CN104099179A - Method for preparation of cigarette filter stick perfume beads through solid-phase Maillard reaction - Google Patents
Method for preparation of cigarette filter stick perfume beads through solid-phase Maillard reaction Download PDFInfo
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- CN104099179A CN104099179A CN201410352373.5A CN201410352373A CN104099179A CN 104099179 A CN104099179 A CN 104099179A CN 201410352373 A CN201410352373 A CN 201410352373A CN 104099179 A CN104099179 A CN 104099179A
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- Prior art keywords
- maillard reaction
- cigarette filter
- reducing sugar
- beads
- solid phase
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 29
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 27
- 239000011324 bead Substances 0.000 title claims abstract description 21
- 239000007790 solid phase Substances 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000002304 perfume Substances 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 150000001413 amino acids Chemical class 0.000 claims abstract description 7
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 239000000419 plant extract Substances 0.000 claims abstract description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000284 extract Substances 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 239000006187 pill Substances 0.000 claims description 4
- XUYPXLNMDZIRQH-LURJTMIESA-N N-acetyl-L-methionine Chemical compound CSCC[C@@H](C(O)=O)NC(C)=O XUYPXLNMDZIRQH-LURJTMIESA-N 0.000 claims description 3
- 229930182817 methionine Natural products 0.000 claims description 3
- 239000004475 Arginine Substances 0.000 claims description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 2
- 241000756943 Codonopsis Species 0.000 claims 1
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims 1
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 claims 1
- 241000218231 Moraceae Species 0.000 claims 1
- 235000008708 Morus alba Nutrition 0.000 claims 1
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 claims 1
- 235000009392 Vitis Nutrition 0.000 claims 1
- 241000219095 Vitis Species 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000661 sodium alginate Substances 0.000 abstract description 5
- 229940005550 sodium alginate Drugs 0.000 abstract description 5
- 239000011259 mixed solution Substances 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000796 flavoring agent Substances 0.000 description 7
- 235000019634 flavors Nutrition 0.000 description 7
- 241000208125 Nicotiana Species 0.000 description 6
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 6
- 239000003094 microcapsule Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 241000287828 Gallus gallus Species 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 235000010410 calcium alginate Nutrition 0.000 description 2
- 239000000648 calcium alginate Substances 0.000 description 2
- 229960002681 calcium alginate Drugs 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 238000006757 chemical reactions by type Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 nitrogenous compound Chemical class 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000013409 condiments Nutrition 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 210000000867 larynx Anatomy 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention discloses a method for preparation of cigarette filter stick perfume beads through solid-phase Maillard reaction. The method comprises the following steps: step 1, directly mixing 0.1-1 part by weight of sodium alginate, 2-10 parts by weight of glycerinum and 40-60 parts by weight of water, heating for dissolution, cooling to normal temperature, adding amino acid and reducing sugar or adding amino acid and natural plant extract containing reducing sugar, so as to enable the molar ratio of amino nitrogen to reducing sugar to be 1:(0.5-2), stirring uniformly, and performing still standing until bubbles in the mixed solution disappear; step 2, dropwise adding the mixed solution into a calcium chloride solution with the mass concentration of 1-5%, filtering and washing after standing for solidification, and balancing in a constant temperature and humidity room with the temperature of 25-35 DEG C and environment humidity of 15-40%, so as to enable the water content of beads prepared through dripping to be 15%-40%; step 3, placing the balanced beads into a microwave oven for heating, so as to perform solid-phase Maillard reaction, and finally, obtaining perfume beads for aroma-increasing of the cigarette filter stick.
Description
Technical field
The present invention relates to technical field of cigarettes, specifically a kind of method of utilizing solid phase Maillard reaction to prepare cigarette filter rod perfumed beads.
Background technology
Maillard reaction type spices is regarded as " natural " as a kind of chemical reaction class fragrance matter by internal authority mechanism, in novel flavouring essence for tobacco, is widely adopted.Maillard reaction is one of important reaction of tobacco characteristic chicken flavor formation, it can produce the fragrance matters such as oxygenatedchemicals, nitrogenous compound, sulfur heterocyclic compound, the wherein fragrant harmony of most of and cigarette, can effectively improve the quality of low order tobacco, reduce wooden assorted gas, increase cigarette fragrant, thereby become the good tobacco aromatics using of a class.
