CN1211473C - Method for producing cigarette spicery made from extractive material of tobacco as raw material - Google Patents
Method for producing cigarette spicery made from extractive material of tobacco as raw material Download PDFInfo
- Publication number
- CN1211473C CN1211473C CN 02145153 CN02145153A CN1211473C CN 1211473 C CN1211473 C CN 1211473C CN 02145153 CN02145153 CN 02145153 CN 02145153 A CN02145153 A CN 02145153A CN 1211473 C CN1211473 C CN 1211473C
- Authority
- CN
- China
- Prior art keywords
- tobacco
- reaction
- cigarette
- extract
- spicery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000208125 Nicotiana Species 0.000 title claims abstract description 87
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 87
- 239000002994 raw material Substances 0.000 title claims abstract description 15
- 239000000463 material Substances 0.000 title claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 235000019504 cigarettes Nutrition 0.000 title abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 235000013599 spices Nutrition 0.000 claims abstract description 32
- 150000001413 amino acids Chemical class 0.000 claims abstract description 30
- -1 amino group compound Chemical class 0.000 claims abstract description 27
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000000376 reactant Substances 0.000 claims abstract description 8
- 239000000779 smoke Substances 0.000 claims abstract description 3
- 239000000284 extract Substances 0.000 claims description 47
- 229940024606 amino acid Drugs 0.000 claims description 29
- 235000001014 amino acid Nutrition 0.000 claims description 29
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 17
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 13
- 239000008103 glucose Substances 0.000 claims description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 12
- 230000001143 conditioned effect Effects 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 8
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 229960002989 glutamic acid Drugs 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 5
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims description 5
- 239000004471 Glycine Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 4
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 claims description 4
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 claims description 4
- 235000003704 aspartic acid Nutrition 0.000 claims description 4
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 claims description 4
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- RHDGNLCLDBVESU-UHFFFAOYSA-N but-3-en-4-olide Chemical compound O=C1CC=CO1 RHDGNLCLDBVESU-UHFFFAOYSA-N 0.000 claims description 3
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 claims description 2
- ZPSJGADGUYYRKE-UHFFFAOYSA-N 2H-pyran-2-one Chemical compound O=C1C=CC=CO1 ZPSJGADGUYYRKE-UHFFFAOYSA-N 0.000 claims description 2
- VYIBCOSBNVFEIW-UHFFFAOYSA-N 3-phenylpropanamide Chemical compound NC(=O)CCC1=CC=CC=C1 VYIBCOSBNVFEIW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004475 Arginine Substances 0.000 claims description 2
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 claims description 2
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical compound CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 claims description 2
- 229930091371 Fructose Natural products 0.000 claims description 2
- 239000005715 Fructose Substances 0.000 claims description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 2
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 2
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 claims description 2
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 2
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 claims description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 2
- 239000003906 humectant Substances 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 229940055329 tobacco leaf extract Drugs 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 238000013019 agitation Methods 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
- 239000002304 perfume Substances 0.000 description 22
- 239000000047 product Substances 0.000 description 20
- 239000003205 fragrance Substances 0.000 description 17
- 239000007789 gas Substances 0.000 description 7
- 239000002002 slurry Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- 230000035484 reaction time Effects 0.000 description 5
- OXQOBQJCDNLAPO-UHFFFAOYSA-N 2,3-Dimethylpyrazine Chemical compound CC1=NC=CN=C1C OXQOBQJCDNLAPO-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- KVFIJIWMDBAGDP-UHFFFAOYSA-N ethylpyrazine Chemical compound CCC1=CN=CC=N1 KVFIJIWMDBAGDP-UHFFFAOYSA-N 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- MRWLZECVHMHMGI-UHFFFAOYSA-N 3,5-Diethyl-2-methylpyrazine Chemical compound CCC1=CN=C(C)C(CC)=N1 MRWLZECVHMHMGI-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 3
- 235000011089 carbon dioxide Nutrition 0.000 description 3
- 235000009508 confectionery Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000019633 pungent taste Nutrition 0.000 description 3
- 150000003216 pyrazines Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- RAFHQTNQEZECFL-UHFFFAOYSA-N 2-Ethyl-6-methylpyrazine Chemical compound CCC1=CN=CC(C)=N1 RAFHQTNQEZECFL-UHFFFAOYSA-N 0.000 description 2
