CN104271546B - 酯的生产方法及其用途 - Google Patents
酯的生产方法及其用途 Download PDFInfo
- Publication number
- CN104271546B CN104271546B CN201380022538.6A CN201380022538A CN104271546B CN 104271546 B CN104271546 B CN 104271546B CN 201380022538 A CN201380022538 A CN 201380022538A CN 104271546 B CN104271546 B CN 104271546B
- Authority
- CN
- China
- Prior art keywords
- oil
- water
- ozone
- ester
- azeotrope
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/29—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of oxygen-containing functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261604267P | 2012-02-28 | 2012-02-28 | |
| US61/604,267 | 2012-02-28 | ||
| PCT/MY2013/000038 WO2013129907A1 (en) | 2012-02-28 | 2013-02-28 | Method for the production of esters and uses thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104271546A CN104271546A (zh) | 2015-01-07 |
| CN104271546B true CN104271546B (zh) | 2017-06-09 |
Family
ID=49083016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380022538.6A Active CN104271546B (zh) | 2012-02-28 | 2013-02-28 | 酯的生产方法及其用途 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9505701B2 (enExample) |
| EP (1) | EP2819985B1 (enExample) |
| JP (1) | JP6097771B2 (enExample) |
| KR (1) | KR102061374B1 (enExample) |
| CN (1) | CN104271546B (enExample) |
| MY (1) | MY174607A (enExample) |
| SG (1) | SG11201405265QA (enExample) |
| WO (1) | WO2013129907A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG11201405265QA (en) | 2012-02-28 | 2014-09-26 | Petroliam Nasional Berhad | Method for the production of esters and uses thereof |
| KR102061375B1 (ko) * | 2012-02-28 | 2019-12-31 | 페트롤리암 내셔널 버하드 (페트로나스) | 생물-윤활제 및 생물-폴리머용 생물-폴리올 및 그의 제조 방법 |
| SG11201405270UA (en) | 2012-02-28 | 2014-09-26 | Petroliam Nasional Berhad | Method for the production of polyols and uses thereof |
| WO2013129909A1 (en) | 2012-02-28 | 2013-09-06 | Petroliam Nasional Berhad | Lubricant composition of matter and methods of preparation |
| SG11201405266WA (en) | 2012-02-28 | 2014-09-26 | Petroliam Nasional Berhard | Composition of matter polyols for polyurethane applications |
| MY169226A (en) | 2013-02-28 | 2019-03-19 | Petroliam Nasional Berhad | Preparation of biopolyol esters for lubricant application |
| CN108164416B (zh) * | 2018-01-05 | 2021-02-19 | 浙江工业大学 | 一种基于生物柴油制备壬二酸单甲酯的新工艺 |
| US11845903B2 (en) * | 2021-11-02 | 2023-12-19 | ExxonMobil Technology and Engineering Company | High yield jet fuel and chemicals from ozonolysis of triglycerides |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5773256A (en) * | 1991-08-12 | 1998-06-30 | Ulice Sa | Methods for the production of esters of α-glucosides and uses thereof |
| CN1332716A (zh) * | 1998-12-28 | 2002-01-23 | Dsm精细化学奥地利Nfg两合公司 | 制备乙醛酸酯或其水合物的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2566559A (en) * | 1951-09-04 | Preparation of agetals | ||
| US667043A (en) | 1900-09-13 | 1901-01-29 | James Steep | Seed-drill. |
| US2401338A (en) * | 1941-09-23 | 1946-06-04 | Buckeye Lab Corp | Treatment of vegetable fatty substances |
| US2813113A (en) | 1953-05-07 | 1957-11-12 | Emery Industries Inc | Method of making azelaic acid |
| US3048608A (en) | 1959-03-18 | 1962-08-07 | Heyden Newport Chemical Corp | Neopentyl glycol esters |
| US2997493A (en) | 1959-09-29 | 1961-08-22 | Procter & Gamble | Method for preparing straight chain hexitol fatty esters |