The carrying out of Maillard reaction must require moisture content in reaction system to be greater than 10%, and generally more than 15%, so its reaction system is all liquid-phase system substantially, and solid system research is less.Chinese patent application 201010594498.0 adopts solid phase Maillard reaction to produce shrimp seafood condiment with rich flavor, and has avoided the loss of later stage drying process flavor.Chinese patent application 201210566748.9 joins a certain amount of reducing sugar in the dried rapeseed cake powder of enzymolysis, adjusts pH value and moisture, carries out microwave heating under solid state shape, makes it that Maillard reaction occur.
Summary of the invention
The invention provides a kind of method of utilizing solid phase Maillard reaction to prepare cigarette filter rod perfumed beads, by sol-gel technique, microwave heating and solid phase Maillard reaction are prepared the perfumed beads that can be used for cigarette filter rod flavouring.
Technical solution of the present invention is as follows:
Step 1,40～60 parts of 0.1～1 part of the sodium alginates in weight part, 2～10 parts of glycerine, water are directly mixed, being heated to 70 ℃ makes it to dissolve, after its solution temperature is down to normal temperature (25 ℃～35 ℃), add a certain amount of amino acid and reducing sugar, or amino acid and containing the cigarette natural plant extracts of reducing sugar, and the mol ratio that makes amino nitrogen and reducing sugar is 1:0.5～2, so that Maillard reaction thing reacts completely, stir, standing, until bubble collapse in mixing solutions.Described sodium alginate can be used as the case material of microcapsule, for the solidifying agent calcium chloride solution adding with subsequent step, reacts and generates calcium alginate microcapsule, and described glycerine plays the effect of plasticising to calcium alginate microcapsule, be conducive to the moulding of microcapsule.
Step 2, to utilize automatization pill dripping machine to splash into mass concentration above-mentioned mixing solutions be in 1～5% calcium chloride solution (as solidifying agent), after standing solidifying, filter, wash, and it is 25 ℃～35 ℃ in temperature, ambient moisture is balance in 15%～40% fixed temperature and humidity room, makes pearl water content that dripping goes out in 15%～40% scope.
Step 3, the good pearl of balance is put into microwave oven heat, carry out solid phase Maillard reaction, the final perfumed beads that can be used for cigarette filter rod flavouring that obtains.
The inventive method has been prepared the perfumed beads that contains tobacco characteristic chicken flavor by solid phase Maillard reaction, added in cigarette filter rod, can enrich cigarette flavor, improves tobacco suction quality.Compare with the pattern of traditional liquid system Maillard reaction, the prepared product of the inventive method is directly solid spice pearl, the product of having avoided liquid phase Maillard reaction the scattering and disappearing of flavour ingredient in later stage drying process, in addition, compare with the pattern of solid phase Maillard reaction in the past, the inventive method is first the raw material packet of Maillard reaction to be rolled in the capsule pearl of macromolecular material sodium alginate dripping one-tenth, and then carry out solid phase Maillard reaction, therefore the flavour ingredient that its reaction produces will be attracted in the cyberspace hole of capsule pearl, can not scatter and disappear rapidly, played certain slow releasing function.
Embodiment
Below in conjunction with specific embodiment, the technical scheme in the present invention is clearly and completely described.
Embodiment 1
(1) first get sodium alginate 0.2g, glycerine 5g, water 50g directly mixes, be heated to 70 ℃ and make it to dissolve, after its solution temperature is down to normal temperature (25 ℃～35 ℃), add a certain amount of glucose and arginine, glucose and arginic mol ratio are 1:1, stir, standing, until bubble collapse in mixing solutions.
(2) 1g calcium chloride is dissolved in 99g water, make mass concentration and be 1% calcium chloride solution, utilize automatization pill dripping machine to splash in calcium chloride solution the mixing solutions in step (1) again, after standing solidifying, filter, wash, then the ball of moulding being put into temperature is 25 ℃, and balance in the fixed temperature and humidity room that humidity is 20% makes water content approximately 20% left and right in pearl.
(3) the good pearl of balance is put into microwave oven and heat, microwave power 400W, microwave time 4min, prepares the perfumed beads that can be used for cigarette filter rod flavouring by solid phase Maillard reaction.
This perfumed beads is added in cigarette filter rod, and the personnel that smoke panel test are to its smoking, and result shows, compare with control sample (common cigarette), and this perfumed beads can soft flue gas, reduce pungency and the assorted gas of cigarette.
Embodiment 2
(1) first get sodium alginate 0.5g, glycerine 7g, water 50g directly mixes, be heated to 70 ℃ and make it to dissolve, after its solution temperature is down to normal temperature (25 ℃～35 ℃), add a certain amount of Fructus Jujubae extract and Methionin, reducing sugar content in Fructus Jujubae extract and the mol ratio of Methionin are 1:1, stir, standing, until bubble collapse in mixing solutions.
