CN1042327C - 苯二甲酸二甲酯氢化生成相应的环己烷二甲酸二甲酯的低压方法 - Google Patents

苯二甲酸二甲酯氢化生成相应的环己烷二甲酸二甲酯的低压方法 Download PDF

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Publication number
CN1042327C
CN1042327C CN94106440A CN94106440A CN1042327C CN 1042327 C CN1042327 C CN 1042327C CN 94106440 A CN94106440 A CN 94106440A CN 94106440 A CN94106440 A CN 94106440A CN 1042327 C CN1042327 C CN 1042327C
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China
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palladium
catalyzer
weight
dimethyl
content
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Expired - Lifetime
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CN94106440A
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English (en)
Chinese (zh)
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CN1099745A (zh
Inventor
B·L·古斯塔森
B·A·坦南特
郭永健
T·W·普赖斯
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Eastman Chemical Co
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Eastman Chemical Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN94106440A 1993-06-15 1994-06-10 苯二甲酸二甲酯氢化生成相应的环己烷二甲酸二甲酯的低压方法 Expired - Lifetime CN1042327C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US076,675 1993-06-15
US08/076,675 US5286898A (en) 1993-06-15 1993-06-15 Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxlates

Publications (2)

Publication Number Publication Date
CN1099745A CN1099745A (zh) 1995-03-08
CN1042327C true CN1042327C (zh) 1999-03-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN94106440A Expired - Lifetime CN1042327C (zh) 1993-06-15 1994-06-10 苯二甲酸二甲酯氢化生成相应的环己烷二甲酸二甲酯的低压方法

Country Status (11)

Country Link
US (1) US5286898A (enExample)
EP (1) EP0703894B1 (enExample)
JP (1) JP3499557B2 (enExample)
KR (1) KR100390121B1 (enExample)
CN (1) CN1042327C (enExample)
CA (1) CA2165207C (enExample)
DE (1) DE69412827T2 (enExample)
ES (1) ES2120054T3 (enExample)
SG (1) SG47888A1 (enExample)
TW (1) TW265332B (enExample)
WO (1) WO1994029260A1 (enExample)

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CN106866415A (zh) * 2015-12-12 2017-06-20 中国科学院大连化学物理研究所 一种脂环族羧酸酯的制造方法