| FR2254633B1 (enExample) | 1973-12-12 | 1976-10-08 | Inst Francais Du Petrole | |
| US4263216A (en) | 1978-10-20 | 1981-04-21 | The Procter & Gamble Company | Diglyceride manufacture |
| IE50028B1 (en) | 1979-12-19 | 1986-02-05 | Tate & Lyle Plc | Process for the production of a surfactant containing sucrose esters |
| US4313890A (en) | 1980-01-29 | 1982-02-02 | Union Carbide Corporation | Polyol ester functional fluids |
| JPS57185235A (en) | 1981-05-07 | 1982-11-15 | Mitsui Toatsu Chem Inc | Preparation of neopentyl polyol ester from fatty acid |
| JPH0418049A (ja) | 1990-05-09 | 1992-01-22 | Lion Corp | 不飽和脂肪酸低級アルキルエステルのオゾン化物の酸素酸化分解方法 |
| EP0644921B1 (en) | 1992-06-03 | 2000-08-16 | Henkel Corporation | Polyol ester lubricants for refrigerant heat transfer fluids |
| IT1254974B (it) | 1992-06-18 | 1995-10-11 | Bayer Italia Spa | Granulati compositi, scorrevoli,idrofobi,un procedimento per la loro preparazione nonche' loro impiego |
| US5362368A (en) | 1993-06-03 | 1994-11-08 | Scott Lynn | Chlorine generator |
| BR9504838A (pt) | 1994-11-15 | 1997-10-07 | Lubrizol Corp | Ester de poliol composição de óleo lubrificante |
| FI104553B (fi) | 1997-05-07 | 2000-02-29 | Fortum Oil & Gas Oy | Menetelmä kompleksiesterien valmistamiseksi ja puhdistamiseksi |
| DE19727950A1 (de) | 1997-07-01 | 1999-01-07 | Clariant Gmbh | Verfahren zur Herstellung von Mischungen aus Sorbitmonoestern, Sorbitdiestern und Partialglyceriden |
| GB0112557D0 (en) | 2001-05-23 | 2001-07-11 | Infineum Int Ltd | A process for manufacturing monoesters of polyhydroxyalcohols |
| WO2003020782A2 (en) | 2001-08-29 | 2003-03-13 | Ptc Organics, Inc. | Transesterification using phase transfer catalysts |
| MY140833A (en) | 2003-03-18 | 2010-01-29 | Univ Putra Malaysia | Palm oil based trimethylolpropane esters |
| WO2004087847A1 (ja) | 2003-03-31 | 2004-10-14 | New Japan Chemical Co., Ltd. | 潤滑油及び潤滑方法 |
| WO2004099227A2 (en) | 2003-04-30 | 2004-11-18 | Michigan State University | Polyol fatty acid polyesters process and polyurethanes therefrom |
| US7192457B2 (en) | 2003-05-08 | 2007-03-20 | Cargill, Incorporated | Wax and wax-based products |
| EP1529828A1 (en) | 2003-10-31 | 2005-05-11 | Malaysian Palm Oil Board | Lubricant base oil of palm fatty acid origin |
| MY141241A (en) | 2003-11-20 | 2010-03-31 | Malaysia Palm Oil Board | Lubricant base from palm oil and its by-products |
| WO2006093874A2 (en) | 2005-02-28 | 2006-09-08 | Michigan State University | Novel triglycerides and method of preparation thereof |
| JP5139973B2 (ja) | 2005-04-26 | 2013-02-06 | バテル・メモリアル・インスティテュート | 油からポリオールを製造する方法、並びにポリエステル及びポリウレタンの製造におけるそれらの使用 |
| WO2010078493A1 (en) | 2008-12-31 | 2010-07-08 | Battelle Memorial Institute | Solvent-less preparation of polyols by ozonolysis |
| US8877952B2 (en) | 2005-04-26 | 2014-11-04 | Battelle Memorial Institute | Pre-esterification of primary polyols to improve solubility in solvents used in the polyol process |
| JP4633765B2 (ja) | 2006-06-07 | 2011-02-16 | 花王株式会社 | エステルの製造方法 |
| AU2007301112A1 (en) | 2006-09-27 | 2008-04-03 | Asahi Glass Company, Limited | Method for producing soft polyurethane foam |
| EP2134822A2 (en) | 2007-04-09 | 2009-12-23 | Dow Global Technologies Inc. | Capped polyester polyol lubricant composition |
