CN108048215A - A kind of preparation method of tobacco fig maillard reaction thing - Google Patents
A kind of preparation method of tobacco fig maillard reaction thing Download PDFInfo
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- CN108048215A CN108048215A CN201711320243.3A CN201711320243A CN108048215A CN 108048215 A CN108048215 A CN 108048215A CN 201711320243 A CN201711320243 A CN 201711320243A CN 108048215 A CN108048215 A CN 108048215A
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- maillard reaction
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 47
- 241000208125 Nicotiana Species 0.000 title claims abstract description 25
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 108
- 239000000284 extract Substances 0.000 claims abstract description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000000855 fermentation Methods 0.000 claims abstract description 21
- 239000000243 solution Substances 0.000 claims abstract description 17
- 238000010790 dilution Methods 0.000 claims abstract description 16
- 239000012895 dilution Substances 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 241000894006 Bacteria Species 0.000 claims abstract description 8
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims abstract description 8
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 8
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 claims abstract description 8
- 235000013923 monosodium glutamate Nutrition 0.000 claims abstract description 8
- 238000001556 precipitation Methods 0.000 claims abstract description 8
- 229940073490 sodium glutamate Drugs 0.000 claims abstract description 8
- 239000003906 humectant Substances 0.000 claims abstract description 7
- 239000004310 lactic acid Substances 0.000 claims abstract description 6
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 34
- 238000000605 extraction Methods 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 17
- 239000012141 concentrate Substances 0.000 claims description 14
- 230000004151 fermentation Effects 0.000 claims description 11
- 235000013305 food Nutrition 0.000 claims description 9
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 8
- 239000008103 glucose Substances 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000000622 liquid--liquid extraction Methods 0.000 claims description 7
- 238000005374 membrane filtration Methods 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 7
- 238000000638 solvent extraction Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 125000000070 5-oxo-L-proline group Chemical group [H]N1[C@@](C(=O)[*])([H])C([H])([H])C([H])([H])C1=O 0.000 claims description 2
- 238000013517 stratification Methods 0.000 claims 1
- 235000019504 cigarettes Nutrition 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003546 flue gas Substances 0.000 abstract description 9
- 210000000214 mouth Anatomy 0.000 abstract description 8
- 235000009508 confectionery Nutrition 0.000 abstract description 4
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 238000003810 ethyl acetate extraction Methods 0.000 abstract 1
- SBNFWQZLDJGRLK-UHFFFAOYSA-N phenothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-UHFFFAOYSA-N 0.000 description 7
- 239000000796 flavoring agent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 229940024606 amino acid Drugs 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 241000218218 Ficus <angiosperm> Species 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Seasonings (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
The present invention provides a kind of preparation method of tobacco fig maillard reaction thing, by the way that fig is toasted, water raises fig first extract, fig first extract is after lactic acid bacteria anaerobic fermentation, it adds in ethyl alcohol and precipitation solution is made, then it is filtered concentration, it is extracted with ethyl acetate after adding water dilution, ethyl acetate extraction phase is concentrated under reduced pressure to obtain fig medicinal extract, fig medicinal extract carries out heating reaction in Maillard reaction tank body with proline, sodium glutamate and concentrated ammonia liquor, humectant is added, tobacco fig maillard reaction thing is made.The present invention can increase flue gas concentration and promote aroma quality, be stimulated reducing throat, improve the flue gas property sent out and oral cavity pleasant impression thoroughly, increase the sweet sense in oral cavity and have preferably application effect in terms of assigning cigarette feature style.
Description
Technical field
The present invention relates to a kind of preparation method of tobacco aromaticss, specifically a kind of tobacco fig maillard reaction thing
Preparation method.
Background technology
Fig is under the jurisdiction of Moraceae Ficus, belongs to subtropical zone defoliation small arbor.In fruit containing abundant glucose, fructose,
Sucrose, citric acid and a small amount of malic acid, succinic acid etc., there is the benefits of clearing heat and promoting fluid, spleen benefiting and stimulating the appetite, subdhing swelling and detoxicating.Fig removes
Eat raw, be medicinal outer, can also the system of processing do, preserved fruit processed, jam etc..Fig and its correlated product are mainly used in food neck at present
Domain is related to and few in essence spice for cigarette field.
Maillard reaction is also known as " non enzymatic browning reacton ", is to be happened at carbonyls (recuding sugars) and amination
The reaction between object (amino acid and protein) is closed, is a kind of essence and flavoring agent production application technology more popular at present, extensively should
For food and association area.