- OXCKCFJIKRGXMM-UHFFFAOYSA-N 2-ethyl-5-methylpyrazine Chemical compound CCC1=CN=C(C)C=N1 OXCKCFJIKRGXMM-UHFFFAOYSA-N 0.000 description 2
- 239000001908 2-ethyl-5-methylpyrazine Substances 0.000 description 2
- 241000208140 Acer Species 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- PTEYJUIKYIKULL-UHFFFAOYSA-N Ethyl pentadecanoate Chemical compound CCCCCCCCCCCCCCC(=O)OCC PTEYJUIKYIKULL-UHFFFAOYSA-N 0.000 description 2
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 2
- NIDGCIPAMWNKOA-WOJBJXKFSA-N Neophytadiene Natural products [C@H](CCC[C@@H](CCCC(C)C)C)(CCCC(C=C)=C)C NIDGCIPAMWNKOA-WOJBJXKFSA-N 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
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- 150000002576 ketones Chemical class 0.000 description 2
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- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 description 1
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- 230000002349 favourable effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002584 ketoses Chemical class 0.000 description 1
- FMMOOAYVCKXGMF-UHFFFAOYSA-N linoleic acid ethyl ester Natural products CCCCCC=CCC=CCCCCCCCC(=O)OCC FMMOOAYVCKXGMF-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000002470 solid-phase micro-extraction Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229960004799 tryptophan Drugs 0.000 description 1
- 229960003487 xylose Drugs 0.000 description 1
Abstract
The present invention discloses a method for producing cigarette spicery made from extractive material of tobaccos as raw material. The present invention makes use of cheap tobacco extractive material as the raw material, one kind or more than one kind of appropriate amino acid or amino group compound is added, appropriate sugar or sugarlike compound, water and solvent are added to form a uniform reactant system, pH of the reactant system which is adjusted to be 4 to 10 is put in a high-pressure reaction vessel, constant temperature and pressure reaction is carried out under conditions of agitation, heating and pressurization to produce the cigarette spicery. The obtained cigarette spicery has the advantages of vivid and natural spice and high spice intensity, and the cigarette spicery can be used as natural spicery in the tobaccos. The cigarette spicery which is added in the tobaccos can enhance and harmonize cigarette spice, the smoke gas is softened and fined, the wood gas is covered, the impure gas is reduced, the suction taste of the tobaccos is improved, and the inherent quality of cigarettes is improved.
Description
Technical field
The present invention relates to a kind of preparation method of spices, particularly relate to a kind of production method of tobacco aromatics using.
Background technology
At present, the tobacco aromatics using that adds in China tobacco, the traditional subscription of most of employing is prepared, that is: allocate with multiple natural perfume and synthetics.With the spices that preparation method makes, though technology is fairly simple, owing to be subjected to the restriction of perfume material, there is the fragrance dullness in gained spices, and fragrance is not true to nature, and is poor to the property improved of tobacco, and state tobacco industrial department is at the state that falls behind relatively still.Though disclose the method that a kind of Maillard reaction is produced tobacco aromatics using abroad, but utilize one or two kind of simple amino acid of minority and glucose response owing to rest on, generate the research of maillard reaction product, so range of product is less, alternative leeway certainly also seldom, and cost need be made raw material with pure amino acid again than higher.The indivedual amino acid of domestic production are still needed and are wanted dependence on import, promptly rely on foreign method and produce spices, not only have the limited restriction of alternative spices kind, and the fragrance of gained spices also owes true to nature, nature, tobacco sucking quality are improved also quite limited; United States Patent (USP) (3,920,026) a kind of " tobacco sweetener " disclosed, it mainly utilizes Xie Ansuan and carbonyl compound such as otan or pyruvic acid to prepare the cigarette sweetener, but exist fragrance to owe true to nature, nature equally, also limited to the cigarette quality improvement, kind is more single in addition, is left with no alternative; Chinese patent (CN1039776C) discloses " a kind of method of producing tobacco aromatics using ", this method is raw material with the tobacco, by pulverizing, add acid and add alkali, enzymolysis, centrifugation, steps such as carbonyl ammonia react are produced spices, as seen this method operational path is tediously long, complicated, time-consuming, and the carbonyl ammonia react in open container under the normal pressure heating carry out, a lot of lower boiling perfume compositions, overflow for a long time and react system, do not participate in the carbonyl ammonia react, so the final gained spices of this method only contains more than 20 low boiling component (seeing the capable record of this license bulletin Instructions Page 3 5-8), makes spices inferior many.
