the soft exquisiteness of flue gas, pleasant impression is comfortable.
Embodiment 5
Be after 1:8 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 400W, temperature processes 35min under being the condition of 55 DEG C.Take 500g ultrasonication liquid, add phenylalanine 5g, α-amino-isovaleric acid 10g, aspartic acid 25g, after mixing, use Na
2hPO
4the aqueous solution regulates the pH value of initial mixed solution to be 10, mixed solution is moved in three-necked flask, load return line, Maillard reaction is there is under stirring, oil bath, condition of normal pressure, it is 115 DEG C that temperature controls, reaction times is 3 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is brown liquid, embodies and significantly toasts fragrance.By products obtained therefrom according to 0.06% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: can perfume quantity be increased, enrich aroma quality, alleviate assorted gas, increase flue gas concentration, reduce stimulate, oral cavity is comparatively clean.
Embodiment 6
Be after 1:7 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 800W, temperature processes 50min under being the condition of 50 DEG C.Take 500g ultrasonication liquid, add L-glutamic acid 20g, proline(Pro) 5g, after mixing, regulate the pH value of initial mixed solution to be 9 with the KOH aqueous solution, mixed solution is moved in three-necked flask, load return line, under stirring, oil bath, condition of normal pressure, Maillard reaction occurs, it is 120 DEG C that temperature controls, and the reaction times is 4 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is brown liquid, embodies and significantly toasts fragrance, and with faint puffed rice breath.By products obtained therefrom according to 0.1% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: coordinates with cigarette perfume, can promote aroma quality, increase cigarette fragrant, cover assorted gas, flue gas concentration has increased slightly, and reduces and stimulates, and remains less.
Embodiment 7
Be after 1:8 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 200W, temperature processes 60min under being the condition of 40 DEG C.Take 500g ultrasonication liquid, add α-amino-isovaleric acid 10g, after mixing, use Na
2hPO
4the aqueous solution regulates the pH value of initial mixed solution to be 8, mixed solution is moved in three-necked flask, load return line, Maillard reaction is there is under stirring, oil bath, condition of normal pressure, it is 110 DEG C that temperature controls, reaction times is 4 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is brown liquid, embodies and significantly toasts fragrance.By products obtained therefrom according to 0.09% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: can perfume quantity be increased, enrich aroma quality, alleviate assorted gas, increase flue gas concentration, reduce stimulate, oral cavity is comparatively clean.
Embodiment 8
Be after 1:4 dilutes by orgeat according to the mass ratio with water, ultrasonic power be 400W, temperature processes 55min under being the condition of 80 DEG C.Take 500g ultrasonication liquid, add arginine 5g, after mixing, use Na
2cO
3the aqueous solution regulates the pH value of initial mixed solution to be 11, mixed solution is moved in three-necked flask, load return line, Maillard reaction is there is under stirring, oil bath, condition of normal pressure, it is 110 DEG C that temperature controls, reaction times is 5 hours, by reacted material after filtration, after concentrating under reduced pressure, namely obtain orgeat Maillard reaction type tobacco aromatics using.
Products obtained therefrom is brown liquid, embodies strong roasting fragrant and sweet gas.By products obtained therefrom according to 0.08% mass ratio add in blank pipe tobacco, draw through sensory evaluating smoking: fragrance is abundanter, promote fragrance texture, coordinates with cigarette perfume, increase flue gas concentration, the soft exquisiteness of flue gas, reduce stimulation, oral cavity is comparatively clean.
Above-described embodiment is only the best and exemplifies, and is not the restriction to embodiments of the present invention.
Claims (5)
1. a preparation method for orgeat Maillard reaction type tobacco aromatics using, is characterized in that: comprise the steps:
1) by orgeat dilute with water, for subsequent use;
2) by step 1) dilution after orgeat solution carry out ultrasonic pretreatment, obtain ultrasonication liquid;
3) to step 2) add the amino acid that treatment solution mass ratio is 1 ~ 8% in the ultrasonication liquid that obtains, after mixing, the pH value of initial mixed solution is regulated to be 8 ~ 12 with alkali lye, mixed solution is transferred in flask, it is 100 ~ 120 DEG C that temperature controls, and under constantly stirring, Maillard reaction occurs, the reaction times is 2 ~ 5 hours, by reacted material after filtration, after concentrating under reduced pressure, both obtained orgeat Maillard reaction type tobacco aromatics using.
2. the preparation method of orgeat Maillard reaction type tobacco aromatics using according to claim 1, it is characterized in that: described step 2) in supersonic treatment condition be: ultrasonic power is 200 ~ 800W, ultrasonic temperature is 40 ~ 80 DEG C, and ultrasonic time is 30 ~ 60min.
3. the preparation method of orgeat Maillard reaction type tobacco aromatics using according to claim 1, is characterized in that: described step 3) in amino acid be one or more in L-Ala, aspartic acid, halfcystine, L-glutamic acid, leucine, Methionin, arginine, phenylalanine, glycine, proline(Pro), α-amino-isovaleric acid.
4. the preparation method of orgeat Maillard reaction type tobacco aromatics using according to claim 1, is characterized in that: described step 3) in alkali lye be the NaOH aqueous solution, the KOH aqueous solution, Na
2hPO
4the aqueous solution or Na
2cO
3the aqueous solution.
5. the preparation method of orgeat Maillard reaction type tobacco aromatics using according to claim 1, is characterized in that: described orgeat is commercially available prod.
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| CN111700216A (en) * | 2020-05-08 | 2020-09-25 | 李苗 | Preparation method of oat concentrated pulp with high protein heat stability |
| CN114752440A (en) * | 2022-02-15 | 2022-07-15 | 河北中烟工业有限责任公司 | Lotus seed Maillard reactant, preparation method thereof and cigarette feeding liquid |
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