At present, most tobacco fig extracts, mainly using fig as raw material, by simply extracting filtering
The techniques such as concentration, are prepared Fructus Fici extract.The extract fragrance that the method obtains is not abundant enough, the application effect in cigarette
Fruit is comparatively single, is only capable of increasing flue gas concentration, slightly increases the sweet sense in oral cavity, and is promoting cigarette flavor matter, reduces throat
It stimulates, improving flue gas, the property sent out and oral cavity pleasant impression and imparting cigarette characteristic flavor on basis aspect go back Shortcomings thoroughly.
Also there is patent to disclose the method for preparing essence spice for cigarette using fig, such as Patent No. at present：CN
201310322435.3 first pass through fig raw material are toasted, and recycle cellulase and non-starch polysaccharide enzyme to fig
Extracting solution carries out enzymolysis processing, is then concentrated by reverse osmosis membrane low temperature, finally recycles Polyacrylamide Gel Column to no flower
Fruit dilution carries out separation and purification treatment, obtains the product of five kinds of different application effects.Patent No.：CN201310218524.3
Fig raw material is suitably crushed, by primary enzymolysis, secondary enzymolysis, refluxing extraction, be concentrated under reduced pressure, adding carbohydrate and amino acid
Etc. programs, carry out Maillard reaction fragrance is prepared.
Although the above method can also prepare tobacco fig extract, fragrant-inducing property in the Fructus Fici extract prepared
Chemical composition species is not abundant enough, and Type of aroma is also comparatively single, not apparent enough to the promotion degree of cigarette flavor matter.
The content of the invention
In view of the above shortcomings of the prior art, a kind of preparation method of tobacco fig maillard reaction thing, the method are provided
With strong points, extract fragrance enriches, and can increase flue gas concentration and promote aroma quality.
Technical solution provided by the invention：A kind of preparation method of tobacco fig maillard reaction thing, specific steps are such as
Under：
(1) by fig raw material simple crushing, using rotary baking machine, constantly 3- is toasted in agitation under the conditions of 85-95 DEG C
Then 6h is cooled to 50-65 DEG C, continue stirring baking 5-8h.
(2) the 8-12 times of pure water measured will be added in, under the conditions of 60-75 DEG C through step (1) treated fig raw material
Dynamic countercurrent extracts 2-4h, and after extraction, fig first extract is obtained by filtration in 100 mesh screens.
(3) it will be cooled in the fig first extract input biological fermentation tank of room temperature, and add in its weight 0.2%-0.5%
Lactic acid bacteria, the glucose of 0.5%-1.2% and the 95% food grade alcohol of 5%-10%, in 25-32 DEG C, speed of agitator 30-
Under the conditions of 60r/min, continue anaerobic fermentation 5-7 days.
(4) after anaerobic fermentation, 95% ethanol solution of 2-3 times of its weight is added in into zymotic fluid, stirs 30min,
24-36h is stood at ambient temperature.
(5) precipitation solution for obtaining step (4), using 100nm ceramic membrane filters, by membrane filtration liquid in -0.085MPa--
0.095MPa, under the conditions of 45 DEG C -50 DEG C, relative density 1.1800 ± 0.0080 is concentrated under reduced pressure into, obtains fig concentrate.
(6) pure water of 2-3 times of weight is added in into fig concentrate, stirs evenly, obtains fig dilution.
(7) ethyl acetate of 2-4 times of weight is added in into fig dilution, is sufficiently mixed carry out liquid-liquid extraction, is stood
Layering, obtains ethyl acetate phase.
(8) extraction 2-3 time mutually will be repeated with the ethyl acetate of 2-4 times of weight again through step (7) treated water, merged often
Secondary obtained ethyl acetate phase.
(9) ethyl acetate phase after merging is carried out being concentrated under reduced pressure into half flowing medicinal extract shape, fig medicinal extract is prepared.
(10) in the fig medicinal extract input Maillard reaction tank body prepared step (9), its weight is sequentially added
The concentrated ammonia liquor of the L-PROLINE of 3.5%-5%, the sodium glutamate of 1.5%-2.5% and 1%-1.5% is keeping heating temperature 80
DEG C -85 DEG C, under the conditions of stir speed (S.S.) 20-30r/min, react 5-8h.
(11) after reaction, stop heating immediately, and add in reactant weight 50%-75%'s into reaction tank
Humectant stirs evenly, the tobacco fig maillard reaction thing as prepared.