| CN101077856B (zh) | 2007-06-26 | 2011-06-08 | 上海大学 | 固体酸催化制备壬二酸的方法 |
| EP2291435B1 (en) | 2008-06-03 | 2016-08-17 | Dow Global Technologies LLC | A composite dispersion, method of producing the same, and articles made therefrom |
| US8419968B2 (en) | 2008-11-13 | 2013-04-16 | Chemtura Corporation | Lubricants for refrigeration systems |
| MX2011006961A (es) | 2008-12-31 | 2011-09-27 | Battelle Memorial Institute | Uso de acidos grasos como material de alimentacion en el proceso de poliol. |
| CA2748622C (en) * | 2008-12-31 | 2016-11-01 | Battelle Memorial Institute | Preparation of esters and polyols by initial oxidative cleavage of fatty acids followed by esterification reactions |
| EP2382288B1 (en) | 2009-01-26 | 2017-03-01 | Chemtura Corporation | Production of polyol ester lubricants for refrigeration systems |
| DE102009042522A1 (de) | 2009-09-22 | 2011-04-07 | Clariant International Ltd. | Kontinuierliches Umesterungsverfahren |
| CN101812349B (zh) | 2010-05-11 | 2013-05-01 | 上海海都化学科技有限公司 | 润滑油及润滑脂基础油及其制备方法与应用 |
| CN102010772A (zh) | 2010-12-01 | 2011-04-13 | 中国科学院新疆理化技术研究所 | 哑铃型结构酯类润滑基础油及其制备方法 |
| SG11201405265QA (en) | 2012-02-28 | 2014-09-26 | Petroliam Nasional Berhad | Method for the production of esters and uses thereof |
| SG11201405266WA (en) | 2012-02-28 | 2014-09-26 | Petroliam Nasional Berhard | Composition of matter polyols for polyurethane applications |
| SG11201405270UA (en) | 2012-02-28 | 2014-09-26 | Petroliam Nasional Berhad | Method for the production of polyols and uses thereof |
| KR102061375B1 (ko) * | 2012-02-28 | 2019-12-31 | 페트롤리암 내셔널 버하드 (페트로나스) | 생물-윤활제 및 생물-폴리머용 생물-폴리올 및 그의 제조 방법 |
| WO2013129909A1 (en) | 2012-02-28 | 2013-09-06 | Petroliam Nasional Berhad | Lubricant composition of matter and methods of preparation |
| MY169226A (en) | 2013-02-28 | 2019-03-19 | Petroliam Nasional Berhad | Preparation of biopolyol esters for lubricant application |
-
2013
- 2013-02-28 SG SG11201405265QA patent/SG11201405265QA/en unknown
- 2013-02-28 EP EP13755664.3A patent/EP2819985B1/en active Active
- 2013-02-28 KR KR1020147027181A patent/KR102061374B1/ko active Active
- 2013-02-28 US US14/381,530 patent/US9505701B2/en active Active
- 2013-02-28 JP JP2014559851A patent/JP6097771B2/ja active Active
- 2013-02-28 WO PCT/MY2013/000038 patent/WO2013129907A1/en not_active Ceased
- 2013-02-28 MY MYPI2014002503A patent/MY174607A/en unknown
- 2013-02-28 CN CN201380022538.6A patent/CN104271546B/zh active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5773256A (en) * | 1991-08-12 | 1998-06-30 | Ulice Sa | Methods for the production of esters of α-glucosides and uses thereof |
| CN1332716A (zh) * | 1998-12-28 | 2002-01-23 | Dsm精细化学奥地利Nfg两合公司 | 制备乙醛酸酯或其水合物的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013129907A8 (en) | 2013-12-05 |
| EP2819985B1 (en) | 2018-02-28 |
| WO2013129907A1 (en) | 2013-09-06 |
| US20150080599A1 (en) | 2015-03-19 |
| MY174607A (en) | 2020-04-29 |
| CN104271546A (zh) | 2015-01-07 |
| US9505701B2 (en) | 2016-11-29 |
| EP2819985A4 (en) | 2015-05-27 |
| KR102061374B1 (ko) | 2019-12-31 |
| EP2819985A1 (en) | 2015-01-07 |
| JP6097771B2 (ja) | 2017-03-15 |
| KR20140144689A (ko) | 2014-12-19 |
| SG11201405265QA (en) | 2014-09-26 |
| JP2015511954A (ja) | 2015-04-23 |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |