ES2120054T3 - Procedimiento de hidrogenacion a baja presion de bencenodicarboxilato de dimetilo en los ciclohexanodicarboxilatos de dimetilo correspondientes. - Google Patents

Procedimiento de hidrogenacion a baja presion de bencenodicarboxilato de dimetilo en los ciclohexanodicarboxilatos de dimetilo correspondientes.

Info

Publication number
ES2120054T3
ES2120054T3 ES94919348T ES94919348T ES2120054T3 ES 2120054 T3 ES2120054 T3 ES 2120054T3 ES 94919348 T ES94919348 T ES 94919348T ES 94919348 T ES94919348 T ES 94919348T ES 2120054 T3 ES2120054 T3 ES 2120054T3
Authority
ES
Spain
Prior art keywords
dimethyl
cyclohexanodicarboxylates
benzenodicarboxylate
low pressure
pressure hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94919348T
Other languages
English (en)
Spanish (es)
Inventor
Bruce Leroy Gustafson
Brent Alan Tennant
Yeong-Jen Kuo
Timothy Warren Price
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of ES2120054T3 publication Critical patent/ES2120054T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
ES94919348T 1993-06-15 1994-06-03 Procedimiento de hidrogenacion a baja presion de bencenodicarboxilato de dimetilo en los ciclohexanodicarboxilatos de dimetilo correspondientes. Expired - Lifetime ES2120054T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/076,675 US5286898A (en) 1993-06-15 1993-06-15 Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxlates

Publications (1)

Publication Number Publication Date
ES2120054T3 true ES2120054T3 (es) 1998-10-16

Family

ID=22133530

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94919348T Expired - Lifetime ES2120054T3 (es) 1993-06-15 1994-06-03 Procedimiento de hidrogenacion a baja presion de bencenodicarboxilato de dimetilo en los ciclohexanodicarboxilatos de dimetilo correspondientes.

Country Status (11)