Further, the humectant in the step (11) is the new humectants of PDS, and main component is 2-pyrrolidone-5-carboxylic acid
Class component, using the new humectant containing a variety of natural moisturizing factor of optimization compounded technology synthesis.
Beneficial effects of the present invention：The present invention can increase flue gas concentration and promote aroma quality, stimulate, change reducing throat
Kind the flue gas property sent out and oral cavity pleasant impression thoroughly increase the sweet sense in oral cavity and have in terms of assigning cigarette feature style and preferably apply
Effect.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
(1) by fig raw material simple crushing, using rotary baking machine, constantly 5h is toasted in agitation under the conditions of 85 DEG C, so
After be cooled to 55 DEG C, continue stirring baking 8h.
(2) pure water of 8 times of amounts, the dynamic inverse under the conditions of 65 DEG C will through step (1) treated fig raw material, be added in
Stream extraction 3.5h, after extraction, fig first extract is obtained by filtration in 100 mesh screens.
(3) it will be cooled in the fig first extract input biological fermentation tank of room temperature, and add in the lactic acid of its weight 0.2%
Bacterium, 1.0% glucose and 10% 95% food grade alcohol under the conditions of 30 DEG C, speed of agitator 60r/min, continue anaerobism
Fermentation 7 days.
(4) after anaerobic fermentation, 95% ethanol solution of 2.5 times of its weight is added in into zymotic fluid, stirs 30min,
It stands at ambient temperature for 24 hours.
(5) precipitation solution for obtaining step (4), using 100nm ceramic membrane filters, by membrane filtration liquid -0.095MPa, 45 DEG C
Under the conditions of, relative density 1.1810 is concentrated under reduced pressure into, obtains fig concentrate.
(6) pure water of 2 times of weight is added in into fig concentrate, stirs evenly, obtains fig dilution.
(7) ethyl acetate of 3 times of weight is added in into fig dilution, is sufficiently mixed carry out liquid-liquid extraction, stands and divides
Layer, obtains ethyl acetate phase.
(8) extraction 2 times mutually will be repeated with the ethyl acetate of 3 times of weight again through step (7) treated water, and will merge each obtains
The ethyl acetate phase arrived.
(9) ethyl acetate phase after merging is carried out being concentrated under reduced pressure into half flowing medicinal extract shape, fig medicinal extract is prepared.
(10) in the fig medicinal extract input Maillard reaction tank body prepared step (9), its weight 3.5% is sequentially added
L-PROLINE, 2.0% sodium glutamate and 1% concentrated ammonia liquor, keep 82 DEG C of heating temperature, stir speed (S.S.) 30r/min items
Under part, 6.5h is reacted.
(11) after reaction, stop heating immediately, and the PDS guarantors of reactant weight 60% are added in into reaction tank
Moisten agent, stir evenly, the tobacco fig maillard reaction thing as prepared.
Embodiment 2
(1) by fig raw material simple crushing, using rotary baking machine, constantly 3h is toasted in agitation under the conditions of 95 DEG C, so
After be cooled to 50 DEG C, continue stirring baking 7h.
(2) pure water of 9 times of amounts, the dynamic inverse under the conditions of 75 DEG C will through step (1) treated fig raw material, be added in
Stream extraction 2h, after extraction, fig first extract is obtained by filtration in 100 mesh screens.
(3) it will be cooled in the fig first extract input biological fermentation tank of room temperature, and add in the breast of its weight 0.25%
Sour bacterium, 0.8% glucose and 7.5% 95% food grade alcohol, under the conditions of 28 DEG C, speed of agitator 40r/min, persistently detest
Aerobe fermentation 5 days.
(4) after anaerobic fermentation, 95% ethanol solution of 2 times of its weight is added in into zymotic fluid, stirs 30min,
36h is stood under room temperature.
(5) precipitation solution for obtaining step (4), using 100nm ceramic membrane filters, by membrane filtration liquid -0.085MPa, 48 DEG C
Under the conditions of, relative density 1.1750 is concentrated under reduced pressure into, obtains fig concentrate.
(6) pure water of 3 times of weight is added in into fig concentrate, stirs evenly, obtains fig dilution.
(7) ethyl acetate of 2 times of weight is added in into fig dilution, is sufficiently mixed carry out liquid-liquid extraction, stands and divides
Layer, obtains ethyl acetate phase.
(8) extraction 2 times mutually will be repeated with the ethyl acetate of 4 times of weight again through step (7) treated water, and will merge each obtains
The ethyl acetate phase arrived.