In a word, up to the present, disclosed tobacco aromatics using kind is also fewer, available leeway is also little, hindered further developing of tobacco industry to a certain extent, branch of industry wishes relevant scientific and technical personnel for this reason, and a kind of preparation method of good and cheap simple tobacco aromatics using is provided, and can produce the numerous tobacco aromatics using of kind, to promote the technical progress of tobacco industry.
Summary of the invention
The purpose of this invention is to provide a kind of is the method for raw material production tobacco aromatics using with the tobacco extract, the spices that it is made, it is low not only to have cost, raw material sources are extensive, true to nature, the nature of fragrance, fragrant intensity height, tobacco is improved advantages such as performance is good, and can obtain numerous tobacco aromatics using kinds simplely, ensure that tobacco industry obtains to select the space widely, to prepare many high-quality cigarettes.
Design of the present invention is such:
Adopting commercially available tobacco extract is main raw material, the sugar that adds an amount of one or more is or/and the class saccharide compound, add the amino acid or the amino compound of an amount of one or more, and water and solvent, place autoclave to stir into the reaction system of homogeneous, with the PH of basic cpd or acidic cpd conditioned reaction system, stirring, heat, adding to depress and carry out constant temperature, constant voltage reaction, make tobacco aromatics using then.
Wherein tobacco extract itself also is a tobacco aromatics using, is raw material with it, adds other auxiliary materials again and carries out Maillard reaction, and it is higher to make grade, the tobacco aromatics using that kind is abundanter.
Because reaction must be carried out under heating, in order not make volatile perfume composition effusion reaction system in the reaction system, react in the system and be trapped in all the time, and participate in reaction, so reaction should be pressurizeed in airtight autoclave and be carried out, and compressive reaction helps the formation of fragrance matter.
The place of production, kind, the quantity of tobacco extract in the change reactant, change sugar is or/and the kind of class saccharide compound and amount and proportioning, the amount and the kind of change amino acid or amino compound, the amount and the kind of change solvent, thereby can obtain tobacco aromatics using various in style, select fragrant leeway widely to ensure that the tobacco worker has in the tobacco curing process, thereby produce a large amount of fine cigarette.
The present invention also is achieved in that
Because reducing sugar in the tobacco extract and total sugar content are than higher, therefore can utilize its sugared source as tobacco aromatics using, but the carbohydrate kind in the tobacco extract is more single, can cause the fragrance of reaction product abundant inadequately like this, so must be toward wherein adding one or more sugar or/and class saccharide compound, the preferably mixture of more than one saccharide compound or class saccharide compound.Said sugar or class saccharide compound are one or more in glucose, fructose, ribose, maltose, furanone, pyrone, dimethyl diketone, diacetylmethane, the Protosol.Said tobacco extract is a kind of in commercially available tobacco leaf extract or low order tobacco extract or the inferior material of the tobacco industry-offal medicinal extract, should select tobacco extract fire-cured tobacco type or the Turkish tobaccos type for use.The consumption of tobacco extract is the 5-15% of reaction-ure mixture.If (commercially available tobacco extract is the tobacco extract of burley tobaccos type or Maryland type, because its total sugar content is less relatively, so the used in amounts of tobacco extract suitably increases, be preferably the 25-40% of reaction-ure mixture, sugar that adds and class saccharide compound also increase accordingly, and the sugar degree when keeping that total reducing sugar amount and Turkish tobaccos type tobacco extract are made raw material in the reaction system is degree of being substantially quite).Said sugar is or/and the add-on of class saccharide compound is the 10-20% of tobacco extract amount.
Because the amino acid whose content in the tobacco extract is relatively low, so will in tobacco extract, add a certain amount of amino acid composition or amino compound.Said amino acid composition promptly can be single amino acid composition, also can be multiple amino acids blending ingredients, the preferably blending ingredients of multiple amino acids.Proper amino acid and amino compound are: one or more in Serine, arginine, L-Ala, L-glutamic acid, aspartic acid, tyrosine, Xie Ansuan, glycine, Gelucystine, proline(Pro), l-asparagine, the hydrocinnamamide.The add-on of amino acid or amino compound is the 10-25% for the tobacco extract amount.
