CN106190569A - A kind of method that Fructus Pruni extract and aromatics beta amino acids prepare tobacco aromatics using - Google Patents
A kind of method that Fructus Pruni extract and aromatics beta amino acids prepare tobacco aromatics using Download PDFInfo
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- CN106190569A CN106190569A CN201610793843.0A CN201610793843A CN106190569A CN 106190569 A CN106190569 A CN 106190569A CN 201610793843 A CN201610793843 A CN 201610793843A CN 106190569 A CN106190569 A CN 106190569A
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- amino acids
- fructus pruni
- aromatics
- mixture
- reaction
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/301—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by aromatic compounds
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
- A24B15/303—Plant extracts other than tobacco
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
Abstract
The invention discloses a kind of method that Fructus Pruni extract and aromatics beta amino acids prepare tobacco aromatics using, its method step is as follows: A, Fructus Pruni extract, aromatics beta amino acids are mixed according to following mass ratio: Fructus Pruni extract: aromatics beta amino acids=1～10:1；Then Fructus Pruni extract is mixed according to following mass ratio with reaction dissolvent with aromatics beta amino acids mixture: Fructus Pruni extract and aromatics beta amino acids mixture: reaction dissolvent=1:5～20；B, Fructus Pruni extract, aromatics beta amino acids, the mixed mixture of reaction dissolvent in step A being heated in 20～30 minutes 80～140 DEG C, mixture carries out Maillard reaction at a temperature of 80～140 DEG C；Mixture in C, step B sustained response 0.5～obtain tobacco aromatics using reactant in 6 hours at a temperature of 80～140 DEG C.The present invention enriches musical tone, and plentiful cigarette is fragrant, hence it is evident that promoting cigarette flavor matter, promote the production of body fluid Hui Tian in oral cavity, and especially in terms of covering miscellaneous QI, reducing stimulation, effect is notable.
Description
Technical field
The present invention relates to essence spice for cigarette technical field, particularly relate to a kind of Fructus Pruni extract and aromatics beta-amino acids
Maillard reaction prepares the method for tobacco aromatics using, is specifically related to Fructus Pruni extract as sugar source and the Mei La of aromatics beta-amino acids
The application in perfuming cigarette of tobacco aromatics using and tobacco aromatics using thereof is prepared in moral reaction.
Background technology
Since Maillard reaction (also known as Maillard reaction) self-discovery, at bromatology, threpsology, flavor chemistry, toxicity
Learn and Chinese materia medica research becomes unfailing research topic.Maillard reaction can produce a large amount of aroma component,
It is applied to preparing all kinds of essence and flavoring agent, fumet.This reaction gained essence is also regarded as " organically " by internal authority mechanism
" green ", thus its application is the most concerned, grinding of the fields such as organic chemistry, Food Chemistry, flavor chemistry, tobacco industry
Study carefully in the ascendant.
Mai11ard reaction is exactly the reaction occurred between amino-compound and reducing sugar or carbonyl compound, owing to it is final
Reaction is brown, so also having people referred to as browning reaction.The end product of browning reaction can be because of reaction bar
The difference of part or the raw material of participation reaction are different, and generate the product of different flavor.
Maillard reacts the three below stage that may be summarized to be: 1) starting stage, aldose or ketose and amine compound
Carry out condensation reaction, form Schiff's base, form corresponding N-through cyclisation and replace aldose base amine or N-replacement ketose base amine, warp
Amadori resets and forms 1-amino-1-deoxidation-2-ketose, or resets formation 2-amino-2-deoxidation-1-aldose through Heyns；2)
Second stage, resets during the heating of Amadori and Heyns intermediate and deamination forms reductone, dehydrogenase/reductase ketone, can be converted into
Alditol compounds；3) phase III, reductone and the cracking of dehydrogenase/reductase ketone form methylglyoxal, Biformyl, glyceraldehyde, ethanol
Aldehyde, 2, the dicarbonyl compound such as 3-diacetyl, hydroxypropanone-, it is anti-that dicarbonyl compound and aminoacid carry out Strecker degraded
Should, producing alpha-amido ketone, alpha-amido ketone can ultimately generate the heterocyclic compounds such as Pyrazine, pyroles, pyridines by cyclisation
Thing.The various heterocyclic compounds produced in Maillard reaction are the important fragrance components of Nicotiana tabacum L., and this material can be as food, Medicated cigarette
Flavoring substances.
It practice, the baking in the modulation of Nicotiana tabacum L., alcoholization and production of cigarettes processes, all there is Maillard reaction, reaction is produced
Thing has many compounds such as pyroles, Pyrazine, furans, and alcohol, aldehyde, ketone, amide.Particularly Maillard reaction can be produced
Uncured tobacco coordinates fragrance, to improving the characteristic perfume of medicated cigarette, covering miscellaneous QI, alleviate stimulations, improve pleasant impression and have and significantly act on.
Chinese patent (CN1415717A and CN1175623A) discloses " side being raw material production spice with tobacco extract
Method " and " preparation method of tobacco reacting substance perfume and utilization ", they are all with tobacco extract as raw material, add sugar and a-amino acid
There is Maillard reaction, although this method make use of Maillard reaction, but owing to the kind of institute's sugaring is single, merely add
This perfume of Nicotiana tabacum L. and burnt odor, perfume quantity is the abundantest, and aroma quality is also difficult to reach promising result.Chinese patent
(CN101654637A) disclose and utilize reducing sugar and a-amino acid in Fructus Pruni extract to react to carry out Maillard reaction tobacco aromatics using
Preparation, although it has and covers miscellaneous QI, reduces the effect such as stimulation, but the perfume quantity of its Maillard reaction and aroma quality need
Further promote.Chinese patent (CN103146481A) also discloses that and utilizes reducing sugar and aminoacid to carry out Maillard reaction system
The research of standby tobacco aromatics using, its preparation method has the features such as the simple yield of technique is high, production process is pollution-free, easy to operate,
But its reaction class balsamic tolerance generated is abundant not, aroma quality also needs to be improved further.Chinese patent
(CN104498184A) disclose fragrance of a flower Mel to be sugar source carry out Maillard reaction with alpha amino acid and prepare cigarette tobacco aromatics using, profit
Both reducing sugar can be provided with fragrance of a flower Mel to carry out Maillard reaction, fragrance of a flower component can have been increased again and enrich and improve perfume quantity
And aroma quality, but the rich of fragrance has much room for improvement.