(2) 1g calcium chloride is dissolved in 99g water, make mass concentration and be 1% calcium chloride solution, utilizing automatization pill dripping machine to splash in calcium chloride solution the mixing solutions in step (1), after standing solidifying, filter, wash, then the ball of moulding being put into temperature is 25 ℃, and balance in the fixed temperature and humidity room that humidity is 30% makes water content approximately 30% left and right in pearl.
(3) the good pearl of balance is put into microwave oven and heat, microwave power 600W, microwave time 4min, prepares the perfumed beads that can be used for cigarette filter rod flavouring by solid phase Maillard reaction.
This perfumed beads is added in cigarette filter rod, and the personnel that smoke panel test are to its smoking, and result shows, compares with control sample (common cigarette), and this perfumed beads has certain Jiao fragrant and sweet, but increased the excitement of throat, have the sensation of pasting larynx.
The above; be only the specific embodiment of the present invention, but protection scope of the present invention is not limited to this, anyly belongs to those skilled in the art in the technical scope that the present invention discloses; the variation that can expect easily or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.
Claims (3)
1. utilize solid phase Maillard reaction to prepare a method for cigarette filter rod perfumed beads, it is characterized in that comprising the steps:
Step 1,40～60 parts of 0.1～1 part of the sodium alginates in weight part, 2～10 parts of glycerine, water are directly mixed, being heated to 70 ℃ makes it to dissolve, until its solution temperature, be down to after 25 ℃～35 ℃, add a certain amount of amino acid and reducing sugar, or amino acid and containing the cigarette natural plant extracts of reducing sugar, and to make the mol ratio of amino nitrogen and reducing sugar be 1:0.5～2, stirs, standing, until bubble collapse in mixing solutions;
Step 2, to utilize automatization pill dripping machine to splash into mass concentration above-mentioned mixing solutions be in 1～5% calcium chloride solution, after standing solidifying, filter, wash, and it is 25 ℃～35 ℃ in temperature, ambient moisture is balance in 15%～40% fixed temperature and humidity room, makes pearl water content that dripping goes out in 15%～40% scope;
Step 3, the good pearl of balance is put into microwave oven heating to carry out solid phase Maillard reaction, microwave power 400W-600W, microwave time 1-4min, the final perfumed beads that can be used for cigarette filter rod flavouring that obtains.
2. the method for utilizing solid phase Maillard reaction to prepare cigarette filter rod perfumed beads as claimed in claim 1, is characterized in that: the described cigarette natural plant extracts containing reducing sugar is Fructus Jujubae extract, Fructus Vitis viniferae extract, Radix Codonopsis extraction or mulberries extract.
3. the method for utilizing solid phase Maillard reaction to prepare cigarette filter rod perfumed beads as claimed in claim 1, is characterized in that: described amino acid is arginine, Methionin, L-Ala, proline(Pro) or α-amino-isovaleric acid.
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| CN201410352373.5A CN104099179B (en) | 2014-07-23 | 2014-07-23 | A kind of method utilizing solid phase Maillard reaction to prepare cigarette filter rod perfumed beads |
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| CN201410352373.5A CN104099179B (en) | 2014-07-23 | 2014-07-23 | A kind of method utilizing solid phase Maillard reaction to prepare cigarette filter rod perfumed beads |
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| CN104099179A true CN104099179A (en) | 2014-10-15 |
| CN104099179B CN104099179B (en) | 2016-03-09 |
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Cited By (13)
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| CN104489899A (en) * | 2014-11-25 | 2015-04-08 | 深圳梵活生物科技有限公司 | Brittle dropping pill and preparation method thereof |
| CN105200857A (en) * | 2015-08-20 | 2015-12-30 | 嘉兴景程生物科技有限公司 | Fresh-scent cigarette paper and preparation method thereof |
