CN104487406A - Articles for in-home composting - Google Patents
Articles for in-home composting Download PDFInfo
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- CN104487406A CN104487406A CN201380021217.4A CN201380021217A CN104487406A CN 104487406 A CN104487406 A CN 104487406A CN 201380021217 A CN201380021217 A CN 201380021217A CN 104487406 A CN104487406 A CN 104487406A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/14—Tablets, spikes, rods, blocks or balls
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/16—Films or sheets; Webs; Fibres
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/18—Semi-solid fertilisers, e.g. foams or gels
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
- C05G5/37—Layered or coated, e.g. dust-preventing coatings layered or coated with a polymer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/45—Form not covered by groups C05G5/10 - C05G5/18, C05G5/20 - C05G5/27, C05G5/30 - C05G5/38 or C05G5/40, e.g. soluble or permeable packaging
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Abstract
Unit dose articles containing N-P-K added to compost are a convenient and economical way to customize fertilizer. An article comprising from about 0.1 g to about 1,000 g of a fertilizer composition wherein the fertilizer composition is contained by a biodegradable film. A compressed tablet comprising from about 0.1 g to about 100 g of a fertilizer composition, wherein the tablet is a compressed shaped body. A multi-compartment article comprising a first composition and a second composition; wherein the first composition comprises a fertilizer composition contained by a film to form a first compartment of the article; and wherein the second composition is contained by the film to form a second compartment of the article. A method of treating compost comprising the step of administering an article of a fertilizer composition contained by a biodegradable film or pressed shaped body into a composting appliance. A starter kit comprising: a composting appliance and/or an article according to claim 1, 6, 10 and optionally instructions for administering the article to the composting appliance.
Description
Technical field
The present invention is relevant to the unit dose articles for using in family expenses compost.
Background technology
Describe family expenses compost utensil.See such as US 2008/0209967 A1; JP 3601973B2.Indoor compost provides convenient.Just food waste is placed within the appliance (relative to being discarded in rubbish container).The benefit of compost comprises the minimizing of rubbish in garbage bury ground and the economical source of plant food.But in-house research is pointed out, the stench caused by composting process may be the remarkable obstacle that wide-scale distribution human consumer adopts family expenses compost.Equipped gas exhaust duct is expensive, complicated to make utensil to outdoor discharge, and is not desired by human consumer usually.The use of the activated carbon air filter of some commercially available acquisitions in removing stench only obtaining section divide successfully.In order to push waste gas by strainer, powerful fan (therefore produce noise and consume energy) may be needed.And when the capping of compost utensil is lifted (such as, to add the food waste etc. for compost) thus destroys the vacuum that vent fan produces, usually give out stench.
Exist for a kind of needs being easy to the product used by human consumer, this product uses simple also high performance-price ratio, and provides the effective control to the stench from composting process, and is environmental protection.
The compost obtained by family expenses composting process is fabulous for general fertilising.But, also there are the needs for customizing compost for concrete fertilising application.Also exist for make customization concerning human consumer easily and need easily.
Summary of the invention
The present invention attempts solving these and other needs any.A first aspect of the present invention provides a kind of goods, and it comprises and has 1g to 1, the first composition of the gac of 000g, and wherein the first composition tunicle encapsulating is to form unitary dose.Not bound by theory, gac controls the effective means from the stench of composting process.Unit dosage provides convenient for human consumer.A second aspect of the present invention provides a kind of method of compost, and it comprises the step using goods to compost utensil, and wherein goods comprise and have 1g to 1, the first composition of the gac of 000g, and wherein the first composition tunicle encapsulating is to form water soluble unit dose.A third aspect of the present invention provides a kind of many compartment article, and it comprises the first composition and the second composition.First composition comprises 1g to 1, the gac of 000g, and wherein the first composition tunicle comprises the first compartment forming goods.Second composition tunicle comprises the second compartment forming goods.A fourth aspect of the present invention provides a kind of Deodor scheme method, and it is included in the time period step at least using the first goods comprising gac and the second goods comprising gac in compost utensil.Time period at least comprises the first unit time and the second unit time, and wherein the first unit time is not identical with the second unit time.After the first unit time, use the first goods, and use the second goods after the second unit time.A fifth aspect of the present invention provides a kind of method of the stench processed in compost utensil, and it comprises the step using tablet in compost utensil, and wherein tablet is for comprising the main body of the compression molding of the gac of about 1g to about 1,000g.A sixth aspect of the present invention provides a kind of product comprising bucket and multiple goods, and wherein bucket comprises multiple goods.Each in multiple goods comprises the gac of about 1g to about 1,000g.A seventh aspect of the present invention provides a kind of product comprising pliable and tough sealable bag and multiple goods, and wherein this bag comprises multiple goods.Each in multiple goods comprises the gac of about 1g to about 1000g.Goods are selected from: compressed tablets; And comprising the unit dose articles of biodegradable and water miscible film, described film comprises gac.A eighth aspect of the present invention provides a kind of introduction external member, and it comprises compost utensil; Aforementioned articles; And for using the explanation of goods to compost utensil.