(9) ethyl acetate phase after merging is carried out being concentrated under reduced pressure into half flowing medicinal extract shape, fig medicinal extract is prepared.
(10) in the fig medicinal extract input Maillard reaction tank body prepared step (9), its weight 5% is sequentially added
L-PROLINE, 1.8% sodium glutamate and 1.2% concentrated ammonia liquor are keeping 85 DEG C of heating temperature, stir speed (S.S.) 25r/min items
Under part, 5.5h is reacted.
(11) after reaction, stop heating immediately, and the PDS guarantors of reactant weight 55% are added in into reaction tank
Moisten agent, stir evenly, the tobacco fig maillard reaction thing as prepared.
Embodiment 3
(1) by fig raw material simple crushing, using rotary baking machine, constantly 3h is toasted in agitation under the conditions of 90 DEG C, so
After be cooled to 60 DEG C, continue stirring baking 6h.
(2) pure water of 8 times of amounts, the dynamic inverse under the conditions of 75 DEG C will through step (1) treated fig raw material, be added in
Stream extraction 2h, after extraction, fig first extract is obtained by filtration in 100 mesh screens.
(3) it will be cooled in the fig first extract input biological fermentation tank of room temperature, and add in the lactic acid of its weight 0.3%
Bacterium, 0.9% glucose and 7.5% 95% food grade alcohol under the conditions of 31 DEG C, speed of agitator 35r/min, continue anaerobism
Fermentation 5 days.
(4) after anaerobic fermentation, 95% ethanol solution of 3 times of its weight is added in into zymotic fluid, stirs 30min,
30h is stood under room temperature.
(5) precipitation solution for obtaining step (4), using 100nm ceramic membrane filters, by membrane filtration liquid -0.091MPa, 48 DEG C
Under the conditions of, relative density 1.1833 is concentrated under reduced pressure into, obtains fig concentrate.
(6) pure water of 2.5 times of weight is added in into fig concentrate, stirs evenly, obtains fig dilution.
(7) ethyl acetate of 2.5 times of weight is added in into fig dilution, is sufficiently mixed carry out liquid-liquid extraction, is stood
Layering, obtains ethyl acetate phase.
(8) extraction 2 times mutually will be repeated with the ethyl acetate of 2 times of weight again through step (7) treated water, and will merge each obtains
The ethyl acetate phase arrived.
(9) ethyl acetate phase after merging is carried out being concentrated under reduced pressure into half flowing medicinal extract shape, fig medicinal extract is prepared.
(10) in the fig medicinal extract input Maillard reaction tank body prepared step (9), its weight 4.2% is sequentially added
L-PROLINE, 2.1% sodium glutamate and 1.25% concentrated ammonia liquor, keep 82 DEG C of heating temperature, stir speed (S.S.) 20r/min
Under the conditions of, react 8h.
(11) after reaction, stop heating immediately, and the PDS guarantors of reactant weight 50% are added in into reaction tank
Moisten agent, stir evenly, the tobacco fig maillard reaction thing as prepared.
Embodiment 4
(1) by fig raw material simple crushing, using rotary baking machine, constantly 4.5h is toasted in agitation under the conditions of 92 DEG C,
Then 65 DEG C are cooled to, continues stirring baking 5h.
(2) pure water of 12 times of amounts, the dynamic under the conditions of 70 DEG C will through step (1) treated fig raw material, be added in
Adverse current extraction 2.5h, after extraction, fig first extract is obtained by filtration in 100 mesh screens.
(3) it will be cooled in the fig first extract input biological fermentation tank of room temperature, and add in the lactic acid of its weight 0.4%
Bacterium, 1.2% glucose and 9% 95% food grade alcohol under the conditions of 26 DEG C, speed of agitator 60r/min, continue anaerobism hair
Ferment 7 days.
(4) after anaerobic fermentation, 95% ethanol solution of 3 times of its weight is added in into zymotic fluid, stirs 30min,
It stands under room temperature for 24 hours.
(5) precipitation solution for obtaining step (4), using 100nm ceramic membrane filters, by membrane filtration liquid -0.087MPa, 50 DEG C
Under the conditions of, relative density 1.1806 is concentrated under reduced pressure into, obtains fig concentrate.
(6) pure water of 3 times of weight is added in into fig concentrate, stirs evenly, obtains fig dilution.
(7) ethyl acetate of 2 times of weight is added in into fig dilution, is sufficiently mixed carry out liquid-liquid extraction, stands and divides
Layer, obtains ethyl acetate phase.