In sum, domestic carried out some in the preparation of tobacco aromatics using and explore and grind carrying out Maillard reaction and carry out
Studying carefully, these job contents are concentrated mainly on kind selection, reducing sugar and the addition of a-amino acid of reducing sugar and a-amino acid
Deng on direction, note and rich the needing of its fragrance are improved further.
Fructus Pruni is one of Main Cultivation fruit variety of China, and Apricot Fruit is nutritious, containing multiple organic component and people
Vitamin necessary to body and inorganic salts, be the fruit that a kind of nutritive value is higher.The nutrition of Semen Armeniacae Amarum is more rich, containing protein
23～27%, crude fat 50～60%, saccharide 10%, possibly together with inorganic salts and multivitamins such as phosphorus, ferrum, potassium, it is nourishing
Good merchantable brand.Fructus Pruni fruit has good medical function, occupies critical role in Chinese herbal medicine.Fructus Pruni fruit is used for curing mainly wind and cold pneumonopathy, promoting the production of body fluid to quench thirst,
Moistening the lung and resolving phlegm, heat-clearing and toxic substances removing.
In recent years, the effect of Fructus Pruni further extends into tobacco business, and the Fructus Pruni extract utilizing Fructus Pruni fruit to prepare exists
Nicotiana tabacum L. can substantially be covered miscellaneous QI, reduce and stimulate, make that pleasant impression is the most comfortable, the soft exquisiteness of flue gas is mellow.Fructus Pruni extract contains
A certain amount of reducing sugar, such as glucose, fructose, possibly together with saccharides such as some other xylose, sucrose.
Maillard reaction phase III aminoacid, with the effect of dicarbonyl compound, exists at dicarbonyl compound
Under, aminoacid can occur decarboxylation, deamination, generates aldehyde and carbon dioxide, and its amino acid whose amino transfers to two carbonyls through deamination
Generating Si Teleke aldehydes or ketones (alpha-amido aldehydes or ketones) on based compound, alpha-amido aldehydes or ketones is the important thing producing flavor molecule
Matter, they with self-condensation, or can be condensed with alditol or other dehydration products, generates heterocyclic fragrance matter and other are fragrant
Taste material.As, the self-condensation of two molecule Si Teleke aldehyde can generate Pyrazine flavor component.It addition, after aminoacid deamination
The flavor molecules such as the aldehyde produced and the alcohol of further reaction generation, acid, ester also have important help to abundant Medicated cigarette note.
Summary of the invention
The weak point existed for prior art, it is an object of the invention to provide a kind of Fructus Pruni extract and aromatics
Beta-amino acids prepares the method for tobacco aromatics using, utilizes the reducing sugar in Fructus Pruni extract completely or partially to substitute Maillard reaction institute
The sugar needed, reacts with aromatics beta-amino acids, can prepare more preferable fragrance-enhancing tobacco flavoring agent.Fructus Pruni extract
In do not contain only the reducing sugar participating in reaction, cause fragrant components, the cause perfumery produced except Maillard reaction possibly together with many volatility
Outside matter, the fragrance that aromatics beta-amino acids degraded simultaneously produces causes fragrant component, can increase the perfume quantity of Medicated cigarette, can promote again volume
The aroma quality of cigarette, thus the cigarette reaching to achieve many things at one stroke causes fragrant effect.This Fructus Pruni extract is utilized to enter with β-ArAA
Row Maillard reaction prepares the method for tobacco aromatics using, and its raw material sources are extensive, and the reaction class spice of preparation, perfume quantity is richer
Richness, aroma quality is higher, has well improvement to cigarette quality quality.The present invention utilizes Maillard reaction to prepare tobacco aromatics using, will
Sugar required for the part or all of vicarious responding of Fructus Pruni extract, and fragrance beta-amino acids is in certain temperature and certain molten
Agent is reacted, it is thus achieved that perfume quantity can be enriched, promote the tobacco aromatics using of aroma quality.
The purpose of the present invention is achieved through the following technical solutions:
A kind of method that Fructus Pruni extract and aromatics beta-amino acids prepare tobacco aromatics using, its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are mixed according to following mass ratio: Fructus Pruni extract: aromatics
Beta-amino acids=1～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with reaction dissolvent according to following matter
Amount ratio mixes: Fructus Pruni extract and aromatics beta-amino acids mixture: reaction dissolvent=1:5～20；Regulation Fructus Pruni extracts
After the mixing of thing, aromatics beta-amino acids, reaction dissolvent, the pH value of mixture reaction system is 7～10；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
Being heated to 80～140 DEG C in clock, mixture carries out Maillard reaction at a temperature of 80～140 DEG C；
Mixture in C, step B sustained response 0.5～obtain reactant in 6 hours at a temperature of 80～140 DEG C is the most right
Reactant carries out cooling process and i.e. can get tobacco aromatics using.
It is as follows that what the present invention was further preferred prepares tobacco aromatics using method, and its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=1～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture
It is stirred mixing in reaction vessel according to following mass ratio with reaction dissolvent: Fructus Pruni extract mixes with aromatics beta-amino acids
Compound: reaction dissolvent=1:5～20；Mixture reaction after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
The pH value of system is 7～10；The speed of stirring is 100～400rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 80～140 DEG C in clock, the reaction appearance of Fructus Pruni extract, aromatics beta-amino acids, reaction solvent mixture will be deposited
Device heats and made mixture be heated to 80～140 DEG C in 20～30 minutes；Mixture is carried out at a temperature of 80～140 DEG C
Maillard reaction；
Mixture in C, step B be heated to 90～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 110～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.