After adding amino acid or amino compound, add a certain amount of water toward above-mentioned system again, these water can be distilled water, deionized water or tap water.The water yield of adding is at least the 10-40% of reaction-ure mixture, is preferably 15-30%.Add after amino acid or the amino compound, should stir, make them dissolve fully and be dispersed in the reaction system.But before adding amino acid or amino compound, preferably with suitable water amino acid or amino compound are dissolved earlier, join again in the tobacco extract after the dissolving, help the quick dispersion of amino acids component like this, form a reaction system uniformly.
Add certain amount of solvent again, they are one or more the mixtures in ethylene glycol, propylene glycol, the glycerol.Said ethylene glycol, propylene glycol, glycerol are the very good humectant for smoke of a kind of performance, also be a kind of important spices organic solvent, because they have two or three hydroxyls, therefore, they have stronger water feature, that is to say that these organic solvents and water can dissolve each other fully.They have the dual-use function of solvent and raw material in the reaction system, its addition is the 50-80% of reaction-ure mixture.
Above-mentioned all reactants are joined in the autoclave, stir into the homogeneous reaction system, first then pH=4-10 with basic cpd or acidic cpd conditioned reaction system.Said basic cpd is one or more in strong aqua, saleratus, sodium bicarbonate, sodium hydroxide, the potassium hydroxide; Said acidic cpd is one or more in hydrochloric acid, the acetic acid; The suitable preferential reaction system that uses pH=6-8, the pH of regulation and control reaction system can make to be reflected under the comparatively ideal condition and carry out, and obtains high-quality tobacco aromatics using.Why reaction process is selected for use in autoclave is carried out, and the underlying cause has only one, even the volatile components in the reaction system is trapped in the system when reacting by heating all the time, and participates in reaction, thereby guarantees the quality of reaction product.Said autoclave can bear the pressure of 5MPa at least, ties up to safety operation under the 1-3MPa to guarantee reactant.In addition, said autoclave also should have cooling, magnetic agitation and outer heating unit.Wherein outer heating unit can adopt the electric power heating, also can adopt thermal oil or steam heating; During the design new device, should adopt thermal oil or steam heating.
In order to make reaction system thermally equivalent, in heating, must stir.Stir and should adopt magnetic agitation, this is for autoclave, and its safety performance is best.Concerning reaction system of the present invention, stir revolution and should choose 100-600 rev/min of scope, relatively more suitable stirring revolution is 200-400 rev/min.
Make the temperature of reaction system reach the temperature of reaction of being scheduled to rapidly, usually temperature of reaction different and different along with carbohydrate components that tobacco extract added and amino acids component, its range of reaction temperature should be chosen 100 ℃ of-200 ℃ of scopes, and relatively optimal temperature is 110 ℃-160 ℃.
Reaction times changes along with the difference of temperature of reaction.Temperature of reaction is high more, and the reaction times can correspondingly shorten, but the reaction times should be controlled in 0.5-5 hour scope, the comparatively ideal reaction times is 1-3 hour.Be reflected under the constant temperature and pressure and carry out.Wherein said constant temperature is meant the temperature after temperature is selected in 100～200 ℃; Described constant voltage is meant the pressure after pressure is selected in 1～3MPa.
After reaction finished, water flowing cooling was rapidly reduced to below 30 ℃ temperature of charge, and cooled product should keep in reactor and spends the night, and further refined, upgrading.
After opening reactor, reaction product is removed by filter insolubles with gauze or common filter plant, gained filtrate is product of the present invention, and products obtained therefrom is enclosed package rapidly, and preserves under 4 ℃ of low temperature or room temperature.