(8) extraction 3 times mutually will be repeated with the ethyl acetate of 2 times of weight again through step (7) treated water, and will merge each obtains
The ethyl acetate phase arrived.
(9) ethyl acetate phase after merging is carried out being concentrated under reduced pressure into half flowing medicinal extract shape, fig medicinal extract is prepared.
(10) in the fig medicinal extract input Maillard reaction tank body prepared step (9), its weight 4.5% is sequentially added
L-PROLINE, 2.0% sodium glutamate and 1% concentrated ammonia liquor, keep 83 DEG C of heating temperature, stir speed (S.S.) 28r/min items
Under part, 7.5h is reacted.
(11) after reaction, stop heating immediately, and the PDS guarantors of reactant weight 60% are added in into reaction tank
Moisten agent, stir evenly, the tobacco fig maillard reaction thing as prepared.
Embodiment 5
(1) by fig raw material simple crushing, using rotary baking machine, constantly 3.5h is toasted in agitation under the conditions of 88 DEG C,
Then 52 DEG C are cooled to, continues stirring baking 8h.
(2) pure water of 8 times of amounts, the dynamic inverse under the conditions of 65 DEG C will through step (1) treated fig raw material, be added in
Stream extraction 2.5h, after extraction, fig first extract is obtained by filtration in 100 mesh screens.
(3) it will be cooled in the fig first extract input biological fermentation tank of room temperature, and add in the breast of its weight 0.25%
Sour bacterium, 0.55% glucose and 6% 95% food grade alcohol, under the conditions of 32 DEG C, speed of agitator 30r/min, persistently detest
Aerobe fermentation 7 days.
(4) after anaerobic fermentation, 95% ethanol solution of 2.5 times of its weight is added in into zymotic fluid, stirs 30min,
28h is stood at ambient temperature.
(5) precipitation solution for obtaining step (4), using 100nm ceramic membrane filters, by membrane filtration liquid -0.089MPa, 47 DEG C
Under the conditions of, relative density 1.1783 is concentrated under reduced pressure into, obtains fig concentrate.
(6) pure water of 2.8 times of weight is added in into fig concentrate, stirs evenly, obtains fig dilution.
(7) ethyl acetate of 2.2 times of weight is added in into fig dilution, is sufficiently mixed carry out liquid-liquid extraction, is stood
Layering, obtains ethyl acetate phase.
(8) extraction 3 times mutually will be repeated with the ethyl acetate of 2 times of weight again through step (7) treated water, and will merge each obtains
The ethyl acetate phase arrived.
(9) ethyl acetate phase after merging is carried out being concentrated under reduced pressure into half flowing medicinal extract shape, fig medicinal extract is prepared.
(10) in the fig medicinal extract input Maillard reaction tank body prepared step (9), its weight 5% is sequentially added
L-PROLINE, 1.75% sodium glutamate and 1.2% concentrated ammonia liquor are keeping 85 DEG C of heating temperature, stir speed (S.S.) 30r/min items
Under part, 6h is reacted.
(11) after reaction, stop heating immediately, and the PDS guarantors of reactant weight 75% are added in into reaction tank
Moisten agent, stir evenly, the tobacco fig maillard reaction thing as prepared.
Cigarette is smoked panel test experiment with effect：
By the tobacco fig maillard reaction thing prepared in above-mentioned five embodiments adding according to 0.1%-0.5% respectively
Adding ratio, sprinkling in the tobacco, rolls into cigarette, and to be not added with the cigarette of tobacco fig maillard reaction thing as compareing
Product.9 personnel that smoke panel test are chosen to smoke panel test.Smoking result shows that the cigarette for being with the addition of tobacco fig maillard reaction thing is fragrant
Gas enriches, and flavouring is with obvious effects, more coordinates with cigarette perfume.Specific smoking result such as the following table 1：
1 tobacco fig maillard reaction thing of table is smoked panel test effect table
In said effect table, aroma quality effect is better, and score value is higher, and full marks 18 divide；Perfume quantity effect more good grades are higher,
Full marks 15 divide；Smoke behavior is better, and score value is higher, and full marks 10 divide；The miscellaneous fewer score value of gas is higher, and full marks 12 divide；Smaller point of irritation
Value is higher, and full marks 20 divide；Pleasant impression is more comfortable, and score value is higher, and full marks 25 divide, and amounts to full marks 100 and divides.