The present invention the first preferably to prepare tobacco aromatics using method as follows, its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=3～8:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with
Reaction dissolvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract mixes with aromatics beta-amino acids
Thing: reaction dissolvent=1:10～15；Mixture reaction after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
The pH value of system is 7～10；The speed of stirring is 265～350rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 100～120 DEG C in clock, the reaction appearance of Fructus Pruni extract, aromatics beta-amino acids, reaction solvent mixture will be deposited
Device heats and made mixture be heated to 100～120 DEG C in 20～30 minutes；Mixture enters at a temperature of 100～120 DEG C
Row Maillard reaction；
Mixture in C, step B be heated to 100～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 110～120 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.
It is as follows that the second of the present invention preferably prepares tobacco aromatics using method, and its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=1～4:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with
Reaction dissolvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract mixes with aromatics beta-amino acids
Thing: reaction dissolvent=1:5～10；Mixture reaction body after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
The pH value of system is 7～10；The speed of stirring is 300～400rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 100～140 DEG C in clock, Fructus Pruni extract, aromatics beta-amino acids, the reactor of reaction solvent mixture will be deposited
Heat and made mixture be heated to 100～140 DEG C in 20～30 minutes；Mixture is carried out at a temperature of 100～140 DEG C
Maillard reaction；
Mixture in C, step B be heated to 103～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 130～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.
The present invention the third preferably to prepare tobacco aromatics using method as follows, its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=4～7:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with
Reaction dissolvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract mixes with aromatics beta-amino acids
Thing: reaction dissolvent=1:10～15；Mixture reaction after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
The pH value of system is 7～10；The speed of stirring is 200～300rpm；
B, by Fructus Pruni extract in step A, fragrance beta-amino acids, the mixed mixture of reaction dissolvent at 20～30 minutes
Inside it is heated to 90～140 DEG C, Fructus Pruni extract, aromatics beta-amino acids, the reaction vessel of reaction solvent mixture will be deposited
Heat and made mixture be heated to 90～140 DEG C in 20～30 minutes；Mixture carries out U.S. at a temperature of 90～140 DEG C
Maillard reaction；
Mixture in C, step B be heated to 97～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 120～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.
It is as follows that the present invention the 4th kind preferably prepares tobacco aromatics using method, and its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=7～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture
It is placed in reaction vessel according to following mass ratio with reaction dissolvent and is stirred mixing: Fructus Pruni extract mixes with fragrance beta-amino acids
Compound: reaction dissolvent=1:15～20；After regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing, mixture is anti-
The pH value answering system is 7～10；The speed of stirring is 100～200rpm；
B, by Fructus Pruni extract in step A, fragrance beta-amino acids, the mixed mixture of reaction dissolvent at 20～30 minutes
Inside it is heated to 90～140 DEG C, Fructus Pruni extract will be deposited, fragrance beta-amino acids, the reaction vessel of reaction solvent mixture add
Heat and made mixture be heated to 90～140 DEG C in 20～30 minutes；Mixture carries out Mei La at a temperature of 90～140 DEG C
Moral is reacted；
Mixture in C, step B be heated to 90～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 110～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.
It is as follows that the present invention prepares preferred reaction dissolvent composition in tobacco aromatics using method, and described reaction dissolvent is water or polynary
Alcohol or water and polyol blends, described polyhydric alcohol is the one of ethylene glycol, propylene glycol, 1,3 butylene glycol, diethylene glycol or glycerol
Or it is multiple.
The present invention prepares in tobacco aromatics using method, and described Fructus Pruni extract is Fructus Pruni extractum or apricot juice, and described Fructus Pruni soaks
Cream is the concentrate after being extracted by water or water and alcohol mixed solvent, and described apricot juice is the juice that squeezing Fructus Pruni sarcocarp obtains
Liquid；Material included by described Fructus Pruni extract is as follows: glucide, alcohols material, Ester, acid.
It is β-phenylalanine, β-tyrosine, β-color that the present invention prepares aromatics beta-amino acids described in tobacco aromatics using method
Propylhomoserin, Betahistidine one or more.
As preferably, described reaction dissolvent is polyhydric alcohol and aqueous mixtures, and wherein polyhydric alcohol is 4～8 with the volume ratio of water:
1。
The present invention compared with the prior art, has the following advantages and beneficial effect:
The present invention is the cigarette perfume carrying out Maillard reaction based on aromatics beta-amino acids and Fructus Pruni extract and preparing
Material product, this tobacco aromatics using product can be obviously improved cigarette flavor matter, and abundant plentiful cigarette is fragrant, improves fragrance, the association of note
Tonality；Can also improve Medicated cigarette pleasant impression, promote the production of body fluid Hui Tian, improves suction quality, aesthetic quality mark total score improve about 3～6 points；
Present invention effect in terms of covering miscellaneous QI, reducing stimulation is especially pronounced.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail:
Embodiment
A kind of method that Fructus Pruni extract prepares tobacco aromatics using with fragrance beta-amino acids Maillard reaction, its method step is such as
Under:
A, Fructus Pruni extract, aromatics beta-amino acids are mixed according to following mass ratio: Fructus Pruni extract: aromatics
Beta-amino acids=1～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with reaction dissolvent according to following matter
Amount ratio mixes: Fructus Pruni extract and aromatics beta-amino acids mixture: reaction dissolvent=1:5～20；With ammonia or Fructus Citri Limoniae
The potassium salt of acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or sodium hydroxide or potassium hydroxide regulation Fructus Pruni extract, aromatics
After the mixing of beta-amino acids, reaction dissolvent, the pH value of mixture reaction system is 7～10；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
Being heated to 80～140 DEG C in clock, mixture carries out Maillard reaction at a temperature of 80～140 DEG C；
Mixture in C, step B sustained response 0.5～obtain reactant in 6 hours at a temperature of 80～140 DEG C is the most right
Reactant carries out cooling process and i.e. can get tobacco aromatics using.