To a kind of tobacco aromatics using product among the present invention, the employing solid phase micro-extraction technique extracts, gas chromatograph-mass spectrometer (be called for short the GC-MS instrument, U.S. Agilent company produces) its low boiling component of analyzing and testing, detects more than 50 kind of perfume composition altogether.Table 1 has been listed with detected 37 kinds of main volatile components of gas chromatograph-mass spectrometer and relative content thereof.As seen contain a large amount of pyrazine compounds in this tobacco aromatics using, as two isomer and 6 of two isomer of three isomer of methylpyrazine, ethyl pyrazine, dimethylpyrazine, ethyl pyrazine, trimethylpyrazine, dimethylpyrazine, Tetramethylpyrazine, diethyl-dimethyl pyrazine, diethylmethyl pyrazine, 7-dihydroxyl-5-methyl-5H-cyclopentyl pyrazine.Except these pyrazine compounds, also contain distinctive aroma component in the tobaccos such as dorinone, Megastigmatrienone, eggplant Buddhist nun ketone, neophytadiene in this sample.Sample has kept the many aroma components in the tobacco extract well, and big variation does not all take place these aroma components, on the basis that keeps these materials, has generated non-existent aroma component in many tobacco extracts by reaction.For the high boiling point macromolecular components, as the intermediate product glucosyl group amine of Maillard reaction, ketose, aldose, hydroxymethylfurfural etc., and the high-carbon stearic acid that contains in the tobacco extract, high-carbon stearates etc. can't detect with gas chromatograph-mass spectrometer.But these high boiling point low volatility component very useful latent perfumery matter that is some, these materials itself do not have fragrance, but they can produce important aroma component when tobacco burns and sucks.In tobacco aromatics using of the present invention, kept this class material, be expected the improvement of cigarette quality is brought beyond thought effect.
Embodiment
Further illustrate content of the present invention below in conjunction with embodiment, but these embodiment do not limit protection scope of the present invention.
Embodiment 1
Take by weighing 450g Turkish tobaccos medicinal extract, add 100g water in container, stir into uniform tobacco extract slurries, in container, dissolve the 50g L-Ala with 300g water, 45g maltose, the 1g furanone, the 2g otan becomes solution, above-mentioned slurries and solution are poured in the autoclave, poured in the autoclave behind residual slurries and the solution in the rinsing vessel respectively with 100g water again, add the reaction system that the 3000g propylene glycol stirs into homogeneous then, pH=8 with strong aqua conditioned reaction system, airtight good autoclave, the heat temperature raising of under agitation switching on, stir speed (S.S.) is 200 rev/mins, when temperature is raised to after 150 ℃, with nitrogen or carbonic acid gas conditioned reaction still pressure is 2MPa, then constant temperature and pressure (150 ℃ 2MPa) were reacted 2 hours down.After reaction finished, water flowing cooled to below 30 ℃, and reaction product is deposited in reactor and spent the night, and is beneficial to the further alcoholization of reaction product.Open still afterreaction product and remove by filter insolubles with double gauze, gained filtrate is product of the present invention, encapsulates with Plastic Bottle immediately, and room temperature is deposited.Products obtained therefrom shows stronger cigarette perfume (or spice), baking perfume (or spice) and nutty.This product is applied in the single-tobacco-typed cigarette with 0.2% amount smokes panel test, find that this product can significantly promote fragrance, increase fragrance concentration, fine and smooth soft flue gas, pure and mild cigarette perfume (or spice), assorted gas is fully covered, and has significantly improved the grade of cigarette.
Embodiment 2
Take by weighing 500 gram water, be used for dissolving 50g L-glutamic acid, 15g glycine, 50g glucose and 350g yunyan extract.After the dissolving, glucose and amino acid are joined in the autoclave, adding the 2000g propylene glycol then, is 5 with the pH of acetic acid conditioned reaction system, the good seal autoclave, the energising heat temperature raising, stir simultaneously, stir speed (S.S.) 300rpm is when temperature is raised to after 140 ℃, conditioned reaction pressure is 1.0MPa, constant temperature and pressure reaction 4 hours.After reaction finished, water flowing cooled to 25 ℃.Sample is deposited in reactor and is spent the night, and helps the further alcoholization of sample.Filter with double gauze, the elimination insolubles, gained filtrate is product-tobacco aromatics using of the present invention.Encapsulate with Plastic Bottle, 4 ℃ of refrigerators are deposited.The gained tobacco aromatics using be burnt fragrant and sweet, cocoa is fragrant, fermentation is fragrant, powder is fragrant.Perfuming is smoked panel test and is found that this product can make cigarette perfume (or spice) soft, fine and smooth, elegant, significantly promotes fragrance, increases fragrance concentration, fine and smooth soft flue gas, and pure and mild cigarette perfume (or spice), assorted gas is fully covered, and mouthfeel is pleasant.