It can be seen that be with the addition of the five kinds of different tobacco figs prepared in the present invention by said effect contrast table
After maillard reaction thing, cigarette flavor enriches, and flavouring is with obvious effects, more coordinates with cigarette perfume, being added in cigarette increases flue gas
Concentration and promotion aroma quality, stimulate reducing throat, improve the flue gas property sent out and oral cavity pleasant impression thoroughly, increase the sweet sense in oral cavity.
The foregoing is merely the detailed descriptions of specific embodiments of the present invention, do not limit the present invention with this, all at this
All any modification, equivalent and improvement made in the mentality of designing of invention etc., should be included in protection scope of the present invention it
It is interior.
Claims (2)
1. a kind of preparation method of tobacco fig maillard reaction thing, it is characterised in that include the following steps：
(1) by fig raw material simple crushing, using rotary baking machine, constantly 3- is toasted in agitation under the conditions of 85 DEG C -95 DEG C
Then 6h is cooled to 50 DEG C -65 DEG C, continue stirring baking 5-8h；
(2) pure water of its 8-12 times of quality through step (1) treated fig raw material, will be added in, in 60 DEG C of -75 DEG C of conditions
Lower dynamic countercurrent extracts 2-4h, and after extraction, fig first extract is obtained by filtration in 100 mesh screens；
(3) the fig first extract that will be cooled to room temperature is put into biological fermentation tank, and adds in its weight 0.2%-0.5%'s
The 95% food grade alcohol of lactic acid bacteria, the glucose of 0.5%-1.2% and 5%-10%, in 25-32 DEG C, speed of agitator 30-
Under the conditions of 60r/min, continue anaerobic fermentation 5-7 days；
(4) after anaerobic fermentation, 95% ethanol solution of 2-3 times of its weight is added in into zymotic fluid, 30min is stirred, in room
24-36h is stood under the conditions of temperature；
(5) precipitation solution for obtaining step (4), using 100nm ceramic membrane filters, by membrane filtration liquid -0.085MPa--
0.095MPa, under the conditions of 45 DEG C -50 DEG C, relative density 1.1800 ± 0.0080 is concentrated under reduced pressure into, obtains fig concentrate；
(6) pure water of 2-3 times of weight is added in into the fig concentrate obtained by step (5), stirs evenly, obtains fig
Dilution；
(7) ethyl acetate of 2-4 times of weight is added in into fig dilution, is sufficiently mixed carry out liquid-liquid extraction, stratification,
Obtain ethyl acetate phase；
(8) extraction 2-3 time mutually will be repeated with the ethyl acetate of 2-4 times of weight again through step (7) treated water, and will merge each obtains
The ethyl acetate phase arrived；
(9) ethyl acetate phase after merging is carried out being concentrated under reduced pressure into half flowing medicinal extract shape, fig medicinal extract is prepared；
(10) in the fig medicinal extract input Maillard reaction tank body prepared step (9), its weight 3.5%-5% is sequentially added
L-PROLINE, the sodium glutamate of 1.5%-2.5% and the concentrated ammonia liquor of 1%-1.5%, keep 80 DEG C -85 DEG C of heating temperature,
Under the conditions of stir speed (S.S.) 20-30r/min, 5-8h is reacted；
(11) after reaction, stop heating immediately, and the humectation of reactant weight 50%-75% is added in into reaction tank
Agent stirs evenly, the tobacco fig maillard reaction thing as prepared.
2. the preparation method of tobacco fig maillard reaction thing according to claim 1, it is characterised in that：The step
(11) humectant in is the new humectants of PDS, and main component is 2-pyrrolidone-5-carboxylic acid's class component.
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| CN108968132A (en) * | 2018-10-09 | 2018-12-11 | 湖北中烟工业有限责任公司 | A kind of preparation method of reconstituted tobacco coating fluid |
| CN111378527A (en) * | 2018-12-29 | 2020-07-07 | 贵州中烟工业有限责任公司 | Method for preparing Maillard reaction product by adopting fig extract, Maillard reaction product and application |
| CN112841712A (en) * | 2021-02-07 | 2021-05-28 | 无锡华叶生物科技有限公司 | Preparation method of tobacco fig isolate |
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| CN108968132A (en) * | 2018-10-09 | 2018-12-11 | 湖北中烟工业有限责任公司 | A kind of preparation method of reconstituted tobacco coating fluid |
| CN111378527A (en) * | 2018-12-29 | 2020-07-07 | 贵州中烟工业有限责任公司 | Method for preparing Maillard reaction product by adopting fig extract, Maillard reaction product and application |
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