A ninth aspect of the present invention provides one to comprise the goods of the Ru 2006101161 of about 0.1g to about 1,000g, and wherein Ru 2006101161 is comprised by biodegradable and preferred water miscible film.Not bound by theory, adding Ru 2006101161 to compost is a kind of mode customizing compost for concrete end-use.Unit dosage provides convenient for human consumer.A tenth aspect of the present invention provides a kind of tablet comprising the compression of the Ru 2006101161 of about 0.1g to about 100g, and wherein tablet is the main body of compression molding.A eleventh aspect of the present invention provides a kind of many compartment article comprising the first composition and the second composition.First composition comprises Ru 2006101161, and described Ru 2006101161 tunicle comprises the first compartment forming goods.Second composition tunicle comprises the second compartment forming goods.A twelveth aspect of the present invention provides a kind of method processing compost; The step of aforementioned articles is used in compost utensil.A thirteenth aspect of the present invention provides a kind of introduction external member, and it comprises: compost utensil; And aforementioned articles; And for using the explanation of goods to compost utensil.A fourteenth aspect of the present invention provides bucket and multiple goods, and wherein bucket comprises multiple goods.Each in multiple goods comprises the Ru 2006101161 of about 0.1g to about 1,000g.A fifteenth aspect of the present invention provides a kind of product comprising pliable and tough sealable bag and multiple goods, and wherein bag comprises multiple goods.Each in multiple goods comprises the gac of about 1g to about 1,000g.Goods are selected from: compressed tablets; And comprising the unit dose articles of biodegradable and preferred water miscible film, described film comprises Ru 2006101161.
Embodiment
gac
Term " gac " uses to comprise any type of carbon that can absorb smell with broadest sense at this.Not bound by theory, porosity is responsible for stench most probably and is absorbed.The limiting examples of gac comprises activated charcoal, active coal and charcoal.
The present invention is based in part on following observation: if add gac to family expenses compost utensil during composting process, so gac eliminates the stench that (or at least alleviating) can be produced by compost originally.Not bound by theory, sufficient gac must be there is and control to provide enough stenches, but can not be too much, because gac can such as have a negative impact to the pH balance of compositing system.Another aspect of the present invention is based on following observation: if add gac with single dose, so gac may not provide effective stench to control within the whole time period of composting process.Not bound by theory, the stench binding site in gac can become and be blocked by the content of compost/pre-composting material.Therefore, one aspect of the present invention is to provide the unitary dose that comprises gac as a scheme (such as, once a day, continuing two weeks).On the other hand, the unitary dose comprising gac does not contain or is substantially free of other material or composition.
The use of gac also provides the attendant advantages of serving as the soil conditioner that can improve plant-growth.Described by the goods comprising gac have.Provide the method using gac, comprise scheme.Finally, the external member comprising various goods of the present invention is provided.
Gac work is utilized to there is shortcoming.Process gac is messy.The gac (especially in solution processes) that human consumer measures appropriate amount is also inconvenient.Exist for making human consumer process easily and using the needs of the gac for family expenses compost.
The present invention solves these problems by the gac of the amount measured in advance being provided for the application of family expenses compost with unit dose articles easily.In one embodiment, goods are biodegradable.In another embodiment, goods are water miscible.
One aspect of the present invention providing package is containing the unit dose articles of the gac of 1 gram to 1,000 gram, and wherein gac is encapsulated by biodegradable material or water-soluble material to form goods.
Another aspect of the present invention provides a kind of method for family expenses compost, and it comprises the step using the unit dose articles comprising gac in family expenses compost utensil.In another embodiment, provide a kind of scheme, wherein a time period (such as, one week, two weeks, three weeks, one month, two months etc.) process in, the unitary dose comprising gac is used on time per unit basis (such as, once a day, every two days once, inferior on every Mondays).
Another aspect of the present invention provides a kind of method for family expenses compost, it comprises the step to family expenses compost utensil administration of unit doses goods, wherein water soluble unit dose comprises 1 gram to 1, the gac of 000 gram, wherein gac tunicle encapsulating at least in part, preferably whole tunicle encapsulating is to form unit dose articles, the preferred biodegradable film of described film, or biodegradable water-solubility membrane.
Another aspect of the present invention provides a kind of method for family expenses compost, and it comprises the step using the unit dose articles comprising compost microbe and/or microorganism supplement.In one embodiment, gac and microorganism and/or microorganism supplement be separate or be what to separate substantially.In another embodiment, gac mixes in a compartment of goods with microorganism and/or microorganism supplement.In another embodiment, provide a kind of composition, it comprises: the gac (or 40wt% to 60wt%) of 30wt% to 70wt%; The compost microbe (or 20wt% to 30wt%) of 15wt% to 35wt%; And the microorganism supplement (or 20wt% to 30wt%) of 15wt% to 35wt%.
Provide external member and processing scheme.In one aspect, provide multiple unit dose articles as a part for processing scheme, wherein dosing first goods during the first unit time; Dosing second goods during the second unit time, wherein the second unit time is after the first unit time; And wherein scheme goes through a time period process of (such as, a week, month etc.).Processing scheme also can have the 3rd, the 4th or more goods.In one embodiment, each unit time independently selected from about half a day to about three months, or about 1 day to about 14 days, or once a day.In another embodiment, the time period was independently selected from 3 days, one week, two weeks, three weeks, one month, two months, six months etc.In another embodiment, goods are used on basis (that is, when there is stench) as required.External member can comprise identical or different goods of the present invention.