It is as follows that what the present invention was further preferred prepares tobacco aromatics using method, and its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=1～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture
It is stirred mixing in reaction vessel according to following mass ratio with reaction dissolvent: Fructus Pruni extract mixes with aromatics beta-amino acids
Compound: reaction dissolvent=1:5～20；With the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or hydrogen-oxygen
Change the pH of mixture reaction system after sodium or potassium hydroxide regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
Value is 7～10；The speed of stirring is 100～400rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 80～140 DEG C in clock, the reaction appearance of Fructus Pruni extract, aromatics beta-amino acids, reaction solvent mixture will be deposited
Device heats and made mixture be heated to 80～140 DEG C in 20～30 minutes；Mixture is carried out at a temperature of 80～140 DEG C
Maillard reaction, by the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or sodium hydroxide or hydroxide
It is 7～10 that potassium regulation controls the pH of reactant mixture, so can improve the efficiency of Maillard reaction；
Mixture in C, step B be heated to 90～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 110～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.
The present invention the first preferably to prepare tobacco aromatics using method as follows, its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=3～8:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with
Reaction dissolvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract mixes with aromatics beta-amino acids
Thing: reaction dissolvent=1:10～15；By the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or hydroxide
The pH value of mixture reaction system after sodium or potassium hydroxide regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
It is 7～10；The speed of stirring is 265～350rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 100～120 DEG C in clock, the reaction appearance of Fructus Pruni extract, aromatics beta-amino acids, reaction solvent mixture will be deposited
Device heats and made mixture be heated to 100～120 DEG C in 20～30 minutes；Mixture enters at a temperature of 100～120 DEG C
Row Maillard reaction；With the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or sodium hydroxide or hydrogen-oxygen
The pH changing potassium regulation control reactant mixture is 7～10.
Mixture in C, step B be heated to 100～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 110～120 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.Specific as follows: the mixture in step B be heated to 100～110 DEG C at a temperature of sustained response
1～1.5 hour, sustained response 0.5～1 hour at a temperature of being warming up to 110～120 DEG C the most again；Step B and step C obtain
Reactant, then carries out cooling process and i.e. can get tobacco aromatics using reactant.
It is as follows that the second of the present invention preferably prepares tobacco aromatics using method, and its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=1～4:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with
Reaction dissolvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract mixes with aromatics beta-amino acids
Thing: reaction dissolvent=1:5～10；By the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or hydroxide
The pH value of mixture reaction system after potassium or sodium hydroxide regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
It is 7～10；The speed of stirring is 300～400rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 100～140 DEG C in clock, the reaction appearance of Fructus Pruni extract, aromatics beta-amino acids, reaction solvent mixture will be deposited
Device heats and made mixture be heated to 100～140 DEG C in 20～30 minutes；Mixture enters at a temperature of 100～140 DEG C
Row Maillard reaction；With the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or potassium hydroxide or hydrogen-oxygen
The pH changing sodium regulation control reactant mixture is 7～10, so can improve Maillard reaction efficiency.
Mixture in C, step B be heated to 103～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 130～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.At a temperature of mixture in step B is heated to 103～110 DEG C, sustained response 1～1.5 is little
Time, sustained response 0.5～1 hour at a temperature of being warming up to 130～140 DEG C the most again；Step B and step C obtain reactant, so
Afterwards reactant is carried out cooling process and i.e. can get tobacco aromatics using.
The present invention the third preferably to prepare tobacco aromatics using method as follows, its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=4～7:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture with
Reaction dissolvent is passed through in reaction vessel according to following mass ratio and is stirred mixing: Fructus Pruni extract mixes with aromatics beta-amino acids
Compound: reaction dissolvent=1:10～15；With the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or hydrogen-oxygen
Change the pH of mixture reaction system after potassium or sodium hydroxide regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
Value is 7～10；The speed of stirring is 200～300rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 90～140 DEG C in clock, the reaction appearance of Fructus Pruni extract, aromatics beta-amino acids, reaction solvent mixture will be deposited
Device heats and made mixture be heated to 90～140 DEG C in 20～30 minutes；Mixture is carried out at a temperature of 90～140 DEG C
Maillard reaction；By the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or sodium hydroxide or hydroxide
It is 7～10 that potassium regulation controls the pH of reactant mixture, so can improve Maillard reaction efficiency
Mixture in C, step B be heated to 97～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 120～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.Specific as follows: the mixture in step B be heated to 97～110 DEG C at a temperature of sustained response 1
～1.5 hours, sustained response 0.5～1 hour at a temperature of being warming up to 120～140 DEG C the most again；Step B and step C obtain anti-
Answer thing, then reactant is carried out cooling process and i.e. can get tobacco aromatics using.
It is as follows that the present invention the 4th kind preferably prepares tobacco aromatics using method, and its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio it are stirred mixing
Close: Fructus Pruni extract: aromatics beta-amino acids=7～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture
It is passed through in reaction vessel according to following mass ratio with reaction dissolvent and is stirred mixing: Fructus Pruni extract and aromatics beta-amino acids
Mixture: reaction dissolvent=1:15～20；With the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or hydrogen
Mixture reaction system after sodium oxide or potassium hydroxide regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
PH value is 7～10；The speed of stirring is 100～200rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A at 20～30 points
It is heated to 90～140 DEG C in clock, the reaction appearance of Fructus Pruni extract, aromatics beta-amino acids, reaction solvent mixture will be deposited
Device heats and made mixture be heated to 90～140 DEG C in 20～30 minutes；Mixture is carried out at a temperature of 90～140 DEG C
Maillard reaction；By the potassium salt of ammonia or citric acid, tartaric acid, malic acid, acetic acid etc. or sodium salt or sodium hydroxide or hydroxide
It is 7～10 that potassium regulation controls the pH of reactant mixture, so can improve Maillard reaction efficiency.