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DE19927978A1 (de) * 1999-06-18 2000-12-21 Basf Ag Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester
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CN101927166B (zh) * 2010-07-23 2013-01-23 南京大学 一种担载镍催化剂及其制法和用途
CN102381976B (zh) * 2010-09-01 2013-09-04 中国石油天然气股份有限公司 一种制备1，4-环己烷二甲酸二甲酯的方法
CN102476052A (zh) * 2010-11-29 2012-05-30 中国石油化工股份有限公司 一种负载型钌催化剂及其制备方法
CN102796001A (zh) * 2011-05-25 2012-11-28 江苏恒祥化工有限责任公司 无溶剂制备1，4-环己烷二甲酸二甲酯
TWI421240B (zh) 2011-12-12 2014-01-01 Ind Tech Res Inst 苯多羧酸或其衍生物形成環己烷多元酸酯之氫化方法
CN102631925B (zh) * 2012-03-30 2015-03-25 中国科学院山西煤炭化学研究所 一种苯羧酸酯加氢催化剂及其制备方法和应用
ITMI20121641A1 (it) 2012-10-02 2014-04-03 Polynt S P A Procedimento per l'idrogenazione di esteri di acidi carbossilici aromatici a dare loro omologhi saturi, nuovi usi per detti omologhi, e nuove miscele polimeriche plastificate.
EP2716623A1 (de) 2012-10-05 2014-04-09 Basf Se Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil
US9090553B2 (en) 2012-10-05 2015-07-28 Basf Se Process for preparing cyclohexanepolycarboxylic acid derivatives having a low proportion of by-products
CN102921409A (zh) * 2012-10-26 2013-02-13 中国海洋石油总公司 一种加氢生产1,2环己烷二羧酸酯的催化剂的制法
CN102935365B (zh) * 2012-11-12 2014-12-03 中国石油化工股份有限公司 一种制备1，4-环己烷二甲酸二甲酯的催化剂及方法
CN103157468A (zh) * 2013-03-14 2013-06-19 北京化工大学 一种低含量负载型钌-钯双金属加氢催化剂及其制备方法
CN104649864A (zh) * 2013-11-19 2015-05-27 中国石油天然气股份有限公司 一种对苯二甲酸二烷基酯加氢生产1,4-环己烷二甲醇的方法
US9346737B2 (en) 2013-12-30 2016-05-24 Eastman Chemical Company Processes for making cyclohexane compounds
US9340482B2 (en) 2013-12-30 2016-05-17 Eastman Chemical Company Processes for making cyclohexane compounds
US9328050B1 (en) 2014-12-23 2016-05-03 Eastman Chemical Company Processes for making hydroxymethylbenzoic acid compounds
KR101905165B1 (ko) * 2015-04-01 2018-10-05 한화케미칼 주식회사 프탈레이트 화합물의 수소화 촉매의 재생 방법
TWI577658B (zh) * 2015-05-06 2017-04-11 中國石油化學工業開發股份有限公司 １，４－環己烷二甲酸二甲酯及１，４－環己烷二甲醇之製法
KR101780405B1 (ko) * 2015-09-24 2017-09-20 롯데케미칼 주식회사 1,4-사이클로헥산디카르복실산의 제조 방법
JP2019531873A (ja) 2016-08-18 2019-11-07 ザ ユニバーシティ オブ シカゴＴｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｃｈｉｃａｇｏ 高度に効率的な有機変換のための金属酸化物に支持された地球に豊富な金属の触媒
KR101883993B1 (ko) * 2016-09-29 2018-07-31 롯데케미칼 주식회사 1,3-사이클로헥산디카르복시산의 제조 방법
FR3059253B1 (fr) * 2016-11-29 2020-01-17 IFP Energies Nouvelles Catalyseur d'hydrogenation selective d'une coupe d'hydrocarbures c3.
FR3059252B1 (fr) * 2016-11-29 2018-11-16 IFP Energies Nouvelles Catalyseur d’hydrogenation selective de coupes c3 de vapocraquage et/ou de craquage catalytique
KR102506281B1 (ko) * 2017-11-29 2023-03-06 한화솔루션 주식회사 프탈레이트 화합물의 수소화 방법
TWI684585B (zh) * 2018-11-14 2020-02-11 中國石油化學工業開發股份有限公司 １,４-環己烷二甲酸二甲酯之製法
CN112916022A (zh) * 2021-01-21 2021-06-08 西南化工研究设计院有限公司 一种选择性加氢催化剂及其制备方法和应用
CN119056308A (zh) * 2024-02-29 2024-12-03 中国石油天然气集团有限公司 用于1,4环己烷二甲酸二甲酯加氢过程的物料稳态输送方法

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CN106866415A (zh) * 2015-12-12 2017-06-20 中国科学院大连化学物理研究所 一种脂环族羧酸酯的制造方法

Also Published As

Publication number Publication date
SG47888A1 (en) 1998-04-17
EP0703894A1 (en) 1996-04-03
DE69412827D1 (de) 1998-10-01
WO1994029260A1 (en) 1994-12-22
JPH08511775A (ja) 1996-12-10
ES2120054T3 (es) 1998-10-16
CN1099745A (zh) 1995-03-08
EP0703894B1 (en) 1998-08-26
JP3499557B2 (ja) 2004-02-23
DE69412827T2 (de) 1999-01-14
CA2165207A1 (en) 1994-12-22
KR960703099A (ko) 1996-06-19
KR100390121B1 (ko) 2003-11-13
TW265332B (enExample) 1995-12-11
CA2165207C (en) 1998-08-18
US5286898A (en) 1994-02-15

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