compost utensil
Compost utensil (being preferred for domestic applications), in the simplest sense, comprises and is applicable to comprise food waste and for the reaction vessel of other suitable material of compost or designated area.Reaction vessel is generally about 1 and rises to about 100 liters, or 25 rise to 75 liters, or 35 rise to 65 liters, or their combination.Utensil can comprise closed/enter capping or other like of reaction vessel (and the content wherein comprised).Capping alleviates distributing of the stench distributed by the material be included in reaction vessel.Family's compost utensil generally includes hydrid component, and it is by the content of mixed reaction vessel thus be conducive to composting process (such as, improving air flowing).Hydrid component can engage in cycle basis or continuous foundation or their combination.Utensil can optionally comprise heater block (such as, electrically heated chuck) with the content comprised in reacting by heating container and/or container to be conducive to composting process, because many compost microbe preferences are higher than the temperature (that is, higher than about 21 DEG C) of envrionment temperature.Preferably, reaction vessel be heat insulation make heating more effectively/economical.Capping can be played and avoids the content of container to spill during mixing process and/or keep the effect of the heat comprised in container/content (should use well heater).In some compost utensils, there is curing vessel.In other words, some utensils have two phase process-initial activity stage and subsequent cure stage.Cure stage in time usually the specific activity stage long.Curing vessel can have as previous for the volumetric parameter described by reaction vessel.The limiting examples of compost utensil is included in JP 3601973 B2; And have described those in US 2008/0209967 A1.In one embodiment, to compost utensil or specifically use goods of the present invention in the activating container of family expenses compost utensil.In another embodiment, in the curing vessel of family expenses compost utensil, goods are used.In other embodiment, in the activating container and curing vessel of family expenses compost utensil, use goods.In one embodiment, family expenses compost carries out in case, bucket or bag, alternatively, does not have mechanically mixing and/or does not have indirect heating.
One aspect of the present invention provides a kind of compost utensil comprising divider, and described divider and reaction vessel and/or curing vessel (or utensil may have other container) fluid is communicated with.Divider also comprises distribution container, and it can comprise one or more compositions of the present invention, and preferably the part of composition is assigned in the container of compost utensil.In one embodiment, the volume of distribution container be about 10ml to about 4,000ml (or more), or about 100ml is to about 2,000ml, or about 500ml is to about 1,000ml, or their combination.Alternatively, divider can comprise multiple unitary dose of the present invention, or multiple unit dose articles of the present invention, and preferably these unitary doses or unit dose articles is assigned in the container of compost utensil.Distribute composition/unitary dose/goods by divider to be triggered by one or more event.Event can be that user opens button on capping or pressing utensil or the predetermined timed interval (such as, every day) or sensor detect stimulation (such as, stench, is added into the weight etc. of the pre-compost of reaction vessel).
Utensil can comprise more than one divider.The first divider being exclusively used in reaction vessel and the second divider being exclusively used in curing vessel can be there is.Alternatively, the first divider being exclusively used in and the first composition being dispensed to reaction vessel can be there is and be exclusively used in the second divider the second composition being also dispensed to reaction vessel.3rd divider and the 4th divider can be exclusively used in and the 3rd composition of correspondence and the 4th composition are dispensed to curing vessel.It will also be appreciated that the combination of these dividers.
comprise the composition of gac
One aspect of the present invention provides a kind of composition comprising gac.In one embodiment, composition comprises the gac of about 1% to about 100%, or 80% to 99%, or 85% to 100%, or 90% to 100%, or 50% to 90%, or the gac of 50% to 99% or their combination.Composition also can comprise other composition, such as softening agent, microorganism (being applicable to compost), microorganism supplement, enzyme or their combination.In one embodiment, composition comprises about 1g to about 1000g, or about 25g to about 500g, or the gac of about 50g to about 250g or their combination.Not bound by theory, this amounts of activated carbon is applicable to control the stench in typical family expenses compost utensil.
Composition can be liquid, slurries, gel, powder, granular or their combination.In one embodiment, composition can comprise the water being less than 10%.Not bound by theory, in composition, more the water of high-content can have disadvantageous effect to the water-soluble material (in those embodiments using this type of material) for the preparation of goods of the present invention.
In one embodiment, goods can comprise 2,3 or more compartments, make to comprise different compositions with these compartments.In one embodiment, the first compartment comprise gac and the second composition to be included in the second compartment (wherein preferably the second composition not containing or be substantially free of gac).Multiple compartment can provide advantage such as separated by inconsistent composition or be convenient to dosing.
customizable fertilizer
One aspect of the present invention provides a kind of unit dose articles comprising Ru 2006101161.Ru 2006101161 usually comprises nitrogen (from nitrogenous source) and preferably also comprises phosphoric acid salt and potassium (respectively from phosphoric acid salt and potassium source).Fertilizer is named by the content of one or more these components.The content of these components in fertilizer shows by N-P-K value (wherein N=nitrogen content by weight percentage, P=phosphorus content by weight percentage, and K=potassium content by weight percentage).Suitable N-P-K value depends on fertilising application, its then substantially by plant and/or soil regime need determine.Such as, general fertilizer will comprise the weight ratio of the 12-12-12 of N-P-K respectively, or the potassium of the nitrogen of 12wt%, the phosphorus of 12wt% and 12wt%.Remaining component is generally filler.
According to some non-limiting example, Ru 2006101161 of the present invention can have N component, and the scope of its N-P-K value is 0 to 20 or 5 to 10 or 10 to 20 or 5 to 15 or 8 to 20 or 10 to 20 or their combination.
The limiting examples of nitrogenous source comprises ammonium nitrate, ammonium sulfate, urea, ammonium phosphate, their mixture of anhydrous ammonia.In one embodiment, Ru 2006101161 of the present invention can comprise the nitrogenous source of 0-1000 gram, or 0.01-100 gram or 0.1-10 gram, 0.2-0.5 gram or their combination nitrogenous source.
The limiting examples in phosphorus source comprises Arizona bacilli or phosphorous acid (such as, phosphorous acid comprises phosphorous acid, Hypophosporous Acid, 50, poly-phosphorous acid, poly-Hypophosporous Acid, 50, or their mixture) or their mixture.In one embodiment, Ru 2006101161 of the present invention can comprise the phosphorus source of 0-1000 gram, or 0.01-100 gram, or 0.1-10 gram, the phosphorus source of 0.2-0.5 gram or their combination.