Mixture in C, step B be heated to 90～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again
Sustained response 1～2 hours at a temperature of 110～140 DEG C；Step B and step C obtain reactant, then reactant is carried out cold
But process and i.e. can get tobacco aromatics using.Specific as follows: the mixture in step B be heated to 90～110 DEG C at a temperature of sustained response 1
～1.5 hours, sustained response 0.5～1 hour at a temperature of being warming up to 110～140 DEG C the most again；Step B and step C obtain anti-
Answer thing, then reactant is carried out cooling process and i.e. can get tobacco aromatics using.
It is as follows that the present invention prepares preferred reaction dissolvent composition in tobacco aromatics using method, and described reaction dissolvent is water or polynary
Alcohol or water and polyol blends, described polyhydric alcohol is the one of ethylene glycol, propylene glycol, 1,3 butylene glycol, diethylene glycol or glycerol
Or it is multiple.
The present invention prepares in tobacco aromatics using method, and described Fructus Pruni extract is Fructus Pruni extractum or apricot juice, and described Fructus Pruni soaks
Cream is the concentrate after being extracted by water or water and alcohol mixed solvent, and described apricot juice is the juice that squeezing Fructus Pruni sarcocarp obtains
Liquid；Material included by described Fructus Pruni extract is as follows: glucide, alcohols material, Ester, acid.
The present invention prepares in tobacco aromatics using method, and described aromatics beta-amino acids is β-phenylalanine, β-tyrosine, β-color
Propylhomoserin, Betahistidine one or more.
As preferably, described reaction dissolvent is polyhydric alcohol and aqueous mixtures, and wherein polyhydric alcohol is 4～8 with the volume ratio of water:
1。
Control sample 1
Take blank tobacco shred, according to the process of conventional flavoring and casing, adding by tobacco shred weight 0.1% on blank tobacco shred
Dosage uniformly sprays blank solvent, is 22 DEG C ± 1 DEG C in temperature, relative humidity be 60% ± 2% climatic chamber in balance
48 hours, then make into Medicated cigarette by hand.Carrying out sense organ comparison to smoke panel test. smoking result is shown in Table 1.
Control sample 2
Weigh 30g Fructus Pruni extract and 1.65g α-phenylalanine, put in there-necked flask, add 316g propylene glycol and water
Mixed solution, and with ammonia regulation solution pH value be 8, start stirring, mixing speed is 180rpm；Then returned cold is connected
Solidifying pipe, is heated to 100 DEG C with oil bath and reacts 3 hours, terminates heating after then heating to 120 DEG C of stirrings 2 hours, and mixing speed is
180rpm；Pour out reactant after natural cooling and i.e. can get tobacco aromatics using, be sample controls sample 2.Prepared cigarette is fragrant
Material is diluted to certain density solution, according to the process of conventional flavoring and casing, by tobacco shred weight 0.1% (in an embodiment
In the range of 0.01～0.5% can be selected, but identical at the addition of control sample 2, embodiment 1～5) addition uniformly spray
On the tobacco shred of unprinted leaf group of formula, be 22 DEG C ± 1 DEG C in temperature, relative humidity be 60% ± 2% climatic chamber in flat
Weigh 48 hours, then make into Medicated cigarette by hand.Carrying out sense organ comparison to smoke panel test, this product of discovery of smokeing panel test contributes to soft flue gas, covers
Lid miscellaneous QI, aroma quality and note are rich slightly to be promoted.Smoking result is shown in Table 1.
Embodiment 1
Weigh 22.5g Fructus Pruni extract and 0.413g β-phenylalanine, put in there-necked flask, add 115g propylene glycol and
The mixed solution of water, and with ammonia regulation solution pH value be 8, start stirring, mixing speed is 180rpm；Then backflow is connected
Condensing tube, is heated to 100 DEG C with oil bath and reacts 3 hours, and mixing speed is 180rpm, after then heating to 120 DEG C of stirrings 2 hours
Terminating heating, mixing speed is 180rpm；Pour out reactant after natural cooling and i.e. can get tobacco aromatics using, be the product of the present invention
Product (Samples EXAMPLE 1).Obtained reactant (tobacco aromatics using) shows stronger fragrance of a flower rhythm.By prepared tobacco aromatics using
It is diluted to certain density solution (its concentration is identical with the diluted concentration of control sample 2), (is implementing by the 0.1% of tobacco shred weight
In the range of example can select 0.01～0.5%, but identical at the addition of control sample 2, embodiment 1～5) ratio, according to
The process of conventional flavoring and casing, is uniformly sprayed on the tobacco shred of unprinted leaf group of formula, is 22 DEG C ± 1 DEG C in temperature, relatively
Humidity be 60% ± 2% climatic chamber in balance 48 hours, then make into Medicated cigarette by hand.In this example by this product with
The addition of 0.1% joins and carries out cigarette effect in blank tobacco shred and smoke panel test, and finds that this product can make the soft exquisiteness of flue gas, cover
Lid miscellaneous QI, suppression stimulate, pleasant impression is the most comfortable, promote aroma quality.Contrast smoking result is shown in Table 1.