| CN107034019A (en) * | 2017-04-27 | 2017-08-11 | 河南中烟工业有限责任公司 | A kind of cigarette quick-fried pearl red-jujube flavor essence and its application in cigarette |
| CN107594618A (en) * | 2017-11-08 | 2018-01-19 | 湖北中烟工业有限责任公司 | Sustained release pellet based on natural perfume material Ultramicro-powder and preparation method thereof |
| CN108707510A (en) * | 2018-06-07 | 2018-10-26 | 湖北中烟工业有限责任公司 | A kind of preparation method and applications of the compound maillard reaction thing of jujube tobacco |
| CN108703402A (en) * | 2018-06-07 | 2018-10-26 | 湖北中烟工业有限责任公司 | The method that alanine solid phase Maillard reaction improves stem quality |
| CN109198721A (en) * | 2018-08-06 | 2019-01-15 | 江西中烟工业有限责任公司 | A kind of middle branch cigarette filter tip and preparation method thereof containing bulky grain solid-state perfume (or spice) pearl |
| CN109330021A (en) * | 2018-05-03 | 2019-02-15 | 四川三联新材料有限公司 | A kind of material, cigarette and production method for tobacco curing |
| CN109536280A (en) * | 2018-11-27 | 2019-03-29 | 湖北中烟工业有限责任公司 | The quick-fried pearl preparation method of cigarette of internal essence further progress Maillard reaction after molding |
| CN109536279A (en) * | 2018-11-27 | 2019-03-29 | 湖北中烟工业有限责任公司 | A method of jujube maillard reaction thing is prepared using microwave |
| CN110558610A (en) * | 2019-09-20 | 2019-12-13 | 安徽坤大生物工程技术有限公司 | Chuzhou chrysanthemum taste blasting bead for cigarettes and preparation method thereof |
| CN112586803A (en) * | 2020-12-31 | 2021-04-02 | 南京植创生物技术研究院有限公司 | Carrier gel microsphere, cigarette filter tip liquorice moisture-retaining aroma-enhancing bead and preparation method |
| CN112980580A (en) * | 2021-03-11 | 2021-06-18 | 吉林烟草工业有限责任公司 | Maillard reaction spice and preparation method and application thereof |
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| CN104489899A (en) * | 2014-11-25 | 2015-04-08 | 深圳梵活生物科技有限公司 | Brittle dropping pill and preparation method thereof |
| CN105200857A (en) * | 2015-08-20 | 2015-12-30 | 嘉兴景程生物科技有限公司 | Fresh-scent cigarette paper and preparation method thereof |
| CN105200857B (en) * | 2015-08-20 | 2017-04-19 | 嘉兴景程生物科技有限公司 | Fresh-scent cigarette paper and preparation method thereof |
| CN107034019A (en) * | 2017-04-27 | 2017-08-11 | 河南中烟工业有限责任公司 | A kind of cigarette quick-fried pearl red-jujube flavor essence and its application in cigarette |
| CN107594618A (en) * | 2017-11-08 | 2018-01-19 | 湖北中烟工业有限责任公司 | Sustained release pellet based on natural perfume material Ultramicro-powder and preparation method thereof |
| CN109330021A (en) * | 2018-05-03 | 2019-02-15 | 四川三联新材料有限公司 | A kind of material, cigarette and production method for tobacco curing |
| CN108703402A (en) * | 2018-06-07 | 2018-10-26 | 湖北中烟工业有限责任公司 | The method that alanine solid phase Maillard reaction improves stem quality |
| CN108707510A (en) * | 2018-06-07 | 2018-10-26 | 湖北中烟工业有限责任公司 | A kind of preparation method and applications of the compound maillard reaction thing of jujube tobacco |
| CN108707510B (en) * | 2018-06-07 | 2021-07-06 | 湖北中烟工业有限责任公司 | Preparation method and application of red date and tobacco composite Maillard reactant |
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| CN109198721B (en) * | 2018-08-06 | 2021-04-16 | 江西中烟工业有限责任公司 | Medium cigarette filter tip containing large-particle solid aromatic beads and preparation method thereof |
| CN109536280A (en) * | 2018-11-27 | 2019-03-29 | 湖北中烟工业有限责任公司 | The quick-fried pearl preparation method of cigarette of internal essence further progress Maillard reaction after molding |
| CN109536279A (en) * | 2018-11-27 | 2019-03-29 | 湖北中烟工业有限责任公司 | A method of jujube maillard reaction thing is prepared using microwave |
| CN110558610A (en) * | 2019-09-20 | 2019-12-13 | 安徽坤大生物工程技术有限公司 | Chuzhou chrysanthemum taste blasting bead for cigarettes and preparation method thereof |
| CN112586803A (en) * | 2020-12-31 | 2021-04-02 | 南京植创生物技术研究院有限公司 | Carrier gel microsphere, cigarette filter tip liquorice moisture-retaining aroma-enhancing bead and preparation method |
| CN112980580A (en) * | 2021-03-11 | 2021-06-18 | 吉林烟草工业有限责任公司 | Maillard reaction spice and preparation method and application thereof |
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