The limiting examples in potassium source comprises Repone K, potash or their mixture.In one embodiment, Ru 2006101161 of the present invention can comprise the potassium source of 0-1000 gram, or 0.01-100 gram or 0.1-10 gram, 0.2-0.5 gram or their combination potassium source.
Ru 2006101161 of the present invention also can comprise other nutrient substance such as from corresponding calcium, magnesium and sulphur of originating.Ru 2006101161 of the present invention also can comprise micro-nutrients such as boron, copper and iron-also from corresponding source.
The source of NPK can be organically, synthesis or their combination.In one embodiment, the source of NPK is synthesis or is mainly synthesis.Not bound by theory, the synthesis source of NPK is more easily plant gained usually, and in the case, organic origin is really not so.In this embodiment, the organic origin of fertilizer can be provided and synthesize the desirable balance between originating.The compost obtained by family expenses compost will serve as the organic origin of fertilizer.Supplement family expenses compost with the synthesis source of the unitary dose of fertilizer and the nutraceutical balance of originating and originating with slow releasing that is easy to get will be provided for plant.
Another advantage of the present invention is the fertilizer of many commercially available acquisitions, is in particular synthesis source, will comprises filler.The use of filler adds manufacture and transportation cost.In one embodiment, water soluble unit dose of the present invention is substantially free of filler.Filler is generally inert material such as sand, lime, broken corn cob etc.
In one embodiment, Ru 2006101161 of the present invention comprises Methionin source.The limiting examples in Methionin source comprises Methionin one hydrochloride, lysine hydrate, lysine dihydrochloride, lysidine vitriol or their combination.Methionin source can from Archer-Daniels-Midland Company, and Decatur, Ill are commercially available.
In one embodiment, composition comprises alkalinity source or acidifying source.Alkalinity source comprises lime or wood ash.Acidifying source comprises sulphur or Tai-Ace S 150.
enzyme
One aspect of the present invention provides composition, and it comprises one or more enzymes, to contribute to composting process.Enzyme can be used alone or is combined with compost microbe.The example of enzyme comprises: cellulase, hemicellulase, peroxidase, proteolytic enzyme, glucose-amylase, amylase, zytase, lipase, Phospholipid hydrolase, esterase, at, polygalacturonase, keratanase, reductase enzyme, oxydase, phenol oxidase, lipoxygenase, lignoenzyme, Starch debranching enzyme, tannase, pentosanase, Mai Laning enzyme, beta-glucanase, arabinofuranosidase/xylosidase, Unidasa, chondroitinase, laccase or their mixture.In one embodiment, enzyme comprises proteolytic enzyme, amylase, lipase, peroxidase, at and/or cellulase, in conjunction with one or more plant cell-wall degrading enzymes.In another embodiment, the level residing for enzyme is 0.0001 % by weight to 2 % by weight of composition.The supplier of enzyme can comprise Star Engineering Co.Ltd., Japan.
unit dose articles
Another aspect of the present invention is provided in unit dose articles and comprises foregoing with the amount expected." unit dose articles " can be parcel, tablet, or the tablet in parcel.Unit dose articles comprises one or more compositions of the present invention.
parcel
Term " parcel " uses with broadest sense, to comprise pouch, capsule, sack, folliculus etc.Parcel comprises compartment, and described compartment comprises composition, tablet or their combination.The content be included in compartment is separated with outside atmosphere by material block usually.Contemplate various shape and the size of parcel.Material for the formation of the compartment of goods can be the form of film.Term " film " broadly uses, to comprise shell, sheet etc.Film by material cast, blowing, extrude or blow squeeze formed.Material can be not biodegradable, biodegradable, water miscible or their combination.In one embodiment, material is polymer materials, is preferably water-soluble and biodegradable.
Be suitable for use as being encapsulated composition to form the polymkeric substance of the material of unit dose articles of the present invention, the limiting examples of multipolymer or their derivative is selected from polyvinyl alcohol, the polyvinyl acetate of partial hydrolysis, polyvinylpyrrolidone, polyalkylene oxides, acrylamide, vinylformic acid, Mierocrystalline cellulose, ether of cellulose, cellulose ester, cellulose amides, polyvinyl acetate, poly carboxylic acid and salt, polyamino acid or peptide, polymeric amide, polyacrylamide, toxilic acid/acrylic copolymer, comprise the polysaccharide of starch and gelatin, the natural gum of such as xanthan gum and carrageenin, and their combination.In one embodiment, polymkeric substance is selected from polyacrylic ester and water miscible acrylate copolymer, methylcellulose gum, Xylo-Mucine, dextrin, ethyl cellulose, Natvosol, Vltra tears, hydroxy butyl methyl cellulose, Star Dri 5 and polymethacrylate.In another embodiment, polymkeric substance is selected from polyvinyl alcohol, polyvinyl alcohol copolymer, the polyvinyl acetate of partial hydrolysis and Vltra tears (HPMC), hydroxy butyl methyl cellulose (HBMC) and their combination.Polymkeric substance can have any weight-average molecular weight.In one embodiment, weight-average molecular weight is about 1,000 to about 1,000,000, or about 10,000 to about 300,000, or about 20,000 to about 150,000.The known commodity of polyvinyl alcohol film are called Monosol, and by Chris-Craft IndustrialProducts of Gary, Indiana, U.S.A sell.
Other limiting examples being applicable to the material comprising composition of the present invention comprises: gelatin, starch, polyvinyl alcohol, polyoxyethylene glycol, ether of cellulose, gelatin, alginic acid or pectinic acid etc., or their combination.Material optionally comprises the additive of solubleness in its elasticity of adjustment and water.In another embodiment, material comprise the biodegradable polyester of low melting point (such as, pla-pcl)-in film form or in the extrudate form be coated on paper.In another embodiment, material comprise poly-succsinic acid fourth diester or comprise its multipolymer-in film form or in the extrudate form be coated on paper.