Embodiment 2
Weigh 22.5g Fructus Pruni extract and 0.0.413 β-phenylalanine, put in there-necked flask, add 115g propylene glycol and
The mixed solution of water, and with ammonia regulation solution pH value be 8, start stirring, mixing speed is 180rpm；Then backflow is connected
Condensing tube, is heated to 100 DEG C with oil bath and reacts 3 hours, and mixing speed is 180rpm, after then heating to 120 DEG C of stirrings 2 hours
Terminating heating, mixing speed is 180rpm；Pour out reactant after natural cooling and i.e. can get tobacco aromatics using, be the product of the present invention
Product (Samples EXAMPLE 2).Obtained reactant (tobacco aromatics using) shows the strongest fragrance of a flower and sweet note.By prepared
Tobacco aromatics using is diluted to certain density solution (its concentration is identical with the diluted concentration of control sample 2), by the 0.1% of tobacco shred weight
The ratio of (in the range of 0.01～0.5% can being selected in an embodiment, but identical at the addition of control sample 2, embodiment 1～5)
Example, according to the process of conventional flavoring and casing, is uniformly sprayed on the tobacco shred of unprinted leaf group of formula, is 22 DEG C ± 1 in temperature
DEG C, relative humidity be 60% ± 2% climatic chamber in balance 48 hours, then make into Medicated cigarette by hand.Should in this example
Product joins with the addition of 0.1% and carries out cigarette effect in blank tobacco shred and smoke panel test, and finds that this product can make flue gas promote the production of body fluid
Return sweet sense, to cover miscellaneous QI, pleasant impression the most comfortable, improves the suction quality of Medicated cigarette.Contrast smoking result is shown in Table 1.
Embodiment 3
Weigh 22.5g apricot juice and 0.413g β-tyrosine, put in there-necked flask, add the mixed of 115g propylene glycol and water
Closing solution, and the pH value with ammonia regulation solution is 9, starts stirring, mixing speed is 180rpm；Then reflux condensation mode is connected
Pipe, is heated to 100 DEG C with oil bath and reacts 3 hours, and mixing speed is 180rpm, terminates after then heating to 120 DEG C of stirrings 2 hours
Heating, mixing speed is 180rpm；Pour out reactant after natural cooling and i.e. can get tobacco aromatics using, be the product of the present invention
(Samples EXAMPLE 3).Obtained reactant (tobacco aromatics using) shows the strongest fragrance of a flower and sweet note.By prepared cigarette
It is diluted to certain density solution (its concentration is identical with the diluted concentration of control sample 2), by the 0.1% of tobacco shred weight with spice
The ratio of (in the range of 0.01～0.5% can being selected in an embodiment, but identical at the addition of control sample 2, embodiment 1～5)
Example, according to the process of conventional flavoring and casing, is uniformly sprayed on the tobacco shred of unprinted leaf group of formula, is 22 DEG C ± 1 in temperature
DEG C, relative humidity be 60% ± 2% climatic chamber in balance 48 hours, then make into Medicated cigarette by hand.Should in this example
Product joins with the addition of 0.1% and carries out cigarette effect in blank tobacco shred and smoke panel test, and finds that this product can make flue gas soft
Exquisiteness is mellow, perfume quantity increases, cover miscellaneous QI, suppression stimulates, pleasant impression is the most comfortable, improves the suction quality of Medicated cigarette.Contrast
Smoking result is shown in Table 1.
Embodiment 4
Weigh 22.5g Fructus Pruni extractum and 0.413g Betahistidine, put in there-necked flask, add 115g propylene glycol and water
Mixed solution, and with ammonia regulation solution pH value be 10, start stirring, mixing speed is 180rpm；Then returned cold is connected
Solidifying pipe, is heated to 100 DEG C with oil bath and reacts 3 hours, and mixing speed is 180rpm, whole after then heating to 120 DEG C of stirrings 2 hours
Only heating, mixing speed is 180rpm；Pour out reactant after natural cooling and i.e. can get tobacco aromatics using, be the product of the present invention
(Samples EXAMPLE 4).Obtained reactant (tobacco aromatics using) shows the strongest fragrance of a flower and sweet note.By prepared cigarette
It is diluted to certain density solution (its concentration is identical with the diluted concentration of control sample 2), by the 0.1% of tobacco shred weight with spice
The ratio of (in the range of 0.01～0.5% can being selected in an embodiment, but identical at the addition of control sample 2, embodiment 1～5)
Example, according to the process of conventional flavoring and casing, is uniformly sprayed on the tobacco shred of unprinted leaf group of formula, is 22 DEG C ± 1 in temperature
DEG C, relative humidity be 60% ± 2% climatic chamber in balance 48 hours, then make into Medicated cigarette by hand.Should in this example
Product joins with the addition of 0.1% and carries out cigarette effect in blank tobacco shred and smoke panel test, and finds that this product can make flue gas soft
Exquisiteness is mellow, perfume quantity increases, cover miscellaneous QI, suppression stimulates, pleasant impression is the most comfortable, improves the suction quality of Medicated cigarette.Contrast
Smoking result is shown in Table 1.
Smoke panel test qualification: by specific embodiment (embodiment 1～4) and the essence (i.e. tobacco aromatics using) prepared of control sample 2 exists
Apply same ratio (0.1%) under identical conditions, with reference to Medicated cigarette standard GB/T 5606.4-2005, roll into cigarette, in temperature
Be 22 DEG C ± 1 DEG C, relative humidity be 60% ± 2% climatic chamber in balance 48 hours.And carry out sense organ to applying sample
Smokeing panel test, compare with the blank Medicated cigarette not adding essence and smoke panel test, ten members of sensory evaluating smoking group, standard of smokeing panel test uses
Regulation in GB5606.4-2005, smoking result averages, and its contrast smoking result refers to table 1.Present invention is generally directed to U.S.
Maillard reaction phase III Strecker degradation reaction process, selecting the aminoacid in Maillard reacts is fragrance beta-amino
Acid and natural origin Fructus Pruni extract carry out Maillard and react preparation cigarette flavor.Aromatics beta-amino in degradation process
Acid easily deamination (J.Agri.Food.Chem., 1998,46,1515-1517), be more beneficial for generating important reactive intermediate this
Te Kele aldehydes or ketones, is the most more easily generated flavor matter.Also it is more likely formed fragrance after aromatics amino acid degradation deamination simultaneously
Flavor matter, such as fragrance matters such as aldehyde, acid, ester, alcohol, these fragrance matters can more enrich the note of flue gas, improves suction
Quality.
