CN104402367B - 无泛碱高强瓷砖胶粘剂 - Google Patents
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Abstract
一种无泛碱高强瓷砖胶粘剂，它的原料组成及重量百分比配比如下：高铝水泥23～30％，粉煤灰42～50％，高炉渣12～16％，双飞粉6～10％，可再分散乳胶粉3～6％，消泡剂0.5～1％，纤维素醚0.1～0.5％，泛碱抑制剂0.2～0.5％。本发明产品不会在瓷砖表面或砖缝处形成泛碱，具有超强粘结力，抗下垂，抗滑移，具有良好的耐水，耐热老化(70℃)性能，能经受干湿交替及冻融交替的考验，彻底解决了瓷砖泛碱、空鼓、剥落的问题。
Description
技术领域
本发明属于建筑用瓷砖胶粘剂领域，具体涉及一种在使用过程中无泛碱现象出现的高强瓷砖胶粘剂。
背景技术
瓷砖的飞速发展，为美化城市和家居环境做出了重大贡献。传统的瓷砖粘贴方法多采用水泥砂浆，即将砂和水泥现场混合制成简单的水泥砂浆。把这种砂浆涂在预浸或者预润湿瓷砖背面，涂有砂浆的瓷砖压到预先润湿的表面上，然后轻敲瓷砖，以保证瓷砖具有一致的平整度。此过程的主要目的是将砂浆压实，使水泥颗粒进入到瓷砖的多孔背面内部和多孔基材中。这种砂浆的缺点为易泛碱、涂层厚、粘结力弱、耐久性差、容易剥落、施工材料用量大。同时，砂浆还须以合适的比例、稠度进行混合，并且在贴砖之前，需要在瓷砖的背面涂上适量的砂浆，这就需要依赖技术工人的熟练程度和责任心。所以，其施工质量难以保证。在粘贴大型低吸水率瓷砖时，由于瓷砖背面致密光滑，水泥浆无法渗透到瓷砖背面，易出现脱落问题。特别是对于大规格瓷砖的铺贴，采用这种方法还必须进行机械固定或者加固。
发明内容
本发明为解决上述传统瓷砖粘贴的不足和局限性，提供了一种无泛碱高强瓷砖胶粘剂。
本发明的技术方案为：
一种无泛碱高强瓷砖胶粘剂，其特征在于，它的原料组成及重量百分比配比如下：高铝水泥23～30％，粉煤灰42～50％，高炉渣12～16％，双飞粉6～10％，可再分散乳胶粉3～6％，消泡剂0.5～1％，纤维素醚0.1～0.5％，泛碱抑制剂0.2～0.5％。
所述高铝水泥为Al2O3含量≥45wt％的铝酸盐水泥。
所述粉煤灰、高炉渣和双飞粉的细度均≥100目。
所述可再分散乳胶粉为苯乙烯-丙烯酸共聚乳胶粉或乙烯-醋酸乙烯共聚乳胶粉。
所述消泡剂为聚二甲基硅氧烷。
所述纤维素醚为甲基纤维素醚、羧甲基纤维素醚、羧丙基甲基纤维素醚或羧乙基纤维素醚中的一种或几种。
所述泛碱抑制剂为阿克苏诺贝尔特种化学(上海)有限公司生产的ERA100泛碱抑制剂。
所述瓷砖胶粘剂的制备方法为：根据上述规定的重量比分别称取高铝水泥、粉煤灰、高炉渣、双飞粉、可再分散乳胶粉、消泡剂、纤维素醚、泛碱抑制剂，放入搅拌机中，将所有原料混合搅拌均匀，即得所述无泛碱高强瓷砖胶粘剂。
本发明的有益效果：本发明采用高铝水泥为胶凝材料，配以粉煤灰、高炉渣、双飞粉填料，可有效抑制胶粘剂的泛碱现象。加入各种高分子改性剂，提高了胶粘剂的粘结强度，涂层薄，施工材料用量小，且在瓷砖粘贴过程中及粘贴完成后，都不会出现下垂，滑移现象。另外，本发明产品具有良好的耐水，耐热老化(70℃)性能，能经受干湿交替及冻融交替的考验，彻底解决了瓷砖泛碱、空鼓、剥落的问题。
具体实施方式
实施例1
称取高铝水泥26g，粉煤灰46g，高炉渣14g，双飞粉8g，苯乙烯-丙烯酸共聚乳胶粉4g，聚二甲基硅氧烷1g，羧甲基纤维素醚0.5g，ERA100泛碱抑制剂0.5g，放入搅拌机中，将所有原料混合搅拌均匀得无泛碱高强瓷砖胶粘剂。
实施例2
称取高铝水泥23g，粉煤灰50g，高炉渣13g，双飞粉10g，乙烯-醋酸乙烯共聚乳胶粉3g，聚二甲基硅氧烷0.5g，甲基纤维素醚0.1g，羧乙基纤维素醚0.1g，ERA100泛碱抑制剂0.3g，放入搅拌机中，将所有原料混合搅拌均匀得无泛碱高强瓷砖胶粘剂。