Unit dose articles can have single compartment or multiple compartment.When multiple compartment embodiment, unit dose articles can comprise different compositions in each compartment.Inconsistent composition can separate, and is in different compartments.In one embodiment, the compartment of many compartment article can overlap each other.
By ordinary method, such as, by using the conventional equipment with rotating cylinder, encapsulate composition of the present invention by material.See such as US 6,898,921; US 5,617,710; US5,317,849; US 5,188,688; US 4,940,499; US 4,581,875; US 4,478,658; And US 4,089,152.Thermoforming and be injected into other ordinary method.
In one embodiment, goods are in the form of square or rectangle parcel.Material is the material of water-soluble biodegradable, and the form in sheet.Tackiness agent or heated sealant edge region is used to be sealed by one-piece folded or by biplate.In one example in which, by three side seals and the 4th side fill there is the unitary dose of gac after the single folding sheet that seals to form rectangle.Not bound by theory, when using conventional sealed in unit, the parcel that rectangle is shaped is easier to manufacture and sealing than other configuration.In another embodiment, material is for comprising the polyvinyl alcohol of the film purchased from MonoSol, LLC, Merrillville, IN.In another embodiment, the thickness comprising the polyvinyl alcohol of film is about 10 μm to about 1,000 μm, or 20 μm to about 500 μm or their combination.In another embodiment, the volume comprised in compartment is 0.1cm
3to 100cm
3, or 1cm
3to 5cm
3or their combination.Described by a kind of method for the preparation of articles thermoformed therefrom has in WO 00/55045.Film is prepared, described in WO 02/092456 by injection moulding.Unit prepared by pouch, such as, can be rotor drum, as at US 3, and 057, described in 127.
In one aspect of the invention, goods are comprise two, three, many compartment article of a four or more compartment.Each compartment can comprise similar and different composition.Not bound by theory, multiple compartment allows inconsistent composition to be included in one together easily in unitary dose.Multiple compartment unit dose goods at such as US 7,125, described by having in 828.Described by the method preparing multiple compartment unit dose goods has in such as US 2002/0169092 and US 2009/0199877 A1.
In one embodiment, the composition be included in water-soluble material comprises softening agent.In one embodiment, softening agent is polyhydroxy-alcohol (such as aklylene glycol (such as, ethylene glycol, propylene glycol)), glycerine, polyvalent alcohol, sorbyl alcohol or their combination.In another embodiment, composition comprises by weight of the composition about 1% to about 50%, or about 8% to about 12% or their softening agent of combination.Not bound by theory, softening agent can improve snappiness and the splitting resistance of water-soluble material used herein.
tablet
One aspect of the present invention provides and composition of the present invention is formed as tablet.Tablet can be administered to Composter.Alternatively, tablet can be included in the compartment of parcel, wherein parcel can be administered to Composter.An advantage of parcel is that user does not contact with tablet (or other composition of the present invention) or directly contacts.
From manufacture viewpoint, the many compartment pouchs comprising one or more tablet are very convenient, because it may be complicated for filling pouch with granular composition, and easily inaccurate.It normally slowly and may produce dust, makes the dust deposit being very difficult to avoid pouch sealing area.This may be unfavorable for realizing potent sealing.
Any suitable method can be used to form tablet, but preferably by compression, such as, in the tablet machine of compression.Preferably, tablet is by component of the present invention being mixed, and applies at least about 10kg/cm subsequently
2, or at least about 20kg/cm
2, or 40kg/cm
2, or 80kg/cm
2, or 125kg/cm
2, or about 250kg/cm
2or at least about 350kg/cm
2(3.43kN/cm
2) the main body of compression molding prepared of compression pressure.In one embodiment, compression pressure is about 400kg/cm
2to about 2,000kg/cm
2, or about 600kg/cm
2to about 1200kg/cm
2, or their combination." compression pressure " is herein for applied force is divided by the transverse cross-sectional area of cross-sectional area-the be actually punch die of rotary compression of tablet in transverse to the plane of exerted forces.In another embodiment, tablet is carried out at least about 6kg, or be greater than about 8kg, or about 10kg, or about 12kg, and/or the children being greater than about 14kg or their combination bite intensity (Child Bite Strength, " CBS ") test.In one embodiment, 1,000kg is less than to tablet, or is less than the CBS test of about 500kg.CBS measures according to Consumer Product Safety Commission's test specification.
Tablet can take multiple geometrical shape such as spheroid, pipe etc., but preferably has with the axially symmetrical form of the cardinal principle of substantial circular, square or rectangular cross section.
In one aspect of the invention, prepare tablet, make described tablet comprise at least one mould on its surface.Mould can comprise uncompressed part.The uncompressed part of tablet can be in solid, gel or liquid form.
One or more mould also can have difference at size and dimension and they relative on the position of tablet, orientation and topological framework.Such as, the cross section of one or more mould can be substantial circular, square or oval; They can form the cavity of enclose inside, depression or groove in tablet surface, or they can extend (such as, axially relative to internal surface) between the region do not connected of tablet surface, to form one or more topology " hole " in tablets; And they can be relative to tablet axially or otherwise symmetrically arranged, or they can be asymmetric setting.Preferably, mould is preformed, such as, the tablet machine of specially designed compression is used to be formed, wherein pouch is contacted the surface forming of detergent composition, when making when described surface contact and press composition, described surface by one or more mold compresses in tablet.Preferably, mould by have inside concave surface or substantially concave surface to provide shell and the physical storage of the improvement of the uncompressed part of tablet.Alternatively, by compressing the preformed composition main body that arranges ringwise around center punch, thus form the forming body that has in the mould of axially extended cavity format between relative body surfaces to form mould.From holding the viewpoint comprising the compartment of liquid of the present invention, gel or paste composition, the tablet with mould is very useful.