Country Link
US (1) US5286898A (enExample)
EP (1) EP0703894B1 (enExample)
JP (1) JP3499557B2 (enExample)
KR (1) KR100390121B1 (enExample)
CN (1) CN1042327C (enExample)
CA (1) CA2165207C (enExample)
DE (1) DE69412827T2 (enExample)
ES (1) ES2120054T3 (enExample)
SG (1) SG47888A1 (enExample)
TW (1) TW265332B (enExample)
WO (1) WO1994029260A1 (enExample)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6187968B1 (en) 1996-06-28 2001-02-13 Sk Njc Co., Ltd. Process for the preparation of cyclohexanedimethanol
KR100688403B1 (ko) 1997-12-19 2007-03-09 바스프 악티엔게젤샤프트 매크로포어를 함유하는 촉매를 사용하는 벤젠폴리카르복실산 또는 그의 유도체의 수소화 방법
DE19927978A1 (de) * 1999-06-18 2000-12-21 Basf Ag Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester
BR0012743A (pt) * 1999-07-28 2002-04-02 S D Chemie Inc Catalisador de hidrogenação tolerante a enxofre, processo para fabricação e uso do mesmo
DE19939544C1 (de) 1999-08-20 2001-02-15 Haarmann & Reimer Gmbh Verfahren zur Herstellung von Methyl-cyclohexyl-propionat
DE10128242A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Hydrierung organischer Verbindungen
DE10146869A1 (de) 2001-09-24 2003-04-24 Oxeno Olefinchemie Gmbh Alicyclische Polycarbonsäureestergemische mit hohem trans-Anteil und Verfahren zu deren Herstellung
CN1558927A (zh) 2001-09-25 2004-12-29 ����ɭ���ڻ�ѧר����˾ 增塑聚氯乙烯
US6803341B2 (en) * 2002-01-18 2004-10-12 Chinese Petroleum Corporation Method of a high stability selectable hydrogenate catalyst producing and using for DMCHD manufacturing
GB0227087D0 (en) * 2002-11-20 2002-12-24 Exxonmobil Chem Patents Inc Hydrogenation of benzene polycarboxylic acids or derivatives thereof
GB0227086D0 (en) * 2002-11-20 2002-12-24 Exxonmobil Res & Eng Co Hydrogenation processes
DE102004063637A1 (de) 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von alicyclischen Carbonsäuren oder deren Derivaten
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
US7632962B2 (en) * 2006-04-26 2009-12-15 Eastman Chemical Company Hydrogenation process and catalysts
CN101417950B (zh) * 2008-10-27 2012-05-23 中国科学院大连化学物理研究所 一种制备1,2-环己烷二甲酸二元酯的方法
CN101927166B (zh) * 2010-07-23 2013-01-23 南京大学 一种担载镍催化剂及其制法和用途
CN102381976B (zh) * 2010-09-01 2013-09-04 中国石油天然气股份有限公司 一种制备1，4-环己烷二甲酸二甲酯的方法
CN102476052A (zh) * 2010-11-29 2012-05-30 中国石油化工股份有限公司 一种负载型钌催化剂及其制备方法
CN102796001A (zh) * 2011-05-25 2012-11-28 江苏恒祥化工有限责任公司 无溶剂制备1，4-环己烷二甲酸二甲酯
TWI421240B (zh) 2011-12-12 2014-01-01 Ind Tech Res Inst 苯多羧酸或其衍生物形成環己烷多元酸酯之氫化方法
CN102631925B (zh) * 2012-03-30 2015-03-25 中国科学院山西煤炭化学研究所 一种苯羧酸酯加氢催化剂及其制备方法和应用
ITMI20121641A1 (it) 2012-10-02 2014-04-03 Polynt S P A Procedimento per l'idrogenazione di esteri di acidi carbossilici aromatici a dare loro omologhi saturi, nuovi usi per detti omologhi, e nuove miscele polimeriche plastificate.
EP2716623A1 (de) 2012-10-05 2014-04-09 Basf Se Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil
US9090553B2 (en) 2012-10-05 2015-07-28 Basf Se Process for preparing cyclohexanepolycarboxylic acid derivatives having a low proportion of by-products
CN102921409A (zh) * 2012-10-26 2013-02-13 中国海洋石油总公司 一种加氢生产1,2环己烷二羧酸酯的催化剂的制法
CN102935365B (zh) * 2012-11-12 2014-12-03 中国石油化工股份有限公司 一种制备1，4-环己烷二甲酸二甲酯的催化剂及方法
CN103157468A (zh) * 2013-03-14 2013-06-19 北京化工大学 一种低含量负载型钌-钯双金属加氢催化剂及其制备方法
CN104649864A (zh) * 2013-11-19 2015-05-27 中国石油天然气股份有限公司 一种对苯二甲酸二烷基酯加氢生产1,4-环己烷二甲醇的方法
US9346737B2 (en) 2013-12-30 2016-05-24 Eastman Chemical Company Processes for making cyclohexane compounds
US9340482B2 (en) 2013-12-30 2016-05-17 Eastman Chemical Company Processes for making cyclohexane compounds
US9328050B1 (en) 2014-12-23 2016-05-03 Eastman Chemical Company Processes for making hydroxymethylbenzoic acid compounds
KR101905165B1 (ko) * 2015-04-01 2018-10-05 한화케미칼 주식회사 프탈레이트 화합물의 수소화 촉매의 재생 방법
TWI577658B (zh) * 2015-05-06 2017-04-11 中國石油化學工業開發股份有限公司 １，４－環己烷二甲酸二甲酯及１，４－環己烷二甲醇之製法
KR101780405B1 (ko) * 2015-09-24 2017-09-20 롯데케미칼 주식회사 1,4-사이클로헥산디카르복실산의 제조 방법
CN106866415A (zh) * 2015-12-12 2017-06-20 中国科学院大连化学物理研究所 一种脂环族羧酸酯的制造方法
US11673125B2 (en) 2016-08-18 2023-06-13 The University Of Chicago Metal oxide-supported earth-abundant metal catalysts for highly efficient organic transformations
KR101883993B1 (ko) * 2016-09-29 2018-07-31 롯데케미칼 주식회사 1,3-사이클로헥산디카르복시산의 제조 방법
FR3059252B1 (fr) * 2016-11-29 2018-11-16 IFP Energies Nouvelles Catalyseur d’hydrogenation selective de coupes c3 de vapocraquage et/ou de craquage catalytique
FR3059253B1 (fr) * 2016-11-29 2020-01-17 IFP Energies Nouvelles Catalyseur d'hydrogenation selective d'une coupe d'hydrocarbures c3.
KR102506281B1 (ko) * 2017-11-29 2023-03-06 한화솔루션 주식회사 프탈레이트 화합물의 수소화 방법
TWI684585B (zh) * 2018-11-14 2020-02-11 中國石油化學工業開發股份有限公司 １,４-環己烷二甲酸二甲酯之製法
CN112916022A (zh) * 2021-01-21 2021-06-08 西南化工研究设计院有限公司 一种选择性加氢催化剂及其制备方法和应用
CN119056308A (zh) * 2024-02-29 2024-12-03 中国石油天然气集团有限公司 用于1,4环己烷二甲酸二甲酯加氢过程的物料稳态输送方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2675390A (en) * 1950-05-19 1954-04-13 Edgar F Rosenblatt Hydrogenation of cyclic-compounds
GB817736A (en) * 1955-08-26 1959-08-06 Chimiotherapie Lab Franc Esters of trans-hexahydroterephthalic acid and of the mono-acid chloride of trans-hexahydroterephthalic acid
US2794030A (en) * 1955-10-18 1957-05-28 Union Carbide & Carbon Corp Aliphatic esters of 4, 5-epoxycyclohexane-1, 2-dicarboxylic acids
US3027398A (en) * 1960-02-01 1962-03-27 Du Pont Process for preparing dimethyl 1, 4-cyclohexanedicarboxylate
DE1154096B (de) * 1962-02-23 1963-09-12 Witten Gmbh Chem Werke Verfahren zur Herstellung von 1, 4-Cyclohexandicarbonsaeure-dialkylestern
NL6405867A (enExample) * 1963-05-29 1964-11-30
US3334149A (en) * 1964-07-21 1967-08-01 Eastman Kodak Co Plural stage hydrogenation of dialkyl terephthalate using palladium and then copper chromite
US3444237A (en) * 1966-03-23 1969-05-13 Grace W R & Co Esters of cyclohexane-1,2,4-tricarboxylic acid
US4024173A (en) * 1967-09-02 1977-05-17 Dynamit Nobel Aktiengesellschaft Process for the manufacture of cyclohexene dicarboxylic acid esters
US3824193A (en) 1972-03-30 1974-07-16 Eastman Kodak Co Alkaline reactivation of alumina supported palladium catalysts
DE2823165A1 (de) * 1978-05-26 1979-11-29 Bayer Ag Verfahren zur herstellung von cycloaliphatischen carbonsaeureestern
JP2717265B2 (ja) * 1988-06-03 1998-02-18 東都化成株式会社 熱硬化性樹脂組成物