实施例3
称取高铝水泥30g，粉煤灰42g，高炉渣15g，双飞粉6g，乙烯-醋酸乙烯共聚乳胶粉6g，聚二甲基硅氧烷0.6g，羧丙基甲基纤维素醚0.1g，羧乙基纤维素醚0.1g，ERA100泛碱抑制剂0.2g，放入搅拌机中，将所有原料混合搅拌均匀得无泛碱高强瓷砖胶粘剂。
将上述实施例1-3制备的瓷砖胶粘剂产品按照JC/T 547-2005《陶瓷墙地砖胶粘剂》中有关规定进行测试，测试结果如下表1：
表1 产品性能测试结果
由表1可知，本发明实施例1-3制备的瓷砖胶粘剂产品测试结果均符合建筑行业标准规定的使用要求。
Claims (8)
1.一种无泛碱高强瓷砖胶粘剂，其特征在于，它的原料组成及重量百分比配比如下：高铝水泥23～30％，粉煤灰42～50％，高炉渣12～16％，双飞粉6～10％，可再分散乳胶粉3～6％，消泡剂0.5～1％，纤维素醚0.1～0.5％，泛碱抑制剂0.2～0.5％。
2.如权利要求1所述的无泛碱高强瓷砖胶粘剂，其特征在于，它的原料组成及重量百分比配比如下：高铝水泥26％，粉煤灰46％，高炉渣14％，双飞粉8％，可再分散乳胶粉4％，消泡剂1％，纤维素醚0.5％，泛碱抑制剂0.5％。
3.如权利要求1所述的无泛碱高强瓷砖胶粘剂，其特征在于，所述高铝水泥为Al2O3含量≥45wt％的铝酸盐水泥。
4.如权利要求1所述的无泛碱高强瓷砖胶粘剂，其特征在于，所述可再分散乳胶粉为苯乙烯-丙烯酸共聚乳胶粉或乙烯-醋酸乙烯共聚乳胶粉。
5.如权利要求1所述的无泛碱高强瓷砖胶粘剂，其特征在于，所述消泡剂为聚二甲基硅氧烷。
6.如权利要求1所述的无泛碱高强瓷砖胶粘剂，其特征在于，所述纤维素醚为甲基纤维素醚、羧甲基纤维素醚、羧丙基甲基纤维素醚或羧乙基纤维素醚中的一种或几种。
7.如权利要求1所述的无泛碱高强瓷砖胶粘剂，其特征在于，所述泛碱抑制剂为阿克苏诺贝尔特种化学(上海)有限公司生产的ERA100泛碱抑制剂。
8.如权利要求1所述的无泛碱高强瓷砖胶粘剂，其特征在于，所述瓷砖胶粘剂的制备方法为：根据上述规定的重量比分别称取高铝水泥、粉煤灰、高炉渣、双飞粉、可再分散乳胶粉、消泡剂、纤维素醚、泛碱抑制剂，放入搅拌机中，将所有原料混合搅拌均匀，即得所述无泛碱高强瓷砖胶粘剂。
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| CN106396563A (zh) * | 2016-08-26 | 2017-02-15 | 派丽(上海)管理有限公司 | 一种人造石胶粘剂 |
| CN106746989A (zh) * | 2016-12-15 | 2017-05-31 | 赵仁杰 | 一种含纤维素醚的瓷砖胶及其生产工艺 |
| CN106892602A (zh) * | 2017-03-17 | 2017-06-27 | 潘长海 | 一种饰面材料粘结剂 |
| CN108640620B (zh) * | 2018-08-02 | 2021-12-14 | 广东金意陶陶瓷集团有限公司 | 瓷砖胶及其制备方法 |
| CN111154408B (zh) * | 2020-01-10 | 2022-07-08 | 广东合睿智造新材料有限公司 | 一种抗菌高强型瓷砖胶的制备方法 |
| CN113998965A (zh) * | 2021-11-25 | 2022-02-01 | 上海宝田新型建材有限公司 | 发泡陶瓷板用填缝胶及其制备方法和应用 |
| CN115477508A (zh) * | 2022-09-15 | 2022-12-16 | 江门市俞嘉科技有限公司 | 一种利用发泡陶瓷尾料生产瓷砖胶的制备工艺 |
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