In one embodiment, compression section, uncompressed part or their combination can comprise gac, fertilizer, compost microbe, microorganism supplement, spices or their combination.
Described by the method that preparation comprises the tablet of compression section and uncompressed part has in such as United States Patent (USP) 6,399,564B1 (such as, the 35th hurdle the 59th walks to the 37th hurdle the 5th row).In one embodiment, uncompressed part comprises carrier component.Preferred vector component is organic polymer, is preferably solid at ambient temperature.The example of carrier component is polyoxyethylene glycol (PEG).Uncompressed part can comprise other composition, such as solvent, binding agent, jelling agent and/or thickening material, and see United States Patent (USP) 6,399,564 the 5th hurdles the 26th walk to the 9th hurdle the 3rd row.Uncompressed part can be coated with coating.Coating can be used for uncompressed part to be attached to compression section.See United States Patent (USP) 6,399,564 the 9th hurdles the 4th walk to the 35th row.
The compression section of tablet can comprise cracking agent.Cracking agent can be disintegrating agent or effervescent.See United States Patent (USP) 6,399,564 the 4th hurdles the 1st walk to the 18th row.
Tablet of the present invention can comprise about 1g to about 1,000g, or about 100g is to about 2,000g, or about 250g is to about 1,500g, or about 500g is to about 1,000g or their weight of combination.
Tablet of the present invention can comprise 0.1cm
3to about 1,000cm
3, or about 100cm
3to about 2,000cm
3, or about 250cm
3to about 1,5000cm
3, or 500cm
3to about 1,000cm
3or the volume of their combination.
external member
One aspect of the present invention provides a kind of external member, and wherein external member comprises at least one unit dose articles of the present invention and optionally operation instruction.In one embodiment, external member comprises multiple unit dose articles, and wherein the first unitary dose comprises the first Ru 2006101161 and the second unitary dose comprises the second Ru 2006101161, and wherein the first Ru 2006101161 is different from the second Ru 2006101161.These compositions are different based on different application.Such as, the first unit dose articles can for spring, and yearly plant needs more phosphorus for root growth substantially at that time, and the second unit dose articles can for the use in summer, and plant needs more nitrogen to grow for leaf substantially at that time.In another example, the first unit dose articles can for oxyphiles, and the second unit dose articles is for non-oxyphiles.In another example, the first unit dose articles can for vegetable plant, and the second unit dose articles is for fruit-bearing plant.
One aspect of the present invention provides a kind of external member, and described external member comprises and at least onely comprises the unit dose articles of gac and at least one unit dose articles comprising Ru 2006101161.In this aspect of the invention, the goods of human consumer two type are supplied to; The first type of composting process is conducive to by providing stench to control (and optionally compost microbe); And provide the N-P-K value of expectation to customize the second type of compost for the supplementary compost of specific fertilizer application.In one embodiment, goods comprise gac and Ru 2006101161.
Alternatively, provide a kind of product line, wherein the first product contains the unit dose articles comprising gac, and the second product contains the unit dose articles comprising Ru 2006101161.
In one embodiment, a kind of external member comprising multiple goods is provided.Goods can be identical or different.Goods can only comprise gac or goods only can comprise Ru 2006101161.Goods can comprise gac and Ru 2006101161.In one embodiment, the goods of external member are identical, and each self-contained gac of each goods wherein in multiple goods and Ru 2006101161.In another embodiment, external member comprises explanation, and described explanation indicating user uses goods according to scheme to compost utensil.In another embodiment, processing scheme comprises a time period, and at least two unit time of wherein said time period are different (that is, goods frequency of administration change).Such as, scheme can have the about bimestrial time period.The first, second, third and fourth unit time can be once in a week, and the 5th final unit time is about one month (to complete the about bimestrial time period).
compost microbe and microorganism supplement
In one aspect of the invention, composition can comprise compost microbe (such as, bacterium, yeast, mold fungi/spore/hyphal suspension or their combination) and optionally microorganism supplement.
Term " microorganism supplement " comprises microorganism, probiotic bacterium, microbiotic, biocide or their combination.Prebiotics is chemical agent, and it optionally promotes expect microbial growth and/or stop undesirably microbial growth.The limiting examples of prebiotics comprises: optionally food carbon (cofactor of sugar such as fructose oligosaccharides, some alcohols (such as, inositol, mannitol), some optionally required positively charged ion (such as iron, vanadium) or such as protohemine or vitamin K).Probiotic bacterium is compete the expectation microorganism winning and/or optionally suppress less desirable microorganism with less desirable microorganism.The limiting examples of prebiotics is the milk-acid bacteria producing lactic acid, and described milk-acid bacteria suppresses gram-negative pathogens.Microbiotic/biocide be act directly on undesirably on microorganism to suppress described microbial growth or to kill the natural of them or chemical agent.
The composition comprising compost microbe can be included in unit dose articles.Microorganism can be added, one or more to contribute in following functions: the beginning adding the aerobic breakdown of food and plant waste (being included in pre-compost); Stench is provided to control; Strengthen high de-agglomeration with the rate of decomposition of the wide in range organic materials scope in pre-compost and compost and spectrum active, described pre-compost and compost comprise high-cellulose and cellulosic plant/paper wood; Improve compost health; What strengthen bacterium builds group/field planting, to promote the aerobic breakdown of high strength; Raise the temperature of organic compost material, to allow thermophilic decomposition; Contribute to reducing or removing less desirable or pathogenic microbes; Improve the quality (such as, the bioavailability of the per-cent of pH, soil ulmin, water tariff collection, micro-nutrients, and nutritive ingredient) of final compost; Or their combination.