Embodiment 3
Take by weighing 300g yunyan extract, 31g glucose, 2g Protosol, 1g xitix, 10g L-Ala, 8.5g aspartic acid, 3.5g proline(Pro), 6.5g L-glutamic acid and 5g tyrosine.200g water is joined the yunyan extract that places container, stir into the slurries of homogeneous, 800g water is placed all amino acid of container dissolving, glucose, Protosols etc. stir into the solution of homogeneous, above-mentioned slurries and solution are poured in the autoclave, with slurries and solution residual in the 100g water rinsing vessel, pour in the autoclave, add the 2500g glycerol again, stir into the reaction system of homogeneous, pH=7.0 with strong aqua conditioned reaction system, airtight good autoclave, the heat temperature raising of under agitation switching on, stir speed (S.S.) is 300 rev/mins, after temperature is raised to 160 ℃, pressure with nitrogen or carbonic acid gas conditioned reaction still is 2MPa, and (160 ℃, 2MPa) following reaction is 1 hour under constant temperature and pressure.After reaction finished, water flowing cooled to 25 ℃, and reaction product is deposited to spend the night in reactor and made its further alcoholization upgrading.Open still afterreaction product and filter with double gauze, remove insolubles, gained filtrate is product-tobacco aromatics using of the present invention, as early as possible with Plastic Bottle encapsulation airtight after, leave in 4 ℃ the refrigerator or freezer.Gained spices is with popcorn, powder perfume (or spice), fermentation perfume based on nutty, and lasting is lasting.This product is applied in the single-tobacco-typed cigarette with 0.2% amount smokes panel test, find that this product not only can enrich cigarette perfume (or spice), and significantly improve fragrance matter, fine and smooth soft flue gas, pure and mild cigarette perfume (or spice) significantly reduces single-tobacco-typed cigarette inherent pungency, has improved the grade of cigarette greatly.
Embodiment 4
Take by weighing 500g Yunnan offal medicinal extract, 50g glucose, 50g L-glutamic acid, 17g Xie Ansuan and 6g glycine respectively.Getting 800g water places container to be used for dissolving glucose becomes homogeneous with amino acid solution.Solution, offal medicinal extract are joined in the autoclave, also pour in the autoclave behind the washing container respectively with 100g water again, add the 3000g propylene glycol then, stir into the reaction system of homogeneous, with the pH=6 of acetic acid conditioned reaction system.The good seal autoclave, the heat temperature raising of under agitation switching on, stir speed (S.S.) is 400rpm, after temperature was raised to 140 ℃, the pressure of regulating and control reactor with nitrogen or carbonic acid gas was 3MPa, then constant temperature and pressure (140 ℃ 3MPa) were reacted 3 hours down.After reaction finished, water flowing cooled to 25 ℃.Reaction product is deposited in autoclave and is spent the night, and makes reactant further be refined upgrading.Open still afterreaction product and filter with double gauze, remove insolubles, gained filtrate is product-tobacco aromatics using of the present invention.With Plastic Bottle encapsulation airtight after, be stored in 4 ℃ the refrigerator.Products obtained therefrom has cocoa perfume (or spice), nutty, burnt fragrant and sweet, maple maple perfume (or spice) and pyrazine class fragrance.This product is applied in the single-tobacco-typed cigarette with 0.2% amount smokes panel test, find that this product can obviously improve the quality of cigarette, have the cigarette perfume (or spice) of soft coordination, significantly reduce single-tobacco-typed cigarette inherent pungency and assorted gas, improved the grade of cigarette greatly.
Embodiment 5
Take by weighing 450g Yunnan offal medicinal extract, 50g glucose, 50g Threonine, 10g L-Ala and 30g Serine respectively.Getting 800g water places container to be used for dissolving glucose becomes homogeneous with amino acid solution.Solution, offal medicinal extract are joined in the autoclave, also pour in the autoclave behind the washing container respectively with 100g water, add the 2000g propylene glycol then, stir into the reaction system of homogeneous, the remaining reaction condition is all with embodiment 4.The product of reaction gained has nutty, burnt fragrant and sweet, maple maple perfume (or spice) equally.To the tobacco flavoring discovery of smokeing panel test: fragrant saturating the sending out of cigarette, fine and smooth, soft, pleasant impression is cleaner.