Table 1 contrasts smoking result table
| Sample | Gloss | Fragrance | Coordinate | Miscellaneous QI | Stimulate | Pleasant impression | Add up to |
| Control sample-1 | 4.0 | 26.0 | 4.5 | 10.0 | 16.5 | 20.5 | 81.5 |
| Control sample-2 | 4.0 | 27.0 | 4.5 | 10.5 | 16.7 | 21.0 | 83.8 |
| Embodiment 1 | 4.0 | 28.1 | 5.1 | 10.9 | 17.6 | 22.1 | 87.7 |
| Embodiment 2 | 4.0 | 28.4 | 4.5 | 10.5 | 17.5 | 21.5 | 86.4 |
| Embodiment 3 | 4.0 | 27.6 | 4.6 | 10.1 | 17.1 | 21.6 | 84.9 |
| Embodiment 4 | 4.0 | 27.7 | 4.7 | 10.1 | 17.1 | 21.6 | 85.1 |
Show from contrast sensory evaluating smoking's result of table 1: present invention U.S. based on aromatics beta-amino acids Yu Fructus Pruni extract
The tobacco aromatics using product of Maillard reaction can be obviously improved cigarette flavor matter, and abundant plentiful cigarette is fragrant, improves fragrance, the coordination of note
Property, especially in terms of covering miscellaneous QI, reducing stimulation, effect is notable；But also Medicated cigarette pleasant impression can be improved, promote the production of body fluid Hui Tian, improves
Suction quality, aesthetic quality's total score of marking improves about 3～6 points.Also show under equal conditions, the β-phenylpropyl alcohol of fragrance simultaneously
The tobacco aromatics using perfuming cigarette effect that tobacco aromatics using prepared by propylhomoserin Maillard reaction is prepared than α-phenylalanine Maillard reaction
More notable, suction quality improvement becomes apparent from.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.
Claims (10)
1. the method that a Fructus Pruni extract prepares tobacco aromatics using with aromatics beta-amino acids, it is characterised in that: its method step
As follows:
A, Fructus Pruni extract, aromatics beta-amino acids are mixed according to following mass ratio: Fructus Pruni extract: aromatics β-ammonia
Base acid=1～10:1；Then by the mixture of Fructus Pruni extract and aromatics beta-amino acids with reaction dissolvent according to following quality
Ratio mixes: Fructus Pruni extract and aromatics beta-amino acids mixture: reaction dissolvent=1:5～20；Regulation Fructus Pruni extract,
After the mixing of aromatics beta-amino acids, reaction dissolvent, the pH value of mixture reaction system is 7～10；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A in 20～30 minutes
Being heated to 80～140 DEG C, mixture carries out Maillard reaction at a temperature of 80～140 DEG C；
Mixture in C, step B sustained response 0.5～obtain reactant, then to reaction in 6 hours at a temperature of 80～140 DEG C
Thing carries out cooling process and i.e. can get tobacco aromatics using.
2. the method preparing tobacco aromatics using according to a kind of Fructus Pruni extract described in claim 1 and aromatics beta-amino acids, its
It is characterised by: its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio be stirred mixing: Fructus Pruni
Seed extract: aromatics beta-amino acids=1～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture and reaction
Solvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract and aromatics beta-amino acids mixture:
Reaction dissolvent=1:5～20；Mixture reaction system after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
PH value be 7～10；The speed of stirring is 100～400rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A in 20～30 minutes
It is heated to 80～140 DEG C, Fructus Pruni extract will be deposited, aromatics beta-amino acids, the reaction vessel of reaction solvent mixture add
Heat and made mixture be heated to 80～140 DEG C in 20～30 minutes；Mixture carries out Mei La at a temperature of 80～140 DEG C
Moral is reacted；
Mixture in C, step B be heated to 90～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again 110～
Sustained response 1～2 hours at a temperature of 140 DEG C；Step B and step C obtain reactant, then reactant is carried out cooling process
I.e. can get tobacco aromatics using.
3. the method preparing tobacco aromatics using according to a kind of Fructus Pruni extract described in claim 2 and aromatics beta-amino acids, its
It is characterised by: its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio be stirred mixing: Fructus Pruni
Seed extract: aromatics beta-amino acids=3～8:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture and reaction
Solvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract and aromatics beta-amino acids mixture:
Reaction dissolvent=1:10～15；Mixture reaction system after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
PH value be 7～10；The speed of stirring is 265～350rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A in 20～30 minutes
It is heated to 100～120 DEG C, Fructus Pruni extract will be deposited, aromatics beta-amino acids, the reaction vessel of reaction solvent mixture add
Heat and made mixture be heated to 100～120 DEG C in 20～30 minutes；Mixture carries out U.S. at a temperature of 100～120 DEG C
Maillard reaction；
Mixture in C, step B be heated to 100～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again 110～
Sustained response 1～2 hours at a temperature of 120 DEG C；Step B and step C obtain reactant, then reactant is carried out cooling process
I.e. can get tobacco aromatics using.
4. the method preparing tobacco aromatics using according to a kind of Fructus Pruni extract described in claim 2 and aromatics beta-amino acids, its
It is characterised by: its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio be stirred mixing: Fructus Pruni
Seed extract: aromatics beta-amino acids=1～4:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture and reaction
Solvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract and aromatics beta-amino acids mixture:
Reaction dissolvent=1:5～10；Mixture reaction system after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
PH value be 7～10；The speed of stirring is 300～400rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A in 20～30 minutes
It is heated to 100～140 DEG C, Fructus Pruni extract will be deposited, aromatics beta-amino acids, the reaction vessel of reaction solvent mixture add
Heat and made mixture be heated to 100～140 DEG C in 20～30 minutes；Mixture carries out Mei La at a temperature of 100～140 DEG C
Moral is reacted；
Mixture in C, step B be heated to 103～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again 130～
Sustained response 1～2 hours at a temperature of 140 DEG C；Step B and step C obtain reactant, then reactant is carried out cooling process
I.e. can get tobacco aromatics using.