Compost microbe can be used in many ways in compost utensil by goods of the present invention.User can before adding pre-compost to compost utensil, between and add compost microbe and/or microorganism supplement simply afterwards.Alternatively, before the operation started the machine, compost microbe/supplement are added.In one embodiment, compost microbe or microorganism supplement are added according to processing scheme (as described previously) to compost utensil.
Microorganism/supplement can be used as solution or liquid suspension or dried forms (such as powder) and use.In addition to water, suspension/solution can comprise other composition, and it comprises solvent, dispersion agent, stablizer, toxicity modifiers, pH buffer reagent etc.In general, about 1,000,000,000 microorganism cellss are contained in: the solution/suspension of each milliliter; Or the dried forms of a milligram.Solution/suspension is used by water soluble unit dose goods of the present invention.
The list of microorganism can comprise following: genus bacillus (Bacillus) belongs to bacterium; Shi Shi genus bacillus (Bacillus smithii) (preferred Oklin bacterial strain); Sulfolobus solfataricus genus bacillus (Bacillus sulfolobus) (preferred Oklin bacterial strain); Subtilis (Bacillus subtilis); Bacillus licheniformis (Bacillus licheniformis); Bacillus megaterium (Bacillus megaterium); Bacillus polymyxa (Bacillus polymyxa); Bacillus circulans (Bacillus circulans); Bacillus cereus (Bascillus cereus); Bacterium lacticum (Lactobacillus) belongs to bacterium; Lactobacterium acidophilum (Lactobacillusacidophilus), actinomycetes Bacterium lacticum (Lactobacillusactinomyces); Lactobacterium casei (Lactobascillus casei); Streptomycete Bacterium lacticum (Lactobacillus Streptomyces); Forlan bacterium lacticum koseri (Lactobacillus frankia); Fixed nitrogen Bacterium lacticum (LactobacillusAzotobacter); And their combination.
Microorganism can comprise fungi, is preferably combined with bacterium.The list of microorganism can comprise following: aspergillus (Aspergillus) belongs to fungi; Aspergillus niger (Aspergillus niger); Aspergillus oryzae (Aspergillusorizae); Head mold (Rhizopus) belongs to fungi, yeast (Saccaromyces) belongs to fungi; Wood mould (Trichondema) belongs to fungi; And their combination.
The example of supplement can comprise the composition contributing to compost and/or provide better compost.Can help the composition promoting compost, it comprises the component with high nitrogen, such as soybean and clover (with accelerate growth of microorganism); Sawdust (increase circulation, therefore increase oxygen level); Trace mineral; Carbohydrate (such as, molasses, to help to supply nutrients to microorganism); Enzyme (such as, proteolytic enzyme, lipase, cellulase, lignoenzyme, polygalacturonase etc.) and their mixture.Can help to provide the composition of better compost to comprise edaphic condition (such as, soil ulmin and the humic acid leonardite compound being derived from leonardite), root-promoting hormone or their combination.
One aspect of the present invention provides a kind of method using composition to family expenses compost utensil, and wherein composition comprises microorganism and/or microorganism supplement.
Goods of the present invention and/or composition can comprise spices.Spices is open in the U.S. Patent Publication jointly submitted to patent application P & G case 12404P.
secondary encapsulation
One or more unit dose articles of the present invention can be included in secondary packaging.In one embodiment, provide a kind of containment system, comprising: capping and comprise the bucket of rigidity or semi-rigid walls, wherein capping can open the entrance of the internal volume providing bucket.Preferably, capping can be closed after opening.Internal volume comprises at least one preferred multiple unit dose articles.Bucket and capping can be made of plastics.In one embodiment, bucket comprises antetheca, rear wall (relative with antetheca), sidewall (extending between the front and rear walls); Bottom (at antetheca, extending between rear wall and sidewall).In another embodiment, be in being sealed on antetheca, extending between rear wall and one or more sidewall of its off-position, and relative with bottom (that is, forming top).Capping can comprise hinge.See such as US2011/0204087 A1.
In another embodiment, containment system comprises pliable and tough sealable bag, and described bag comprises at least one preferred multiple unit dose articles of the present invention.Bag comprises anter and to join on limit to form the rear panel of closed sack on it along at least two relative edges in the face of relation, and anter and rear panel are engaged at top by frangible seal.Egative film is between anter and rear panel, and by anter and rear chip bonding to form internal volume (to comprise one or more goods).In another embodiment, the anter of bag comprises at least one transparent window portion, wherein can see the one or more unit dose articles being included in bag inside from the outside of sack.See the U.S. Patent Publication such as carrying out the Application U.S. Serial No 12/885,793 (P & G case 11880) that on September 20th, 1 submits to.
In one embodiment, the internal volume (emptying any content) of the container of containment system comprises about 50cm
3to about 4,000cm
3, or about 500cm
3to about 2,000cm
3, or about 1,000cm
3to about 3,000cm
3or the volume of their combination.In another embodiment, the container of containment system comprises the unit dose articles of about 1 to about 150, or about 6 to about 100, or about 12 to about 50, or about 15 to about 25 or their combination.In another embodiment, the container of containment system comprises about 25cm
2to about 500cm
2, or about 50cm
2to about 400cm
2, or about 75cm
2to about 300cm
2, or about 100cm
2to about 200cm
2, or about 150cm
2to about 250cm
2, or the impression area of their combination.
Dimension disclosed herein and value should not be understood to be strictly limited to described exact numerical values recited.On the contrary, except as otherwise noted, each such dimension is intended to the scope representing described value and the functional equivalent around this value.Such as, disclosed dimension " 40mm " is intended to represent " about 40mm ".