Embodiment 6
Take by weighing 350g Yunnan offal medicinal extract, 50g glucose, 5g wood sugar, 3g L-Ala, 8g aspartic acid 6g L-glutamic acid, 29g proline(Pro), 5g tyrosine, 1.5g phenylalanine, 1g tryptophane and 1g Threonine respectively.Getting 800g water places container to be used for dissolving glucose becomes homogeneous with amino acid solution, solution, offal medicinal extract are joined in the autoclave, also pour in the autoclave behind the washing container respectively with 100g water again, add the 1500g propylene glycol then, stir into the reaction system of homogeneous.Other condition is all with embodiment 4.
The reaction products obtained therefrom is dark-brown liquid, has popcorn perfume (or spice), nutty, beans perfume (or spice), band cigarette perfume (or spice), and fragrance is strong, and lasting is lasting.Product is greatly improved to fragrance matter, has increased the soft fine and smooth degree of flue gas, has covered dried-up assorted gas, and pungency is low.
By above enforcement 1-6 as seen:
Replace single amino acid with multi-component amino acid, long reaction time is a bit more excellent than the tobacco aromatics using of short some gained, and fragrance is more sufficient, and is more graceful, more favourable to the quality improving of cigarette.
In a word, method of the present invention can be tobacco industry more thickness spices is provided, and helps the raising of cigarette quality, is expected Chinese industrial and reaches world-class level.
Table 1 sample detected perfume composition of GC-MS instrument and relative content thereof
| Component | Retention time (min) | Relative content (%) | Matching degree |
| Acetaldehyde | 1.73 | 0.09 | 83 |
| 2,4-dimethyl-1,3-dioxolane | 2.98 | 6.89 | 91 |
| 1, the 3-dioxane | 3.24 | 3.76 | 84 |
| 2, the 5-dimethylpyrazine | 10.87 | 0.27 | 91 |
| 2-ethyl-6-methylpyrazine | 12.50 | 0.13 | 87 |
| 2-ethyl-5-methylpyrazine | 12.65 | 0.22 | 91 |
| 3-ethyl-2, the 5-dimethylpyrazine | 14.01 | 4.27 | 94 |
| 3,5-diethyl-2-methylpyrazine | 15.23 | 2.74 | 91 |
| 2,3,5-trimethylammonium-6-ethyl pyrazine | 15.73 | 0.16 | 93 |
| 2,5-diethyl-3,6-dimethylpyrazine | 16.34 | 0.21 | 90 |
| 2,6-diethyl-3,5-dimethylpyrazine | 16.49 | 0.18 | 90 |
| 1,2-propylene glycol (solvent) | 17.69 | 21.49 | 90 |
| 2,4, the 6-trimethylbenzaldehyde | 17.89 | 0.16 | 80 |
| Heptadecane | 20.00 | 0.50 | 99 |
| Eggplant Buddhist nun ketone | 20.68 | 1.22 | 95 |
| Octadecane | 22.19 | 0.53 | 99 |
| Dorinone | 22.68 | 0.24 | 98 |
| 6,10-dimethyl-5,9-diene-Methyl Nonyl Ketone | 23.38 | 0.29 | 83 |
| Nicotine | 23.67 | 0.17 | 97 |
| Nonadecane | 24.31 | 0.45 | 98 |
| Neophytadiene | 24.90 | 29.75 | 99 |
| Eicosane | 26.30 | 0.24 | 99 |
| Ethyl myristate | 27.30 | 0.73 | 98 |
| Heneicosane | 28.22 | 0.13 | 99 |
| The pentadecanoic acid ethyl ester | 29.24 | 0.27 | 96 |
| Megastigmatrienone 1 | 29.33 | 0.14 | 97 |
| 6-third-1-thiazolinyl-9-ethyl purine | 29.45 | 0.13 | 86 |
| Megastigmatrienone 2 | 30.11 | 0.82 | 98 |
| Methyl palmitate | 30.43 | 0.18 | 98 |
| Ethyl palmitate | 31.11 | 6.40 | 99 |
| Megastigmatrienone 4 | 31.37 | 1.76 | 98 |
| The margaric acid ethyl ester | 32.31 | 0.13 | 93 |
| Ethyl Stearate | 34.60 | 0.32 | 98 |
| Ethyl oleate | 34.93 | 0.50 | 99 |
| ] ethyl linoleate | 35.71 | 1.17 | 99 |
| Ethyl linolenate | 36.78 | 2.50 | 99 |
| Oneself two-2-(ethyl hexyl) ester | 40.69 | 2.42 | 91 |
Claims (12)
1. one kind is the method for raw material production tobacco aromatics using with the tobacco extract, it is characterized in that: this method mainly is main raw material with the tobacco extract, add sugar or/and the class saccharide compound, add one or more amino acid or amino compound, and water and solvent, place autoclave, stir into the reaction system of homogeneous, conditioned reaction system pH=4-10, airtight then autoclave, stirring, heating, adding and depress, carrying out constant temperature, constant voltage reaction 0.5-5 hour; Reaction finishes afterwards, and water speed is chilled to≤and 30 ℃, the