5. the method preparing tobacco aromatics using according to a kind of Fructus Pruni extract described in claim 2 and aromatics beta-amino acids, its
It is characterised by: its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio be stirred mixing: Fructus Pruni
Seed extract: aromatics beta-amino acids=4～7:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture and reaction
Solvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract and aromatics beta-amino acids mixture:
Reaction dissolvent=1:10～15；Mixture reaction system after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
PH value be 7～10；The speed of stirring is 200～300rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A in 20～30 minutes
It is heated to 90～140 DEG C, Fructus Pruni extract will be deposited, aromatics beta-amino acids, the reaction vessel of reaction solvent mixture add
Heat and made mixture be heated to 90～140 DEG C in 20～30 minutes；Mixture carries out Mei La at a temperature of 90～140 DEG C
Moral is reacted；
Mixture in C, step B be heated to 97～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again 120～
Sustained response 1～2 hours at a temperature of 140 DEG C；Step B and step C obtain reactant, then reactant is carried out cooling process
I.e. can get tobacco aromatics using.
6. the method preparing tobacco aromatics using according to a kind of Fructus Pruni extract described in claim 2 and aromatics beta-amino acids, its
It is characterised by: its method step is as follows:
A, Fructus Pruni extract, aromatics beta-amino acids are placed in reaction vessel according to following mass ratio be stirred mixing: Fructus Pruni
Seed extract: aromatics beta-amino acids=7～10:1；Then by Fructus Pruni extract and aromatics beta-amino acids mixture and reaction
Solvent is stirred mixing according to following mass ratio in reaction vessel: Fructus Pruni extract and aromatics beta-amino acids mixture:
Reaction dissolvent=1:15～20；Mixture reaction system after regulation Fructus Pruni extract, aromatics beta-amino acids, reaction dissolvent mixing
PH value be 7～10；The speed of stirring is 100～200rpm；
B, by Fructus Pruni extract, aromatics beta-amino acids, the mixed mixture of reaction dissolvent in step A in 20～30 minutes
It is heated to 90～140 DEG C, Fructus Pruni extract will be deposited, aromatics beta-amino acids, the reaction vessel of reaction solvent mixture add
Heat and made mixture be heated to 90～140 DEG C in 20～30 minutes；Mixture carries out Mei La at a temperature of 90～140 DEG C
Moral is reacted；
Mixture in C, step B be heated to 90～110 DEG C at a temperature of sustained response 2～3 hours, be warming up to the most again 110～
Sustained response 1～2 hours at a temperature of 140 DEG C；Step B and step C obtain reactant, then reactant is carried out cooling process
I.e. can get tobacco aromatics using.
7. prepare tobacco aromatics using according to a kind of Fructus Pruni extract described in any one of claim 1～6 and aromatics beta-amino acids
Method, it is characterised in that: described reaction dissolvent is water or polyhydric alcohol or water and polyol blends, and described polyhydric alcohol is second two
One or more of alcohol, propylene glycol, 1,3 butylene glycol, diethylene glycol or glycerol.
8. prepare tobacco aromatics using according to a kind of Fructus Pruni extract described in any one of claim 1～6 and aromatics beta-amino acids
Method, it is characterised in that: described Fructus Pruni extract is Fructus Pruni extractum or apricot juice, described Fructus Pruni extractum be by water or water and
Concentrate after alcohol mixed solvent extraction；Material included by described Fructus Pruni extract is as follows: glucide, alcohols material,
Ester, acid.
9. prepare tobacco aromatics using according to a kind of Fructus Pruni extract described in any one of claim 1～6 and aromatics beta-amino acids
Method, it is characterised in that: described aromatics beta-amino acids is β-phenylalanine, β-tyrosine, β-tryptophan or Betahistidine
One or more.
10. the method preparing tobacco aromatics using according to a kind of Fructus Pruni extract described in claim 7 and aromatics beta-amino acids, its
Being characterised by: described reaction dissolvent is polyhydric alcohol and aqueous mixtures, wherein polyhydric alcohol is 4～8:1 with the volume ratio of water.
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610793843.0A Pending CN106190569A (en) | 2016-08-31 | 2016-08-31 | A kind of method that Fructus Pruni extract and aromatics beta amino acids prepare tobacco aromatics using |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106701325A (en) * | 2017-03-08 | 2017-05-24 | 湖北中烟工业有限责任公司 | Apricot extract for tobaccos and preparation method of apricot extract |
| CN114717050A (en) * | 2021-12-27 | 2022-07-08 | 河南农业大学 | Novel Maillard reaction product, preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101497845A (en) * | 2008-01-30 | 2009-08-05 | 湖北中烟工业有限责任公司 | Method for producing cigarette flavor by maillard reaction with red date extract as raw material |
| CN101654637A (en) * | 2009-06-02 | 2010-02-24 | 华宝食用香精香料（上海）有限公司 | Natural apricot extract containing Mailard compound, preparing method and application thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497845A (en) * | 2008-01-30 | 2009-08-05 | 湖北中烟工业有限责任公司 | Method for producing cigarette flavor by maillard reaction with red date extract as raw material |
| CN101654637A (en) * | 2009-06-02 | 2010-02-24 | 华宝食用香精香料（上海）有限公司 | Natural apricot extract containing Mailard compound, preparing method and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106701325A (en) * | 2017-03-08 | 2017-05-24 | 湖北中烟工业有限责任公司 | Apricot extract for tobaccos and preparation method of apricot extract |
| CN114717050A (en) * | 2021-12-27 | 2022-07-08 | 河南农业大学 | Novel Maillard reaction product, preparation method and application |
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Application publication date: 20161207 |