Unless expressly excluded or otherwise limited, each document quoted herein, comprises any cross reference or relevant patent or patent application, is all incorporated in full herein with way of reference.Quoting of any document is not to its prior art as disclosed herein or claimed any invention; or its individually or with any combination of other reference any, or with reference to, propose, suggestion or disclose any accreditation that this type of is invented.In addition, when any implication of term in any implication of term in the present invention or definition and the file that is incorporated to way of reference or when defining contradiction, the implication or definition of giving this term in the present invention should be obeyed.
Although illustrate and describe the present invention with specific embodiment, it is obvious for those of skill in the art that, can make without departing from the spirit and scope of the present invention many other change and amendment.Therefore, all these being intended to contain in the scope of the invention of following claims change and modification.
Claims (22)
1. one kind comprises the goods of about 0.1g to about 1,000g Ru 2006101161, and wherein said Ru 2006101161 is comprised by biodegradable film.
2. goods according to claim 1, wherein said Ru 2006101161 comprises the nitrogenous source of about 0.1g to about 1,000g.
3. goods according to claim 2, wherein said Ru 2006101161 comprises the phosphorus source of about 0.1g to about 1,000g.
4. goods according to claim 3, wherein said Ru 2006101161 comprises the potassium source of about 0.1g to about 1,000g.
5. goods according to claim 4, wherein said Ru 2006101161 is substantially free of filler.
6. comprise the compressed tablets of about 0.1g to about 100g Ru 2006101161, wherein said tablet is the main body of compression molding.
7. tablet according to claim 6, wherein by applying at least 10kg/cm
2compression pressure prepare described tablet; And wherein said tablet comprises about axially symmetrical form.
8. method according to claim 7, wherein said tablet also comprises uncompressed part.
9. goods according to claim 7, wherein said Ru 2006101161 comprises the nitrogenous source of about 0.1g to about 1,000g.
10. goods according to claim 9, wherein said Ru 2006101161 comprises the phosphorus source of about 0.1g to about 1,000g.
11. goods according to claim 10, wherein said Ru 2006101161 comprises the potassium source of about 0.1g to about 1,000g.
12. 1 kinds of many compartment article comprising the first composition and the second composition;
Wherein said first composition comprises Ru 2006101161, and described Ru 2006101161 tunicle comprises the first compartment forming described goods; And
Wherein said second composition is comprised by described film the second compartment forming described goods.
13. goods according to claim 12, wherein said Ru 2006101161 comprises:
The nitrogenous source of (a) about 0.1g to about 1,000g; And/or
The phosphorus source of (b) about 0.1g to about 1,000g; And/or
The potassium source of (c) about 0.1g to about 1,000g.
14. goods according to claim 13, wherein said second composition comprises gac.
15. goods according to claim 13, wherein said second composition comprises and is selected from following component: compost microbe, microorganism supplement and their combination.
16. 1 kinds of methods processing compost, it comprises the step using goods according to claim 1 in compost utensil.
17. 1 kinds of methods processing compost, it comprises the step using goods according to claim 6 in compost utensil.
18. 1 kinds of methods processing compost, it comprises the step using goods according to claim 10 in compost utensil.
19. 1 kinds of introduction external members, it comprises:
(a) compost utensil; And/or
B () is according to the goods of claim 1,6,10;
C () is optionally for using the explanation of described goods to described compost utensil.
20. 1 kinds of products comprising bucket and multiple goods, wherein said bucket comprises described multiple goods, and each of wherein said multiple goods comprises the Ru 2006101161 of about 0.1g to about 1,000g.
21. products according to claim 20, wherein said goods are selected from: compressed tablets; Comprise the unit dose articles of biodegradable film, described biodegradable film comprises described Ru 2006101161.
22. 1 kinds of products comprising pliable and tough sealable bag and multiple goods, wherein said bag comprises described multiple goods, and each of wherein said multiple goods comprises about 1g to about 1000g gac, and wherein said goods are selected from: compressed tablets; And comprise the unit dose articles of biodegradable and water miscible film, described biodegradable and water miscible film comprises described Ru 2006101161.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261638512P | 2012-04-26 | 2012-04-26 | |
| US61/638,512 | 2012-04-26 | ||
| US201261644546P | 2012-05-09 | 2012-05-09 | |
| US61/644,546 | 2012-05-09 | ||
| PCT/US2013/038309 WO2013163489A1 (en) | 2012-04-26 | 2013-04-26 | Articles for in-home composting |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104487406A true CN104487406A (en) | 2015-04-01 |
Family
ID=48326467
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380021217.4A Pending CN104487406A (en) | 2012-04-26 | 2013-04-26 | Articles for in-home composting |
Country Status (7)
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|---|---|
| US (1) | US20150040624A1 (en) |
| EP (1) | EP2841400A1 (en) |
| JP (1) | JP2015519281A (en) |
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| CA (1) | CA2871218A1 (en) |
| MX (1) | MX2014011541A (en) |
| WO (1) | WO2013163489A1 (en) |
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| CN106118683A (en) * | 2016-06-30 | 2016-11-16 | 山东爱福地生物科技有限公司 | A kind of heavy-metal contaminated soil renovation agent |
Also Published As
| Publication number | Publication date |
|---|---|
| US20150040624A1 (en) | 2015-02-12 |
| WO2013163489A1 (en) | 2013-10-31 |
| MX2014011541A (en) | 2014-11-14 |
| EP2841400A1 (en) | 2015-03-04 |
| JP2015519281A (en) | 2015-07-09 |
| CA2871218A1 (en) | 2013-10-31 |
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