gained reaction product is deposited in reactor and is spent the night, and with further alcoholization, removes unreacted impurity at last after filtration, and gained filtrate is target product-tobacco aromatics using of the present invention; Wherein the consumption of reactant is respectively: the consumption of tobacco extract is 5～10% of a reaction-ure mixture; Sugar is or/and the add-on of class saccharide compound is 10～20% of a tobacco extract amount; The add-on of amino acid or amino compound is 10～25% of a tobacco extract amount; The add-on of water is 10～40% of a reaction-ure mixture; The add-on of solvent is 50～80% of a reaction-ure mixture; Wherein said class saccharide compound be in furanone, pyrone, dimethyl diketone, diacetylmethane, the otan one or more; Wherein said solvent is the humectant for smoke that a class can be dissolved each other with water, they be solvent be again raw material, partial solvent participates in the reaction of system, they are a kind of in ethylene glycol, propylene glycol, the glycerol; Wherein said constant temperature is meant the temperature after temperature is selected in 100～200 ℃; Described constant voltage is meant the pressure after pressure is selected in 1～3MPa.
2. the method for claim 1, it is characterized in that: said tobacco extract is commercially available tobacco leaf extract or discarded tobacco leaf medicinal extract, or a kind of in the inferior material-offal medicinal extract of tobacco industry.
3. method as claimed in claim 2 is characterized in that: said tobacco extract is the tobacco extract of fire-cured tobacco type or Turkish tobaccos type gained.
4. the method for claim 1, it is characterized in that: said sugar is one or more in glucose, fructose, ribose, the maltose.
5. the method for claim 1, it is characterized in that: said amino acid or amino compound are one or more in Serine, arginine, L-Ala, L-glutamic acid, aspartic acid, tyrosine, Xie Ansuan, glycine, proline(Pro) and l-asparagine, the hydrocinnamamide.
6. the method for claim 1, it is characterized in that: the add-on of said water is the 15-30% of reaction-ure mixture.
7. the method for claim 1, it is characterized in that: the material of conditioned reaction system pH is basic cpd or acidic cpd; Said basic cpd is one or more in strong aqua, saleratus, sodium bicarbonate, potassium hydroxide, the sodium hydroxide; Said acidic cpd is one or more in hydrochloric acid, the acetic acid; The pH value of reaction system should preferentially be regulated and control to 6-8.
8. the method for claim 1 is characterized in that: the mixing speed of reaction system is 100-600 rev/min.
9. method as claimed in claim 8 is characterized in that: the mixing speed of reaction system is 200-400 rev/min.
10. the method for claim 1 is characterized in that: 110 ℃-160 ℃ of the temperature of reaction of reaction system.
11. the method for claim 1 is characterized in that: reactant ties up under the constant temperature and pressure and reacted 1-3 hour.
12. the method for claim 1, it is characterized in that: the target product-tobacco aromatics using of gained, should in autoclave, deposit and spend the night, make spices further refine upgrading, discharging removes by filter behind the insolubles enclosed package immediately, and preserves under 4 ℃ of low temperature or room temperature.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114886155A (en) * | 2022-05-27 | 2022-08-12 | 河南中烟工业有限责任公司 | Additive for improving filter tip ventilated cigarette concentration sense and preparation method thereof |
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2002
- 2002-11-08 CN CN 02145153 patent/CN1211473C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497845B (en) * | 2008-01-30 | 2012-10-03 | 湖北中烟工业有限责任公司 | Method for producing cigarette flavor by maillard reaction with red date extract as raw material |
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| CN1415717A (en) | 2003-05-07 |
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