Also Published As

Publication number Publication date
DE69412827T2 (de) 1999-01-14
EP0703894B1 (en) 1998-08-26
CN1099745A (zh) 1995-03-08
CA2165207A1 (en) 1994-12-22
EP0703894A1 (en) 1996-04-03
WO1994029260A1 (en) 1994-12-22
CN1042327C (zh) 1999-03-03
JP3499557B2 (ja) 2004-02-23
US5286898A (en) 1994-02-15
TW265332B (enExample) 1995-12-11
KR960703099A (ko) 1996-06-19
JPH08511775A (ja) 1996-12-10
CA2165207C (en) 1998-08-18
KR100390121B1 (ko) 2003-11-13
DE69412827D1 (de) 1998-10-01
SG47888A1 (en) 1998-04-17

Similar Documents

Publication Publication Date Title
ES2120054T3 (es) Procedimiento de hidrogenacion a baja presion de bencenodicarboxilato de dimetilo en los ciclohexanodicarboxilatos de dimetilo correspondientes.
ES2118418T3 (es) Preparacion de ciclohexanodicarboxilatos de dimetilo.
ES2121793T3 (es) Composiciones de uso local para la administracion transdermica de derivados profarmacos de morfina.
ES2182403T3 (es) Complejos de bisciclopentadienil-dieno, su preparacion y composiciones cataliticas que los contienen.
ES2064871T3 (es) Procedimiento catalitico de carbonilacion.
ES2118246T3 (es) Banda polimerica con secciones deformadas que proporcionan a la banda una elasticidad sustancialmente incrementada.
ES2060983T3 (es) Utilizacion en cosmetica de una dispersion acuosa a base de organopolisilosanos y un copolimero de acrilato de amonio/acrilamida reticulados.
ES2188147T3 (es) Anti-irritantes en composiciones cosmeticas.
ES2086956T3 (es) Composicion detergente.
ES8704757A1 (es) Procedimiento de hidrogenacion de aceites, grasas, acidos grasos y derivados de los mismos
ES2093531T3 (es) Procedimiento para el teñido de material textil, que contiene celulosa, con indigo hidrogenado.
ES234703U (es) Soporte movil para portalamparas y similares.
MX9304837A (es) Peptidos capaces de inhibir la actividad de proteasa vih, su preparacion y su uso terapeutico.
MX9301129A (es) Nuevas ciclosporinas y composiciones farmaceuticas que las contienen.
ES2121601T3 (es) Productos a base de silicona para el cuidado de la piel.
ES2031016T3 (es) Atraccion de parque de atracciones.
ES2068975T3 (es) Metodo de separacion y agente de separacion.
ES2162903T3 (es) Utilizacion de una suspension coloidal a base de cargas minerales como composicion cosmetica que permite formar una pelicula sobre los cabellos, la piel y/o las uñas.
ES2068202T3 (es) Composicion liquida suavizante para prendas de ropa.
ES2086617T3 (es) Composicion cosmetica dermatologica a base de mezclas polivitaminicas.
ES2049695T3 (es) Procedimiento para la obtencion de cera de manzana, cera de manzana obtenible mediante este procedimiento y productos cosmeticos con contenido en cera de manzana.
ES2172748T3 (es) Uso de un inhibidor de aldosa reductasa para la reduccion de daño en tejido no cardiaco.
ES2168285T3 (es) Agentes endoparasiticidas que contienen praziquantel y epsiprantel.
ES465529A1 (es) Procedimiento para la obtencion de nuevas feniletilaminas.
ES2058096T3 (es) Producto cosmetico que contiene derivados n-hidroxi-propil-isopropileter de la quitosana.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 703894

Country of ref document: ES